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CN115520953A - Coal chemical industry advanced wastewater treatment CoSD reaction tower - Google Patents

Coal chemical industry advanced wastewater treatment CoSD reaction tower Download PDF

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Publication number
CN115520953A
CN115520953A CN202210752389.XA CN202210752389A CN115520953A CN 115520953 A CN115520953 A CN 115520953A CN 202210752389 A CN202210752389 A CN 202210752389A CN 115520953 A CN115520953 A CN 115520953A
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pipe
ozone
cosd
coal chemical
chemical industry
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CN115520953B (en
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胡长龙
孙宇
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Hubei Jinkong Gas Co ltd
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    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/72Treatment of water, waste water, or sewage by oxidation
    • C02F1/78Treatment of water, waste water, or sewage by oxidation with ozone
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/008Control or steering systems not provided for elsewhere in subclass C02F
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/72Treatment of water, waste water, or sewage by oxidation
    • C02F1/725Treatment of water, waste water, or sewage by oxidation by catalytic oxidation
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2103/00Nature of the water, waste water, sewage or sludge to be treated
    • C02F2103/34Nature of the water, waste water, sewage or sludge to be treated from industrial activities not provided for in groups C02F2103/12 - C02F2103/32
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2201/00Apparatus for treatment of water, waste water or sewage
    • C02F2201/002Construction details of the apparatus
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2209/00Controlling or monitoring parameters in water treatment
    • C02F2209/23O3

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Hydrology & Water Resources (AREA)
  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Treatment Of Water By Oxidation Or Reduction (AREA)

Abstract

The invention relates to the technical field of coal chemical industry wastewater treatment, in particular to a CoSD reaction tower for advanced treatment of coal chemical industry wastewater; a tower body; one end of the ozone pipe is communicated with the bottom of the tower body; the feeding pipe is positioned on one side far away from the tower body, and an opening at the bottom of the feeding pipe is communicated with the outer wall of the ozone pipe; the ozone booster pump is positioned on one side far away from the tower body, and a first air inlet of the ozone booster pump is communicated with the other end of the ozone pipe; the ozone generator is positioned at one side close to the ozone booster pump; a feeding unit positioned in the feeding pipe and used for controlling the feeding of the catalyst; according to the invention, the ozone and the ozone catalyst are mixed into the wastewater, so that the ozone and the ozone catalyst are fully mixed, the reaction efficiency of the ozone and the wastewater is improved, and the ozone-wastewater mixed reactor has the characteristics of high efficiency, convenience in operation, economy and practicability.

Description

一种煤化工废水深度处理CoSD反应塔CoSD reaction tower for advanced treatment of coal chemical wastewater

技术领域technical field

本发明涉及煤化工废水处理技术领域,具体说是一种煤化工废水深度处理CoSD反应塔。The invention relates to the technical field of coal chemical wastewater treatment, in particular to a CoSD reaction tower for advanced treatment of coal chemical wastewater.

背景技术Background technique

煤化工废水以高浓度煤气洗涤废水为主,其中含酚类、烷烃类,芳香烃类、氰等有毒有害物质。其中,煤化工废水处理的主要工作流程为预处理-生化处理-深度处理。Coal chemical industry wastewater is mainly high-concentration coal gas washing wastewater, which contains toxic and harmful substances such as phenols, alkanes, aromatic hydrocarbons, and cyanide. Among them, the main workflow of coal chemical wastewater treatment is pretreatment-biochemical treatment-advanced treatment.

煤化工废水中有机物的处理是一个极为复杂且难以处理的过程,因此需要对废水深度处理才能减少废水中的有机物,同时在深度处理过程中臭氧催化氧化技术比臭氧氧化技术处理效果更好。煤化工废水在反应塔中处理保证臭氧催化氧化技术的处理效果良好,需在臭氧与臭氧催化剂混合均匀的前提下,否则臭氧在受到臭氧催化剂催化前便于废水反应,降低了臭氧的利用率。The treatment of organic matter in coal chemical wastewater is an extremely complex and difficult process. Therefore, advanced treatment of wastewater is required to reduce organic matter in wastewater. At the same time, ozone catalytic oxidation technology is better than ozone oxidation technology in the process of advanced treatment. Coal chemical wastewater is treated in the reaction tower to ensure that the ozone catalytic oxidation technology has a good treatment effect. It is necessary to mix the ozone and the ozone catalyst evenly, otherwise the ozone will facilitate the reaction of the wastewater before being catalyzed by the ozone catalyst, which will reduce the utilization rate of the ozone.

