CN206457467U - Movable skid-mounted natual gas dehydrate unit - Google Patents
Movable skid-mounted natual gas dehydrate unit Download PDFInfo
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Abstract
Description
技术领域technical field
本实用新型涉及天然气净化处理领域,具体而言,涉及一种可移动撬装的天然气脱水装置。The utility model relates to the field of natural gas purification treatment, in particular to a movable skid-mounted natural gas dehydration device.
背景技术Background technique
目前,为降低燃煤锅炉、汽车排放等对大气环境造成的严重污染,我国近年来大力发展煤改气工程以及汽车清洁能源。随着西气东输、西气东输二、三线、陕京线、忠武线、川气东输等主输气管线的贯通,大量的燃煤锅炉甚至电厂都改为了天然气作为燃料,天然气加气站及加气母站在各沿线城市得到了大力的发展。At present, in order to reduce the serious pollution of the atmospheric environment caused by coal-fired boilers and automobile emissions, my country has vigorously developed coal-to-gas projects and automobile clean energy in recent years. With the completion of main gas pipelines such as the West-East Gas Pipeline, the Second and Third West-East Gas Pipelines, the Shaanxi-Beijing Line, the Zhongwu Line, and the Sichuan-East Gas Pipeline, a large number of coal-fired boilers and even power plants have been replaced by natural gas as fuel. Gas stations and refueling mother stations have been vigorously developed in cities along the line.
天然气来自地下,天然气井口流出的天然气几乎都为气相水所饱和,甚至会携带一定量的液态水。天然气中水分的存在往往会造成严重的后果:含有CO2和H2S的天然气在有水存在的情况下形成酸而腐蚀管路和设备;在一定条件下形成天然气水合物而堵塞阀门、管道和设备;降低管道输送能力,造成不必要的动力消耗。水分在天然气的存在是非常不利的事,因此,需要脱水的要求更为严格。Natural gas comes from the ground, and the natural gas flowing out of the wellhead is almost saturated with gas-phase water, and even carries a certain amount of liquid water. The presence of moisture in natural gas often causes serious consequences: natural gas containing CO2 and H2S forms acid in the presence of water and corrodes pipelines and equipment; under certain conditions, natural gas hydrate is formed to block valves, pipelines and equipment; Reduce pipeline transportation capacity, resulting in unnecessary power consumption. The presence of moisture in natural gas is a very unfavorable thing, therefore, the requirement for dehydration is more stringent.
天然气加气站及加气母站中最关键的设备之一也是天然气深度脱水装置。它能有效地对天然气进行深度脱水,且脱水的性能好坏直接影响天然气加气机的加气速度和天然气汽车的行驶性能、以及储气系统和售气系统是否产生“冰堵”现象,并对天然气汽车的储气罐有良好的保护作用。One of the most critical equipment in natural gas refueling stations and refueling mother stations is natural gas deep dehydration device. It can effectively deep dehydrate natural gas, and the performance of dehydration directly affects the filling speed of natural gas filling machine and the driving performance of natural gas vehicles, as well as whether there is "ice blockage" in the gas storage system and gas sales system, and It has a good protective effect on the gas storage tank of natural gas vehicles.
天然气脱水的方法一般包括低温法、溶剂吸收法、固体吸附法、化学反应法和膜分离法等。低温法脱水是利用高压天然气节流膨胀降温或利用气波机膨胀降温而实现的,这种工艺适合于高压天然气;而对于低压天然气,若要使用则必须增压,从而影响了过程的经济性。溶剂吸收法和固体吸附法目前在天然气工业中应用较广泛。其中,井口脱水是最根本的脱水方法,而溶剂吸收法又是井口天然气脱水的最佳选择,其中,甘醇是溶剂的首选。Natural gas dehydration methods generally include low temperature method, solvent absorption method, solid adsorption method, chemical reaction method and membrane separation method. Low-temperature dehydration is achieved by using high-pressure natural gas to expand and cool down or using a gas wave machine to expand and cool down. This process is suitable for high-pressure natural gas; for low-pressure natural gas, it must be pressurized if it is to be used, which affects the economy of the process. . Solvent absorption method and solid adsorption method are currently widely used in the natural gas industry. Among them, wellhead dehydration is the most fundamental dehydration method, and solvent absorption method is the best choice for wellhead natural gas dehydration, among which glycol is the first choice of solvent.
在天然气气脱水工业中曾成功应用的甘醇是:乙二醇(EG)、二甘醇(DEG)、三甘醇(TEG)和四甘醇(TREG)。最早用于天然气脱水的甘醇是二甘醇,由于受再生温度的限制,贫液质量分数一般为95%左右,露点降较低;而三甘醇再生容易,贫液质量分数可达98%~99%,具有更大的露点降,且运行成本较低,因此得到了广泛应用。The glycols that have been successfully used in the natural gas dehydration industry are: ethylene glycol (EG), diethylene glycol (DEG), triethylene glycol (TEG) and tetraethylene glycol (TREG). The earliest glycol used for natural gas dehydration is diethylene glycol. Due to the limitation of regeneration temperature, the mass fraction of lean liquid is generally about 95%, and the dew point drop is low; while triethylene glycol is easy to regenerate, and the mass fraction of lean liquid can reach 98%. ~99%, has a larger dew point drop, and lower operating costs, so it has been widely used.
