CN116698926B - Measuring device and method for monitoring damage degree and corrosion rate of damaged part of coating - Google Patents
Measuring device and method for monitoring damage degree and corrosion rate of damaged part of coating Download PDFInfo
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- G01N27/00—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means
- G01N27/02—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means by investigating impedance
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Abstract
本发明公开了一种监测涂层损伤程度和破损处腐蚀速率的测量装置及测量方法。一种监测涂层损伤程度和破损处腐蚀速率的传感器,包括能够导电的壳体、多个电极、测温元件和填充胶,多个电极均布于壳体的开口处且和壳体不接触;测温元件能够实时监测电极的温度变化,测温元件设置于电极背向涂层的一侧,测温元件和电极绝缘设置;填充胶能够将电极和测温元件固设于壳体的内部。本发明公开的监测涂层损伤程度和破损处腐蚀速率的测量装置及测量方法,能够更准确的判断涂层的渗水情况;同时结合了噪声信号的分析,可以在发现涂层破损的基础上,通过电位和电流的噪声波动更早的预知涂层面临的破损风险,发现涂层老化的趋势。
The present invention discloses a measuring device and a measuring method for monitoring the degree of damage to a coating and the corrosion rate at a damaged part. A sensor for monitoring the degree of damage to a coating and the corrosion rate at a damaged part comprises a conductive shell, a plurality of electrodes, a temperature measuring element and a filling glue, wherein the plurality of electrodes are evenly distributed at the opening of the shell and are not in contact with the shell; the temperature measuring element can monitor the temperature change of the electrode in real time, the temperature measuring element is arranged on the side of the electrode facing away from the coating, and the temperature measuring element and the electrode are insulated; the filling glue can fix the electrode and the temperature measuring element inside the shell. The measuring device and the measuring method for monitoring the degree of damage to a coating and the corrosion rate at a damaged part disclosed by the present invention can more accurately judge the water seepage of the coating; at the same time, combined with the analysis of noise signals, it can predict the risk of damage faced by the coating earlier through the noise fluctuations of the potential and current on the basis of discovering the damage to the coating, and discover the aging trend of the coating.
Description
技术领域Technical Field
本发明涉及智能测控装置领域,尤其涉及监测涂层损伤程度和破损处腐蚀速率的测量装置及测量方法。The invention relates to the field of intelligent measurement and control devices, and in particular to a measuring device and a measuring method for monitoring the degree of coating damage and the corrosion rate of a damaged part.
背景技术Background technique
海洋环境中的钢结构长时间遭受海水的侵蚀和海浪、海洋生物及各类海面漂浮物的撞击,腐蚀破坏极为严重。目前,在海洋环境中各种金属涂层广泛应用于钢结构表面上,表现出了较好的耐蚀性能。虽然金属涂层发挥了保护钢结构的作用,但是腐蚀行为仍在不断进行,一旦涂层发生破损,破损的涂层与金属基体会形成微小缝隙,缝隙内部会发生阴极屏蔽效应而得不到完整的阴极保护,腐蚀介质将直接腐蚀基体,进而在破损部位引发严重的局部腐蚀,导致钢结构的强度降低,某些关键部位一旦出现开孔、破损将会导致严重的海损事故。因此,及时掌握涂层的腐蚀状态,具有十分重要的意义。Steel structures in the marine environment have been subjected to long-term erosion by seawater and impacts by waves, marine organisms and various floating objects on the sea surface, resulting in extremely serious corrosion damage. At present, various metal coatings are widely used on the surface of steel structures in the marine environment, showing good corrosion resistance. Although the metal coating plays a role in protecting the steel structure, the corrosion behavior is still ongoing. Once the coating is damaged, a tiny gap will be formed between the damaged coating and the metal substrate. The cathode shielding effect will occur inside the gap and the complete cathodic protection will not be obtained. The corrosive medium will directly corrode the substrate, and then cause severe local corrosion at the damaged part, resulting in a reduction in the strength of the steel structure. Once certain key parts have openings or damage, it will cause serious marine damage accidents. Therefore, it is of great significance to grasp the corrosion state of the coating in a timely manner.
目前,对海洋钢结构的腐蚀状况通常采取定期检查的方式,但腐蚀是不间断的进行,两次检查间隔出现的腐蚀安全问题往往不容易发现,由于检测周期较长,检测的项目有限,不能反应涂层损伤程度和腐蚀速率,不能实现在线监测。At present, the corrosion condition of marine steel structures is usually inspected regularly, but corrosion occurs continuously. Corrosion safety problems that occur between two inspections are often not easy to detect. Due to the long inspection cycle and limited inspection items, the degree of coating damage and corrosion rate cannot be reflected, and online monitoring cannot be achieved.
