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KR840007433A - 열분해 가솔린 중 디엔류를 선택적으로 수호하는 방법 - Google Patents

열분해 가솔린 중 디엔류를 선택적으로 수호하는 방법 Download PDF

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Publication number
KR840007433A
KR840007433A KR1019830005559A KR830005559A KR840007433A KR 840007433 A KR840007433 A KR 840007433A KR 1019830005559 A KR1019830005559 A KR 1019830005559A KR 830005559 A KR830005559 A KR 830005559A KR 840007433 A KR840007433 A KR 840007433A
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South Korea
Prior art keywords
catalyst
stage
pyrolysis gasoline
group
catalysts
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KR1019830005559A
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English (en)
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KR910004883B1 (ko
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그로오넨달(외 2) 윌럼
Original Assignee
안토니우스 토니스 푸이슈터
셀 인터나쵸나아레 레사아치 마아츠샤피 비이부이
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Publication of KR840007433A publication Critical patent/KR840007433A/ko
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Publication of KR910004883B1 publication Critical patent/KR910004883B1/ko
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Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • C10G45/32—Selective hydrogenation of the diolefin or acetylene compounds
    • C10G45/34—Selective hydrogenation of the diolefin or acetylene compounds characterised by the catalyst used
    • C10G45/36—Selective hydrogenation of the diolefin or acetylene compounds characterised by the catalyst used containing nickel or cobalt metal, or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G65/00—Treatment of hydrocarbon oils by two or more hydrotreatment processes only
    • C10G65/02—Treatment of hydrocarbon oils by two or more hydrotreatment processes only plural serial stages only
    • C10G65/04—Treatment of hydrocarbon oils by two or more hydrotreatment processes only plural serial stages only including only refining steps
    • C10G65/06—Treatment of hydrocarbon oils by two or more hydrotreatment processes only plural serial stages only including only refining steps at least one step being a selective hydrogenation of the diolefins
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
    • C10G2400/02—Gasoline

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  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

내용 없음.

Description

열분해 가솔린 중 디엔류를 선택적으로 수호하는 방법
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (11)

  1. 열분해 가솔린을 지지촉매 존재하에 고온, 고압에서 수소와 그 단계로 접촉시키는 것으로 구성되며, 1단계 촉매가 1-5%w(총촉매를 기준으로)의 원소 주기율표, 8족의 금속하나 또는 그 이상으로 구성되며, 그 단계 촉매가 5-40%w(총촉매를 기준으로)의 8족 금속 하나 또는 그 이상으로 구성되어 있는 열분해 가솔린에서 디엠을 선택적으로 수소화하는 방법.
  2. 제1항에 있어서, 1단계 및 2단계 촉매 모두가 8족 금속인 니켈로 구성되어 있는 방법.
  3. 제1항 또는 2항에 있어서, 1단계 및 2단계 촉매가 모두가 0-6중량%의 실리카를 함유하는 알루미나를 지지체로 구성하고 있는 방법.
  4. 제1항 내지 3항중 어느 하나에서 1단계 촉매가 1-4Mpa의 벌크파쇄 강도를 가지고 있는 방법.
  5. 제1항 내지 4항중 어느 하나에서 1단계 촉매가 그 최소크기가 약 2-30mm인 입자로 구성되어 있는 방법.
  6. 제1항 내지 5항중 어느 하나에서 상기한 입자가 구형인 방법.
  7. 제1항 내지 6항중 어느 하나에서 1단계 및 2단계 촉매 모두가 단일 반응대역내에 차례로 하나씩 설치되는 방법.
  8. 제1항 내지 7항중 어느 하나에서 두단계 모두에서 온도가 50-300범위이며, 총압력이 10-100바아 abs범위이며 수소부분압이 5-80바아 abs범위이며, 수소공급율이 50-1000NI/공금물 kg/이며 공간속도가 0.1-10kg공급물/촉매 1개/시간인 방법.
  9. 제1항에 있어서 실시예를 참조로 설명된 바와같은 방법.
  10. 제1항 내지 9항중 어느한 방법에 의해 제조된 수소화된 열 분해 가솔린.
  11. ※ 참고사항:최초출원 내용에 의하여 공개하는 것임.
KR1019830005559A 1982-11-26 1983-11-24 열분해가솔린 중 디엔류를 선택적으로 수소화하는 방법 Expired KR910004883B1 (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GB8233746 1982-11-26
GB08233746A GB2131043B (en) 1982-11-26 1982-11-26 Selective hydrogenation of dienes in pyrolysis gasoline