最近已经有成熟的天然气三甘醇脱水装置,但是利用吸收塔和再生塔,体积庞大,需要的三甘醇量比较大。难以形成撬装装置,仅适合就地建设,无法移动。Recently, there have been mature natural gas triethylene glycol dehydration devices, but the use of absorption towers and regeneration towers is bulky and requires a relatively large amount of triethylene glycol. It is difficult to form a skid-mounted device, which is only suitable for in-situ construction and cannot be moved.
针对可移动撬装三甘醇天然气脱水的问题,目前尚未提出有效的解决方案。No effective solution has been proposed so far for the dehydration problem of mobile skid-mounted TEG natural gas.
实用新型内容Utility model content
本实用新型的主要目的在于提供一种可移动撬装的天然气脱水装置,以解决现有技术中的天然气三甘醇脱水装置难以移动和撬装的问题。The main purpose of the utility model is to provide a movable skid-mounted natural gas dehydration device to solve the problem that the natural gas triethylene glycol dehydration device is difficult to move and skid-mount in the prior art.
为了实现上述目的,根据本实用新型的一个方面,提供了一种可移动撬装的天然气脱水装置,包括:三甘醇超重力吸收装置,与湿天然气管网连接,用于通过三甘醇对天然气进行脱水处理;超重力三甘醇再生装置,与三甘醇超重力吸收装置的三甘醇出口连通,用于对吸水后的三甘醇进行再生处理。In order to achieve the above object, according to one aspect of the utility model, a movable skid-mounted natural gas dehydration device is provided, including: a triethylene glycol supergravity absorption device, connected with a wet natural gas pipeline network, for The natural gas is dehydrated; the supergravity triethylene glycol regeneration device is connected with the triethylene glycol outlet of the triethylene glycol supergravity absorption device, and is used to regenerate the triethylene glycol after water absorption.
进一步地,三甘醇超重力吸收装置包括:聚结过滤器,与湿天然气管网连通,用于分离天然气中的游离态液滴与固体杂质;以及三甘醇超重力机,与聚结过滤器连通,用于通过三甘醇吸收天然气中的水分,以得到天然气和富三甘醇液。Further, the triethylene glycol supergravity absorption device includes: a coalescing filter, which communicates with the wet natural gas pipeline network, and is used to separate free liquid droplets and solid impurities in natural gas; and a triethylene glycol supergravity machine, which is connected with the coalescence filter Connected, used to absorb moisture in natural gas through triethylene glycol to obtain natural gas and triethylene glycol-rich liquid.
进一步地,超重力三甘醇再生装置包括:闪蒸罐,与三甘醇超重力机连通,用于闪蒸分离出溶解在富三甘醇液中的烃气体;过滤器组,与闪蒸罐连通,用于过滤富三甘醇液中的杂质;换热器组,与过滤器组连通,用于将富三甘醇液加热;再生超重力机,与过滤器组连通,用于分离三甘醇与水蒸汽,以得到贫三甘醇液和再生尾气。Further, the high-gravity triethylene glycol regeneration device includes: a flash tank, communicated with the triethylene glycol high-gravity machine, used for flash separation to separate the hydrocarbon gas dissolved in the rich triethylene glycol liquid; filter group, connected with the flash tank The tank is connected to filter impurities in the triethylene glycol-rich liquid; the heat exchanger group is connected to the filter group to heat the triethylene glycol-rich liquid; the regenerative supergravity machine is connected to the filter group to separate Triethylene glycol and water vapor to obtain triethylene glycol-lean liquid and regeneration tail gas.
进一步地,过滤器组包括:前过滤器,与闪蒸罐连通,用于过滤富三甘醇液中的部分重烃及三甘醇再生时的降解物质;后过滤器,与前过滤器连通,用于除去富三甘醇液中的5μm以上的固体杂质。Further, the filter set includes: a pre-filter, communicated with the flash tank, used to filter some heavy hydrocarbons in the triethylene glycol-rich liquid and degradation substances during triethylene glycol regeneration; a post-filter, communicated with the pre-filter , used to remove solid impurities above 5 μm in triethylene glycol-rich liquid.
进一步地,换热器组包括:贫富液换热器,与过滤器组连通,用于将富三甘醇液与贫三甘醇液换热;再沸器,分别与再生超重力机和贫富液换热器连通,用于加热富三甘醇液。Further, the heat exchanger group includes: a poor-rich liquid heat exchanger, which communicates with the filter group, and is used to exchange heat between the rich triethylene glycol liquid and the poor triethylene glycol liquid; The poor-rich liquid heat exchanger is connected to heat the rich triethylene glycol liquid.
进一步地,超重力三甘醇再生装置还包括:气液换热器,分别与贫富液换热器和三甘醇超重力机连通,用于将天然气与贫三甘醇液换热。Further, the high-gravity triethylene glycol regeneration device also includes: a gas-liquid heat exchanger, which is respectively connected to the lean-rich liquid heat exchanger and the triethylene glycol high-gravity machine, and is used to exchange heat between natural gas and triethylene glycol-poor liquid.
