FI71723B - Nya cyklopropankarboxylsyraestrar med en polyhalogen-substituent foerfarande foer deras framstaellning samt pesticidkompositioner - Google Patents
Nya cyklopropankarboxylsyraestrar med en polyhalogen-substituent foerfarande foer deras framstaellning samt pesticidkompositioner Download PDFInfo
- Publication number
- FI71723B FI71723B FI772745A FI772745A FI71723B FI 71723 B FI71723 B FI 71723B FI 772745 A FI772745 A FI 772745A FI 772745 A FI772745 A FI 772745A FI 71723 B FI71723 B FI 71723B
- Authority
- FI
- Finland
- Prior art keywords
- ppm
- cyclopropane
- dimethyl
- peaks
- hydrogen
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D209/00—Heterocyclic compounds containing five-membered rings, condensed with other rings, with one nitrogen atom as the only ring hetero atom
- C07D209/02—Heterocyclic compounds containing five-membered rings, condensed with other rings, with one nitrogen atom as the only ring hetero atom condensed with one carbocyclic ring
- C07D209/44—Iso-indoles; Hydrogenated iso-indoles
- C07D209/48—Iso-indoles; Hydrogenated iso-indoles with oxygen atoms in positions 1 and 3, e.g. phthalimide
- C07D209/49—Iso-indoles; Hydrogenated iso-indoles with oxygen atoms in positions 1 and 3, e.g. phthalimide and having in the molecule an acyl radical containing a saturated three-membered ring, e.g. chrysanthemumic acid esters
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N53/00—Biocides, pest repellants or attractants, or plant growth regulators containing cyclopropane carboxylic acids or derivatives thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61P—SPECIFIC THERAPEUTIC ACTIVITY OF CHEMICAL COMPOUNDS OR MEDICINAL PREPARATIONS
- A61P31/00—Antiinfectives, i.e. antibiotics, antiseptics, chemotherapeutics
- A61P31/04—Antibacterial agents
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C255/00—Carboxylic acid nitriles
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C61/00—Compounds having carboxyl groups bound to carbon atoms of rings other than six-membered aromatic rings
- C07C61/15—Saturated compounds containing halogen
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D307/00—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
- C07D307/02—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings
- C07D307/34—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
- C07D307/38—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with substituted hydrocarbon radicals attached to ring carbon atoms
- C07D307/40—Radicals substituted by oxygen atoms
- C07D307/42—Singly bound oxygen atoms
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Agronomy & Crop Science (AREA)
- Dentistry (AREA)
- Wood Science & Technology (AREA)
- Plant Pathology (AREA)
- Zoology (AREA)
- Pest Control & Pesticides (AREA)
- Environmental Sciences (AREA)
- Nuclear Medicine, Radiotherapy & Molecular Imaging (AREA)
- Communicable Diseases (AREA)
- Public Health (AREA)
- Animal Behavior & Ethology (AREA)
- Pharmacology & Pharmacy (AREA)
- Medicinal Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oncology (AREA)
- Veterinary Medicine (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Acyclic And Carbocyclic Compounds In Medicinal Compositions (AREA)
- Fodder In General (AREA)
- Heterocyclic Compounds That Contain Two Or More Ring Oxygen Atoms (AREA)
- Furan Compounds (AREA)
- Indole Compounds (AREA)
Claims (6)
1. Polyhalogenerade cyklopropankarboxylsyraestrar med pesti-cid verkan och med formeln Xl\ V H3C\/CH3 O x/2 1/C~0R <I) 3 3 » i alla möjliga isomerformer, i vilken formel betecknar en fluor-, klor- eller bromatom, X2» som är lik eller olik X^, betecknar en fluor-, klor- eller bromatom, X3 betecknar en klor- eller bromatom och R betecknar - antingen gruppen H - eller gruppen 92 71 723 H3C\,_/«3 i vilken R3 betecknar propen-l-yl, - eller gruppen H (~y< i vilken R4 betecknar en väteatom eller gruppen -CeN, - eller gruppen 0 66- i vilken symbolen S/I betecknar en aromatisk ring eller en motsva-rande dihydro- eller tetrahydroring.
