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CN204444225U - Add the cigarette filter rod that load has the filter screen of graphene oxide - Google Patents

Add the cigarette filter rod that load has the filter screen of graphene oxide Download PDF

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Publication number
CN204444225U
CN204444225U CN201520065360.XU CN201520065360U CN204444225U CN 204444225 U CN204444225 U CN 204444225U CN 201520065360 U CN201520065360 U CN 201520065360U CN 204444225 U CN204444225 U CN 204444225U
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filter
filter rod
graphene oxide
rod
cigarette
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Expired - Lifetime
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CN201520065360.XU
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Chinese (zh)
Inventor
高明奇
张展
冯晓民
李明哲
鲁平
纪朋
刘文博
杨金初
李禄成
聂聪
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China Tobacco Henan Industrial Co Ltd
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China Tobacco Henan Industrial Co Ltd
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Abstract

本实用新型属于烟草滤棒生产技术领域,具体涉及一种添加负载有氧化石墨烯的滤网的卷烟滤棒。该滤棒包括滤棒丝束、过滤网、滤棒成型纸,其中滤棒成型纸包裹滤棒丝束组成滤棒,过滤网在滤棒中以单片或者多片等距放置于滤棒丝束中间;所述过滤网上负载吸附有氧化石墨烯材料。本实用新型中,滤网大小可控、负载氧化石墨烯方式多样,负载量易于控制,是优良的减害降焦吸附剂的负载载体;同时由于滤网在卷烟滤棒中的数量和位置可调,因而能够较好的调节卷烟滤棒的吸阻。通过调节、设计滤网在滤棒中的位置,能够较好的实现滤棒吸阻的调节,同时本实用新型对设备要求简单,易于实现,且可以与其他类型的卷烟滤棒复合制备、使用,具有较好的实用价值。

The utility model belongs to the technical field of tobacco filter rod production, in particular to a cigarette filter rod added with a filter screen loaded with graphene oxide. The filter rod includes a filter rod tow, a filter screen, and a filter rod forming paper, wherein the filter rod forming paper wraps the filter rod tow to form a filter rod, and the filter screen is placed on the filter rod in a single or multiple In the middle of the bundle; the filter is loaded with graphene oxide material for adsorption. In the utility model, the size of the filter screen is controllable, there are various ways to load graphene oxide, and the load capacity is easy to control. It is an excellent load carrier for harm-reducing and tar-reducing adsorbents; Therefore, it can better adjust the draw resistance of the cigarette filter rod. By adjusting and designing the position of the filter screen in the filter rod, the adjustment of the suction resistance of the filter rod can be better realized. At the same time, the utility model has simple requirements on equipment, is easy to realize, and can be prepared and used in combination with other types of cigarette filter rods. , has good practical value.

Description

添加负载有氧化石墨烯的滤网的卷烟滤棒Cigarette filter rod with added graphene oxide-loaded filter

技术领域 technical field

本实用新型属于烟草滤棒生产技术领域,具体涉及一种添加负载有氧化石墨烯的滤网的卷烟滤棒。  The utility model belongs to the technical field of tobacco filter rod production, in particular to a cigarette filter rod added with a filter screen loaded with graphene oxide. the

背景技术 Background technique

随着消费者的健康意识的不断增强,控烟形势变得日益严峻,同时,也督促着卷烟技术不断发展。近年来,多种新型卷烟降焦减害技术得到开发应用,例如接装纸新型打孔技术、新型卷烟纸、新型滤嘴添加剂等,但是总体而言,烟气过滤方式仍然主要是通过对烟气中气溶胶颗粒的碰撞、截留等物理方式来实现。 With the continuous enhancement of consumers' health awareness, the situation of tobacco control has become increasingly severe, and at the same time, it is also urging the continuous development of cigarette technology. In recent years, a variety of new cigarette tar and harm reduction technologies have been developed and applied, such as new punching technology for tipping paper, new cigarette paper, and new filter additives. It is realized by physical methods such as collision and interception of aerosol particles in the air.

