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FI79134B - Ditiofosfor/amin-salter innehaollande vattenhaltiga kompositioner. - Google Patents

Ditiofosfor/amin-salter innehaollande vattenhaltiga kompositioner. Download PDF

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Publication number
FI79134B
FI79134B FI840004A FI840004A FI79134B FI 79134 B FI79134 B FI 79134B FI 840004 A FI840004 A FI 840004A FI 840004 A FI840004 A FI 840004A FI 79134 B FI79134 B FI 79134B
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Finland
Prior art keywords
carbon atoms
radicals
hydrocarbon
group
hydrocarbon radicals
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FI840004A
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English (en)
Finnish (fi)
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FI79134C (sv
FI840004A0 (fi
FI840004A (fi
Inventor
John Wesley Forsberg
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Lubrizol Corp
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Publication of FI840004A publication Critical patent/FI840004A/fi
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Publication of FI79134C publication Critical patent/FI79134C/sv

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    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02Phosphorus compounds
    • C07F9/28Phosphorus compounds with one or more P—C bonds
    • C07F9/38Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)]
    • C07F9/40Esters thereof
    • C07F9/4003Esters thereof the acid moiety containing a substituent or a structure which is considered as characteristic
    • C07F9/4021Esters of aromatic acids (P-C aromatic linkage)
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    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02Phosphorus compounds
    • C07F9/06Phosphorus compounds without P—C bonds
    • C07F9/16Esters of thiophosphoric acids or thiophosphorous acids
    • C07F9/165Esters of thiophosphoric acids
    • C07F9/17Esters of thiophosphoric acids with hydroxyalkyl compounds without further substituents on alkyl
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    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02Phosphorus compounds
    • C07F9/28Phosphorus compounds with one or more P—C bonds
    • C07F9/30Phosphinic acids [R2P(=O)(OH)]; Thiophosphinic acids ; [R2P(=X1)(X2H) (X1, X2 are each independently O, S or Se)]
    • C07F9/304Aromatic acids (P-C aromatic linkage)
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    • C10M137/00Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing phosphorus
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    • C10M137/00Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing phosphorus
    • C10M137/02Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing phosphorus having no phosphorus-to-carbon bond
    • C10M137/04Phosphate esters
    • C10M137/10Thio derivatives
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    • C10M173/00Lubricating compositions containing more than 10% water
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    • C10M173/02Lubricating compositions containing more than 10% water not containing mineral or fatty oils
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    • C10M2201/02Water
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    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10Carboxylix acids; Neutral salts thereof
    • C10M2207/14Carboxylix acids; Neutral salts thereof having carboxyl groups bound to carbon atoms of six-membered aromatic rings
    • C10M2207/141Carboxylix acids; Neutral salts thereof having carboxyl groups bound to carbon atoms of six-membered aromatic rings monocarboxylic
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    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
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    • C10M2209/00Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/10Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/103Polyethers, i.e. containing di- or higher polyoxyalkylene groups
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    • C10M2215/00Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant Compositions
    • C10M2215/02Amines, e.g. polyalkylene polyamines; Quaternary amines
    • C10M2215/04Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms
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    • C10M2215/00Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant Compositions
    • C10M2215/02Amines, e.g. polyalkylene polyamines; Quaternary amines
    • C10M2215/04Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2215/042Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms containing hydroxy groups; Alkoxylated derivatives thereof
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    • C10M2215/26Amines
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    • C10M2219/00Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/06Thio-acids; Thiocyanates; Derivatives thereof
    • C10M2219/062Thio-acids; Thiocyanates; Derivatives thereof having carbon-to-sulfur double bonds
    • C10M2219/066Thiocarbamic type compounds
    • C10M2219/068Thiocarbamate metal salts
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    • C10M2223/00Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
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    • C10M2223/00Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • C10M2223/02Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
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    • C10M2223/045Metal containing thio derivatives
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    • C10M2223/00Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • C10M2223/02Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
    • C10M2223/04Phosphate esters
    • C10M2223/047Thioderivatives not containing metallic elements
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    • C10N2010/00Metal present as such or in compounds
    • C10N2010/04Groups 2 or 12
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    • C10N2010/14Group 7
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    • C10N2010/16Groups 8, 9, or 10
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    • C10N2040/00Specified use or application for which the lubricating composition is intended
    • C10N2040/08Hydraulic fluids, e.g. brake-fluids
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    • C10N2040/20Metal working
    • C10N2040/22Metal working with essential removal of material, e.g. cutting, grinding or drilling
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    • C10N2050/00Form in which the lubricant is applied to the material being lubricated
    • C10N2050/01Emulsions, colloids, or micelles

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Biochemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Molecular Biology (AREA)
  • Lubricants (AREA)
  • Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Claims (10)