中国专利CN202210611417.6公开了一种监测涂层剥离深度和破损处腐蚀状态的传感器及监测方法,通过设置多电极耦合电流测量电路和多分区电阻法的测量电路,在多电极耦合电流测量电路的作用下识别涂层的腐蚀位置,并在到达腐蚀位置后将电路切换至多分区电阻法的测量电路,通过检测测量敏感元件不同位置处的电压情况,判断腐蚀位置内不同区域的腐蚀情况,从而对海洋风电设备涂层的剥离深度进行监测。但是该传感器采用阵列的长条形电阻电极结构,通过测量相邻电阻试片的耦合电流值大小来判断涂层损伤程度,无法提前预知涂层破损的风险。Chinese patent CN202210611417.6 discloses a sensor and monitoring method for monitoring the coating peeling depth and corrosion state at the damaged part. By setting a multi-electrode coupling current measurement circuit and a multi-partition resistance method measurement circuit, the corrosion position of the coating is identified under the action of the multi-electrode coupling current measurement circuit, and the circuit is switched to the multi-partition resistance method measurement circuit after reaching the corrosion position. By detecting the voltage conditions at different positions of the measurement sensitive element, the corrosion conditions in different areas of the corrosion position are judged, thereby monitoring the peeling depth of the coating of the offshore wind power equipment. However, the sensor adopts an array of long strip resistor electrode structures, and judges the degree of coating damage by measuring the coupling current values of adjacent resistor test pieces, and cannot predict the risk of coating damage in advance.
发明内容Summary of the invention
本发明提供一种监测涂层损伤程度和破损处腐蚀速率的测量装置及测量方法,以克服现有技术中仅能发现涂层破损,无法提前预知涂层面临的破损风险的问题。The present invention provides a measuring device and a measuring method for monitoring the damage degree of a coating and the corrosion rate at a damaged part, so as to overcome the problem that the prior art can only detect coating damage but cannot predict in advance the damage risk faced by the coating.
为了实现上述目的,本发明的技术方案是:一种监测涂层损伤程度和破损处腐蚀速率的传感器,包括能够导电的壳体、多个电极、测温元件和填充胶,所述壳体具有一侧开口的空腔,多个所述电极均布于壳体的开口处,且和壳体不接触,所述壳体开口端朝向待测涂层,所述电极表面和待测涂层表面接触;In order to achieve the above-mentioned purpose, the technical scheme of the present invention is: a sensor for monitoring the degree of damage of a coating and the corrosion rate at a damaged part, comprising a conductive shell, a plurality of electrodes, a temperature measuring element and a filling glue, wherein the shell has a cavity with an opening on one side, the plurality of electrodes are evenly distributed at the opening of the shell and do not contact the shell, the opening end of the shell faces the coating to be measured, and the surface of the electrode contacts the surface of the coating to be measured;
所述测温元件能够实时监测电极的温度变化,所述测温元件设置于电极背向涂层的一侧,所述测温元件和电极绝缘设置;所述填充胶能够将电极和测温元件固设于壳体的内部。The temperature measuring element can monitor the temperature change of the electrode in real time. The temperature measuring element is arranged on the side of the electrode facing away from the coating. The temperature measuring element and the electrode are insulated. The filling glue can fix the electrode and the temperature measuring element inside the shell.
进一步地,所述电极包括多个平行且间隔设置的水平段,相邻所述水平段之间设置有回折段,相邻水平段设置于回折段的同侧,相邻回折段设置于水平段的异侧,且相邻回折段之间的间隔等于对应水平段的长度。Furthermore, the electrode includes a plurality of parallel and spaced horizontal segments, a return segment is arranged between adjacent horizontal segments, adjacent horizontal segments are arranged on the same side of the return segment, adjacent return segments are arranged on opposite sides of the horizontal segment, and the interval between adjacent return segments is equal to the length of the corresponding horizontal segment.
进一步地,相邻所述电极之间的距离等于电极端部和壳体内壁之间的距离,相邻所述电极之间的距离不超过0.5mm。Furthermore, the distance between adjacent electrodes is equal to the distance between the electrode end and the inner wall of the shell, and the distance between adjacent electrodes does not exceed 0.5 mm.
进一步地,所述测温元件和电极之间设置有导热硅胶垫。Furthermore, a thermally conductive silicone pad is provided between the temperature measuring element and the electrode.
为了实现上述目的,本发明的技术方案还包括:一种监测涂层损伤程度和破损处腐蚀速率的测量装置,包括具有空腔的防水密封仓、传感器、线缆和电化学检测系统以及固定胶,所述传感器固设于防水密封仓的外部,所述电化学检测系统通过固定胶固设于防水密封仓的内部,所述传感器和电化学检测系统通过电缆电性连接;In order to achieve the above-mentioned purpose, the technical solution of the present invention also includes: a measuring device for monitoring the degree of damage of the coating and the corrosion rate of the damaged part, comprising a waterproof sealed chamber with a cavity, a sensor, a cable, an electrochemical detection system and a fixing glue, wherein the sensor is fixedly arranged outside the waterproof sealed chamber, the electrochemical detection system is fixedly arranged inside the waterproof sealed chamber by the fixing glue, and the sensor and the electrochemical detection system are electrically connected by a cable;
所述电化学检测系统包括电化学阻抗谱测量模块、电化学噪声模块和多分区电阻测量模块,所述电化学阻抗谱测量模块、电化学噪声模块和多分区电阻测量模块并联后和传感器电连接。The electrochemical detection system comprises an electrochemical impedance spectrum measurement module, an electrochemical noise module and a multi-partition resistance measurement module, which are connected in parallel and electrically connected to a sensor.
进一步地,所述防水密封仓的外部固设有固定挂耳,所述固定挂耳能够将测量装置固定在待检测位置。Furthermore, a fixing lug is fixedly provided on the outside of the waterproof sealed chamber, and the fixing lug can fix the measuring device at a position to be detected.