现有技术中的煤化工废水深度处理方案中使用臭氧催化氧化技术,臭氧催化氧化相比于臭氧氧化具有更好的处理效果,是煤化工废水深度处理中的优选技术。但是现有技术中需将臭氧催化剂在通入臭氧前一次性从塔体外壁上方侧壁投入,而无法持续添加,否则在臭氧与废水反应时添加臭氧催化剂会导致塔体内未反应的臭氧会从臭氧催化剂投料口进入,同时臭氧催化剂进入塔体后会逐渐在水底堆积,均会造成臭氧催化剂在塔体内分布不均匀,因此臭氧与臭氧催化剂之间的混合不均匀,从而使臭氧在臭氧催化剂对臭氧催化之前便与废水反应,造成臭氧利用率过低,因此增加了臭氧催化氧化时的使用成本和废水处理时长。Ozone catalytic oxidation technology is used in the advanced treatment scheme of coal chemical industry wastewater in the prior art. Compared with ozone oxidation, ozone catalytic oxidation has a better treatment effect and is the preferred technology in the advanced treatment of coal chemical industry wastewater. However, in the prior art, the ozone catalyst needs to be put into the side wall above the outer wall of the tower at one time before the ozone is introduced, and cannot be continuously added, otherwise the addition of the ozone catalyst when the ozone reacts with the wastewater will cause the unreacted ozone in the tower to be discharged from the tower. The ozone catalyst enters the feeding port, and at the same time, the ozone catalyst will gradually accumulate at the bottom of the water after entering the tower body, which will cause uneven distribution of the ozone catalyst in the tower body, so the mixing between the ozone and the ozone catalyst is uneven, so that the ozone is in the ozone catalyst. Before ozone is catalyzed, it reacts with wastewater, resulting in low ozone utilization rate, which increases the cost of ozone catalytic oxidation and the duration of wastewater treatment.

鉴于此,为了克服上述技术问题,本发明提出了一种煤化工废水深度处理CoSD反应塔,解决了上述技术问题。In view of this, in order to overcome the above technical problems, the present invention proposes a CoSD reaction tower for the advanced treatment of coal chemical wastewater, which solves the above technical problems.

发明内容Contents of the invention

为了弥补现有技术的不足,本发明提出了一种煤化工废水深度处理CoSD反应塔,通过加强臭氧与臭氧催化剂在废水中的混合,从而提高臭氧的利用率,使得本发明具有高效、操作便捷和经济实用的特点。In order to make up for the deficiencies in the prior art, the present invention proposes a CoSD reaction tower for the advanced treatment of coal chemical wastewater. By strengthening the mixing of ozone and ozone catalyst in the wastewater, the utilization rate of ozone is improved, so that the present invention has high efficiency and convenient operation. And economical and practical features.

本发明解决其技术问题所采用的技术方案是:本发明所述的一种煤化工废水深度处理CoSD反应塔,包括:The technical solution adopted by the present invention to solve the technical problem is: a CoSD reaction tower for the advanced treatment of coal chemical wastewater according to the present invention, comprising:

塔体;Tower body;

臭氧管,所述臭氧管的一端与所述塔体的底部连通;Ozone tube, one end of the ozone tube communicates with the bottom of the tower body;

进料管,所述进料管位于远离所述塔体的一侧且所述进料管底部的开口与所述臭氧管外壁连通;A feed pipe, the feed pipe is located on a side away from the tower body and the opening at the bottom of the feed pipe communicates with the outer wall of the ozone pipe;

臭氧增压泵,所述臭氧增压泵位于远离所述塔体的一侧,所述臭氧增压泵的一号进气口与所述臭氧管另一端连通;An ozone booster pump, the ozone booster pump is located on a side away from the tower body, and the No. 1 air inlet of the ozone booster pump communicates with the other end of the ozone tube;

臭氧发生器,所述臭氧发生器位于靠近所述臭氧增压泵的一侧,所述臭氧发生器的三号出气口与所述臭氧增压泵的一号进气口连通;An ozone generator, the ozone generator is located on a side close to the ozone booster pump, and the No. 3 gas outlet of the ozone generator communicates with the No. 1 air inlet of the ozone booster pump;

进料单元,所述进料单元位于所述进料管内,用于控制催化剂的进料。A feeding unit, which is located in the feeding pipe, is used to control the feeding of the catalyst.