进一步地,超重力三甘醇再生装置还包括:增压泵,设置于贫富液换热器与气液换热器之间,贫富液换热器通过增压泵与气液换热器连通,增压泵用于将贫三甘醇液增压。Further, the high-gravity triethylene glycol regeneration device also includes: a booster pump, which is arranged between the lean-rich liquid heat exchanger and the gas-liquid heat exchanger, and the lean-rich liquid heat exchanger passes through the booster pump and the gas-liquid heat exchanger connected, the booster pump is used to pressurize the lean triethylene glycol liquid.
进一步地,超重力三甘醇再生装置还包括:尾气换热器,设置于三甘醇超重力机与再生超重力机之间并与三甘醇超重力机连通,用于将再生尾气与富三甘醇液换热。Further, the supergravity triethylene glycol regeneration device also includes: a tail gas heat exchanger, which is arranged between the triethylene glycol supergravity machine and the regenerative supergravity machine and communicated with the triethylene glycol supergravity machine, for regenerating tail gas and rich Triethylene glycol liquid heat exchange.
进一步地,超重力三甘醇再生装置还包括:尾气分离器,与尾气换热器连通,用于对换热后的再生尾气进行脱水处理,并将脱水后的再生尾气输送至增压回收单元。Further, the high-gravity TEG regeneration device also includes: a tail gas separator, which communicates with the tail gas heat exchanger, and is used for dehydrating the regenerated tail gas after heat exchange, and transporting the dehydrated regenerated tail gas to the pressurized recovery unit .
进一步地,超重力三甘醇再生装置还包括:尾气冷却器,设置于尾气换热器与尾气分离器之间,用将换热后的再生尾气冷却。Further, the high-gravity TEG regeneration device further includes: a tail gas cooler, which is arranged between the tail gas heat exchanger and the tail gas separator, and cools the regenerated tail gas after heat exchange.
应用本实用新型的技术方案,提供了一种包括可移动撬装的天然气脱水装置,由于该天然气脱水装置包括三甘醇超重力吸收装置和超重力三甘醇再生装置,三甘醇超重力吸收装置与湿天然气管网相连接,用于脱除天然气中的水分,超重力三甘醇再生装置与三甘醇超重力吸收装置相连接,用于将吸水后的富三甘醇溶液脱水,使之再生,循环使用,从而通过对天然气中的水分吸收、吸收剂的再生以及吸收剂的循环,达到了几乎完全脱除天然气中水分、降低吸收剂使用量以及节约能源和装置占地面积的技术效果,进而提供了一种可移动撬装的天然气脱水装置。Applying the technical scheme of the utility model, a natural gas dehydration device including a movable skid is provided. Since the natural gas dehydration device includes a triethylene glycol supergravity absorption device and a supergravity triethylene glycol regeneration device, the triethylene glycol supergravity absorption The device is connected with the wet natural gas pipeline network for removing moisture in the natural gas, and the supergravity triethylene glycol regeneration device is connected with the triethylene glycol supergravity absorption device for dehydrating the rich triethylene glycol solution after absorbing water, so that Regeneration and recycling, so that through the absorption of moisture in natural gas, the regeneration of absorbents and the recycling of absorbents, the technology of almost completely removing moisture in natural gas, reducing the amount of absorbent used, and saving energy and equipment footprint Effect, and then provides a movable skid-mounted natural gas dehydration device.
除了上面所描述的目的、特征和优点之外,本实用新型还有其它的目的、特征和优点。下面将参照图,对本实用新型作进一步详细的说明。In addition to the purposes, features and advantages described above, the present invention has other purposes, features and advantages. Below with reference to figure, the utility model is described in further detail.
附图说明Description of drawings
构成本实用新型的一部分的说明书附图用来提供对本实用新型的进一步理解,本实用新型的示意性实施例及其说明用于解释本实用新型,并不构成对本实用新型的不当限定。在附图中:The accompanying drawings constituting a part of the utility model are used to provide a further understanding of the utility model, and the schematic embodiments of the utility model and their descriptions are used to explain the utility model and do not constitute improper limitations to the utility model. In the attached picture:
图1示出了本实用新型实施方式所提供的一种可移动撬装的天然气脱水装置的连接结构示意图;以及Fig. 1 shows a schematic diagram of the connection structure of a movable skid-mounted natural gas dehydration device provided by an embodiment of the present invention; and
图2示出了本实用新型实施方式所提供的一种可选的可移动撬装的天然气脱水装置的连接结构示意图。Fig. 2 shows a schematic diagram of the connection structure of an optional movable skid-mounted natural gas dehydration device provided by the embodiment of the present invention.
其中,上述附图包括以下附图标记:Wherein, the above-mentioned accompanying drawings include the following reference signs:
10、三甘醇超重力吸收装置;101、聚结过滤器;102、三甘醇超重力机;20、超重力三甘醇再生装置;201、尾气换热器;202、闪蒸罐;203、前过滤器;204、后过滤器;205、贫富液换热器;206、再沸器;207、再生超重力机;208、增压泵;209、气液换热器;210、尾气冷却器;211、尾气分离器。10. Triethylene glycol supergravity absorption device; 101. Coalescing filter; 102. Triethylene glycol supergravity machine; 20. Supergravity triethylene glycol regeneration device; 201. Tail gas heat exchanger; 202. Flash tank; 203 , front filter; 204, rear filter; 205, poor-rich liquid heat exchanger; 206, reboiler; 207, regenerative supergravity machine; 208, booster pump; 209, gas-liquid heat exchanger; 210, tail gas Cooler; 211. Exhaust gas separator.
