Room-Temperature Spin Crossover Observed for [(TPyA)FeII(DBQ2-)FeII(TPyA)]2+ [TPyA = Tris(2-pyridylmethyl)amine; DBQ2- = 2,5-Di-tert-butyl-3,6-dihydroxy-1 …
KS Min, A DiPasquale, AL Rheingold… - Inorganic …, 2007 - ACS Publications
Inorganic chemistry, 2007•ACS Publications
Dinuclear [(TPyA) FeII (DBQ2-) FeII (TPyA)](BF4) 2 possesses extensive π− π interactions
between the FeII dimers that give rise to a two-dimensional supramolecular sheet structure.
The magnetic susceptibility shows a room-temperature spin-crossover behavior; however,
thermal hysteresis is not observed.
between the FeII dimers that give rise to a two-dimensional supramolecular sheet structure.
The magnetic susceptibility shows a room-temperature spin-crossover behavior; however,
thermal hysteresis is not observed.
Dinuclear [(TPyA)FeII(DBQ2-)FeII(TPyA)](BF4)2 possesses extensive π−π interactions between the FeII dimers that give rise to a two-dimensional supramolecular sheet structure. The magnetic susceptibility shows a room-temperature spin-crossover behavior; however, thermal hysteresis is not observed.
ACS Publications