优选的,所述进料单元包括电机、电动推杆、单向阀、进料口、活塞,所述电机位于所述进料管顶部,所述电机用于驱动所述电动推杆,所述电动推杆位于所述进料管内部,所述电动推杆的一端固连有所述活塞,所述活塞与所述进料管内壁滑动连接,所述单向阀位于所述进料管的下端开口,所述进料口与所述进料管上部外壁连通。Preferably, the feed unit includes a motor, an electric push rod, a one-way valve, a feed port, and a piston, the motor is located at the top of the feed pipe, and the motor is used to drive the electric push rod. The electric push rod is located inside the feed pipe, one end of the electric push rod is fixedly connected with the piston, and the piston is slidably connected with the inner wall of the feed pipe, and the one-way valve is located at the end of the feed pipe. The lower end is open, and the feed port communicates with the upper outer wall of the feed pipe.

优选的,所述进料单元包括气泵、进料盖、单向阀;所述气泵位于所述塔体与所述进料管之间且所述气泵的二号出气管与所述进料管侧壁连通,所述进料盖与所述进料管顶部连接,用于控制所述气管内气体流通。Preferably, the feed unit includes an air pump, a feed cover, and a one-way valve; the air pump is located between the tower body and the feed pipe, and the second outlet pipe of the air pump is connected to the feed pipe The side wall is in communication, and the feeding cap is connected with the top of the feeding pipe for controlling gas circulation in the air pipe.

优选的,所述进料管的侧壁连通有气管的一端,所述气管的另一端与所述臭氧管连通,所述气管内设有控制阀,所述进料管内壁安装有臭氧检测器。Preferably, one end of the air pipe is communicated with the side wall of the feed pipe, the other end of the air pipe is connected with the ozone pipe, a control valve is arranged in the air pipe, and an ozone detector is installed on the inner wall of the feed pipe .

优选的,所述气泵的二号出气口与所述塔体外壁通过出气管连通,所述进料盖上安装有真空泄压阀。Preferably, the No. 2 gas outlet of the gas pump communicates with the outer wall of the tower through a gas outlet pipe, and a vacuum relief valve is installed on the feed cover.

优选的,所述塔体内部的底面中心位置设有进气管,所述进气管与所述臭氧管的一端连通,所述进气管外壁连通有多个曝气管,所述进气管底部的外壁固连多个排料管,且所述排料管与所述进气管内部连通,所述进气管下部的内壁固连有过滤网,所述过滤网用于过滤催化剂,防止所述催化剂堵住所述曝气管。Preferably, an air intake pipe is provided at the center of the bottom surface inside the tower, and the air intake pipe communicates with one end of the ozone pipe. A plurality of discharge pipes are fixedly connected, and the discharge pipe communicates with the inside of the intake pipe, and a filter screen is fixedly connected to the inner wall of the lower part of the intake pipe, and the filter screen is used to filter the catalyst to prevent the catalyst from being blocked The aeration tube.

优选的,所述过滤网底部端面中心位置向下鼓起。Preferably, the center of the bottom end surface of the filter screen bulges downwards.

优选的,所述排料管开口方向斜向上。Preferably, the opening direction of the discharge pipe is obliquely upward.

优选的,所述进气管上包括多个转动管和多个固定管,多个所述固定管通过多个U型杆固连,所述转动管位于所述两个固定管之间,所述转动管与所述固定管的下端面设有环形T型槽,所述转动管与所述固定管的上端面设有环形T型块,所述环形T型块与相近的所述环形T型槽转动密封连接。Preferably, the intake pipe includes a plurality of rotating pipes and a plurality of fixed pipes, the plurality of fixed pipes are fixedly connected by a plurality of U-shaped rods, the rotating pipe is located between the two fixed pipes, the The lower end surfaces of the rotating tube and the fixed tube are provided with an annular T-shaped groove, and the upper end surfaces of the rotating tube and the fixed tube are provided with an annular T-shaped block, and the annular T-shaped block and the adjacent annular T-shaped block Groove rotary seal connection.