具体实施方式detailed description
需要说明的是,在不冲突的情况下,本实用新型中的实施例及实施例中的特征可以相互组合。下面将参考附图并结合实施例来详细说明本实用新型。It should be noted that, in the case of no conflict, the embodiments of the present invention and the features in the embodiments can be combined with each other. The utility model will be described in detail below with reference to the accompanying drawings and in conjunction with the embodiments.
为了使本技术领域的人员更好地理解本实用新型方案,下面将结合本实用新型实施例中的附图,对本实用新型实施例中的技术方案进行清楚、完整地描述,显然,所描述的实施例仅仅是本实用新型一部分的实施例,而不是全部的实施例。基于本实用新型中的实施例,本领域普通技术人员在没有做出创造性劳动前提下所获得的所有其他实施例,都应当属于本实用新型保护的范围。In order to enable those skilled in the art to better understand the solution of the utility model, the technical solution in the embodiment of the utility model will be clearly and completely described below in conjunction with the accompanying drawings in the embodiment of the utility model. Obviously, the described The embodiments are only some of the embodiments of the present invention, not all of them. Based on the embodiments of the present utility model, all other embodiments obtained by persons of ordinary skill in the art without making creative efforts shall fall within the protection scope of the present utility model.
需要说明的是,本实用新型的说明书和权利要求书及上述附图中的术语“第一”、“第二”等是用于区别类似的对象,而不必用于描述特定的顺序或先后次序。应该理解这样使用的数据在适当情况下可以互换,以便这里描述的本实用新型的实施例。此外,术语“包括”和“具有”以及他们的任何变形,意图在于覆盖不排他的包含,例如,包含了一系列步骤或单元的过程、方法、系统、产品或设备不必限于清楚地列出的那些步骤或单元,而是可包括没有清楚地列出的或对于这些过程、方法、产品或设备固有的其它步骤或单元。It should be noted that the terms "first" and "second" in the specification and claims of the present utility model and the above drawings are used to distinguish similar objects, but not necessarily used to describe a specific order or sequence . It should be understood that the data so used may be interchanged under appropriate circumstances in order to facilitate the embodiments of the invention described herein. Furthermore, the terms "comprising" and "having", as well as any variations thereof, are intended to cover a non-exclusive inclusion, for example, a process, method, system, product or device comprising a sequence of steps or elements is not necessarily limited to the expressly listed instead, may include other steps or elements not explicitly listed or inherent to the process, method, product or apparatus.
正如背景技术中所介绍的,现有技术中的天然气三甘醇脱水装置利用吸收塔和再生塔,体积庞大,需要的三甘醇量比较大。难以形成撬装装置,仅适合就地建设,无法移动。本实用新型针对上述问题进行研究,提出了一种可移动撬装的天然气脱水装置,如图1所示,包括:三甘醇超重力吸收装置10,与湿天然气管网连接,用于通过三甘醇对天然气进行脱水处理;超重力三甘醇再生装置20,与三甘醇超重力吸收装置10的三甘醇出口连通,用于对吸水后的三甘醇进行再生处理。As introduced in the background art, the natural gas triethylene glycol dehydration device in the prior art uses an absorption tower and a regeneration tower, which are bulky and require a relatively large amount of triethylene glycol. It is difficult to form a skid-mounted device, which is only suitable for in-situ construction and cannot be moved. The utility model studies the above-mentioned problems, and proposes a movable skid-mounted natural gas dehydration device, as shown in Figure 1, including: a triethylene glycol supergravity absorption device 10, which is connected with the wet natural gas pipeline network, and is used for passing through three Glycol dehydrates the natural gas; the supergravity triethylene glycol regenerating device 20 communicates with the triethylene glycol outlet of the triethylene glycol supergravity absorption device 10, and is used for regenerating the triethylene glycol after absorbing water.
上述天然气脱水装置中由于包括三甘醇超重力吸收装置和超重力三甘醇再生装置,三甘醇超重力吸收装置与湿天然气管网相连接,用于脱除天然气中的水分,超重力三甘醇再生装置与三甘醇超重力吸收装置相连接,用于将吸水后的富三甘醇溶液脱水,使之再生,循环使用,从而通过对天然气中的水分吸收、吸收剂的再生以及吸收剂的循环,达到了几乎完全脱除天然气中水分、降低吸收剂使用量以及节约能源和装置占地面积的技术效果,进而提供了一种可移动撬装的天然气脱水装置。The above-mentioned natural gas dehydration device includes a triethylene glycol supergravity absorption device and a supergravity triethylene glycol regeneration device, and the triethylene glycol supergravity absorption device is connected with the wet natural gas pipeline network to remove moisture in natural gas. The glycol regeneration device is connected with the triethylene glycol supergravity absorption device, which is used to dehydrate the triethylene glycol-rich solution after water absorption, regenerate it, and recycle it, so as to absorb moisture in natural gas, regenerate absorbent and absorb The circulation of the agent achieves the technical effects of almost completely removing moisture in natural gas, reducing the amount of absorbent used, saving energy and the area occupied by the device, and then provides a movable skid-mounted natural gas dehydration device.