1. Komposition användbar som funktionell vätska för hydrauliska och/eller i metallskärningsändamäl, och vil-ken omfattar en vattenhaltig vätska samt en förening som framställts genom omsättning av (A) minst en ditiofos-forsyraförening med formeln S r! Il p-SH R2 36 7 *154 R3 N —fP,4 N)— H i3 I3n R RJ i vilken formel n är ett heltal 1 - cirka 10, varvid varje radikal R^ är individuellt vald ur gruppen som om-fattar väteatomer, kolväteradikaler med 1 - cirka 40 kolatomer och hydroxisubstituerade kolväteradikaler med 1 - cirka 40 kolatomer, och R4 är en tvävärd kolväteba-serad radikal som innehctller 1 - cirka 18 kolatomer.
2. Komposition enligt patentkravet 1, k änneteck-n a d därav, att (A) är en ditiofosforförening i vilken Rl och R2 är individuellt valda ur gruppen som om-fattar kolväteradikaler med 1 - cirka 20 kolatomer och kolväteoxiradikaler med 1 - cirka 20 kolatomer.
3. Komposition enligt patentkravet 2, känneteck-n a d därav, att (A) är en ditiofosforförening i vilken bäde Rl och R2 är kolväteoxiradikaler med 1 - cirka 18 kolatomer.
4. Komposition enligt patentkravet 3, känneteck-n a d därav, att bäde R·1- och R2 är alifatiska kolväteoxiradikaler.
5. Komposition enligt patentkravet 4, känneteck-n a d därav, att bäde R1 och R2 är alkyloxiradikaler.
6. Komposition enligt patentkravet 1, känneteck-n a d därav, att (B) är en alkylenpolyamin, i vilken n är ett heltal 1 - cirka 8, varje R^ är individuellt vald ur gruppen som omfattar väte, alkylradikaler med 1 -cirka 10 kolatomer och hydroxisubstituerade alkylradikaler med 1 - cirka 10 kolatomer och R4 är en lägalkylen-radikal med 1 - cirka 10 kolatomer. 3, 79134
7. Komposition enligt patentkravet 6, känneteck-n a d därav, att n är ett heltal 1 - cirka 4, varje R3 betecknar väte och R4 är en lägalkylenradikal med 2 -cirka 6 kolatomer.
8. Komposition användbar som funktionalla vätskor för hydrauliska och metallskärningsändamlil och som innehäl-ler en kontinuerlig vattenhaltig fas, (A) minst ett fosforsyra/aminsalt, vilket framställts genom omsättning av (I) minst en ditiofosforsyraförening med formeln «’-J ^ P - SH i vilken R1 och R2 Sr individuellt valda ur gruppen som omfattar kolväteradikaler med 1 - cirka 30 kolatomer och kolväteoxiradikaler med 1 - cirka 30 kolatomer, med (II) minst en aminoförening vald ur gruppen som omfattar cyk-liska polyaminer, alkylenpolyaminer med den allmänna formeln R— N -4R — N)— H (i) l3 l3n R RJ cykliska monoaminer och monoaminer med formeln R6
5 I 7 (ii) R-—N - r' vilka formler var och en av radikalerna R3, R^, R6 och R7 är individuellt valda ur gruppen som omfattar vätea-tomer, kolväteradikaler med 1 - cirka 40 kolatomer och hydroxisubstituerade kolväteradikaler med 1 - cirka 40 kolatomer, under den förutsättningen att dä aminoföre-ningen är en monoamin med formeln (A) (II) (ii) alla av 2 radikalerna R5, R® och R7 är inte samtidigt väte och
FI840004A 1983-01-07 1984-01-02 Ditiofosfor/amin-salter innehållande vattenhaltiga kompositioner FI79134C (sv)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US06/456,219 US4721802A (en) 1983-01-07 1983-01-07 Dithiophosphorus/amine salts
US45621983 1983-01-07

Publications (4)

Publication Number Publication Date
FI840004A0 FI840004A0 (fi) 1984-01-02
FI840004A FI840004A (fi) 1984-07-08
FI79134B true FI79134B (fi) 1989-07-31
FI79134C FI79134C (sv) 1989-11-10

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FI840004A FI79134C (sv) 1983-01-07 1984-01-02 Ditiofosfor/amin-salter innehållande vattenhaltiga kompositioner

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Country Link
US (1) US4721802A (sv)
EP (1) EP0116399B1 (sv)
JP (1) JPS59136396A (sv)
AU (1) AU565134B2 (sv)
BR (1) BR8400067A (sv)
CA (1) CA1222741A (sv)
DE (1) DE3481619D1 (sv)
DK (1) DK166216C (sv)
ES (1) ES8604982A1 (sv)
FI (1) FI79134C (sv)
IN (1) IN160840B (sv)
MX (1) MX161993A (sv)
NO (1) NO840039L (sv)
ZA (1) ZA8426B (sv)

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US5352374A (en) * 1993-02-22 1994-10-04 Exxon Research & Engineering Co. Lubricant composition containing alkoxylated amine salt of a dihydrocarbyldithiophosphoric acid (law024)
US5545237A (en) * 1994-07-08 1996-08-13 Exxon Research And Engineering Company Smoke reducing additive for two-cycle engine fuel mixture
US5916850A (en) * 1997-11-06 1999-06-29 Indian Oil Corporaton Limited Multifunctional additives from cashew nut shell liquid
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Also Published As

Publication number Publication date
EP0116399A2 (en) 1984-08-22
US4721802A (en) 1988-01-26
JPS59136396A (ja) 1984-08-04
DK7084A (da) 1984-07-08
NO840039L (no) 1984-07-09
BR8400067A (pt) 1984-08-14
ES528718A0 (es) 1986-04-01
ZA8426B (en) 1984-08-29
IN160840B (sv) 1987-08-08
FI79134C (sv) 1989-11-10
FI840004A0 (fi) 1984-01-02
DE3481619D1 (de) 1990-04-19
ES8604982A1 (es) 1986-04-01
FI840004A (fi) 1984-07-08
MX161993A (es) 1991-03-18
EP0116399B1 (en) 1990-03-14
CA1222741A (en) 1987-06-09
DK166216C (da) 1993-08-16
DK7084D0 (da) 1984-01-06
DK166216B (da) 1993-03-22
AU2308784A (en) 1984-07-12
AU565134B2 (en) 1987-09-03
JPH0425995B2 (sv) 1992-05-06
EP0116399A3 (en) 1985-09-11

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