现有烟气减害技术中一种常用方式是在滤棒中添加各种添加剂来对烟气进行物理或化学吸附来降低烟气中的有害成分,但是这种方式普遍存在添加剂添加量大、接触面积有限等缺陷。在各种减害材料中,氧化石墨烯是一种常用的和有较多报道的添加剂材料。氧化石墨烯是一种经电化学或酸处理后的改性石墨烯,除具备普通石墨烯的优良特性外,其表面还含有丰富的羟基、羧基和碳氧官能团,易与羟基、氨基、羧基等极性基团形成氢键作用,因此,氧化石墨烯对共轭分子、碱基和醛酮分子等具有很好的吸附作用。如CN201310001588.8报道过将石墨烯类材料负载到炭纤维或者醋酸纤维载体上,采用行业现有的二元滤嘴制作方式将该载体添加到滤嘴中,制成复合滤嘴,在添加量极少的情况下即可达到良好减害效果。但是由于氧化石墨烯材料必须依赖于特定的吸附材料才能发挥较好的减害降焦作用,而现有的吸附材料往往存在一定的吸阻过大、抽吸困难等弊端,因而仍需进一步的改进。  A commonly used method in the existing flue gas harm reduction technology is to add various additives to the filter rod to physically or chemically adsorb the flue gas to reduce the harmful components in the flue gas, but this method generally has a large amount of additives, Defects such as limited contact area. Among various harm reduction materials, graphene oxide is a commonly used and widely reported additive material. Graphene oxide is a kind of modified graphene after electrochemical or acid treatment. In addition to the excellent characteristics of ordinary graphene, its surface also contains abundant hydroxyl, carboxyl and carbon-oxygen functional groups, which are easy to combine with hydroxyl, amino and carboxyl groups. Such polar groups form hydrogen bonds, so graphene oxide has a good adsorption effect on conjugated molecules, bases and aldehyde and ketone molecules. As reported in CN201310001588.8, graphene materials are loaded onto carbon fiber or cellulose acetate carrier, and the carrier is added to the filter by using the existing binary filter manufacturing method in the industry to make a composite filter. Good damage reduction can be achieved in very few cases. However, because graphene oxide materials must rely on specific adsorbent materials to play a good role in reducing harm and coke, and the existing adsorbent materials often have certain disadvantages such as excessive suction resistance and difficult suction, so further research is still needed. Improve. the

发明内容 Contents of the invention

本实用新型目的在于提供一种添加负载有氧化石墨烯的滤网的卷烟滤棒,该滤棒中的氧化石墨烯滤负载于滤网中,在解决减害降焦技术问题同时,通过调整滤网位置,可以较好的解决滤棒吸阻问题。 The purpose of the utility model is to provide a cigarette filter rod added with a filter screen loaded with graphene oxide. The graphene oxide filter in the filter rod is loaded in the filter screen. The location of the mesh can better solve the problem of filter rod suction resistance.

本实用新型的具体技术方案如下。 Concrete technical scheme of the present utility model is as follows.

一种添加负载有氧化石墨烯的滤网的卷烟滤棒,包括滤棒丝束、过滤网、滤棒成型纸, 其中滤棒成型纸包裹滤棒丝束组成滤棒,过滤网在滤棒中以单片或者多片等距放置于滤棒丝束中间; A cigarette filter rod added with a filter screen loaded with graphene oxide, including a filter rod tow, a filter screen, and a filter rod forming paper, wherein the filter rod forming paper wraps the filter rod tow to form a filter rod, and the filter screen is in the filter rod Place one piece or multiple pieces equidistantly in the middle of the filter rod tow;

所述过滤网上负载有氧化石墨烯材料;所述氧化石墨烯材料通过喷涂、涂布或浸泡等工艺负载于过滤网上。 Graphene oxide material is loaded on the filter net; the graphene oxide material is loaded on the filter net through processes such as spraying, coating or soaking.