需要说明的是,上述天然气脱水装置应用于对天然气进行脱水处理,以达到处理后的天然气可以满足长距离运输和工业、民用的要求。It should be noted that the above-mentioned natural gas dehydration device is used to dehydrate natural gas so that the treated natural gas can meet the requirements of long-distance transportation and industrial and civil use.
天然气开采出以后含有一定量的轻烃甚至重质烃和水,为了稳定天然气的品质,脱除水和轻烃,上述天然气脱水装置通过有吸收装置10和再生装置20对天然气进行处理和吸收剂再生。具体地,利用吸收装置10对湿天然气进行脱水处理,利用再生装置20再生吸收后的三甘醇,从而达到了天然气脱水、降低天然气管线腐蚀性等目的,进而解决了天然气三甘醇脱水装置难以移动和撬装的技术问题,进而实现了提高天然气的品质稳定性的效果。Natural gas contains a certain amount of light hydrocarbons or even heavy hydrocarbons and water after extraction. In order to stabilize the quality of natural gas and remove water and light hydrocarbons, the above-mentioned natural gas dehydration device has an absorption device 10 and a regeneration device 20 to treat the natural gas and absorb it. regeneration. Specifically, the absorption device 10 is used to dehydrate the wet natural gas, and the regeneration device 20 is used to regenerate the absorbed triethylene glycol, thereby achieving the purpose of dehydrating the natural gas and reducing the corrosion of the natural gas pipeline, and further solving the problem of the natural gas triethylene glycol dehydration device. The technical problems of moving and skid-mounting have achieved the effect of improving the quality and stability of natural gas.
在本实用新型上述天然气脱水装置中,为了利用吸收装置10实现对天然气的脱水处理,可选地,如图2所示,吸收装置10包括:聚结过滤器101和三甘醇超重力机102,聚结过滤器101与湿天然气管网连通,用于分离天然气中的游离态液滴与固体杂质;三甘醇超重力机102与聚结过滤器101连通,用于通过三甘醇吸收天然气中的水分,以得到天然气和富三甘醇液。In the above-mentioned natural gas dehydration device of the present invention, in order to utilize the absorption device 10 to realize the dehydration treatment of natural gas, optionally, as shown in Figure 2, the absorption device 10 includes: a coalescence filter 101 and a triethylene glycol supergravity machine 102 , the coalescing filter 101 is connected with the wet natural gas pipeline network, and is used for separating free liquid droplets and solid impurities in the natural gas; the triethylene glycol supergravity machine 102 is connected with the coalescing filter 101, and is used for absorbing the natural gas by triethylene glycol of moisture to obtain natural gas and TEG-rich liquid.
具体地,通过聚结过滤器101的呈水饱和状态的湿天然气进入超三甘醇超重力机102,在一定压力下,天然气与三甘醇气液逆向接触,天然气中的水被吸收到三甘醇中,天然气出口的捕雾丝网除去大于5μm的甘醇液滴。其中,在三甘醇超重力机102中可以按照天然气含水要求填充有填料,以达到最好的吸收效率要求的目的;需要说明的是,超重力机102中填充的填料的形状材料质地不同也可以控制三甘醇超重力吸收装置10的吸收效果。Specifically, the wet natural gas in a water-saturated state passing through the coalescing filter 101 enters the ultra-TEG supergravity machine 102, and under a certain pressure, the natural gas and the triethylene glycol gas-liquid reverse contact, and the water in the natural gas is absorbed into the three In glycol, the mist-catching wire mesh at the natural gas outlet removes glycol droplets larger than 5 μm. Among them, the triethylene glycol supergravity machine 102 can be filled with fillers according to the water content requirements of natural gas, so as to achieve the purpose of the best absorption efficiency requirements; The absorption effect of the triethylene glycol supergravity absorption device 10 can be controlled.
在本实用新型上述天然气脱水装置中,为了利用再生装置20实现对吸水后三甘醇的再生,可选地,如图2所示,超重力三甘醇再生装置20包括闪蒸罐202,与三甘醇超重力机102连通,用于闪蒸分离出溶解在富三甘醇液中的烃气体;上述超重力三甘醇再生装置20还包括过滤器组,与闪蒸罐202连通,用于过滤富三甘醇液中的杂质;上述超重力三甘醇再生装置20还包括换热器组,与过滤器组连通,用于将富三甘醇液加热;再生超重力机207,与过滤器组连通,用于分离三甘醇与水蒸汽,以得到贫三甘醇液和再生尾气。In the above-mentioned natural gas dehydration device of the present invention, in order to use the regeneration device 20 to realize the regeneration of TEG after water absorption, optionally, as shown in Figure 2, the high-gravity TEG regeneration device 20 includes a flash tank 202, and The triethylene glycol supergravity machine 102 communicates, and is used for flashing to separate the hydrocarbon gas dissolved in the rich triethylene glycol liquid; the above-mentioned supergravity triethylene glycol regeneration device 20 also includes a filter group, which communicates with the flash tank 202, and uses For filtering the impurities in the rich triethylene glycol liquid; the above-mentioned high gravity triethylene glycol regeneration device 20 also includes a heat exchanger group, communicated with the filter group, and is used to heat the rich triethylene glycol liquid; regeneration supergravity machine 207, and The filter group is connected to separate triethylene glycol and water vapor to obtain triethylene glycol-deficient liquid and regeneration tail gas.