进一步地,所述电化学阻抗谱测量模块具有3个第一接线端口,每个第一接线端口处分别连接有第一继电器,所述电化学阻抗谱测量模块通过第一继电器和传感器连接;Furthermore, the electrochemical impedance spectroscopy measurement module has three first wiring ports, each of which is connected to a first relay, and the electrochemical impedance spectroscopy measurement module is connected to the sensor via the first relay;
所述电化学噪声模块具有3个第二接线端口,每个第二接线端口处分别连接有第二继电器,所述电化学噪声模块通过第二继电器和传感器连接;The electrochemical noise module has three second wiring ports, each of which is connected to a second relay, and the electrochemical noise module is connected to the sensor via the second relay;
所述多分区电阻测量模块具有4个外部接口,4个外部接口中包括2个电流接口和2个电压接口,每个所述外部接口分别连接有第三继电器,所述多分区电阻测量模块通过第三继电器和传感器连接。The multi-partition resistance measurement module has four external interfaces, including two current interfaces and two voltage interfaces, each of the external interfaces is respectively connected to a third relay, and the multi-partition resistance measurement module is connected to the sensor via the third relay.
进一步地,所述第三继电器和电极之间设置有多个电流接线柱和多个电压接线柱,所述电流接线柱和电压接线柱互相间隔设置;Furthermore, a plurality of current binding posts and a plurality of voltage binding posts are arranged between the third relay and the electrode, and the current binding posts and the voltage binding posts are arranged at intervals from each other;
所述电极上均匀分布有多个导电触点,任意导电触点与电流接线柱和/或电压接线柱连接,多个所述导电触点将电极表面均分为多个分区。A plurality of conductive contacts are evenly distributed on the electrode, and any conductive contact is connected to the current terminal and/or the voltage terminal. The plurality of conductive contacts divide the electrode surface into a plurality of partitions.
为了实现上述目的,本发明的技术方案还包括:一种基于所述的测量装置的测试涂层内部渗水情况或涂层的损伤程度的方法,包括如下步骤:In order to achieve the above object, the technical solution of the present invention also includes: a method for testing the water seepage inside the coating or the degree of damage to the coating based on the measuring device, comprising the following steps:
闭合电化学阻抗谱测量模块,控制电化学阻抗谱测量模块进行测量,并对获得的数据进行分析,通过计算2个电极之间的电容来分析涂层内部渗水情况;Close the electrochemical impedance spectroscopy measurement module, control the electrochemical impedance spectroscopy measurement module to perform measurement, and analyze the acquired data, and analyze the water seepage inside the coating by calculating the capacitance between the two electrodes;
或闭合电化学噪声模块,控制电化学噪声模块进行测量,并对获得的数据进行分析,分析2个电极之间电流噪声信号和电极与壳体之间的电位噪声信号得到电极表面涂层的损伤程度信息。Or close the electrochemical noise module, control the electrochemical noise module to measure, and analyze the obtained data, analyze the current noise signal between the two electrodes and the potential noise signal between the electrode and the shell to obtain the damage degree information of the electrode surface coating.
为了实现上述目的,本发明的技术方案还包括:一种基于所述的测量装置的测试金属腐蚀速率的方法,包括如下步骤:In order to achieve the above object, the technical solution of the present invention also includes: a method for testing the metal corrosion rate based on the measuring device, comprising the following steps:
S1:将测量装置固定在待检测位置,通过测温元件测量传感器表面温度数据;S1: Fix the measuring device at the position to be detected and measure the surface temperature data of the sensor through the temperature measuring element;
S2:闭合多分区电阻测量模块,分别测量2个电极的局部电阻变化;分析电阻测量模块的数据,结合步骤S1的温度测量结果,计算各分区的金属腐蚀速率。S2: Close the multi-partition resistance measurement module to measure the local resistance changes of the two electrodes respectively; analyze the data of the resistance measurement module, and calculate the metal corrosion rate of each partition in combination with the temperature measurement result of step S1.
综上所述,本发明具有以下有益效果:In summary, the present invention has the following beneficial effects:
1、本发明采用电化学阻抗谱测量模块实时监测涂层内部渗水情况,结合电化学噪声模块采集涂层表面损伤信息,从而实现涂层损伤监测和风险预估。1. The present invention adopts an electrochemical impedance spectroscopy measurement module to monitor the water seepage inside the coating in real time, and combines it with an electrochemical noise module to collect coating surface damage information, thereby realizing coating damage monitoring and risk estimation.
2、本发明中优选采用多分区电阻测量模块监测电极之间各分区的局部电阻,并基于温度测量结果修正温度对阻值变化的影响,提高腐蚀速率计算结果的可靠性。2. In the present invention, a multi-partition resistance measurement module is preferably used to monitor the local resistance of each partition between electrodes, and the influence of temperature on the resistance change is corrected based on the temperature measurement result to improve the reliability of the corrosion rate calculation result.