所述过滤网材质为纤维素网片或者其他吸附材料网片。 The material of the filter screen is a cellulose mesh or other absorbent material mesh.

所述过滤网的网孔大小或多少可以根据卷烟吸阻设计而进行调整。 The mesh size or number of the filter screen can be adjusted according to the design of cigarette draw resistance.

所述过滤网片可以通过二元或多元滤棒复合工艺放置于基棒衔接处或者直接置于普通醋纤滤棒的居中位置。 The filter mesh can be placed at the junction of the base rods through a binary or multi-component filter rod compounding process or directly placed in the center of an ordinary acetate filter rod.

所述滤网片在单支卷烟滤棒中的数量以1~2片为宜。 The number of the filter screen in a single cigarette filter rod is preferably 1-2.

本实用新型所述的添加负载有氧化石墨烯的滤网的卷烟滤棒既可以单独应用,也可以与其他滤棒复合应用。 The cigarette filter rod added with the filter screen loaded with graphene oxide described in the utility model can be used alone or combined with other filter rods.

本实用新型中,滤网大小可控、负载氧化石墨烯方式多样,负载量易于控制,是优良的减害降焦吸附剂的负载载体;同时由于滤网在卷烟滤棒中的数量和位置可调,因而能够较好的调节卷烟滤棒的吸阻。通过调节、设计滤网在滤棒中的位置,在使卷烟主流烟气与氧化石墨烯材料充分接触、截留有害成分的同时,能够较好的实现滤棒吸阻的调节,同时本实用新型对设备要求简单,易于实现,且可以与其他类型的卷烟滤棒复合制备、使用,因而具有较好的实用价值。 In the utility model, the size of the filter screen is controllable, there are various ways of loading graphene oxide, and the load capacity is easy to control. It is an excellent load carrier for harm-reducing and tar-reducing adsorbents; Therefore, it can better adjust the draw resistance of the cigarette filter rod. By adjusting and designing the position of the filter screen in the filter rod, while making the mainstream smoke of the cigarette fully contact with the graphene oxide material and intercepting harmful components, the adjustment of the filter rod's suction resistance can be better realized. The equipment requirement is simple, easy to implement, and can be prepared and used in combination with other types of cigarette filter rods, so it has good practical value.

附图说明 Description of drawings

图1是本实用新型所提供的负载有氧化石墨烯的过滤网结构示意图; Fig. 1 is the schematic diagram of the filter screen structure provided by the utility model loaded with graphene oxide;

图2是本实用新型所提供的负载有氧化石墨烯的滤网的卷烟滤棒结构示意图。 Fig. 2 is a schematic structural diagram of a cigarette filter rod loaded with a graphene oxide filter provided by the present invention.

具体实施方式 Detailed ways

下面结合附图对本实用新型做进一步的解释说明。 Below in conjunction with accompanying drawing, the utility model is described further.

实施例 Example

如图1所示,过滤网负载有氧化石墨烯吸附材料形状为规则的圆形,但根据需要或者工艺,过滤网也可为其他形状或不规则形状。 As shown in Figure 1, the shape of the filter net loaded with graphene oxide adsorption material is a regular circle, but according to the needs or process, the filter net can also be in other shapes or irregular shapes.

以某具体规格为例,过滤网材质为纤维素网片,网孔直径大小约为0.2mm,单片滤网负载氧化石墨烯量约为0.5mg,氧化石墨烯通过浸泡方式负载于过滤网片上。 Taking a specific specification as an example, the material of the filter is cellulose mesh, the diameter of the mesh is about 0.2mm, the amount of graphene oxide loaded on a single filter is about 0.5mg, and the graphene oxide is loaded on the filter mesh by soaking .