为了实现过滤器组对富三甘醇液中杂质的过滤,可选地,如图2所示,上述过滤器组包括前过滤器203,与闪蒸罐202连通,用于过滤富三甘醇液中的部分重烃及三甘醇再生时的降解物质;上述过滤器组还包括后过滤器204,与前过滤器203连通,用于除去富三甘醇液中的5μm以上的固体杂质。In order to realize the filtration of impurities in the rich triethylene glycol liquid by the filter group, optionally, as shown in Figure 2, the above-mentioned filter group includes a pre-filter 203, communicated with the flash tank 202, and is used for filtering rich triethylene glycol Part of the heavy hydrocarbons in the liquid and degradation substances during the regeneration of TEG; the above-mentioned filter group also includes a post filter 204, which communicates with the front filter 203, and is used to remove solid impurities above 5 μm in the TEG-rich liquid.
为了利用换热器组实现对富三甘醇液的加热,可选地,如图2所示,上述换热器组包括贫富液换热器205,与过滤器组连通,用于将富三甘醇液与贫三甘醇液换热;上述换热器组还包括再沸器206,分别与再生超重力机207和贫富液换热器连通,用于加热富三甘醇液。In order to utilize the heat exchanger group to realize the heating of the rich triethylene glycol liquid, optionally, as shown in FIG. The TEG liquid exchanges heat with the TEG-poor liquid; the above-mentioned heat exchanger group also includes a reboiler 206, which communicates with the regeneration supergravity machine 207 and the poor-rich liquid heat exchanger respectively, and is used for heating the TEG-rich liquid.
为了实现对富三甘醇液再生之前的预热,可选地,如图2所示,上述超重力三甘醇再生装置20还包括尾气换热器201,设置于三甘醇超重力机102与再生超重力机207之间并与三甘醇超重力机102连通,用于将再生尾气与富三甘醇液换热。In order to realize the preheating before the regeneration of the rich triethylene glycol liquid, optionally, as shown in Figure 2, the above-mentioned high-gravity triethylene glycol regeneration device 20 also includes a tail gas heat exchanger 201, which is arranged on the triethylene glycol high-gravity machine 102 It communicates with the regenerative supergravity machine 207 and the triethylene glycol supergravity machine 102, and is used to exchange heat between the regeneration tail gas and the triethylene glycol-rich liquid.
为了实现对上述换热后再生尾气的处理,可选地,如图2所示,超重力三甘醇再生装置20还包括尾气分离器211,与上述尾气换热器201连通,用于对换热后的再生尾气进行脱水处理,并将脱水后的再生尾气输送至增压回收单元;并且,可选地,超重力三甘醇再生装置20还包括尾气冷却器210,设置于尾气换热器201与尾气分离器211之间,用将换热后的再生尾气冷却。具体地,再生尾气经尾气换热器201回收热量后经尾气冷却器210使用循环水进一步冷却,然后经尾气分离器211气液分离,处理后的再生尾气去增压回收单元,污水去污水处理系统。In order to realize the treatment of the tail gas regenerated after the above-mentioned heat exchange, optionally, as shown in FIG. The heated regeneration tail gas is dehydrated, and the dehydrated regeneration tail gas is sent to the pressurized recovery unit; and, optionally, the high-gravity triethylene glycol regeneration device 20 also includes a tail gas cooler 210, which is arranged in the tail gas heat exchanger Between 201 and tail gas separator 211, the regenerated tail gas after heat exchange is used for cooling. Specifically, the regenerated tail gas passes through the tail gas heat exchanger 201 to recover heat, then passes through the tail gas cooler 210 and uses circulating water to further cool it, and then passes through the tail gas separator 211 for gas-liquid separation, and the treated regenerated tail gas goes to the pressurized recovery unit, and the sewage goes to the sewage treatment system.
上述超重力三甘醇再生装置20中的再沸器206可以采用燃料直接加热,温度优选为198~200℃,三甘醇重量百分比浓度可达98.5~99.0%,底部通入热干气对贫液进行汽提,三甘醇重量百分比浓度可达99.8%;并且,再生超重力机207可以内置填料。需要说明的是,再沸器206通入的热干气比例以及再生超重力机207中填充的填料的形状材料质地不同也可以控制再生装置20的再生效果。The reboiler 206 in the above-mentioned high-gravity triethylene glycol regenerating device 20 can be directly heated by fuel, the temperature is preferably 198-200°C, the concentration of triethylene glycol can reach 98.5-99.0% by weight, and the bottom is fed with hot dry gas to deplete the air. The liquid is stripped, and the concentration of triethylene glycol can reach 99.8% by weight; moreover, the regenerative supergravity machine 207 can have a built-in filler. It should be noted that the ratio of the hot dry gas fed into the reboiler 206 and the shape, material and texture of the filler filled in the regeneration supergravity machine 207 can also control the regeneration effect of the regeneration device 20 .