优选的,所述转动管内壁固连有多个扇叶,所述曝气管位于所述转动管的外壁。Preferably, a plurality of fan blades are fixedly connected to the inner wall of the rotating tube, and the aeration tube is located on the outer wall of the rotating tube.

本发明的有益效果如下:The beneficial effects of the present invention are as follows:

1.本发明通过将臭氧与臭氧催化剂混合进入废水中,保证了臭氧与臭氧催化剂的充分混合,提高了臭氧与废水的反应效率,使得本发明具有高效、操作便捷和经济实用的特点。1. The present invention ensures the sufficient mixing of ozone and ozone catalyst by mixing ozone and ozone catalyst into wastewater, improves the reaction efficiency of ozone and wastewater, and makes the present invention have the characteristics of high efficiency, convenient operation and economical and practical.

2.本发明通过臭氧催化剂受到加压臭氧气体向上的力从排料口排出,臭氧催化剂受到加压臭氧气体的作用在废水中将持续向上移动,同时进气管中的旋转管旋转带动曝气管在废水中旋转,曝气管旋转时会搅拌废水,带动废水在塔体内运动,而且曝气管产生的臭氧气泡稍微带动臭氧催化剂的运动,因此臭氧催化剂会打破废水中的臭氧气泡,使臭氧催化剂与臭氧混合均匀,增加了臭氧的利用率,使臭氧与废水反应更充分。2. In the present invention, the ozone catalyst is discharged from the discharge port by the upward force of the pressurized ozone gas. The ozone catalyst will continue to move upward in the waste water under the action of the pressurized ozone gas. At the same time, the rotating pipe in the intake pipe rotates to drive the aeration pipe Rotating in the wastewater, the aeration tube will stir the wastewater when it rotates, driving the wastewater to move in the tower body, and the ozone bubbles generated by the aeration tube will slightly drive the movement of the ozone catalyst, so the ozone catalyst will break the ozone bubbles in the wastewater and make the ozone catalyst Mix evenly with ozone, increase the utilization rate of ozone, make ozone and wastewater react more fully.

3.本发明中通过进料管中的进料单元控制臭氧催化剂进入臭氧管与臭氧混合,同时进一步利用臭氧气体的利用率,使臭氧推动臭氧催化剂从进料管内排出,减少了额外的动力源。3. In the present invention, the feed unit in the feed pipe controls the ozone catalyst to enter the ozone pipe and mix with the ozone, and at the same time further utilizes the utilization rate of the ozone gas to make the ozone push the ozone catalyst to be discharged from the feed pipe, reducing the additional power source .

附图说明Description of drawings

下面结合附图和实施方式对本发明进一步说明。The present invention will be further described below in conjunction with the accompanying drawings and embodiments.

图1是本发明的立体图;Fig. 1 is a perspective view of the present invention;

图2是图1中一种实施方式的剖视图;Fig. 2 is a sectional view of an embodiment in Fig. 1;

图3是图1中另一种实施方式的剖视图;Fig. 3 is a sectional view of another embodiment in Fig. 1;

图4是图2中C处的局部放大图;Fig. 4 is a partial enlarged view of place C in Fig. 2;

图5是图6中B-B处的局部剖视图;Fig. 5 is a partial sectional view at B-B place among Fig. 6;

图6是图2中A处的局部放大图;Fig. 6 is a partial enlarged view of place A in Fig. 2;