本申请通过改进电极的形式,可以开展电化学阻抗的测试,能够更准确的判断涂层的渗水情况;同时结合了噪声信号的分析,可以通过电位和电流的噪声波动更早的预知涂层面临的破损风险,能更早的发现涂层老化的趋势,而不仅仅是单纯的发现涂层破损。By improving the form of the electrode, the present application can carry out electrochemical impedance testing, which can more accurately determine the water permeability of the coating; at the same time, combined with the analysis of noise signals, the risk of damage faced by the coating can be predicted earlier through the noise fluctuations of potential and current, and the aging trend of the coating can be discovered earlier, rather than simply discovering coating damage.
附图说明BRIEF DESCRIPTION OF THE DRAWINGS
为了更清楚地说明本发明实施例或现有技术中的技术方案,下面将对实施例或现有技术描述中所需要使用的附图作一简单地介绍,显而易见地,下面描述中的附图是本发明的一些实施例,对于本领域普通技术人员来讲,在不付出创造性劳动性的前提下,还可以根据这些附图获得其他的附图。In order to more clearly illustrate the embodiments of the present invention or the technical solutions in the prior art, the following briefly introduces the drawings required for use in the embodiments or the description of the prior art. Obviously, the drawings described below are some embodiments of the present invention. For ordinary technicians in this field, other drawings can be obtained based on these drawings without paying creative labor.
图1为本发明公开的测量装置的整体结构示意图;FIG1 is a schematic diagram of the overall structure of a measuring device disclosed in the present invention;
图2为本发明公开的测量装置中显示传感器内部结构的示意图;FIG2 is a schematic diagram showing the internal structure of a sensor in the measuring device disclosed in the present invention;
图3为本发明公开的传感器中显示2个电极之间位置关系的结构示意图;FIG3 is a schematic structural diagram showing the positional relationship between two electrodes in the sensor disclosed in the present invention;
图4为本发明公开电化学阻抗谱测量模块电气接线示意图;FIG4 is a schematic diagram of electrical wiring of an electrochemical impedance spectroscopy measurement module disclosed in the present invention;
图5为本发明公开电化学噪声模块电气接线示意图;FIG5 is a schematic diagram of electrical wiring of an electrochemical noise module disclosed in the present invention;
图6为本发明公开电阻测量模块电气接线示意图;FIG6 is a schematic diagram of electrical wiring of a resistance measurement module disclosed in the present invention;
图7为本发明实施例2公开测量方法步骤流程图;FIG7 is a flow chart of the steps of the measurement method disclosed in Example 2 of the present invention;
图8为本发明实施例3公开测量方法步骤流程图;FIG8 is a flow chart of the steps of the measurement method disclosed in Example 3 of the present invention;
图9为本发明实施例4公开测量方法步骤流程图;FIG9 is a flow chart of the steps of the measurement method disclosed in Example 4 of the present invention;
图10为本发明实施例5公开测量方法步骤流程图。FIG. 10 is a flow chart of the steps of the measurement method disclosed in Example 5 of the present invention.
图中:1、防水密封仓;2、传感器;21、壳体;22、电极;221、水平段;222、回折段;23、温度探头;24、填充胶;3、电化学检测系统;31、电化学阻抗谱测量模块;32、电化学噪声模块;33、多分区电阻测量模块;34、温度测量模块;35、电源模块;36、通讯模块;4、固定胶;5、水下电缆接头;6、固定挂耳;7、有机涂层;8、导线;9、导热硅胶垫。In the figure: 1. Waterproof sealing chamber; 2. Sensor; 21. Shell; 22. Electrode; 221. Horizontal section; 222. Folding section; 23. Temperature probe; 24. Filling glue; 3. Electrochemical detection system; 31. Electrochemical impedance spectroscopy measurement module; 32. Electrochemical noise module; 33. Multi-partition resistance measurement module; 34. Temperature measurement module; 35. Power module; 36. Communication module; 4. Fixing glue; 5. Underwater cable connector; 6. Fixing ear; 7. Organic coating; 8. Wire; 9. Thermal conductive silicone pad.
具体实施方式Detailed ways
为使本发明实施例的目的、技术方案和优点更加清楚,下面将结合本发明实施例中的附图1-10,对本发明实施例中的技术方案进行清楚、完整地描述,显然,所描述的实施例是本发明一部分实施例,而不是全部的实施例。基于本发明中的实施例,本领域普通技术人员在没有作出创造性劳动前提下所获得的所有其他实施例,都属于本发明保护的范围。In order to make the purpose, technical solution and advantages of the embodiments of the present invention clearer, the technical solution in the embodiments of the present invention will be clearly and completely described below in conjunction with Figures 1-10 in the embodiments of the present invention. Obviously, the described embodiments are part of the embodiments of the present invention, not all of the embodiments. Based on the embodiments of the present invention, all other embodiments obtained by ordinary technicians in this field without creative work are within the scope of protection of the present invention.
实施例1Example 1
结合图1和图2,一种监测涂层损伤程度和破损处腐蚀速率的测量装置,包括具有空腔的防水密封仓、传感器和电化学检测系统以及固定胶,传感器通过焊接的方式固定在防水密封仓外部,电化学检测系统通过固定胶固定在防水密封仓内部,防水密封仓的侧壁留有水下电缆接头。In conjunction with Figures 1 and 2, a measuring device for monitoring the degree of coating damage and the corrosion rate at the damaged part includes a waterproof sealed chamber with a cavity, a sensor, an electrochemical detection system, and a fixing glue. The sensor is fixed to the outside of the waterproof sealed chamber by welding, and the electrochemical detection system is fixed to the inside of the waterproof sealed chamber by fixing glue. An underwater cable connector is left on the side wall of the waterproof sealed chamber.
