[go: up one dir, main page]

DE69916834D1 - Verfahren zur polymerisation von olefinen unter verwendung von aktivierten lewis säure-base komplexen - Google Patents

Verfahren zur polymerisation von olefinen unter verwendung von aktivierten lewis säure-base komplexen

Info

Publication number
DE69916834D1
DE69916834D1 DE69916834T DE69916834T DE69916834D1 DE 69916834 D1 DE69916834 D1 DE 69916834D1 DE 69916834 T DE69916834 T DE 69916834T DE 69916834 T DE69916834 T DE 69916834T DE 69916834 D1 DE69916834 D1 DE 69916834D1
Authority
DE
Germany
Prior art keywords
lewis acid
acid base
base complexes
activated lewis
polymerizing olefines
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
DE69916834T
Other languages
English (en)
Other versions
DE69916834T2 (de
Inventor
W Holtcamp
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Univation Technologies LLC
Original Assignee
Univation Technologies LLC
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Univation Technologies LLC filed Critical Univation Technologies LLC
Application granted granted Critical
Publication of DE69916834D1 publication Critical patent/DE69916834D1/de
Publication of DE69916834T2 publication Critical patent/DE69916834T2/de
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
    • C08F4/61908—Component covered by group C08F4/60 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
    • C08F4/6192—Component covered by group C08F4/60 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943—Polymerization with metallocene catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
DE69916834T 1998-06-12 1999-06-03 Verfahren zur polymerisation von olefinen unter verwendung von aktivierten lewis säure-base komplexen Expired - Fee Related DE69916834T2 (de)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US8902398P 1998-06-12 1998-06-12
US89023P 1998-06-12
PCT/US1999/012491 WO1999064476A1 (en) 1998-06-12 1999-06-03 Olefin polymerization process using activated lewis acid-base complexes

Publications (2)

Publication Number Publication Date
DE69916834D1 true DE69916834D1 (de) 2004-06-03
DE69916834T2 DE69916834T2 (de) 2004-09-30

Family

ID=22215054

Family Applications (1)

Application Number Title Priority Date Filing Date
DE69916834T Expired - Fee Related DE69916834T2 (de) 1998-06-12 1999-06-03 Verfahren zur polymerisation von olefinen unter verwendung von aktivierten lewis säure-base komplexen

Country Status (9)

Country Link
US (1) US6211312B1 (de)
EP (1) EP1090045B1 (de)
JP (1) JP2002517571A (de)
AU (1) AU743376B2 (de)
BR (1) BR9911158A (de)
CA (1) CA2330529A1 (de)
DE (1) DE69916834T2 (de)
ES (1) ES2216586T3 (de)
WO (1) WO1999064476A1 (de)