图中:1、塔体;2、臭氧管;21、臭氧增压泵;211、一号出气口;212、一号进气口;22、臭氧发生器;221、三号出气口;3、进料管;31、进料单元;311、电机;312、电动推杆;313、单向阀;314、进料口;315、活塞;321、气泵;322、进料盖;323、臭氧检测器;324、真空泄压阀;325、二号进气口;326、二号出气口;327、出气管;33、气管;331、控制阀;4、进气管;41、曝气管;42、过滤网;43、排料管;44、转动管;45、固定管;46、扇叶;47、环形T型块;48、U型杆;49、环形T型槽;5、进水口。In the figure: 1. Tower body; 2. Ozone tube; 21. Ozone booster pump; 211. No. 1 gas outlet; 212. No. 1 air inlet; 22. Ozone generator; 221. No. 3 gas outlet; 3. Feed pipe; 31, feed unit; 311, motor; 312, electric push rod; 313, one-way valve; 314, feed port; 315, piston; 321, air pump; 322, feed cover; 323, ozone detection 324, vacuum relief valve; 325, No. 2 air inlet; 326, No. 2 air outlet; 327, outlet pipe; 33, air pipe; 331, control valve; 4, air inlet pipe; 41, aeration pipe; 42 , filter screen; 43, discharge pipe; 44, rotating pipe; 45, fixed pipe; 46, fan blade; 47, annular T-shaped block; 48, U-shaped bar; 49, annular T-shaped groove; 5, water inlet.

具体实施方式detailed description

为了使本发明实现的技术手段、创作特征、达成目的与功效易于明白了解,下面结合,具体实施方式,进一步阐述本发明。In order to make the technical means, creative features, goals and effects achieved by the present invention easy to understand, the following will further elaborate the present invention in combination with specific implementation methods.

如图1至图6所示;As shown in Figure 1 to Figure 6;

实施例1;Embodiment 1;

一种煤化工废水深度处理CoSD反应塔,包括:A CoSD reaction tower for advanced treatment of coal chemical wastewater, comprising:

塔体1;tower body 1;

臭氧管2,所述臭氧管2的一端与所述塔体1的底部连通;Ozone tube 2, one end of the ozone tube 2 communicates with the bottom of the tower body 1;

进料管3,所述进料管3位于远离所述塔体1的一侧且所述进料管3底部的开口与所述臭氧管2外壁连通;Feed pipe 3, the feed pipe 3 is located on the side away from the tower body 1 and the opening at the bottom of the feed pipe 3 communicates with the outer wall of the ozone pipe 2;

臭氧增压泵21,所述臭氧增压泵21位于远离所述塔体1的一侧,所述臭氧增压泵21的一号进气口212与所述臭氧管2另一端连通;An ozone booster pump 21, the ozone booster pump 21 is located on a side away from the tower body 1, and the No. 1 air inlet 212 of the ozone booster pump 21 communicates with the other end of the ozone tube 2;

臭氧发生器22,所述臭氧发生器22位于靠近所述臭氧增压泵21的一侧,所述臭氧发生器22的三号出气口221与所述臭氧增压泵21的一号进气口212连通;Ozone generator 22, described ozone generator 22 is positioned at the side close to described ozone booster pump 21, No. 3 gas outlet 221 of described ozone generator 22 and No. 1 air inlet of described ozone booster pump 21 212 connected;

进料单元31,所述进料单元31位于所述进料管3内,用于控制催化剂的进料。The feeding unit 31, which is located in the feeding pipe 3, is used to control the feeding of the catalyst.

工作时,现有技术中的煤化工废水深度处理方案中使用臭氧催化氧化技术,臭氧催化氧化相比于臭氧氧化具有更好的处理效果,煤化工废水深度处理中的优选技术。但是现有技术中需将臭氧催化剂在通入臭氧前一次性从塔体外壁上方侧壁投入,而无法持续添加,同时臭氧催化剂进入塔体后会逐渐在水底堆积,均会造成臭氧催化剂在塔体内分布不均匀,因此臭氧与臭氧催化剂之间的混合不均匀,从而使臭氧在臭氧催化剂对臭氧催化之前便与废水反应,造成臭氧利用率过低,因此增加了臭氧催化氧化时的使用成本和废水处理时长。When working, ozone catalytic oxidation technology is used in the advanced treatment scheme of coal chemical industry wastewater in the prior art. Compared with ozone oxidation, ozone catalytic oxidation has better treatment effect, and it is the preferred technology in the advanced treatment of coal chemical industry wastewater. However, in the prior art, the ozone catalyst needs to be put into the side wall above the outer wall of the tower at one time before the ozone is introduced, and cannot be continuously added. At the same time, the ozone catalyst will gradually accumulate at the bottom of the water after entering the tower body, which will cause the ozone catalyst The distribution in the body is uneven, so the mixing between ozone and the ozone catalyst is uneven, so that the ozone reacts with the wastewater before the ozone catalyst catalyzes the ozone, resulting in low ozone utilization rate, thus increasing the use cost and cost of ozone catalytic oxidation. Wastewater treatment time.

