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KR950032434A - 라벨용 고 용융 접착 조성물 - Google Patents

라벨용 고 용융 접착 조성물 Download PDF

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Publication number
KR950032434A
KR950032434A KR1019950008583A KR19950008583A KR950032434A KR 950032434 A KR950032434 A KR 950032434A KR 1019950008583 A KR1019950008583 A KR 1019950008583A KR 19950008583 A KR19950008583 A KR 19950008583A KR 950032434 A KR950032434 A KR 950032434A
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South Korea
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block copolymer
composition
weight
arene
monoalkenyl
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KR1019950008583A
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English (en)
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KR100330058B1 (ko
Inventor
지오르다노 세르지오
구르나리 안토니오
파로디 카를라
비올라 지안토마소
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마르코 게나리
에니켐 엘라스토메리 에스. 알. 엘.
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Publication of KR950032434A publication Critical patent/KR950032434A/ko
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F297/00—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
    • C08F297/02—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type
    • C08F297/04—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type polymerising vinyl aromatic monomers and conjugated dienes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L53/00—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
    • C08L53/02—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers of vinyl-aromatic monomers and conjugated dienes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F297/00—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
    • C08F297/02—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type
    • C08F297/04—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type polymerising vinyl aromatic monomers and conjugated dienes
    • C08F297/044—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type polymerising vinyl aromatic monomers and conjugated dienes using a coupling agent
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J153/00—Adhesives based on block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Adhesives based on derivatives of such polymers
    • C09J153/02—Vinyl aromatic monomers and conjugated dienes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2666/00—Composition of polymers characterized by a further compound in the blend, being organic macromolecular compounds, natural resins, waxes or and bituminous materials, non-macromolecular organic substances, inorganic substances or characterized by their function in the composition
    • C08L2666/02—Organic macromolecular compounds, natural resins, waxes or and bituminous materials
    • C08L2666/24—Graft or block copolymers according to groups C08L51/00, C08L53/00 or C08L55/02; Derivatives thereof

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Inorganic Chemistry (AREA)
  • Adhesives Or Adhesive Processes (AREA)
  • Graft Or Block Polymers (AREA)
  • Adhesive Tapes (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

Abstract

블럭 공중합체 조성물은 모노알케닐 -아렌과 4 내지 5탄소원자의 공역디엔의 공중합 반응에서 유도되며;-30 내지 55 특히 34 내지 50중량%의 비-결합 선형구조와; -25 내지 40중량% 특히 30 내지 35중량% 결합 선형구조와; -20 내지 40 특히 24 내지 35중량% 측쇄구조로 된다.
이 조성물 제조방법과 접착 테이프 및 라벨 제형의 용도는 잘 알려져 있다.

Description

라벨용 고 용융 접착 조성물
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (19)