在一种优选的实施方式中,对天然气进行脱水处理后形成的富三甘醇液首先进入上述尾气换热器201,与再生超重力机207中产生的尾气换热,从而降低尾气温度,同时把富三甘醇液加热到35~60℃;预热后的富三甘醇液进入上述闪蒸罐202,闪蒸出吸收在三甘醇内的烃气体,闪蒸气直接进入燃料气系统;闪蒸后的富三甘醇液经过上述前过滤器203,过滤掉其中的部分重烃及三甘醇再生时的降解物质,然后经后过滤器204,除去其中5μm以上的固体杂质;经过滤后的富三甘醇液进入上述贫富液换热器205,与由再沸器206下部缓冲罐流出的热贫甘醇液换热升温至110℃~120℃,再进入缓冲罐内置换热盘管进一步与热贫甘醇换热升温至140℃~170℃;加热后的富三甘醇液进入上述再生超重力机207,富甘醇中的水分及很小部分烃类被分离出去,作为尾气排出并进入尾气换热器201中对富三甘醇液预热。In a preferred embodiment, the triethylene glycol-rich liquid formed after dehydration of natural gas first enters the above-mentioned tail gas heat exchanger 201, and exchanges heat with the tail gas generated in the regenerative supergravity machine 207, thereby reducing the temperature of the tail gas, and at the same time Heating the TEG-rich liquid to 35-60°C; the preheated TEG-rich liquid enters the above-mentioned flash tank 202 to flash the hydrocarbon gas absorbed in the TEG, and the flash gas directly enters the fuel gas system; The flashed TEG-rich liquid passes through the above-mentioned pre-filter 203 to filter out part of the heavy hydrocarbons and degradation substances during TEG regeneration, and then passes through the post-filter 204 to remove solid impurities above 5 μm; The final rich triethylene glycol liquid enters the above-mentioned lean-rich liquid heat exchanger 205, exchanges heat with the hot lean glycol liquid flowing out of the buffer tank at the lower part of the reboiler 206, and raises the temperature to 110°C-120°C, and then enters the buffer tank for heat exchange The coil further exchanges heat with the hot lean glycol to raise the temperature to 140°C-170°C; the heated triethylene glycol-rich liquid enters the above-mentioned regenerative supergravity machine 207, and the moisture and a small part of hydrocarbons in the rich glycol are separated, It is discharged as tail gas and enters the tail gas heat exchanger 201 to preheat the triethylene glycol-rich liquid.
为了实现对再生后三甘醇的循环利用,可选地,如图2所示,上述超重力三甘醇再生装置20还包括气液换热器209,分别与贫富液换热器205和三甘醇超重力机102连通,用于将天然气与贫三甘醇液换热;并且,可选地,超重力三甘醇再生装置20还包括增压泵208,设置于贫富液换热器205与气液换热器209之间,贫富液换热器205通过增压泵208与气液换热器209连通,增压泵208用于将贫三甘醇液增压。In order to realize the recycling of TEG after regeneration, optionally, as shown in FIG. The triethylene glycol supergravity machine 102 communicates with the natural gas and the lean triethylene glycol liquid heat exchange; and, optionally, the supergravity triethylene glycol regeneration device 20 also includes a booster pump 208, which is arranged on the lean rich liquid heat exchange Between the gas-liquid heat exchanger 205 and the gas-liquid heat exchanger 209, the poor-rich liquid heat exchanger 205 communicates with the gas-liquid heat exchanger 209 through a booster pump 208, and the booster pump 208 is used to pressurize the triethylene glycol-poor liquid.
具体地,经过三甘醇超重力吸收装置10脱水后的天然气成为了干天然气,温度较低,采用上述气液换热器209能够升高天然气的温度;同时,上述气液换热器209还能够降低进入三甘醇超重力吸收装置10中贫三甘醇液的温度,然后进入外输管网,吸收水分后的三甘醇成为富三甘醇液,再进入超重力三甘醇再生装置20中进行再生处理,然后循环使用。Specifically, the natural gas dehydrated by the triethylene glycol supergravity absorption device 10 becomes dry natural gas with a relatively low temperature, and the above-mentioned gas-liquid heat exchanger 209 can be used to increase the temperature of the natural gas; meanwhile, the above-mentioned gas-liquid heat exchanger 209 also It can reduce the temperature of the TEG-poor liquid entering the TEG supergravity absorption device 10, and then enter the external pipeline network, and the TEG after absorbing water becomes a TEG-rich liquid, and then enters the supergravity TEG regeneration device 20 for regeneration, and then recycled.
在一种优选的实施方式中,再生后的贫三甘醇液在再沸器206下部的缓冲罐中通过换热盘管与富甘醇液换热,并经过缓冲罐外壁的冷却,温度降至140℃左右出缓冲罐,进入贫富液换热器205中与富甘醇液换热,温度降至65~75℃左右进增压泵208,由增压泵208增压后进气液换热器209与外输气换热至36~56℃,最后进入三甘醇超重力机102中吸收天然气中的水分,以实现三甘醇的循环利用。In a preferred embodiment, the regenerated triethylene glycol-poor liquid passes through heat exchange coils in the buffer tank at the bottom of the reboiler 206 to exchange heat with the glycol-rich liquid, and is cooled by the outer wall of the buffer tank, and the temperature drops At about 140°C, it exits the buffer tank, enters the poor-rich liquid heat exchanger 205 to exchange heat with the rich glycol liquid, and when the temperature drops to about 65-75°C, it enters the booster pump 208, and the intake liquid is pressurized by the booster pump 208 The heat exchanger 209 exchanges heat with the external gas to 36-56°C, and finally enters the triethylene glycol supergravity machine 102 to absorb the moisture in the natural gas, so as to realize the recycling of triethylene glycol.