因此本工作发明人员将废水通入从进水口5塔体1内,再将臭氧发生器22打开提供臭氧,臭氧通过臭氧增压泵21进入臭氧管2,同时进料管3内部的臭氧催化剂在进料单元31的作用下进入臭氧管2,臭氧带着臭氧催化剂一同进入进气管4,催化剂和一部分臭氧从排料口进入塔体1与废水反应,另一部分臭氧在进气管4内部流通并从曝气管41排出,而臭氧在废水中的气泡直径过大,与水的接触面积很小,同时臭氧催化剂由于受到加压臭氧气体向上的力从排料口排出且持续向上移动,使臭氧催化剂打破臭氧气泡,增加臭氧与废水的接触面积,同时臭氧催化剂催化臭氧加速臭氧与废水之间的反应,而且臭氧在进气管4内部流通时,经过臭氧增压泵21增压的臭氧带动转动管44内壁固连的扇叶46进行转动,从而扇叶46带动转动管44使曝气管41在废水内转动,因此曝气管能够在废水中搅拌,同时曝气管41喷出的臭氧气体也可以带动废水在塔体1内的运动,因此废水在塔体1内不断运动会带动排料管43排出的臭氧催化剂一起运动,所以臭氧催化剂不断在废水中运动,使得臭氧与臭氧催化剂接触面积更大,进一步提高了废水处理的效果。Therefore this work inventor feeds waste water in the tower body 1 from water inlet 5, then opens ozone generator 22 to provide ozone, and ozone enters ozone pipe 2 by ozone booster pump 21, and the ozone catalyst inside feed pipe 3 is in simultaneously Under the action of the feed unit 31, it enters the ozone pipe 2, and the ozone enters the inlet pipe 4 together with the ozone catalyst. The catalyst and a part of the ozone enter the tower body 1 from the discharge port to react with the waste water, and the other part of the ozone circulates inside the inlet pipe 4 and flows from the The aeration pipe 41 is discharged, and the bubble diameter of the ozone in the waste water is too large, and the contact area with the water is very small. Break the ozone bubbles, increase the contact area between ozone and wastewater, and at the same time, the ozone catalyst catalyzes the reaction between ozone and wastewater, and when the ozone circulates inside the intake pipe 4, the ozone boosted by the ozone booster pump 21 drives the rotating pipe 44 The fan blade 46 fixed to the inner wall rotates, so that the fan blade 46 drives the rotating pipe 44 to make the aeration pipe 41 rotate in the waste water, so the aeration pipe can stir in the waste water, and the ozone gas ejected from the aeration pipe 41 can also Drive the movement of the waste water in the tower body 1, so the continuous movement of the waste water in the tower body 1 will drive the ozone catalyst discharged from the discharge pipe 43 to move together, so the ozone catalyst is constantly moving in the waste water, so that the contact area between the ozone and the ozone catalyst is larger, Further improve the effect of wastewater treatment.

本发明通过控制进料单元31对臭氧催化剂的进料速度进行控制,使臭氧与臭氧催化剂一同进入废水中,同时通过增压后的臭氧气体带动转动管44转动,使转动管44上固连的曝气管41在废水中搅拌,保证臭氧与臭氧催化剂之间的充分接触,使臭氧与废水充分反应。The present invention controls the feeding speed of the ozone catalyst by controlling the feeding unit 31, so that the ozone and the ozone catalyst enter the waste water together, and at the same time, the pressurized ozone gas drives the rotating tube 44 to rotate, so that the fixed connection on the rotating tube 44 The aeration pipe 41 stirs in the waste water to ensure sufficient contact between the ozone and the ozone catalyst, so that the ozone and the waste water fully react.