Families Citing this family (35)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6451938B1 (en) * 1997-02-25 2002-09-17 Exxon Mobil Chemical Patents Inc. Polymerization catalyst system comprising heterocyclic fused cyclopentadienide ligands
US6147173A (en) 1998-11-13 2000-11-14 Univation Technologies, Llc Nitrogen-containing group 13 anionic complexes for olefin polymerization
US6291610B1 (en) 1998-12-18 2001-09-18 Univation Technologies, Llc Haloaryl containing group 13 substituents on bridged metallocene polyolefin catalysts
WO2001062764A1 (en) 2000-02-24 2001-08-30 Basell Technology Company B.V. Organometallic compound useful as cocatalyst for polymerizing olefins
US20040072975A1 (en) 2000-03-17 2004-04-15 Jorg Schottek Salt-like chemical compound, its preparation and its use in catalyst systems for preparing polyolefins
AU2001279978A1 (en) * 2000-09-26 2002-04-08 Bp Chemicals Limited Supported catalyst systems
US7249170B2 (en) * 2000-12-06 2007-07-24 Intelliden System and method for configuration, management and monitoring of network resources
DE10114345A1 (de) * 2001-03-23 2002-09-26 Bayer Ag Katalysator mit einer Donor-Akzeptor-Wechselwirkung
US6960634B2 (en) 2001-10-31 2005-11-01 Univation Technologies, Llc Methods for adjusting melt properties of metallocene catalyzed olefin copolymers
US6703338B2 (en) * 2002-06-28 2004-03-09 Univation Technologies, Llc Polymerization catalyst activators, method of preparing, and their use in polymerization processes
US20030207757A1 (en) * 2002-04-30 2003-11-06 Daelim Industries Co., Ltd. Catalyst composition comprising metallocene compound having bulky cycloalkyl-substituted cyclopentadienyl ligand, and process for olefin polymerization using the same
JP2006508903A (ja) 2002-07-09 2006-03-16 バセル ポリオレフィン ジーエムビーエイチ オレフィン重合用触媒系
AU2003288399A1 (en) * 2002-12-17 2004-07-09 Bp Chemicals Limited Supported olefin polymerization catalyst
US7741417B2 (en) 2004-01-07 2010-06-22 Exxonmobil Chemical Patents Inc. Preparation of polymerization catalyst activators utilizing indole-modified silica supports
WO2007140813A1 (en) 2006-06-02 2007-12-13 L'air Liquide Societe Anonyme Pour L'etude Et L'exploitation Des Procedes Georges Claude Method of forming high-k dielectric films based on novel titanium, zirconium, and hafnium precursors and their use for semiconductor manufacturing
US8022005B2 (en) 2007-11-08 2011-09-20 Exxonmobil Chemical Patents Inc. Halogen substituted heterocyclic heteroatom containing ligands-alumoxane activation of metallocenes
TW200936619A (en) 2007-11-15 2009-09-01 Univation Tech Llc Polymerization catalysts, methods of making, methods of using, and polyolefin products made therefrom
US9234093B2 (en) * 2008-03-31 2016-01-12 Exxonmobil Chemical Patents Inc. Thermoplastic vulcanizates
US9234060B2 (en) 2011-11-08 2016-01-12 Univation Technologies, Llc Methods of preparing a catalyst system
US9034998B2 (en) 2011-12-16 2015-05-19 University Of Massachusetts Polymerization initiating system and method to produce highly reactive olefin functional polymers
US9156924B2 (en) 2013-03-12 2015-10-13 University Of Massachusetts Polymerization initiating system and method to produce highly reactive olefin functional polymers
US9631038B2 (en) 2013-10-11 2017-04-25 University Of Massachusetts Polymerization initiating system and method to produce highly reactive olefin functional polymers
US9771442B2 (en) 2015-05-13 2017-09-26 University Of Massachusetts Polymerization initiating system and method to produce highly reactive olefin functional polymers
US10465289B2 (en) 2016-12-30 2019-11-05 L'Air Liquide, Société Anonyme pour l'Etude at l'Exploitation des Procédés Georges Claude Zirconium, hafnium, titanium precursors and deposition of group 4 containing films using the same
US10337104B2 (en) 2016-12-30 2019-07-02 L'air Liquide, Societe Anonyme Pour L'etude Et L'exploitation Des Procedes Georges Claude Zirconium, hafnium, titanium precursors and deposition of group 4 containing films using the same
US10364259B2 (en) 2016-12-30 2019-07-30 L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges Claude Zirconium, hafnium, titanium precursors and deposition of group 4 containing films using the same
US10508179B2 (en) 2017-02-28 2019-12-17 Exxonmobil Chemical Patents Inc. Thermoplastic vulcanizate prepared with oil-extended, bimodal metallocene-synthesized EPDM
US10167352B1 (en) 2017-06-28 2019-01-01 University Of Massachusetts Polymerization initiating system and method to produce highly reactive olefin functional polymers
US10047174B1 (en) 2017-06-28 2018-08-14 Infineum International Limited Polymerization initiating system and method to produce highly reactive olefin functional polymers
US10174138B1 (en) 2018-01-25 2019-01-08 University Of Massachusetts Method for forming highly reactive olefin functional polymers
US10865258B2 (en) 2018-01-31 2020-12-15 Exxonmobil Chemical Patents Inc. Mixed catalyst systems containing bridged metallocenes with a pendant group 13 element, processes for making a polymer product using same, and products made from same
US10851187B2 (en) 2018-01-31 2020-12-01 Exxonmobil Chemical Patents Inc. Bridged metallocene catalysts with a pendant group 13 element, catalyst systems containing same, processes for making a polymer product using same, and products made from same
WO2019152209A1 (en) * 2018-01-31 2019-08-08 Exxonmobil Chemical Patents Inc. Bridged metallocene catalysts with a pendant group 13 element, catalyst systems containing same, processes for making a polymer product using same, and products made from same
US10829573B1 (en) 2019-05-21 2020-11-10 Infineum International Limited Method for forming highly reactive olefin functional polymers
US20230295407A1 (en) 2020-07-02 2023-09-21 Exxonmobil Chemical Patents Thermoplastic Vulcanizate Compositions Containing Metallocene Multimodal Copolymer Rubber and Processes for Making Same