防水密封仓为具有上端开口的盒体,防水密封仓的开口处设置有盖板,盖板和防水密封仓本体之间采用螺栓连接。防水密封仓朝向钢结构的一侧焊接有固定挂耳,固定挂耳可以通过螺栓固定在钢结构的待检测位置上,实现对测量装置的固定和安装。The waterproof sealed chamber is a box body with an upper opening, a cover plate is provided at the opening of the waterproof sealed chamber, and the cover plate and the waterproof sealed chamber body are connected by bolts. A fixed hanging ear is welded on the side of the waterproof sealed chamber facing the steel structure, and the fixed hanging ear can be fixed to the position to be detected on the steel structure by bolts to achieve the fixation and installation of the measuring device.
结合图2和图3,传感器包括能够导电的壳体、2个电极、测温元件和填充胶,壳体为采用钛合金材质制成的具有一侧的开口的盒体,壳体采用焊接的方式固定在防水密封仓上,且壳体的开口端朝向待检测物。2 and 3 , the sensor includes a conductive shell, two electrodes, a temperature measuring element and a filling glue. The shell is a box body made of titanium alloy with an opening on one side. The shell is fixed on the waterproof sealing chamber by welding, and the open end of the shell faces the object to be detected.
2个电极均设置于壳体的开口端,且2个电极的材料与待检测物的材料一致,2个电极的上表面均涂有有机涂层,有机涂层通过利用刷涂或浸涂或喷涂或电泳涂覆或静电喷涂的方法将有机涂料或塑料涂敷在测量元件上,经固化后形成的有机涂层,从而模拟实际海洋结构物的表面涂层状态。The two electrodes are both arranged at the open end of the shell, and the materials of the two electrodes are consistent with the materials of the object to be detected. The upper surfaces of the two electrodes are coated with an organic coating. The organic coating is formed by applying an organic coating or plastic on the measuring element by brushing, dipping, spraying, electrophoretic coating or electrostatic spraying, and the organic coating is formed after curing, thereby simulating the surface coating state of an actual marine structure.
2个电极为尺寸大小完全相同,电极包括3个平行且间隔设置的水平段,相邻水平段之间设置有回折段,相邻水平段设置于同一回折段的同侧,相邻回折段设置于同一水平段的异侧,且相邻回折段之间的间隔等于对应水平段的长度,使得电极呈Z字型结构,2个电极均折叠呈Z字型布置在壳体的开口端,2个电极之间的距离等于电极端部和壳体内壁之间的距离,2个电极之间的距离不超过0.5mm,以保证较小的间距和较大的接触面积,能够增强电流测量信号。The two electrodes are exactly the same in size, and the electrodes include three parallel and spaced horizontal segments, a folded segment is arranged between adjacent horizontal segments, adjacent horizontal segments are arranged on the same side of the same folded segment, adjacent folded segments are arranged on opposite sides of the same horizontal segment, and the interval between adjacent folded segments is equal to the length of the corresponding horizontal segment, so that the electrode has a Z-shaped structure, the two electrodes are folded in a Z-shape and arranged at the open end of the shell, the distance between the two electrodes is equal to the distance between the electrode end and the inner wall of the shell, and the distance between the two electrodes does not exceed 0.5 mm, so as to ensure a smaller spacing and a larger contact area, and can enhance the current measurement signal.
2个电极和壳体底部分别连接有导线,2个电极的两端分别设置有导线,2个电极串联在一起,串联后电极的导线和壳体的导线分别延伸至防水密封仓的内部,并与防水密封仓内部的电化学检测系统相连。The two electrodes and the bottom of the shell are respectively connected with wires, and wires are respectively arranged at both ends of the two electrodes. The two electrodes are connected in series. After the series connection, the wires of the electrodes and the wires of the shell are respectively extended to the inside of the waterproof sealed chamber and connected to the electrochemical detection system inside the waterproof sealed chamber.
测温元件优选为温度探头,测温元件位于电极远离有机涂层的一侧,能够实时监测电极的温度变化。在测温元件和电极之间布设导热硅胶垫,实现测温元件和电极绝缘设置。填充胶填充于壳体的内部,填充胶优选为环氧树脂填充胶,固化后的环氧树脂填充胶实现对测温元件、导热硅胶垫和导线以及电极位置的定位。测温元件的下端也连接有导线,该导线向下延伸至壳体外部,测温元件能够进行热电转换,可将采集的温度信息转换成电信号,通过导线实现传输,便于对温度信息的采集。The temperature measuring element is preferably a temperature probe, and the temperature measuring element is located on the side of the electrode away from the organic coating, and can monitor the temperature change of the electrode in real time. A thermally conductive silicone pad is arranged between the temperature measuring element and the electrode to realize the insulation setting of the temperature measuring element and the electrode. The filling glue is filled in the interior of the shell, and the filling glue is preferably an epoxy resin filling glue. The cured epoxy resin filling glue realizes the positioning of the temperature measuring element, the thermally conductive silicone pad, the wire and the electrode. The lower end of the temperature measuring element is also connected to a wire, which extends downward to the outside of the shell. The temperature measuring element can perform thermoelectric conversion, and can convert the collected temperature information into an electrical signal, which is transmitted through the wire, so as to facilitate the collection of temperature information.