本实施例中,参照说明书附图2,所述进料单元31包括电机311、电动推杆312、单向阀313、进料口314、活塞315,所述电机311位于所述进料管3顶部,所述电机311用于驱动所述电动推杆312,所述电动推杆312位于所述进料管3内部,所述电动推杆312的一端固连有所述活塞315,所述活塞315与所述进料管3内壁滑动连接,所述单向阀313位于所述进料管3的下端开口,所述进料口314与所述进料管3上部外壁连通。In this embodiment, referring to the accompanying drawing 2 of the specification, the feeding unit 31 includes a motor 311, an electric push rod 312, a one-way valve 313, a feeding port 314, and a piston 315. The motor 311 is located in the feeding pipe 3 At the top, the motor 311 is used to drive the electric push rod 312, the electric push rod 312 is located inside the feed pipe 3, and one end of the electric push rod 312 is fixedly connected with the piston 315, and the piston 315 315 is slidingly connected with the inner wall of the feed pipe 3 , the one-way valve 313 is located at the lower end opening of the feed pipe 3 , and the feed port 314 communicates with the upper outer wall of the feed pipe 3 .

工作时,工作人员打开电机311,使活塞315向上移动漏出进料口314,臭氧催化剂从进料口314进入,再将活塞315向下移动,通过活塞315改变进料管3内的气压压强使臭氧催化剂从进料口314下端开口内的单向阀313通过进入至臭氧管2,臭氧催化剂被增压后的臭氧气体带入塔体1内与废水反应,使臭氧与废水反应时能够充分混合反应,增加臭氧的利用率。When working, the staff turns on the motor 311 to make the piston 315 move upwards and leak out of the feed port 314, the ozone catalyst enters from the feed port 314, and then the piston 315 is moved downwards, and the air pressure in the feed pipe 3 is changed by the piston 315 so that The ozone catalyst enters the ozone pipe 2 through the one-way valve 313 in the opening of the lower end of the feed port 314, and the ozone catalyst is brought into the tower body 1 by the pressurized ozone gas to react with the wastewater, so that the ozone and wastewater can be fully mixed when reacting. Reaction, increase the utilization rate of ozone.

实施例2;Embodiment 2;

与实施例1区别在于:The difference with embodiment 1 is:

本实施例中,参照说明书附图3,所述进料单元31包括气泵321、进料盖322、单向阀313;所述气泵321位于所述塔体1与所述进料管3之间且所述气泵321的二号进气口325与所述进料管3侧壁连通,所述进料盖322与所述进料管3顶部连接,用于控制所述气管33内气体流通。In this embodiment, referring to the accompanying drawing 3 of the specification, the feed unit 31 includes an air pump 321, a feed cover 322, and a one-way valve 313; the air pump 321 is located between the tower body 1 and the feed pipe 3 And the No. 2 air inlet 325 of the air pump 321 communicates with the side wall of the feed pipe 3 , and the feed cover 322 is connected with the top of the feed pipe 3 for controlling the gas circulation in the air pipe 33 .

工作时,工作人员将进料盖322打开,将臭氧催化剂从进料盖322处倒入进料管3,盖上进料盖322,打开气泵321,使气泵321通过二号进气口325往进料管3内增加气体来增加进料管3内部压强,使臭氧催化剂从单向阀313通过进入至臭氧管2,臭氧催化剂被增压后的臭氧气体带入塔体1内与废水反应,使臭氧与废水反应时能够充分混合反应,增加臭氧的利用率。During work, the staff opens the feed cover 322, pours the ozone catalyst into the feed pipe 3 from the feed cover 322, covers the feed cover 322, opens the air pump 321, and makes the air pump 321 pass through the No. 2 air inlet 325 to Add gas in the feed pipe 3 to increase the internal pressure of the feed pipe 3, so that the ozone catalyst passes through the one-way valve 313 and enters the ozone pipe 2, and the ozone catalyst is brought into the tower body 1 by the pressurized ozone gas to react with the waste water. When ozone reacts with wastewater, it can fully mix and react, increasing the utilization rate of ozone.

实施例3;Embodiment 3;

与实施例2区别在于:The difference with embodiment 2 is:

本实施例中,参照说明书附图3,所述进料管3的侧壁连通有气管33的一端,所述气管33的另一端与所述臭氧管2连通,所述气管33内设有控制阀331,所述进料管3内壁安装有臭氧检测器323。In this embodiment, referring to the accompanying drawing 3 of the specification, one end of the air pipe 33 is communicated with the side wall of the feed pipe 3, and the other end of the air pipe 33 is communicated with the ozone pipe 2, and the air pipe 33 is provided with a control A valve 331, an ozone detector 323 is installed on the inner wall of the feed pipe 3.

