Fiber-reinforced composites are gradually replacing the traditional materials in many engineering... more Fiber-reinforced composites are gradually replacing the traditional materials in many engineering applications. However, for many applications these materials are still unsuitable, due to their lack of toughness. In this context, hybridization is a promising strategy in which two or more types of fiber are combined to obtain a better balance of mechanical properties compared to non-hybrid composites. Therefore, the main goal of this work is to study the hybridization effect on the static performance and interlaminar shear strength. For this purpose, carbon, glass, and Kevlar fibers were used and combined in different proportions. It was possible to conclude that there is an ideal value of fiber content to maximize both properties and, depending on the type of fiber, they should be placed specifically on the compression or tensile side. For example, for composites involving carbon and glass fibers the latter must be placed on the compression side, and for a value of 17% by weight the...
Fused filament fabrication (FFF) is the most popular additive manufacturing method, which allows ... more Fused filament fabrication (FFF) is the most popular additive manufacturing method, which allows the production of highly complex three-dimensional parts with minimal material waste. On the other hand, polyethylene terephthalate glycol (PETG) has been used to replace traditional polymers for 3D printing due to its chemical resistance and mechanical performance, among other benefits. However, when fibres are added, these PETG-based composites can be suitable for many different applications. Nevertheless, to guarantee their good performance in-service in these applications, and even extend to new ones, it is necessary for their mechanical properties to be maximized. Therefore, this study intends to optimize the printing parameters (nozzle temperature, printing speed, layer height and filling) in order to maximize the mechanical properties of printed PETG, PETG+CF (carbon fibre-reinforced PETG composites) and PETG+KF (aramid fibre-reinforced PETG composites). The Taguchi method was use...
It is known that 3D-printed PETG composites reinforced with carbon or Kevlar fibres are materials... more It is known that 3D-printed PETG composites reinforced with carbon or Kevlar fibres are materials that can be suitable for specific applications in the aeronautical and/or automotive sector. However, for this purpose, it is necessary to understand their mechanical behaviour, which is not yet fully understood in terms of compression. Therefore, this study intends to increase the knowledge in this domain, especially in terms of static behaviour, as well as with regard to creep and stress relaxation due to the inherent viscoelasticity of the matrix. In this context, static, stress relaxation and creep tests were carried out, in compressive mode, using neat PETG and PETG composites reinforced with carbon and Kevlar fibres. From the static tests, it was found that the yield compressive strength decreased in both composites compared to the neat polymer. Values around 9.9% and 68.7% lower were found, respectively, when carbon and Kevlar fibres were added to the PETG. Similar behaviour was ...
This work intends to study the effect of the curing parameters on the mechanical properties of a ... more This work intends to study the effect of the curing parameters on the mechanical properties of a polyester resin without a complete curing reaction process. For this purpose, cures at room temperature, 40 °C, and 60 °C, and post-cures at 40 °C and 60 °C, with different exposure times, were considered. Three-point bending tests were performed to assess the bending properties and both stress relaxation and creep behavior. The degree of crosslinking was estimated by evaluating the C = C ester bond, by Fourier infrared spectroscopy and complemented with the thermal characterization made by differential scanning calorimetry. The results showed that higher curing temperatures are preferable to methods involving curing and post-curing, which can be confirmed by the higher degree of conversion of unsaturated ester bonds at 60 °C. Compared to the resin cured at room temperature, the bending strength increased by 36.5% at 40 °C and 88.6% at 60 °C. A similar effect was observed for bending sti...