2. Föreningar med den allmänna formeln I, soin definierats i patentkravet 1, kännetecknade därav, att estrarnas syradel har lR-cis- eller lR-trans-struktur.
3. Föreningar enligt patentkravet 1, i form av en av de tva möjliga isomererna i förhällande till den asymmetriska kolatomen i ställning 1' av formeln I, eller i form av en blandning av des-sa isomerer, speciellt följande föreningar: - (S) a-cyano-3-fenoxi-bensyl-lR,cis-2,2-dimetyl-3-(1',2',2',2’-tetrabrometyl)-cyklopropan-l-karboxylat, - (S) a-cyano-3-fenoxi-bensyl-lRrcis-2,2-dimetyl-3-(2'f2'-diklor-1',2'-dibrometyl)-cyklopropan-l-karboxylat.
4. Förfarande för framställning av föreningarna enligt pa-
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FI840658A FI73966C (sv) | 1976-09-21 | 1984-02-17 | Förfarande för framställning av nya cyklopropankarboxylsyraestrar med en polyhalogensubstituent, användbar för bekämpning av parasiter hos v armblodiga djur |
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR7628279 | 1976-09-21 | ||
| FR7628279A FR2364884A1 (fr) | 1976-09-21 | 1976-09-21 | Nouveaux esters d'acides cyclopropane, carboxyliques comportant un substituant polyhalogene, procedes de preparation et compositions insecticides les renfermant |
| FR7722078A FR2398041A2 (fr) | 1977-07-19 | 1977-07-19 | Esters d'acides cyclopropane carboxylique comportant un substituant polyhalogene, procede de preparation et leur application comme insecticides, acaricides, nematicides et comme medicaments veterinaires |
| FR7722078 | 1977-07-19 |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| FI772745A FI772745A (fi) | 1978-03-22 |
| FI71723B true FI71723B (fi) | 1986-10-31 |
| FI71723C FI71723C (sv) | 1987-02-09 |
Family
ID=26219635
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| FI772745A FI71723C (sv) | 1976-09-21 | 1977-09-19 | Nya cyklopropankarboxylsyraestrar med en polyhalogen-substituent, förf arande för deras framställning samt pesticidkompositioner |
| FI840658A FI73966C (sv) | 1976-09-21 | 1984-02-17 | Förfarande för framställning av nya cyklopropankarboxylsyraestrar med en polyhalogensubstituent, användbar för bekämpning av parasiter hos v armblodiga djur |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| FI840658A FI73966C (sv) | 1976-09-21 | 1984-02-17 | Förfarande för framställning av nya cyklopropankarboxylsyraestrar med en polyhalogensubstituent, användbar för bekämpning av parasiter hos v armblodiga djur |
Country Status (31)
| Country | Link |
|---|---|
| US (3) | US4179575A (sv) |
| JP (2) | JPS6011689B2 (sv) |
| AR (1) | AR230423A1 (sv) |
| AT (1) | AT363280B (sv) |
| AU (2) | AU512280B2 (sv) |
| BR (2) | BR7706313A (sv) |
| CA (2) | CA1140589A (sv) |
| CH (2) | CH627431A5 (sv) |
| DD (2) | DD135899A5 (sv) |
| DE (2) | DE2742547A1 (sv) |
| DK (2) | DK156934C (sv) |
| ES (2) | ES462475A1 (sv) |
| FI (2) | FI71723C (sv) |
| GB (2) | GB1561470A (sv) |
| GR (1) | GR70299B (sv) |
| HU (2) | HU178710B (sv) |