Publications (2)

Publication Number Publication Date
KR840007433A true KR840007433A (ko) 1984-12-07
KR910004883B1 KR910004883B1 (ko) 1991-07-15

Family

ID=10534541

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1019830005559A Expired KR910004883B1 (ko) 1982-11-26 1983-11-24 열분해가솔린 중 디엔류를 선택적으로 수소화하는 방법

Country Status (11)

Country Link
JP (1) JPH0631331B2 (ko)
KR (1) KR910004883B1 (ko)
AU (1) AU559246B2 (ko)
BE (1) BE898299A (ko)
CA (1) CA1216311A (ko)
DE (1) DE3342521A1 (ko)
FR (1) FR2536759B1 (ko)
GB (1) GB2131043B (ko)
IT (1) IT1168974B (ko)
NL (1) NL8303740A (ko)
ZA (1) ZA838762B (ko)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112691671A (zh) * 2019-10-23 2021-04-23 中国石油化工股份有限公司 镍催化剂及其制备方法

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE19608241A1 (de) * 1996-03-04 1997-09-18 Basf Ag Verfahren zur selektiven Hydrierung von Dienen
US7153807B2 (en) 2003-03-04 2006-12-26 Exxon Mobil Chemical Patents Inc. Catalysts for selective hydrogenation of alkynes and alkadienes
US7038097B2 (en) 2003-03-04 2006-05-02 Exxonmobil Chemical Patents Inc. Dual bed process using two different catalysts for selective hydrogenation of acetylene and dienes
CN101081998B (zh) * 2006-05-31 2010-05-12 中国石油化工股份有限公司 一种c4馏分的加氢方法
SG176087A1 (en) 2009-06-11 2011-12-29 Shell Int Research A process for the selective hydrogenation and hydrodesulferization of a pyrolysis gasoline feedstock

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB942493A (en) * 1961-05-10 1963-11-20 British Petroleum Co Improvements relating to the hydrogenation of petroleum hydrocarbons
US3388056A (en) * 1966-08-19 1968-06-11 Exxon Research Engineering Co Process for the hydrogenation of steam cracked naphtha
NL161807C (nl) * 1969-03-03 1980-08-15 Shell Int Research Werkwijze voor het winnen van aromatische koolwater- stoffen uit pyrolysebenzine.
GB1346778A (en) * 1971-02-11 1974-02-13 British Petroleum Co Selective hydrogenation of gasolines
GB1380962A (en) * 1972-01-19 1975-01-22 British Petroleum Co Selective hydrogenation of unsaturated gasolines
US4113603A (en) * 1977-10-19 1978-09-12 The Lummus Company Two-stage hydrotreating of pyrolysis gasoline to remove mercaptan sulfur and dienes
FR2410038A1 (fr) * 1977-11-29 1979-06-22 Inst Francais Du Petrole Procede d'hydrogenation selective d'essences contenant a la fois des composes generateurs de gommes et des composes indesirables du soufre

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112691671A (zh) * 2019-10-23 2021-04-23 中国石油化工股份有限公司 镍催化剂及其制备方法

Also Published As

Publication number Publication date
GB2131043B (en) 1986-09-10
DE3342521A1 (de) 1984-05-30
BE898299A (nl) 1984-05-24
CA1216311A (en) 1987-01-06
GB2131043A (en) 1984-06-13
KR910004883B1 (ko) 1991-07-15
IT8323879A0 (it) 1983-11-24
JPS59105083A (ja) 1984-06-18
NL8303740A (nl) 1984-06-18
FR2536759A1 (fr) 1984-06-01
AU2165383A (en) 1984-05-31
IT1168974B (it) 1987-05-20
FR2536759B1 (fr) 1990-02-09
AU559246B2 (en) 1987-03-05
JPH0631331B2 (ja) 1994-04-27
ZA838762B (en) 1984-07-25

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