Due to the enormous benefits inherent to composite materials, they have been widely used in the m... more Due to the enormous benefits inherent to composite materials, they have been widely used in the most diverse fields of engineering. Therefore, it is not surprising that in many of these applications they can be exposed to hostile environments, which can affect the mechanical performance of such materials. Therefore, the main goal of this work was to study the effect of immersion into different hostile solutions on the impact strength and, subsequently, to evaluate the residual fatigue life. For this purpose, the specimens were initially immersed into solutions of hydrochloric acid (HCl), sodium hydroxide (NaOH), sulphuric acid (H2SO4), diesel, distilled water, and seawater. Subsequently, the specimens were subjected to impact loads with an energy of 12 J and, finally, subjected to fatigue loads to assess the residual fatigue life. Seawater and NaOH solution provided the lowest impact strength. This was confirmed by the lower energy restored and impact bending stiffness (IBS), a para...
Composites are used in a wide range of engineering applications, as a result, exposure to hostile... more Composites are used in a wide range of engineering applications, as a result, exposure to hostile environments is rather common and its mechanical properties degradation is unavoidable. It is necessary to have a complete understanding of the impact of hostile environments on mechanical performance, namely critical solicitations as low velocity impacts. Therefore, this work intends to analyse the low velocity impact response of a carbon fibre/epoxy composite, and a similar architecture with an epoxy matrix filled with cork, after immersion into different solutions: diesel, H2SO4, HCl, NaOH, distilled water, seawater, and seawater at 60 °C. These solutions significantly affected the impact properties. In this context, the maximum load, maximum displacement, and restored energy behaviour were studied to understand the influence of exposure time. It was possible to conclude that such impact parameters were significantly affected by the solutions, where the exposure time proved to be det...
Additive manufacturing (AM) is the process through which components/structures are produced layer... more Additive manufacturing (AM) is the process through which components/structures are produced layer-by-layer. In this context, 4D printing combines 3D printing with time so that this combination results in additively manufactured components that respond to external stimuli and, consequently, change their shape/volume or modify their mechanical properties. Therefore, 4D printing uses shape-memory materials that react to external stimuli such as pH, humidity, and temperature. Among the possible materials with shape memory effect (SME), the most suitable for additive manufacturing are shape memory polymers (SMPs). However, due to their weaknesses, shape memory polymer compounds (SMPCs) prove to be an effective alternative. On the other hand, out of all the additive manufacturing techniques, the most widely used is fused filament fabrication (FFF). In this context, the present paper aims to critically review all studies related to the mechanical properties of 4D-FFF materials. The paper p...
Epoxy with carbon nanofibers (CNFs) are effective nano enhanced materials that can be prepared by... more Epoxy with carbon nanofibers (CNFs) are effective nano enhanced materials that can be prepared by easy and low-cost method. The present paper compares the improvements, in terms of flexural and viscoelastic properties, of two epoxy resins reinforced with different weight percentages (wt.%) of CNFs. These epoxy resins have different viscosities, and weight contents between 0% and 1% of CNFs were used to achieve the maximum mechanical properties. Subsequently, for the best configurations obtained, the sensitivity to the strain rate and the viscoelastic behaviour (stress relaxation and creep) were analysed based on international standards. It was possible to conclude that, for both resins, carbon CNFs promote significant improvements in all the studied mechanical properties, even for different contents by weight.
Olives’ consumption produces copious agricultural byproducts that have accompanied humanity for m... more Olives’ consumption produces copious agricultural byproducts that have accompanied humanity for millennia, but the increasing worldwide production complicates its management. Most wastes are generated during olive oil production in form of olive stones and other lignocellulosic derivatives. Industrial processes of chemical or physical nature to recover economically compounds from biomass residues are costly, difficult, and non-environmentally friendly. Cellulose, hemicellulose, and lignin biopolymers are the principal components of olive stones, which present interesting qualities as lignocellulosic fillers in polymeric composites. This review will summarize examples of composites based on thermoplastic polymers, such as polystyrene (PS), polylactide (PLA), polyvinyl chloride (PVC), polypropylene (PP), and polycaprolactone (PCL); thermosetting resins (phenol-formaldehyde, unsaturated polyesters, and epoxy) and acrylonitrile butadiene rubber/devulcanized waste rubber (NBR/DWR) blends...