| IE (2) | IE45594B1 (sv) |
| IL (2) | IL52980A0 (sv) |
| IT (2) | IT1090232B (sv) |
| LU (2) | LU78155A1 (sv) |
| MX (1) | MX5332E (sv) |
| NL (2) | NL182561C (sv) |
| NO (1) | NO148184C (sv) |
| NZ (1) | NZ185226A (sv) |
| OA (1) | OA05761A (sv) |
| PH (1) | PH15593A (sv) |
| PL (1) | PL119266B1 (sv) |
| PT (1) | PT67062B (sv) |
| SE (2) | SE441179B (sv) |
| SU (1) | SU1316553A3 (sv) |
| YU (2) | YU40818B (sv) |
Families Citing this family (38)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2419932A2 (fr) * | 1978-03-17 | 1979-10-12 | Roussel Uclaf | Nouveaux esters d'acides cyclopropane carboxyliques comportant un substituant polyhalogene, procede de preparation et compositions insecticides les renfermant |
| EP0001795B1 (de) * | 1977-11-01 | 1981-01-07 | Ciba-Geigy Ag | Cyclopropankarbonsäure-phenoxy-alpha-vinyl-benzylester, Verfahren zu ihrer Herstellung und ihre Verwendung in der Schädlingsbekämpfung |
| JPS5511576A (en) * | 1978-07-11 | 1980-01-26 | Kuraray Co Ltd | Substituted cyclopropanecarboxylic ester and insecticide containing the same as effective component |
| EP0012722B1 (de) * | 1978-12-15 | 1981-12-09 | Ciba-Geigy Ag | Verfahren zur Herstellung von optisch aktiven, in 3-Stellung substituierten 2-(2',2'-Dihalogenvinyl)-cyclopropan-1-carbonsäuren und deren Derivaten; 4-(2',2',2'-Trihalogenäthyl)-cyclobutan-1-sulfonsäuresalze und deren Herstellung |
| JPS55167256A (en) * | 1979-06-12 | 1980-12-26 | Kuraray Co Ltd | 3-(4-chlorophenoxy)benzyl 2,2-dimethyl-3-(2,2-dichlorovinyl) cyclopropane-carboxylate and insecticide comprising it as active constituent |
| FR2484256B1 (fr) * | 1979-06-29 | 1986-10-24 | Roussel Uclaf | Procede de lutte contre les parasites des animaux a sang chaud |
| US4402973A (en) * | 1980-10-02 | 1983-09-06 | Fmc Corporation | Insecticidal (1,1'-biphenyl)-3-ylmethyl esters |
| BE886160A (nl) * | 1979-11-27 | 1981-05-14 | Shell Int Research | Cyclopropaan-carbonzure ester-derivaten |
| DE3004092A1 (de) * | 1980-02-05 | 1981-08-13 | Bayer Ag, 5090 Leverkusen | Substituierte 3-(1,2-dibrom-alkyl)- 2,2-dimethyl-cyclopropan-1-carbonsaeureester, verfahren sowie zwischenprodukte zu ihrer herstellung und ihre verwendung in schaedlingsbekaempfungsmitteln |
| HU182802B (en) * | 1980-02-26 | 1984-03-28 | Biogal Gyogyszergyar | Fotostabil delousing (insecticide) composition containing synthetic piretroides |
| US4331682A (en) | 1980-03-14 | 1982-05-25 | Ciba-Geigy Corporation | Cyclopropanecarboxylic acid-α-haloethynyl-m-phenoxybenzyl esters and their use for combating insect pests |
| WO1981002892A1 (en) * | 1980-04-10 | 1981-10-15 | Dainippon Jochugiku Kk | Cyclopropanecarboxylic acid ester derivatives,process for their preparation,and insecticidal and acaricidal composition containing such as effective ingredients |
| US4492687A (en) * | 1980-06-11 | 1985-01-08 | Roussel Uclaf | Light-stable pesticidal compositions |