  1. 4 내지 5 탄소원자를 가진 공역디엔과 모노알케닐-아렌의 공중합 반응으로 얻고; (a)30내지 55중량%의 선형구조, 비결합 블럭 공중합체. (b)25내지 40중량%의 선형구조, 결합 블럭 공중합체; (c)20내지 40중량%의 측쇄구조 블럭 공중합체로 구성되며 3성분의 전체비율이 100%인 것을 특징으로 하는 블럭 공중합체 조성물.
  2. 제1항에 있어서; (a)34내지 55중량%의 선형구조, 비결합 블럭 공중합체. (b)30내지 35중량%의 선형구조, 결합 블럭 공중합체; (c)20내지 35중량%의 측쇄구조 블럭 공중합체로 구성된 것을 특징으로 하는 조성물.
  3. 제1항에 있어서, 4내지 5탄소원자를 갖는 공역디엔을 이소프렌과 부타디엔중에서 선택하는 것을 특징으로 하는 조성물.
  4. 제1항에 있어서, 모노알케닐-아렌이 스티렌인 것을 특징으로 하는 조성물.
  5. 제1항에 있어서, 조성물의 평균 분자량은 100,000 내지 200,000인 것을 특징으로 하는 조성물.
  6. 제1항에 있어서, 폴리(모노알케닐 아렌) 전체함량은 8내지 40중량%인 것을 특징으로 하는 조성물.
  7. 제6항에 있어서, 폴리(모노알케닐 아렌) 전체함량은 10 내지 25중량%인 것을 특징으로 하는 조성물.
  8. (a)모노알케닐-아렌을 일반식 R-Li의 리튬 유도체와 반응하고 R이 2내지 20탄소원자의 지방족, 고리지방족 라디칼중 선택된 히드로카르바일 라디칼이며; (b)(a)단계 결과 혼합물을 공역디엔과 반응시키며, (c)(b)단계 결과 혼합물을 리튬 기초의 화학량론적 양의 결합제와 반응시키고 , (c)단계 결합제는 알빈식 R′-Br의 모노브로모-유도체 중에서 선택하고 R′는 알킬, 시클로알킬 및 아릴라디칼중 선택한 단일 작용기 C1-C10히드로카바일 라디칼인 것을 특징을 하는 단계로 구성된 블럭 공중합체 제조방법.
  9. 제8항에 있어서, R′는 C1-C3알칼 라디칼중에서 선택하는 것을 특징으로 하는 제조방법.
  10. 제9항에 있어서, R′는 에틸인 것을 특징으로 하는 제조방법.
  11. 제8항에 있어서, (c)단계의 온도는 70내지 100℃인 것을 특징으로 하는 제조방법.
  12. 기본 고분자 하나이상의 접착제수지, 또한 하나이상의 항산화제와 유동화제수지 또느 유동화제 오일로 구송되고 기본고분자는 모노알케닐-아렌과 4내지 5탄소원자를 갖는 공역디엔의 공중합 반응으로 유도한 블럭 공중합체 조성물이고 한편 이 조성물은; (a)30내지 55중량%의 선형구조, 비결합 블럭 공중합체; (b)25내지 40중량%의 선형구조, 결합 블럭 공중합체; (c)20내지 35중량%의 측쇄구조 블럭 공중합체로 구성되며 3성분의 총 백분율이 100%인 것을 특징으로 하는 접착제 조성물.
  13. 제12항에 있어서, 기본 고분자는 모오알케닐-아렌과 4 내지 5탄소원자의 공역디엔의 공중합 반응에서 유도된 블럭 공중합체 조성물이며 이 조성물은; (a)34내지 50중량%의 선형구조, 비결합 블럭 공중합체; (b)30내지 435중량%의 선형구조, 결합 블럭 공중합체; (c)20내지 35중량%의 측쇄구조 블럭 공중합체로 구성되며 3성분의 총 백분율이 100%인 것을 특징으로 하는 접착제 조성물.
  14. 제12항에 있어서, 모노말케닐-아렌은 스티렌인 것을 특징으로 하는 접착제 조성물.
  15. 제12항에 있어서, 고분자 조성물 평균 분자량은 100,000 내지 400,000 범위인 것을 특징으로 하는 접착제조성물.
  16. 제12항에 있어서, 전체 폴리(모노알케닐 아렌) 함량은 8내지 40중량%인 것을 특징으로 하는 접착제 조성물.
  17. 제16항에 있어서, 전체 폴리(모노알케닐 아렌) 함량은 10내지 25중량%인 것을 특징으로 하는 접착제 조성물.
  18. 제12항에 있어서 100 비율의 기본 고분자 조성물당 50내지 200비율의 접착제 수지(phr), 10내지 100phr의 유동화제 수지, 또한 10내지 100phr의 유동화제 오일을 함유하는 것을 특징으로 하는 접착제 조성물.
  19. 제18항에 있어서, 접착제 수지 량은 50내지 150 phr 범위이고 유동화제 수지량은 20 내지 80 phr 범위이고 유동하제 오일량은 20내지 60 phr인 것을 특징으로 하는 접착제 조성물.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019950008583A 1994-05-20 1995-04-13 라벨용고용융접착조성물 KR100330058B1 (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
ITMI941022A IT1269803B (it) 1994-05-20 1994-05-20 Composizione adesiva hot melt per etichette
ITMI94A001022 1994-05-20

Publications (2)

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KR950032434A true KR950032434A (ko) 1995-12-20
KR100330058B1 KR100330058B1 (ko) 2002-09-17