参照图3,电化学检测系统包括电化学阻抗谱测量模块、电化学噪声模块、多分区电阻测量模块、温度测量模块、电源模块以及通讯模块,温度测量模块和多分区电阻测量模块串联后与电化学阻抗谱测量模块、电化学噪声模块并联组成并联电路,该并联电路和电源模块以及通讯模块串联在一起组成串联电路,该串联电路和水下电缆接头连接在一起,实现对各模块的供电以及实现各模块采集信号向外传输。3 , the electrochemical detection system includes an electrochemical impedance spectroscopy measurement module, an electrochemical noise module, a multi-partition resistance measurement module, a temperature measurement module, a power supply module and a communication module. The temperature measurement module and the multi-partition resistance measurement module are connected in series with the electrochemical impedance spectroscopy measurement module and the electrochemical noise module to form a parallel circuit. The parallel circuit, the power supply module and the communication module are connected in series to form a series circuit. The series circuit is connected to an underwater cable connector to realize power supply to each module and to realize external transmission of collected signals from each module.
参照图4,电化学阻抗谱测量模块具有3个第一接线端口,3个第一接线端口分别记作WE、CE和RE1,每个第一接线端口处分别连接有第一继电器,3个第一继电器分别记作A1、A2和A3,其中WE通过A1与电极的一端通过导线连接,RE1通过A3与另一个电极通过导线连接,CE通过A2与壳体通过导线连接。4 , the electrochemical impedance spectroscopy measurement module has three first wiring ports, which are respectively denoted as WE, CE and RE 1 , and each first wiring port is respectively connected to a first relay, which are respectively denoted as A 1 , A 2 and A3 , wherein WE is connected to one end of the electrode through A 1 through a wire, RE 1 is connected to the other electrode through A 3 through a wire, and CE is connected to the shell through A 2 through a wire.
参照图5,电化学噪声模块具有3个第二接线端口,3个第二接线端口分别记作WE1、RE2和WE2,每个第二接线端口处分别连接有第二继电器,3个第二继电器分别记作B1、B2和B3,其中WE1通过B1与电极的一端通过导线连接,WE2通过B3与另一个电极通过导线连接,RE2通过B2与壳体通过导线连接。Referring to Figure 5, the electrochemical noise module has three second wiring ports, which are respectively denoted as WE 1 , RE 2 and WE 2. Each second wiring port is connected to a second relay, which are respectively denoted as B 1 , B 2 and B 3. WE 1 is connected to one end of the electrode through a wire through B 1 , WE 2 is connected to the other electrode through a wire through B 3 , and RE 2 is connected to the shell through B 2 through a wire.
参照图6,多分区电阻测量模块具有4个外部接口,4个外部接口中包括2个电流接口和2个电压接口,2个电流接口分别记作I+和I-;2个电压接口分别记作U+和U-。电流接口和电压接口相互间隔设置。每个外部接口分别连接有第三继电器,4个第三继电器分别记作G1、G2、G3和G4。6, the multi-partition resistance measurement module has 4 external interfaces, including 2 current interfaces and 2 voltage interfaces, the 2 current interfaces are respectively denoted as I + and I- ; the 2 voltage interfaces are respectively denoted as U + and U- . The current interface and the voltage interface are arranged at intervals from each other. Each external interface is respectively connected to a third relay, and the 4 third relays are respectively denoted as G1 , G2 , G3 and G4 .
2个电极上均匀分布有多个导电触点,多个导电触点将电极表面均分为多个分区,本申请实施例以每个电极上设置17个分区为例,两个电极上分别均匀分布有34个接线柱,其中包括17个电流接线柱和17个电压接线柱,且电流接线柱和电压接线柱互相间隔设置。其中一个电极上的17个电流接线柱分别记作C1-17,17个电压接线柱分别记作D1-17,电流接线柱C1-17并联后通过G1和I+连接,电压接线柱D1-17并联后通过G2和U+连接;另一个电极上的17个电流接线柱分别记作E1-17,17个电压接线柱分别记作F1-17,电流接线柱E1-17并联后通过G4和I-连接,电压接线柱F1-17并联后通过G3和U-连接。There are multiple conductive contacts evenly distributed on the two electrodes, and the multiple conductive contacts divide the electrode surface into multiple partitions. In the embodiment of the present application, 17 partitions are set on each electrode as an example. There are 34 terminals evenly distributed on the two electrodes, including 17 current terminals and 17 voltage terminals, and the current terminals and voltage terminals are arranged at intervals. The 17 current terminals on one electrode are respectively recorded as C 1-17 , and the 17 voltage terminals are respectively recorded as D 1-17 . The current terminals C 1-17 are connected in parallel through G1 and I + , and the voltage terminals D 1-17 are connected in parallel through G 2 and U + ; the 17 current terminals on the other electrode are respectively recorded as E1-17, and the 17 voltage terminals are respectively recorded as F1-17. The current terminals E1-17 are connected in parallel through G4 and I-, and the voltage terminals F 1-17 are connected in parallel through G 3 and U - .