Fiber-reinforced composites are gradually replacing the traditional materials in many engineering... more Fiber-reinforced composites are gradually replacing the traditional materials in many engineering applications. However, for many applications these materials are still unsuitable, due to their lack of toughness. In this context, hybridization is a promising strategy in which two or more types of fiber are combined to obtain a better balance of mechanical properties compared to non-hybrid composites. Therefore, the main goal of this work is to study the hybridization effect on the static performance and interlaminar shear strength. For this purpose, carbon, glass, and Kevlar fibers were used and combined in different proportions. It was possible to conclude that there is an ideal value of fiber content to maximize both properties and, depending on the type of fiber, they should be placed specifically on the compression or tensile side. For example, for composites involving carbon and glass fibers the latter must be placed on the compression side, and for a value of 17% by weight the...
Fused filament fabrication (FFF) is the most popular additive manufacturing method, which allows ... more Fused filament fabrication (FFF) is the most popular additive manufacturing method, which allows the production of highly complex three-dimensional parts with minimal material waste. On the other hand, polyethylene terephthalate glycol (PETG) has been used to replace traditional polymers for 3D printing due to its chemical resistance and mechanical performance, among other benefits. However, when fibres are added, these PETG-based composites can be suitable for many different applications. Nevertheless, to guarantee their good performance in-service in these applications, and even extend to new ones, it is necessary for their mechanical properties to be maximized. Therefore, this study intends to optimize the printing parameters (nozzle temperature, printing speed, layer height and filling) in order to maximize the mechanical properties of printed PETG, PETG+CF (carbon fibre-reinforced PETG composites) and PETG+KF (aramid fibre-reinforced PETG composites). The Taguchi method was use...
It is known that 3D-printed PETG composites reinforced with carbon or Kevlar fibres are materials... more It is known that 3D-printed PETG composites reinforced with carbon or Kevlar fibres are materials that can be suitable for specific applications in the aeronautical and/or automotive sector. However, for this purpose, it is necessary to understand their mechanical behaviour, which is not yet fully understood in terms of compression. Therefore, this study intends to increase the knowledge in this domain, especially in terms of static behaviour, as well as with regard to creep and stress relaxation due to the inherent viscoelasticity of the matrix. In this context, static, stress relaxation and creep tests were carried out, in compressive mode, using neat PETG and PETG composites reinforced with carbon and Kevlar fibres. From the static tests, it was found that the yield compressive strength decreased in both composites compared to the neat polymer. Values around 9.9% and 68.7% lower were found, respectively, when carbon and Kevlar fibres were added to the PETG. Similar behaviour was ...
This work intends to study the effect of the curing parameters on the mechanical properties of a ... more This work intends to study the effect of the curing parameters on the mechanical properties of a polyester resin without a complete curing reaction process. For this purpose, cures at room temperature, 40 °C, and 60 °C, and post-cures at 40 °C and 60 °C, with different exposure times, were considered. Three-point bending tests were performed to assess the bending properties and both stress relaxation and creep behavior. The degree of crosslinking was estimated by evaluating the C = C ester bond, by Fourier infrared spectroscopy and complemented with the thermal characterization made by differential scanning calorimetry. The results showed that higher curing temperatures are preferable to methods involving curing and post-curing, which can be confirmed by the higher degree of conversion of unsaturated ester bonds at 60 °C. Compared to the resin cured at room temperature, the bending strength increased by 36.5% at 40 °C and 88.6% at 60 °C. A similar effect was observed for bending sti...