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US (1) US5627234A (ko)
EP (1) EP0683187B1 (ko)
JP (1) JP3534895B2 (ko)
KR (1) KR100330058B1 (ko)
CN (1) CN1062875C (ko)
AT (1) ATE166898T1 (ko)
DE (1) DE69502771T2 (ko)
ES (1) ES2118467T3 (ko)
IT (1) IT1269803B (ko)
RU (1) RU2159783C2 (ko)
SI (1) SI0683187T1 (ko)

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Publication number Priority date Publication date Assignee Title
US5750607A (en) * 1996-03-08 1998-05-12 Shell Oil Company Adhesive compositions comprising block copolymers of a monovinylaromatic compound and butadiene
US5891957A (en) * 1996-10-24 1999-04-06 Shell Oil Company Adhesive composition for skin adhesion and bandage applications
JP4130983B2 (ja) * 1996-10-30 2008-08-13 日本ゼオン株式会社 芳香族ビニル−イソプレンブロック共重合体混合物、その製法、およびそれを含む粘接着剤組成物
US5912295A (en) * 1997-10-24 1999-06-15 H.B. Fuller Licensing & Financing, Inc. Low viscosity hot melt pressure sensitive adhesive which exhibits minimal staining
JP2003342441A (ja) * 1998-05-13 2003-12-03 Nippon Zeon Co Ltd ブロック共重合体組成物、その製造方法及び粘着剤組成物
WO2000012645A1 (en) * 1998-08-27 2000-03-09 Shell Internationale Research Maatschappij B.V. High peel strength high holding power hot melt disposables adhesive composition
IT1302040B1 (it) * 1998-09-04 2000-07-20 Enichem Spa Copolimeri a blocchi idrogenati aventi struttura parzialmenteramificata.
ES2218864T3 (es) * 1998-10-28 2004-11-16 Minnesota Mining And Manufacturing Company Composicion adhesiva que contiene una composicion de copolimero de bloques y una resina de poli(oxido de fenileno) y sus productos.
IT1304497B1 (it) * 1998-12-22 2001-03-19 Enichem Spa Composizione polimerica ad elevata trasparenza.
US6605680B1 (en) 2000-04-07 2003-08-12 Eastman Chemical Resins, Inc. Low color, aromatic modified C5 hydrocarbon resins
DE10129608A1 (de) * 2001-06-20 2003-05-28 Tesa Ag Stripfähige Systeme auf Basis von Acrylatblockcopolymeren
KR100466200B1 (ko) * 2002-09-02 2005-01-13 금호석유화학 주식회사 다가성 커플링제로 처리된 말단변성 스티렌-디엔블록공중합체
BRPI0810004B1 (pt) * 2007-04-20 2018-07-17 Firestone Polymers Llc composições de asfalto modificado por polímero
CN102639631A (zh) * 2009-12-02 2012-08-15 巴斯夫欧洲公司 光敏分子和金属配合物作为氧清除剂成分的用途

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GB1258611A (ko) * 1968-03-04 1971-12-30
US3607846A (en) * 1969-01-21 1971-09-21 Firestone Tire & Rubber Co Process of joining lithiated polymers or copolymers
JPH0798890B2 (ja) * 1989-06-23 1995-10-25 日本ゼオン株式会社 粘着剤用ブロック共重合体組成物及び粘着剤組成物

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Publication number Publication date
SI0683187T1 (en) 1998-08-31
ES2118467T3 (es) 1998-09-16
IT1269803B (it) 1997-04-15
ITMI941022A1 (it) 1995-11-20
JP3534895B2 (ja) 2004-06-07
RU95108067A (ru) 1997-03-10
CN1117070A (zh) 1996-02-21
US5627234A (en) 1997-05-06
ITMI941022A0 (it) 1994-05-20
ATE166898T1 (de) 1998-06-15
JPH0860124A (ja) 1996-03-05
DE69502771T2 (de) 1998-09-24
KR100330058B1 (ko) 2002-09-17
EP0683187A1 (en) 1995-11-22
DE69502771D1 (de) 1998-07-09
CN1062875C (zh) 2001-03-07
RU2159783C2 (ru) 2000-11-27
EP0683187B1 (en) 1998-06-03

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