实施例2Example 2
参照图7,一种基于本申请实施例1公开的测量装置测试涂层内部渗水情况的方法,包括如下步骤:7 , a method for testing water seepage inside a coating using the measuring device disclosed in Example 1 of the present application includes the following steps:
S1:将测量装置固定在待检测位置,闭合第一继电器A1-3,通过电化学阻抗谱测量模块EIS测量不同频率下传感器的阻抗,绘制阻抗谱图;S1: fix the measuring device at the position to be detected, close the first relay A 1-3 , measure the impedance of the sensor at different frequencies through the electrochemical impedance spectroscopy measurement module EIS, and draw an impedance spectrum;
S2:完整涂层体系的电化学阻抗谱的虚部(-ZIm)计算公式如下:S2: The imaginary part (-Z Im ) of the electrochemical impedance spectrum of the complete coating system is calculated as follows:
式中,f为输入信号频率,Rc为涂层电阻,Cc为涂层电容。当测试频率f足够高时,可以简化如下公式Where f is the input signal frequency, R c is the coating resistance, and C c is the coating capacitance. When the test frequency f is high enough, the following formula can be simplified:
由于随着水渗透进涂层,涂层的介电常数会发生变化,可以计算出2个电极之间t时刻的水渗透率,公式如下:Since the dielectric constant of the coating changes as water penetrates into it, the water permeability between the two electrodes at time t can be calculated as follows:
式中,εt为t时刻的介电常数,εm为涂层有机聚合物的介电常数,εw为水介电常数,φs表示饱和状态下涂层的水渗透率,φt表示t时刻的水涂层的渗透率。In the formula, εt is the dielectric constant at time t, εm is the dielectric constant of the organic polymer of the coating, εw is the dielectric constant of water, φs represents the water permeability of the coating under saturation state, and φt represents the permeability of the water coating at time t.
涂层电容可以表示为: The coating capacitance can be expressed as:
则水渗透率表示为:式中,Ct是t时刻测量的涂层电容,C0是初始时刻的涂层电容。The water permeability is expressed as: Where Ct is the coating capacitance measured at time t, and C0 is the coating capacitance at the initial time.
实施例3Example 3
参照图8,一种基于本申请实施例1公开的测量装置测试涂层的损伤程度的方法,包括如下步骤:8 , a method for testing the degree of damage of a coating based on the measuring device disclosed in Example 1 of the present application comprises the following steps:
S1:将测量装置固定在待检测位置,闭合第二继电器B1-3,控制电化学噪声模块EN进行测量,监测两个电极WE1和WE2之间的电流噪声信号,监测WE1和壳体之间的电位噪声信号。S1: Fix the measuring device at the position to be detected, close the second relay B1-3 , control the electrochemical noise module EN to measure, monitor the current noise signal between the two electrodes WE1 and WE2 , and monitor the potential noise signal between WE1 and the housing.
S2:采用3次多项式拟合法消除噪声信号的直流偏移量;S2: Use the third-order polynomial fitting method to eliminate the DC offset of the noise signal;
S3:基于处理后的数据,计算电位和电流的方差;S3: Based on the processed data, the variance of the potential and current is calculated;
其中m为数据点总个数,Vi,Ii为第i个数据点的电压、电流值,和为电压、电流的平均值Where m is the total number of data points, Vi and Ii are the voltage and current values of the ith data point, and is the average value of voltage and current
S4:通过电位和电流的方差判断涂层表面状态的稳定性,评价涂层发生破损的趋势。S4: The stability of the coating surface state is determined by the variance of potential and current, and the tendency of coating damage is evaluated.
实施例4Example 4
参照图9,一种基于本申请实施例1公开的测量装置测试涂层金属腐蚀速率的方法,包括如下步骤:9 , a method for testing the metal corrosion rate of a coating based on the measuring device disclosed in Example 1 of the present application comprises the following steps:
S1:将测量装置固定在待检测位置,通过测温元件测量传感器表面温度数据,得到待测金属电阻电阻率随温度的变化曲线;S1: Fix the measuring device at the position to be tested, measure the surface temperature data of the sensor through the temperature measuring element, and obtain the change curve of the resistivity of the metal resistor to be tested with temperature;
S2:闭合第三继电器G1-4,通过依次闭合C1-17,和D1-17分别测量电极上分区1-17的局部电阻变化,并记录测量时的温度T0;S2: close the third relay G 1-4 , measure the local resistance change of the subareas 1-17 on the electrode by closing C 1-17 and D 1-17 in sequence, and record the temperature T 0 during the measurement;
然后通过依次闭合E1-17和F1-17测量另一个电极的电极上分区1-17的局部电阻变化,并记录测量时的温度T0;Then, the local resistance change of the subarea 1-17 on the electrode of the other electrode is measured by closing E 1-17 and F 1-17 in sequence, and the temperature T 0 during the measurement is recorded;
以1区RC1D1为例,采用如下公式计算:Taking Zone 1 R C1D1 as an example, the following formula is used for calculation:
式中,a为横截面宽度,d为横截面高度,L为C1D1间距;Where a is the cross-sectional width, d is the cross-sectional height, and L is the spacing between C 1 and D 1 ;
对于第n次测量的电阻, For the nth measured resistance,
根据温度探头得到的实际温度Tn,根据阻值随温度的变化曲线,将电阻修正为T0温度下的电阻:According to the actual temperature Tn obtained by the temperature probe and the resistance-temperature curve, the resistance is corrected to the resistance at T0 :