| FR2498201A2 (fr) * | 1980-06-11 | 1982-07-23 | Roussel Uclaf | Compositions stables a la lumiere contenant des composes pyrethrinoides et des colorants |
| US4376785A (en) * | 1980-06-19 | 1983-03-15 | Sumitomo Chemical Company, Limited | Cyclopropanecarboxylates and a low fish toxic insecticide and/or acaricide containing them |
| IT1150963B (it) * | 1980-07-29 | 1986-12-17 | Montedison Spa | Piretroidi |
| JPS5879909A (ja) * | 1981-11-07 | 1983-05-13 | Yoshio Katsuta | 低魚毒性殺虫・殺ダニ剤及びその製造法 |
| DE3361336D1 (en) * | 1982-05-05 | 1986-01-09 | Bayer Ag | Process for the preparation of 3-vinyl-substituted 2,2-dimethyl-cyclopropane-1-carboxylic acids or their esters, and intermediate products therefor |
| US4493844A (en) * | 1982-08-19 | 1985-01-15 | Fmc Corporation | Insecticidal 2,2'-bridged(1,1'-biphenyl)-3-ylmethyl carboxamides |
| US4487778A (en) * | 1983-01-27 | 1984-12-11 | Fmc Corporation | Insecticidal esters derived from benzocycloalkane-thiophenemethyl compounds |
| US4605748A (en) * | 1983-01-27 | 1986-08-12 | Fmc Corporation | Benzocycloalkane-thiophenemethyl compounds as intermediates |
| DE3623532A1 (de) * | 1986-07-12 | 1988-01-21 | Bayer Ag | Verwendung von thiadiazinonen zur bekaempfung von endoparasiten |
| DE19953775A1 (de) | 1999-11-09 | 2001-05-10 | Bayer Ag | Wirkstoffkombinationen mit insektiziden und akariziden Eigenschaften |
| DE10007411A1 (de) | 2000-02-18 | 2001-08-23 | Bayer Ag | Wirkstoffkombinationen mit insektiziden und akariziden Eigenschaften |
| AR029677A1 (es) | 2000-06-29 | 2003-07-10 | Bayer Ag | Combinaciones de compuestos activos con propiedades insecticidas y acaricidas |
| DE102004001271A1 (de) * | 2004-01-08 | 2005-08-04 | Bayer Cropscience Ag | Wirkstoffkombinationen mit insektiziden Eigenschaften |
| DE102004006324A1 (de) * | 2004-02-10 | 2005-08-25 | Bayer Cropscience Ag | Wirkstoffkombinationen mit insektiziden Eigenschaften |
| US20090281157A1 (en) * | 2006-07-11 | 2009-11-12 | Bayer Cropscience Ag | Active Ingredient Combinations With Insecticidal and Acaricidal Properties |
| DE102006046688B3 (de) * | 2006-09-29 | 2008-01-24 | Siemens Ag | Kälteanlage mit einem warmen und einem kalten Verbindungselement und einem mit den Verbindungselementen verbundenen Wärmerohr |
| CN101541180A (zh) * | 2006-09-30 | 2009-09-23 | 拜尔农作物科学股份公司 | 用于改善农化活性成分根部吸收的胶悬剂 |
| EP2039248A1 (de) * | 2007-09-21 | 2009-03-25 | Bayer CropScience AG | Wirkstoffkombinationen mit insektiziden und akariziden Eigenschaften |
| DE102007045953B4 (de) | 2007-09-26 | 2018-07-05 | Bayer Intellectual Property Gmbh | Wirkstoffkombinationen mit insektiziden und akariziden Eigenschaften |
| MX2010012024A (es) * | 2008-05-07 | 2010-12-07 | Bayer Cropscience Ag | Combinaciones sinergicas de compuestos activos. |
| EP2127522A1 (de) | 2008-05-29 | 2009-12-02 | Bayer CropScience AG | Wirkstoffkombinationen mit insektiziden und akariziden Eigenschaften |