Family Cites Families (37)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
IL85097A (en) 1987-01-30 1992-02-16 Exxon Chemical Patents Inc Catalysts based on derivatives of a bis(cyclopentadienyl)group ivb metal compound,their preparation and their use in polymerization processes
US5198401A (en) 1987-01-30 1993-03-30 Exxon Chemical Patents Inc. Ionic metallocene catalyst compositions
US5153157A (en) 1987-01-30 1992-10-06 Exxon Chemical Patents Inc. Catalyst system of enhanced productivity
US5155080A (en) 1988-07-15 1992-10-13 Fina Technology, Inc. Process and catalyst for producing syndiotactic polyolefins
US5763547A (en) 1992-10-02 1998-06-09 The Dow Chemical Company Supported catalyst complexes for olefin in polymerization
US5763549A (en) 1989-10-10 1998-06-09 Fina Technology, Inc. Cationic metallocene catalysts based on organoaluminum anions
US5387568A (en) 1989-10-30 1995-02-07 Fina Technology, Inc. Preparation of metallocene catalysts for polymerization of olefins
CA2066247C (en) 1990-07-24 1998-09-15 Ryuichi Sugimoto Polymerization catalyst for .alpha.-olefin and method for preparing poly-.alpha.-olefin by using it
JP2895199B2 (ja) 1990-10-02 1999-05-24 三井化学株式会社 オレフィンの重合触媒
WO1992009640A1 (en) 1990-11-30 1992-06-11 Idemitsu Kosan Co., Ltd. Process for producing olefinic polymer
US5721185A (en) 1991-06-24 1998-02-24 The Dow Chemical Company Homogeneous olefin polymerization catalyst by abstraction with lewis acids
US5288677A (en) 1991-06-28 1994-02-22 Exxon Chemical Patents Inc. Immobilized Lewis acid catalysts
EP0614468B1 (de) 1991-11-25 1997-09-17 Exxon Chemical Patents Inc. Polyionische, uebergangsmetall enthaltende katalysatorzusammensetzung
ES2111656T3 (es) 1992-01-06 1998-03-16 Dow Chemical Co Composicion de catalizador mejorada.
US5374696A (en) * 1992-03-26 1994-12-20 The Dow Chemical Company Addition polymerization process using stabilized reduced metal catalysts
US5296433A (en) 1992-04-14 1994-03-22 Minnesota Mining And Manufacturing Company Tris(pentafluorophenyl)borane complexes and catalysts derived therefrom
KR100292158B1 (ko) 1992-08-04 2001-06-01 가지와라 야스시 올레핀중합용 촉매 및 올레핀의 중합방법
KR100311244B1 (ko) 1993-02-22 2001-12-15 가지와라 야스시 에틸렌/α-올레핀공중합체의제조방법
US6313240B1 (en) 1993-02-22 2001-11-06 Tosoh Corporation Process for producing ethylene/α-olefin copolymer
US5498582A (en) 1993-12-06 1996-03-12 Mobil Oil Corporation Supported metallocene catalysts for the production of polyolefins
JP3369294B2 (ja) 1994-03-11 2003-01-20 出光興産株式会社 遷移金属化合物、それを用いた重合用触媒及び該重合用触媒を用いたスチレン系重合体の製造方法
IT1273701B (it) 1994-07-29 1997-07-09 Enichem Elastomers Derivati metallorganici del grupo iiia e procedimento per la loro preparazione
PL318432A1 (en) * 1994-08-03 1997-06-09 Exxon Chemical Patents Inc Ionic supported catalyst composition
US5643847A (en) * 1994-08-03 1997-07-01 Exxon Chemical Patents Inc. Supported ionic catalyst composition
US5625087A (en) 1994-09-12 1997-04-29 The Dow Chemical Company Silylium cationic polymerization activators for metallocene complexes
US5554775A (en) 1995-01-17 1996-09-10 Occidental Chemical Corporation Borabenzene based olefin polymerization catalysts
US5939347A (en) 1995-01-25 1999-08-17 W.R. Grace & Co. -Conn. Supported catalytic activator
WO1996026967A1 (en) 1995-03-01 1996-09-06 Minnesota Mining And Manufacturing Company Tris(pentafluorophenyl)borate complexes and catalysts derived therefrom
US5721183A (en) * 1995-03-10 1998-02-24 The Dow Chemical Company Catalyst system comprising amine or phosphine adducts of tris(organyl)borane compounds
BR9604776A (pt) 1995-03-10 1998-06-23 Dow Chemical Co Componente de catalisador sustentado catalisador sustentado processo para preparar um componente de catalisador sustentado e um catalisador sustentado aduto de um composto organometálico processo de polimerizaçao por adiç o composto complexo e método para preparar um composto complexo
JPH11504361A (ja) 1995-04-25 1999-04-20 ライオンデル ペトロケミカル カンパニー オレフィンの重合の触媒としてのアザボロリニル金属錯体
DE19517851A1 (de) * 1995-05-16 1996-11-21 Hoechst Ag Organometallverbindung
EP0857179A1 (de) 1995-08-18 1998-08-12 Basell Polyolefine GmbH Katalysatorkomponente und katalysatorsystem mit hoher polymerisationsaktivität zur herstellung von polymeren
US5756609A (en) 1995-10-19 1998-05-26 Amoco Corporation Homogeneous metallocene-based olefin polymerization system with increased activity
IT1275812B1 (it) 1995-10-27 1997-10-17 Enichem Spa Sistema catalitico attivato per la (co)polimerizzazione delle alfa-olefine
CZ293472B6 (cs) 1996-07-23 2004-05-12 Theádowáchemicalácompany Katalytická kompozice a použití katalytického systému obsahujícího tuto katalytickou kompozici pro polymeraci adičních polymerizovatelných monomerů
US5854166A (en) 1996-08-19 1998-12-29 Northwestern University Synthesis and use of (perfluoroaryl) fluoro-aluminate anion