如图2所示,添加负载有氧化石墨烯的滤网的卷烟滤棒,包括滤棒丝束1、过滤网2、滤棒成型纸3, 其中滤棒成型纸3包裹滤棒丝束1组成滤棒,过滤网2在滤棒中以单片或者多片等距放置于滤棒丝束1中间; As shown in Figure 2, a cigarette filter rod with a filter screen loaded with graphene oxide is added, including a filter rod tow 1, a filter screen 2, and a filter rod forming paper 3, wherein the filter rod forming paper 3 wraps the filter rod tow 1 to form The filter rod, the filter screen 2 is placed in the middle of the filter rod tow 1 in a single piece or multiple pieces equidistantly in the filter rod;

所述过滤网如上及图1所示,本实施例中过滤网2有两片,分别位于单支卷烟滤棒长度的三分之一处。 The filter screen is as above and shown in FIG. 1 . In this embodiment, there are two filter screens 2, which are respectively located at one-third of the length of a single cigarette filter rod.

抽吸实验表明,相同氧化石墨烯添加量情况下,与氧化石墨烯在滤棒丝束中均匀分布对照相比,本实用新型所提供的卷烟滤棒,吸阻较小,而且主流烟气过滤效果相当甚至更优,因而具有较好的技术效果。 Smoking experiments show that under the same amount of graphene oxide added, compared with the uniform distribution of graphene oxide in the filter rod tow, the cigarette filter rod provided by the utility model has a smaller suction resistance and can filter mainstream smoke. The effect is equivalent or even better, and thus has a better technical effect.

需要强调和说明的是,根据减害降焦效果和成本等要求,过滤网网孔大小、数量可以根据卷烟吸阻设计而进行调整,在滤棒中放置方式也可采取单片或者多片等多种方式。而且,本实用新型所提供的添加负载有氧化石墨烯的滤网的卷烟滤棒既可以单独使用,也可以通过二元或多元滤棒复合工艺放置于基棒衔接处或者直接置于普通醋纤滤棒的居中位置,从而与其他类型滤棒复合应用,因而使用范围较为广泛,具有较好的推广应用价值。  It needs to be emphasized and explained that, according to the requirements of harm reduction and coke reduction effect and cost, the mesh size and quantity of the filter can be adjusted according to the design of cigarette draw resistance, and the placement method of the filter rod can also be single piece or multiple pieces, etc. Variety of ways. Moreover, the cigarette filter rod provided by the utility model with added graphene oxide-loaded filter screen can be used alone, or can be placed at the joint of the base rod through a binary or multi-element filter rod composite process or directly placed in ordinary acetate fiber The central position of the filter rod allows it to be used in combination with other types of filter rods, so it can be used in a wider range and has better promotion and application value. the

Claims (2)

1. one kind is added the cigarette filter rod that load has the filter screen of graphene oxide, it is characterized in that, this filter stick comprises filter stick tow, screen pack, filter stick formation paper, wherein filter stick formation paper bag wraps up in filter stick tow composition filter stick, and screen pack is equidistantly positioned in the middle of filter stick tow with monolithic or multi-disc in filter stick;
On described screen pack, load has graphene oxide composite material.
2. add the cigarette filter rod that load has the filter screen of graphene oxide as claimed in claim 1, it is characterized in that, described screen pack material is cellulose mesh sheet.
CN201520065360.XU 2015-01-30 2015-01-30 Add the cigarette filter rod that load has the filter screen of graphene oxide Expired - Lifetime CN204444225U (en)