| WO2010108505A1 (de) | 2009-03-25 | 2010-09-30 | Bayer Cropscience Ag | Wirkstoffkombinationen mit insektiziden und akariziden eigenschaften |
| DE102009028001A1 (de) | 2009-07-24 | 2011-01-27 | Bayer Cropscience Ag | Wirkstoffkombinationen mit insektiziden und akariziden Eigenschaften |
| EP2382865A1 (de) | 2010-04-28 | 2011-11-02 | Bayer CropScience AG | Synergistische Wirkstoffkombinationen |
| CN109485564B (zh) * | 2018-11-28 | 2021-08-27 | 赵学迅 | 一种制备联苯菊酯的新方法 |
Family Cites Families (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3320121A (en) * | 1963-11-21 | 1967-05-16 | Sun Oil Co | 2-(2',2'-dihalocyclopropyl)-1,1-dihalocyclopropane and 2,2-dihalocyclopropyl carboxylic acid as antibacterial agents |
| GB1168797A (en) * | 1965-12-09 | 1969-10-29 | Nat Res Dev | Cyclopropane Carboxylic Acid Derivatives and their use as Insecticides |
| US3702333A (en) * | 1967-08-11 | 1972-11-07 | Yoshitomi Pharmaceutical | Cyclopropanecarboxylic acid esters possessing pesticidal properties |
| US3666789A (en) * | 1969-05-21 | 1972-05-30 | Sumitomo Chemical Co | Cyclopropanecarboxylic acid esters |
| JPS4821487B1 (sv) * | 1970-08-04 | 1973-06-29 | ||
| GB1331706A (en) * | 1971-04-23 | 1973-09-26 | Shell Int Research | Cyclopropane derivatives and biologicall active compositions thereof |
| GB1413491A (en) * | 1972-05-25 | 1975-11-12 | Nat Res Dev | 3-substituted-2,2-dimethyl-cyclopropane carboxylic acid esters their preparation and their use in pesticidal compositions |
| JPS50895B2 (sv) * | 1972-05-31 | 1975-01-13 | ||
| JPS5521008B2 (sv) * | 1972-11-29 | 1980-06-06 | ||
| JPS5542045B2 (sv) * | 1973-04-20 | 1980-10-28 | ||
| JPS5212697B2 (sv) * | 1973-08-23 | 1977-04-08 | ||
| JPS6059221B2 (ja) * | 1975-02-12 | 1985-12-24 | 住友化学工業株式会社 | アルキルシクロプロピルケトン誘導体の製造方法 |
| JPS5195043A (en) * | 1975-02-12 | 1976-08-20 | beeta jiharogenoetenirushikuropuropanjudotaino seizohoho | |
| GB1519052A (en) * | 1975-05-16 | 1978-07-26 | Ici Ltd | Process for preparing branched carboxylic acids |
| GB1581340A (en) * | 1976-07-26 | 1980-12-10 | Shell Int Research | Preparation of esters |
| DE2805312A1 (de) * | 1977-02-11 | 1978-08-17 | Ciba Geigy Ag | Cyclopropankarbonsaeureester, verfahren zu ihrer herstellung und ihre verwendung in der schaedlingsbekaempfung |
-
1977
- 1977-08-31 SE SE7709801A patent/SE441179B/sv not_active IP Right Cessation
- 1977-08-31 SE SE7709800A patent/SE446527B/sv not_active IP Right Cessation
- 1977-09-05 OA OA56275A patent/OA05761A/xx unknown
- 1977-09-15 HU HU77RO942A patent/HU178710B/hu not_active IP Right Cessation
- 1977-09-15 HU HU77RO941A patent/HU179756B/hu not_active IP Right Cessation
- 1977-09-19 GR GR54381A patent/GR70299B/el unknown
- 1977-09-19 FI FI772745A patent/FI71723C/sv not_active IP Right Cessation
- 1977-09-19 US US05/834,573 patent/US4179575A/en not_active Expired - Lifetime
- 1977-09-20 MX MX776200U patent/MX5332E/es unknown
- 1977-09-20 LU LU78155A patent/LU78155A1/xx unknown