Also Published As

Publication number Publication date
JP2002517571A (ja) 2002-06-18
DE69916834T2 (de) 2004-09-30
ES2216586T3 (es) 2004-10-16
WO1999064476A1 (en) 1999-12-16
US6211312B1 (en) 2001-04-03
AU743376B2 (en) 2002-01-24
AU4333399A (en) 1999-12-30
EP1090045B1 (de) 2004-04-28
CA2330529A1 (en) 1999-12-16
BR9911158A (pt) 2001-04-03
EP1090045A1 (de) 2001-04-11

Similar Documents

Publication Publication Date Title
DE69916834D1 (de) Verfahren zur polymerisation von olefinen unter verwendung von aktivierten lewis säure-base komplexen
DE69806122D1 (de) Verfahren zur polymerisation von ethylen
DE69937681D1 (de) Verfahren zur radikalischen polymerisation
DE59707512D1 (de) Verfahren zur anionischen polymerisation
DE69808622D1 (de) Verfahren zur herstellung von blockcopolymeren durch kontrollierte radikalische polymerisation
DE69127811D1 (de) Verfahren zur herstellung von olefinpolymeren
DE69705526D1 (de) Verfahren zur polymerisation von monomeren mit olefingruppe
ATE227746T1 (de) Verfahren zur olefinpolymerisation
DE69907785D1 (de) Mehrstufiges Verfahren zur Olefinpolymerisation
DE69907459D1 (de) Verbessertes verfahren zur polymerisation von epoxiden
DE69941191D1 (de) Verfahren zur Gasphasenpolymerisation
DE69935259D1 (de) Verfahren zur herstellung von verzweigtem polymer
DE69720823D1 (de) Verfahren zur Olefinpolymerisierung unter Verwendung eines Übergangsmetallkatalysators.
DE69701997D1 (de) Verfahren zur bromierung von styrolpolymeren
DE59610504D1 (de) Verfahren zur herstellung von polymerelektrolyten
DE59908107D1 (de) Verfahren zur retardierten anionischen polymerisation
DE602004010642D1 (de) Verfahren zur polymerisation von olefinmonomeren mit mischkatalysatorsystemen
DE58903308D1 (de) Verfahren zur herstellung von 1-olefinpolymeren.
ATE175683T1 (de) Verfahren zur olefinpolymerisation in der gasphase
DE59905188D1 (de) Verfahren zur retardierten anionischen polymerisation
DE60007152D1 (de) Verfahren zur herstellung von olefinharz
DE60032224D1 (de) Verfahren zur polymerisation von silalkylensiloxanen
DE59813534D1 (de) Geträgertes katalysatorsystem zur polymerisation von alk-1-enen
DE69834718D1 (de) Verfahren zur herstellung von olefinpolymeren
DE69717478D1 (de) Verfahren zur polymerisierung von fluorierten olefinmonomeren

Legal Events

Date Code Title Description
8364 No opposition during term of opposition
8339 Ceased/non-payment of the annual fee