Slow photoelectron velocity-map imaging of cryogenically cooled anions
ML Weichman, DM Neumark - Annual review of physical …, 2018 - annualreviews.org
Slow photoelectron velocity-map imaging spectroscopy of cryogenically cooled anions (cryo-
SEVI) is a powerful technique for elucidating the vibrational and electronic structure of …
SEVI) is a powerful technique for elucidating the vibrational and electronic structure of …
Unveiling the unconventional roles of methyl number on the ring-opening barrier in photocatalytic decomposition of benzene, toluene and o-xylene
The ring-opening reaction is the rate-determining step for photocatalytic decomposition of
aromatic VOCs with different methyl number. However, as a key challenge, the intrinsic …
aromatic VOCs with different methyl number. However, as a key challenge, the intrinsic …
Photocatalytic destruction of volatile aromatic compounds by platinized titanium dioxide in relation to the relative effect of the number of methyl groups on the benzene …
The photocatalytic destruction (PCD) of volatile organic compounds (VOC) into
environmentally benign compounds is one of the most ideal routes for the management of …
environmentally benign compounds is one of the most ideal routes for the management of …
Photochemistry of the pyruvate anion produces CO2, CO, CH3–, CH3, and a low energy electron
The photochemistry of pyruvic acid has attracted much scientific interest because it is
believed to play critical roles in atmospheric chemistry. However, under most …
believed to play critical roles in atmospheric chemistry. However, under most …
Annihilating actinic photochemistry of the pyruvate anion by one and two water molecules
Photochemical behaviors of pyruvic acid in multiple phases have been extensively studied,
while those of its conjugate base, the pyruvate anion (CH3COCOO–, PA–) are less …
while those of its conjugate base, the pyruvate anion (CH3COCOO–, PA–) are less …
Encoding of vinylidene isomerization in its anion photoelectron spectrum
Vinylidene-acetylene isomerization is the prototypical example of a 1, 2-hydrogen shift, one
of the most important classes of isomerization reactions in organic chemistry. This reaction …
of the most important classes of isomerization reactions in organic chemistry. This reaction …
The Impact of Larger Basis Sets and Explicitly Correlated Coupled Cluster Theory on the Feller–Peterson–Dixon Composite Method
The degree of completeness in the one-particle expansion, which in most standard orbital–
based electronic structure methods involves atom-centered Gaussian basis functions, is …
based electronic structure methods involves atom-centered Gaussian basis functions, is …
Methyl cation affinities of canonical organic functional groups
D Kadish, AD Mood, M Tavakoli… - The Journal of …, 2021 - ACS Publications
Methyl cation affinities are calculated for the canonical nucleophilic functional groups in
organic chemistry. These methyl cation affinities, calculated with a solvation model (MCA*) …
organic chemistry. These methyl cation affinities, calculated with a solvation model (MCA*) …
Methide Affinity Scale: Key Thermodynamic Data Underpinning Catalysis, Organic Synthesis, and Organometallic and Polymer Chemistry
WAO Altalhi, B Chan, RAJ O'Hair - The Journal of Physical …, 2024 - ACS Publications
Methide transfer reactions play important roles in many areas of chemistry, including the
Grignard reaction, in the transmetalation steps of metal-catalyzed cross-coupling reactions …
Grignard reaction, in the transmetalation steps of metal-catalyzed cross-coupling reactions …
Photoelectron Spectroscopy Confirms the Gas-Phase Stability of the C3O2– Anion
S Feng, Z Li, W Liu, Q Zhang, Y Chen… - The Journal of Physical …, 2023 - ACS Publications
The carbon suboxide anion with an asymmetric zigzag structure, C3O2–, which was recently
characterized in a solid neon matrix, has not been observed in the gas phase. Here, we …
characterized in a solid neon matrix, has not been observed in the gas phase. Here, we …