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Cited By (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105029694A (en) * 2015-08-11 2015-11-11 广西中烟工业有限责任公司 Harm-reducing type ternary composite filter rod containing graphene oxide particles
CN105361241A (en) * 2015-11-20 2016-03-02 东南大学 Cigarette binary composite filter tip filled with graphene oxide and preparation method of cigarette binary composite filter tip
CN105707978A (en) * 2016-04-14 2016-06-29 红云红河烟草(集团)有限责任公司 Filter stick containing saffron extract-loaded filter screen sheet
CN105707977A (en) * 2016-04-14 2016-06-29 红云红河烟草(集团)有限责任公司 Filter stick containing polygonum multiflorum extract-loaded filter screen sheet
CN105707979A (en) * 2016-04-14 2016-06-29 红云红河烟草(集团)有限责任公司 Filter stick containing wolfberry extract-loaded filter screen sheet
CN105725272A (en) * 2016-04-14 2016-07-06 红云红河烟草(集团)有限责任公司 Filter stick containing pseudo-ginseng extract-loaded filter screen sheet
CN105725268A (en) * 2016-04-14 2016-07-06 红云红河烟草(集团)有限责任公司 Filter stick containing filter screen sheet loaded with lucid ganoderma extract
CN105725271A (en) * 2016-04-14 2016-07-06 红云红河烟草(集团)有限责任公司 Filter stick containing filter screen sheet loaded with cordyceps sinensis extract
CN105725267A (en) * 2016-04-14 2016-07-06 红云红河烟草(集团)有限责任公司 Filter stick containing filter screen sheet loaded with coptis chinensis extract
CN105768216A (en) * 2016-04-14 2016-07-20 红云红河烟草(集团)有限责任公司 Filter stick containing filter screen sheet loaded with ginseng extract
CN105768215A (en) * 2016-04-14 2016-07-20 红云红河烟草(集团)有限责任公司 Filter stick containing licorice extract-loaded filter screen sheet
WO2017124992A1 (en) * 2016-01-18 2017-07-27 张麟德 Cigarette smoke filter device and tobacco product
CN109123765A (en) * 2017-06-16 2019-01-04 安康集团有限公司 tobacco product

Cited By (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105029694A (en) * 2015-08-11 2015-11-11 广西中烟工业有限责任公司 Harm-reducing type ternary composite filter rod containing graphene oxide particles
CN105361241A (en) * 2015-11-20 2016-03-02 东南大学 Cigarette binary composite filter tip filled with graphene oxide and preparation method of cigarette binary composite filter tip
CN105361241B (en) * 2015-11-20 2019-07-12 东南大学 A kind of cigarette binary combined filter tip and preparation method thereof filled with graphene oxide
WO2017124992A1 (en) * 2016-01-18 2017-07-27 张麟德 Cigarette smoke filter device and tobacco product
CN105725268A (en) * 2016-04-14 2016-07-06 红云红河烟草(集团)有限责任公司 Filter stick containing filter screen sheet loaded with lucid ganoderma extract
CN105725272A (en) * 2016-04-14 2016-07-06 红云红河烟草(集团)有限责任公司 Filter stick containing pseudo-ginseng extract-loaded filter screen sheet
CN105707979A (en) * 2016-04-14 2016-06-29 红云红河烟草(集团)有限责任公司 Filter stick containing wolfberry extract-loaded filter screen sheet
CN105725271A (en) * 2016-04-14 2016-07-06 红云红河烟草(集团)有限责任公司 Filter stick containing filter screen sheet loaded with cordyceps sinensis extract
CN105725267A (en) * 2016-04-14 2016-07-06 红云红河烟草(集团)有限责任公司 Filter stick containing filter screen sheet loaded with coptis chinensis extract
CN105768216A (en) * 2016-04-14 2016-07-20 红云红河烟草(集团)有限责任公司 Filter stick containing filter screen sheet loaded with ginseng extract
CN105768215A (en) * 2016-04-14 2016-07-20 红云红河烟草(集团)有限责任公司 Filter stick containing licorice extract-loaded filter screen sheet
CN105707977A (en) * 2016-04-14 2016-06-29 红云红河烟草(集团)有限责任公司 Filter stick containing polygonum multiflorum extract-loaded filter screen sheet
CN105707978A (en) * 2016-04-14 2016-06-29 红云红河烟草(集团)有限责任公司 Filter stick containing saffron extract-loaded filter screen sheet
CN109123765A (en) * 2017-06-16 2019-01-04 安康集团有限公司 tobacco product
CN109123765B (en) * 2017-06-16 2021-10-29 安康集团有限公司 tobacco products

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