JPS56112903A - Polymerization of vinyl monomer - Google Patents
Polymerization of vinyl monomerInfo
- Publication number
- JPS56112903A JPS56112903A JP1578880A JP1578880A JPS56112903A JP S56112903 A JPS56112903 A JP S56112903A JP 1578880 A JP1578880 A JP 1578880A JP 1578880 A JP1578880 A JP 1578880A JP S56112903 A JPS56112903 A JP S56112903A
- Authority
- JP
- Japan
- Prior art keywords
- polymerization
- water
- polymerization vessel
- monomer
- metal salt
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000178 monomer Substances 0.000 title abstract 5
- 238000006116 polymerization reaction Methods 0.000 title abstract 5
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 title abstract 3
- 229920002554 vinyl polymer Polymers 0.000 title abstract 3
- 125000000129 anionic group Chemical group 0.000 abstract 2
- 239000007864 aqueous solution Substances 0.000 abstract 2
- 150000001875 compounds Chemical class 0.000 abstract 2
- 239000002184 metal Chemical class 0.000 abstract 2
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 abstract 2
- 150000003839 salts Chemical class 0.000 abstract 2
- 239000000243 solution Substances 0.000 abstract 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 2
- -1 CaCl2 and Chemical class 0.000 abstract 1
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 abstract 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 abstract 1
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 abstract 1
- 239000000654 additive Substances 0.000 abstract 1
- 239000012736 aqueous medium Substances 0.000 abstract 1
- 239000001110 calcium chloride Substances 0.000 abstract 1
- 229910001628 calcium chloride Inorganic materials 0.000 abstract 1
- 230000008021 deposition Effects 0.000 abstract 1
- 238000001035 drying Methods 0.000 abstract 1
- 238000007720 emulsion polymerization reaction Methods 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- 229920002401 polyacrylamide Polymers 0.000 abstract 1
- 229920000642 polymer Polymers 0.000 abstract 1
- 239000003505 polymerization initiator Substances 0.000 abstract 1
- 239000000725 suspension Substances 0.000 abstract 1
- 238000010557 suspension polymerization reaction Methods 0.000 abstract 1
Landscapes
- Polymerisation Methods In General (AREA)
Abstract
PURPOSE: To prevent deposition of polymer scales, by previously applying an aqueous solution containing an anionic high-molecular compound and a metal salt to the monomer contact areas of a polymerization vessel, such as inner surfaces, and drying the applied solution, in the polymerization of vinyl monomers in an aqueous medium.
CONSTITUTION: An aqueous solution prepared by dissolving in water (i) a water- soluble anionic high-molecular compound such as sulfomethylated polyacrylamide, (ii) a water-soluble metal salt such as CaCl2 and, optionally, (iii) a monohydric C3W6 alcohol such as n-propyl alcohol is applied to the monomer contact areas, such as inner walls, agitator blades and an agitator shaft, of a stainless or glass- lined polymerization vessel, and the applied solution is dried. Next, into this coated polymerization vessel are charged water, a vinyl monomer such as vinyl chloride, a polymerization initiator and other additives. Then, the mixture is subjected to suspension or emulsion polymerization.
COPYRIGHT: (C)1981,JPO&Japio
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP1578880A JPS56112903A (en) | 1980-02-12 | 1980-02-12 | Polymerization of vinyl monomer |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP1578880A JPS56112903A (en) | 1980-02-12 | 1980-02-12 | Polymerization of vinyl monomer |
Publications (2)
Publication Number | Publication Date |
---|---|
JPS56112903A true JPS56112903A (en) | 1981-09-05 |
JPH0214921B2 JPH0214921B2 (en) | 1990-04-10 |
Family
ID=11898567
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP1578880A Granted JPS56112903A (en) | 1980-02-12 | 1980-02-12 | Polymerization of vinyl monomer |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS56112903A (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH03115304A (en) * | 1990-05-25 | 1991-05-16 | Shin Etsu Chem Co Ltd | Prevention of deposition of polymer scale and preventive against deposition of polymer scale |
JPH03115305A (en) * | 1990-05-25 | 1991-05-16 | Shin Etsu Chem Co Ltd | Prevention of deposition of polymer scale and preventive against deposition of polymer scale |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS51112892A (en) * | 1975-03-31 | 1976-10-05 | Shin Etsu Chem Co Ltd | Process for bulk polymerization of vinyl chloride |
JPS5223190A (en) * | 1975-08-15 | 1977-02-21 | Toagosei Chem Ind Co Ltd | Method for the suspension polymerization of vinyl chloride |
JPS5421484A (en) * | 1977-07-19 | 1979-02-17 | Kanegafuchi Chem Ind Co Ltd | Polymerization of vinyl chloride |
JPS55157602A (en) * | 1979-05-25 | 1980-12-08 | Shin Etsu Chem Co Ltd | Polymerization of vinyl monomer |
JPS565444A (en) * | 1979-06-16 | 1981-01-20 | Beecham Group Ltd | Ethanamine derivative* its manufacture and its medicinal composition |
-
1980
- 1980-02-12 JP JP1578880A patent/JPS56112903A/en active Granted
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS51112892A (en) * | 1975-03-31 | 1976-10-05 | Shin Etsu Chem Co Ltd | Process for bulk polymerization of vinyl chloride |
JPS5223190A (en) * | 1975-08-15 | 1977-02-21 | Toagosei Chem Ind Co Ltd | Method for the suspension polymerization of vinyl chloride |
JPS5421484A (en) * | 1977-07-19 | 1979-02-17 | Kanegafuchi Chem Ind Co Ltd | Polymerization of vinyl chloride |
JPS55157602A (en) * | 1979-05-25 | 1980-12-08 | Shin Etsu Chem Co Ltd | Polymerization of vinyl monomer |
JPS565444A (en) * | 1979-06-16 | 1981-01-20 | Beecham Group Ltd | Ethanamine derivative* its manufacture and its medicinal composition |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH03115304A (en) * | 1990-05-25 | 1991-05-16 | Shin Etsu Chem Co Ltd | Prevention of deposition of polymer scale and preventive against deposition of polymer scale |
JPH03115305A (en) * | 1990-05-25 | 1991-05-16 | Shin Etsu Chem Co Ltd | Prevention of deposition of polymer scale and preventive against deposition of polymer scale |
Also Published As
Publication number | Publication date |
---|---|
JPH0214921B2 (en) | 1990-04-10 |
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