- 1977-09-20 DD DD77201117A patent/DD135899A5/xx not_active IP Right Cessation
- 1977-09-20 AR AR269268A patent/AR230423A1/es active
- 1977-09-20 DK DK414577A patent/DK156934C/da not_active IP Right Cessation
- 1977-09-20 GB GB39149/77A patent/GB1561470A/en not_active Expired
- 1977-09-20 NL NLAANVRAGE7710328,A patent/NL182561C/xx not_active IP Right Cessation
- 1977-09-20 LU LU78156A patent/LU78156A1/xx unknown
- 1977-09-20 PL PL1977200963A patent/PL119266B1/pl not_active IP Right Cessation
- 1977-09-20 YU YU2219/77A patent/YU40818B/xx unknown
- 1977-09-20 IT IT51088/77A patent/IT1090232B/it active
- 1977-09-20 ES ES462475A patent/ES462475A1/es not_active Expired
- 1977-09-20 PT PT197767062A patent/PT67062B/pt unknown
- 1977-09-20 IT IT51087/77A patent/IT1090231B/it active Protection Beyond IP Right Term
- 1977-09-20 IE IE1919/77A patent/IE45594B1/en not_active IP Right Cessation
- 1977-09-20 NO NO773224A patent/NO148184C/no unknown
- 1977-09-20 DK DK414477A patent/DK157970C/da not_active IP Right Cessation
- 1977-09-20 NL NLAANVRAGE7710327,A patent/NL180899C/xx not_active IP Right Cessation
- 1977-09-20 ES ES462473A patent/ES462473A1/es not_active Expired
- 1977-09-20 IE IE1920/77A patent/IE45595B1/en not_active IP Right Cessation
- 1977-09-20 GB GB39148/77A patent/GB1561469A/en not_active Expired
- 1977-09-21 DE DE19772742547 patent/DE2742547A1/de active Granted
- 1977-09-21 AU AU28989/77A patent/AU512280B2/en not_active Expired
- 1977-09-21 CA CA000287204A patent/CA1140589A/fr not_active Expired
- 1977-09-21 JP JP52112746A patent/JPS6011689B2/ja not_active Expired
- 1977-09-21 DE DE2742546A patent/DE2742546C2/de not_active Expired
- 1977-09-21 BR BR7706313A patent/BR7706313A/pt unknown
- 1977-09-21 CH CH1156777A patent/CH627431A5/fr not_active IP Right Cessation
- 1977-09-21 IL IL52980A patent/IL52980A0/xx not_active IP Right Cessation
- 1977-09-21 AU AU28990/77A patent/AU514599B2/en not_active Expired
- 1977-09-21 JP JP11274777A patent/JPS5340744A/ja active Granted
- 1977-09-21 CH CH1156677A patent/CH630884A5/fr not_active IP Right Cessation
- 1977-09-21 NZ NZ185226A patent/NZ185226A/xx unknown
- 1977-09-21 DD DD77201145A patent/DD135152A5/xx unknown
- 1977-09-21 IL IL52981A patent/IL52981A0/xx not_active IP Right Cessation
- 1977-09-21 BR BR7706314A patent/BR7706314A/pt unknown
- 1977-09-21 CA CA000287177A patent/CA1242733A/fr not_active Expired
-
1979
- 1979-02-26 AT AT0147279A patent/AT363280B/de not_active IP Right Cessation
- 1979-03-07 US US06/018,166 patent/US4224227A/en not_active Expired - Lifetime
- 1979-06-19 PH PH22669A patent/PH15593A/en unknown
- 1979-06-25 US US06/051,348 patent/US4257978A/en not_active Expired - Lifetime
-
1981
- 1981-03-12 SU SU813254447A patent/SU1316553A3/ru active
-
1983
- 1983-07-05 YU YU1450/83A patent/YU43317B/xx unknown
-
1984
- 1984-02-17 FI FI840658A patent/FI73966C/sv not_active IP Right Cessation
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