其中k为Tn时刻相对于T0时刻的电阻率变化系数;Where k is the resistivity variation coefficient at time T n relative to time T 0 ;
分析电阻测量模块的数据,结合步骤S1的温度测量结果,计算各分区的金属腐蚀速率;Analyze the data of the resistance measurement module, and calculate the metal corrosion rate of each partition in combination with the temperature measurement result of step S1;
腐蚀深度为:ΔdC1D1,n=dC1D1,0-dC1D1,n;The corrosion depth is: Δd C1D1,n = d C1D1,0 - d C1D1,n ;
腐蚀速率表示为(△t为测量周期): The corrosion rate is expressed as (△t is the measurement period):
实施例5Example 5
参照图10,一种基于本申请实施例1公开的测量装置监测涂层损伤程度和破损处金属腐蚀速率的测量方法,包括如下步骤:10 , a method for measuring the degree of coating damage and the metal corrosion rate at the damaged part based on the measuring device disclosed in Example 1 of the present application comprises the following steps:
S1:将测量装置固定在待检测位置;S1: Fix the measuring device at the position to be tested;
S2:断开处于开启状态的温度探头,开启第一继电器A1-3,控制电化学阻抗谱测量模块EIS进行测量并对获得的数据进行分析,通过计算2个电极之间的电容来分析涂层内部渗水情况;S2: disconnect the temperature probe in the on state, turn on the first relay A 1-3 , control the electrochemical impedance spectroscopy measurement module EIS to measure and analyze the obtained data, and analyze the water seepage inside the coating by calculating the capacitance between the two electrodes;
S3:断开第一继电器A1-3,开启第二继电器B1-3,控制电化学噪声模块EN进行测量并对获得的数据进行分析,分析2个电极之间电流噪声信号和电极与壳体之间的电位噪声信号得到电极表面涂层的损伤程度信息;S3: disconnect the first relay A 1-3 , open the second relay B 1-3 , control the electrochemical noise module EN to measure and analyze the acquired data, analyze the current noise signal between the two electrodes and the potential noise signal between the electrode and the shell to obtain the damage degree information of the electrode surface coating;
S4:断开第一继电器A1-3和第二继电器B1-3,开启温度探头,通过测温元件测量传感器表面温度数据;S4: disconnect the first relay A 1-3 and the second relay B 1-3 , turn on the temperature probe, and measure the sensor surface temperature data through the temperature measuring element;
S5:测量温度数据后闭合第三继电器G1-4,通过依次闭合C1-17和D1-17分别测量电极上分区1-17的局部电阻变化;S5: After measuring the temperature data, close the third relay G 1-4 , and measure the local resistance change of the subareas 1-17 on the electrode by closing C 1-17 and D 1-17 in sequence;
然后断开C1-17和D1-17,依次闭合E1-17和F1-17测量另一个电极的电极上分区1-17的局部电阻变化;Then, disconnect C 1-17 and D 1-17 , and close E 1-17 and F 1-17 in sequence to measure the local resistance change of the subarea 1-17 on the electrode of the other electrode;
最后分析ER数据,结合温度测量结果,得到金属局部腐蚀速率。Finally, the ER data is analyzed and combined with the temperature measurement results to obtain the local corrosion rate of the metal.
综上,本发明采用电化学阻抗谱测量模块评估涂层内部渗水情况,结合电化学噪声模块采集电极表面涂层损伤信息,从而实现涂层破损风险预估。同时采用温度测量模块和多分区电阻测量模块,基于温度测量数据修正电极分区阻值,从而计算出破损涂层处的金属腐蚀速率。通过二者结合,本发明不仅能够实现涂层破损状态监测,还能提前预支涂层面临的破损风险。In summary, the present invention uses an electrochemical impedance spectroscopy measurement module to evaluate the water seepage inside the coating, and combines the electrochemical noise module to collect the coating damage information on the electrode surface, so as to realize the estimation of the coating damage risk. At the same time, a temperature measurement module and a multi-partition resistance measurement module are used to correct the electrode partition resistance based on the temperature measurement data, so as to calculate the metal corrosion rate at the damaged coating. Through the combination of the two, the present invention can not only realize the coating damage status monitoring, but also anticipate the damage risk faced by the coating in advance.
最后应说明的是:以上各实施例仅用以说明本发明的技术方案,而非对其限制;尽管参照前述各实施例对本发明进行了详细的说明,本领域的普通技术人员应当理解:其依然可以对前述各实施例所记载的技术方案进行修改,或者对其中部分或者全部技术特征进行等同替换;而这些修改或者替换,并不使相应技术方案的本质脱离本发明各实施例技术方案的范围。Finally, it should be noted that the above embodiments are only used to illustrate the technical solutions of the present invention, rather than to limit it. Although the present invention has been described in detail with reference to the aforementioned embodiments, those skilled in the art should understand that they can still modify the technical solutions described in the aforementioned embodiments, or replace some or all of the technical features therein by equivalents. However, these modifications or replacements do not make the essence of the corresponding technical solutions deviate from the scope of the technical solutions of the embodiments of the present invention.
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