在实际应用场景中,该实施例的天然气脱水装置可以适用于天然气井口,也可用于天然气集输站,或天然气加气站等,典型的适用于天然气井口以及需要脱水的湿天然气管网之中,具体地,天然气井口天然气被采出之后,以及需对湿天然气进行脱水并稳定品质作为生活或工业用气的管网之后,例如,天然气井口采出的天然气,经脱水、脱硫、脱碳处理后进入外输管网,也即本实用新型实施例的脱水装置适用于湿天然气与进入集输或用户管网之间。In practical application scenarios, the natural gas dehydration device of this embodiment can be applied to natural gas wellheads, natural gas gathering and transportation stations, or natural gas filling stations, etc., and is typically suitable for natural gas wellheads and wet natural gas pipeline networks that require dehydration , specifically, after the natural gas is produced from the wellhead, and after the pipeline network needs to dehydrate the wet natural gas and stabilize its quality as domestic or industrial gas, for example, the natural gas produced from the natural gas wellhead is dehydrated, desulfurized, and decarbonized Then it enters the external pipeline network, that is, the dehydration device of the embodiment of the utility model is suitable for use between the wet natural gas and the pipeline network entering the gathering and transportation or users.
本实用新型实施例的天然气脱水装置已经为中东地区多次提供了工业应用。其中,为伊朗提供的三套500km3/h天然气脱水装置,采用三甘醇,达到CE天然气输送标准。The natural gas dehydration device of the embodiment of the utility model has provided industrial applications for many times in the Middle East. Among them, three sets of 500km 3 /h natural gas dehydration units provided for Iran use triethylene glycol to meet CE natural gas transmission standards.
从以上的描述中,可以看出,本实用新型上述的实施例实现了如下技术效果:三甘醇超重力吸收装置与湿天然气管网相连接,用于脱除天然气中的水分,超重力三甘醇再生装置与三甘醇超重力吸收装置相连接,用于将吸水后的富三甘醇溶液脱水,使之再生,循环使用,从而通过对天然气中的水分吸收、吸收剂的再生以及吸收剂的循环,达到了几乎完全脱除天然气中水分、降低吸收剂使用量以及节约能源和装置占地面积的技术效果,进而提供了一种可移动撬装的天然气脱水装置。From the above description, it can be seen that the above-mentioned embodiments of the present invention have achieved the following technical effects: the triethylene glycol supergravity absorption device is connected with the wet natural gas pipeline network for removing moisture in the natural gas, and the supergravity three The glycol regeneration device is connected with the triethylene glycol supergravity absorption device, which is used to dehydrate the triethylene glycol-rich solution after water absorption, regenerate it, and recycle it, so as to absorb moisture in natural gas, regenerate absorbent and absorb The circulation of the agent achieves the technical effects of almost completely removing moisture in natural gas, reducing the amount of absorbent used, saving energy and the area occupied by the device, and then provides a movable skid-mounted natural gas dehydration device.
以上所述仅为本实用新型的优选实施例而已,并不用于限制本实用新型,对于本领域的技术人员来说,本实用新型可以有各种更改和变化。凡在本实用新型的精神和原则之内,所作的任何修改、等同替换、改进等,均应包含在本实用新型的保护范围之内。The above descriptions are only preferred embodiments of the utility model, and are not intended to limit the utility model. For those skilled in the art, the utility model can have various modifications and changes. Any modification, equivalent replacement, improvement, etc. made within the spirit and principles of the present utility model shall be included in the protection scope of the present utility model.
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CN106753644A (en) * | 2017-01-16 | 2017-05-31 | 碧海舟(北京)节能环保装备有限公司 | Movable skid-mounted natual gas dehydrate unit |
CN107460015A (en) * | 2017-09-29 | 2017-12-12 | 北京化工大学 | A kind of deep natural gas dewatering system device and dewatering |
CN107641536A (en) * | 2017-10-19 | 2018-01-30 | 北京化工大学 | The system and device and technique handled suitable for offshore platform liquefaction with gas dehydration |
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CN106753644A (en) * | 2017-01-16 | 2017-05-31 | 碧海舟(北京)节能环保装备有限公司 | Movable skid-mounted natual gas dehydrate unit |
CN107460015A (en) * | 2017-09-29 | 2017-12-12 | 北京化工大学 | A kind of deep natural gas dewatering system device and dewatering |
CN107641536A (en) * | 2017-10-19 | 2018-01-30 | 北京化工大学 | The system and device and technique handled suitable for offshore platform liquefaction with gas dehydration |
CN107641536B (en) * | 2017-10-19 | 2019-12-31 | 北京化工大学 | System device and process suitable for dehydration treatment of natural gas for liquefaction on offshore platforms |
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