Due to the enormous benefits inherent to composite materials, they have been widely used in the m... more Due to the enormous benefits inherent to composite materials, they have been widely used in the most diverse fields of engineering. Therefore, it is not surprising that in many of these applications they can be exposed to hostile environments, which can affect the mechanical performance of such materials. Therefore, the main goal of this work was to study the effect of immersion into different hostile solutions on the impact strength and, subsequently, to evaluate the residual fatigue life. For this purpose, the specimens were initially immersed into solutions of hydrochloric acid (HCl), sodium hydroxide (NaOH), sulphuric acid (H2SO4), diesel, distilled water, and seawater. Subsequently, the specimens were subjected to impact loads with an energy of 12 J and, finally, subjected to fatigue loads to assess the residual fatigue life. Seawater and NaOH solution provided the lowest impact strength. This was confirmed by the lower energy restored and impact bending stiffness (IBS), a para...
Composites are used in a wide range of engineering applications, as a result, exposure to hostile... more Composites are used in a wide range of engineering applications, as a result, exposure to hostile environments is rather common and its mechanical properties degradation is unavoidable. It is necessary to have a complete understanding of the impact of hostile environments on mechanical performance, namely critical solicitations as low velocity impacts. Therefore, this work intends to analyse the low velocity impact response of a carbon fibre/epoxy composite, and a similar architecture with an epoxy matrix filled with cork, after immersion into different solutions: diesel, H2SO4, HCl, NaOH, distilled water, seawater, and seawater at 60 °C. These solutions significantly affected the impact properties. In this context, the maximum load, maximum displacement, and restored energy behaviour were studied to understand the influence of exposure time. It was possible to conclude that such impact parameters were significantly affected by the solutions, where the exposure time proved to be det...
Additive manufacturing (AM) is the process through which components/structures are produced layer... more Additive manufacturing (AM) is the process through which components/structures are produced layer-by-layer. In this context, 4D printing combines 3D printing with time so that this combination results in additively manufactured components that respond to external stimuli and, consequently, change their shape/volume or modify their mechanical properties. Therefore, 4D printing uses shape-memory materials that react to external stimuli such as pH, humidity, and temperature. Among the possible materials with shape memory effect (SME), the most suitable for additive manufacturing are shape memory polymers (SMPs). However, due to their weaknesses, shape memory polymer compounds (SMPCs) prove to be an effective alternative. On the other hand, out of all the additive manufacturing techniques, the most widely used is fused filament fabrication (FFF). In this context, the present paper aims to critically review all studies related to the mechanical properties of 4D-FFF materials. The paper p...
Epoxy with carbon nanofibers (CNFs) are effective nano enhanced materials that can be prepared by... more Epoxy with carbon nanofibers (CNFs) are effective nano enhanced materials that can be prepared by easy and low-cost method. The present paper compares the improvements, in terms of flexural and viscoelastic properties, of two epoxy resins reinforced with different weight percentages (wt.%) of CNFs. These epoxy resins have different viscosities, and weight contents between 0% and 1% of CNFs were used to achieve the maximum mechanical properties. Subsequently, for the best configurations obtained, the sensitivity to the strain rate and the viscoelastic behaviour (stress relaxation and creep) were analysed based on international standards. It was possible to conclude that, for both resins, carbon CNFs promote significant improvements in all the studied mechanical properties, even for different contents by weight.
Olives’ consumption produces copious agricultural byproducts that have accompanied humanity for m... more Olives’ consumption produces copious agricultural byproducts that have accompanied humanity for millennia, but the increasing worldwide production complicates its management. Most wastes are generated during olive oil production in form of olive stones and other lignocellulosic derivatives. Industrial processes of chemical or physical nature to recover economically compounds from biomass residues are costly, difficult, and non-environmentally friendly. Cellulose, hemicellulose, and lignin biopolymers are the principal components of olive stones, which present interesting qualities as lignocellulosic fillers in polymeric composites. This review will summarize examples of composites based on thermoplastic polymers, such as polystyrene (PS), polylactide (PLA), polyvinyl chloride (PVC), polypropylene (PP), and polycaprolactone (PCL); thermosetting resins (phenol-formaldehyde, unsaturated polyesters, and epoxy) and acrylonitrile butadiene rubber/devulcanized waste rubber (NBR/DWR) blends...
Uploads
Papers