工作时,工作人员将进料盖322打开,将臭氧催化剂从进料盖322处倒入进料管3,盖上进料盖322,再将气管33内的控制阀331打开,使臭氧管2内一部分臭氧从气管33进入进料管3内部,使进料管3内部压强增大,使臭氧催化剂从单向阀313通过进入至臭氧管2,臭氧催化剂被增压后的臭氧气体带入塔体1内与废水反应;当工作人员需要添加臭氧催化剂时,关闭气管33内的控制阀331,打开气泵321将进料管3内的臭氧从进料管3下端开口处排出,当臭氧检测器323检测臭氧含量趋近于0或对环境很人体无害后即可打开进料盖322,将臭氧催化剂从进料盖322倒入进料管3内即可补充臭氧催化剂,增加了臭氧的利用率,同时该结构简单便捷,提高了机器的实际使用情况。During work, the staff opens the feed cover 322, pours the ozone catalyst into the feed pipe 3 from the feed cover 322, covers the feed cover 322, and then opens the control valve 331 in the air pipe 33 to make the ozone pipe 2 A part of the ozone enters the inside of the feed pipe 3 from the gas pipe 33 to increase the pressure inside the feed pipe 3, so that the ozone catalyst passes through the one-way valve 313 and enters the ozone pipe 2, and the ozone catalyst is brought into the tower by the pressurized ozone gas. The body 1 reacts with wastewater; when the staff needs to add an ozone catalyst, close the control valve 331 in the air pipe 33, turn on the air pump 321 to discharge the ozone in the feed pipe 3 from the opening at the lower end of the feed pipe 3, and when the ozone detector After the 323 detects that the ozone content is close to 0 or is harmless to the environment and the human body, the feed cover 322 can be opened, and the ozone catalyst can be replenished by pouring the ozone catalyst from the feed cover 322 into the feed pipe 3, which increases the utilization of ozone At the same time, the structure is simple and convenient, which improves the actual use of the machine.

本实施例中,参照说明书附图3,所述气泵321的二号出气口326与所述塔体1外壁通过出气管327连通,所述进料盖322上安装有真空泄压阀324。In this embodiment, referring to the accompanying drawing 3 of the specification, the No. 2 air outlet 326 of the air pump 321 communicates with the outer wall of the tower body 1 through an air outlet pipe 327 , and a vacuum pressure relief valve 324 is installed on the feed cover 322 .

工作时,工作人员将进料管3内的臭氧直接通过气泵321排入塔体1内,直至臭氧检测器323检测进料管3内部的臭氧含量趋近与0或者进料管3内的臭氧含量对人体或环境无害,使臭氧与废水反应,增加了臭氧的利用率;同时,进料管3内的臭氧进入塔体1内后,进料管3内部压强减小,因此通过进料盖322上安装的真空泄压阀324使进气管4内压强与大气压强相等,再将进料盖322打开即可补充臭氧催化剂,增加了机器的安全性和实际使用效果。When working, the staff directly discharges the ozone in the feed pipe 3 into the tower body 1 through the air pump 321 until the ozone detector 323 detects that the ozone content inside the feed pipe 3 approaches 0 or the ozone in the feed pipe 3 The content is harmless to the human body or the environment, which makes the ozone react with the wastewater and increases the utilization rate of the ozone; at the same time, after the ozone in the feed pipe 3 enters the tower body 1, the internal pressure of the feed pipe 3 decreases, so through the feed The vacuum pressure relief valve 324 installed on the cover 322 makes the pressure in the intake pipe 4 equal to the atmospheric pressure, and then the ozone catalyst can be replenished by opening the feeding cover 322, which increases the safety and actual use effect of the machine.

实施例4;Embodiment 4;

与实施例1区别在于:The difference with embodiment 1 is:

本实施例中,参照说明书附图2或3,所述塔体1内部的底面中心位置设有进气管4,所述进气管4与所述臭氧管2的一端连通,所述进气管4外壁连通有多个曝气管41,所述进气管4底部的外壁固连多个排料管43,且所述排料管43与所述进气管4内部连通,所述进气管4下部的内壁固连有过滤网42,所述过滤网42用于过滤催化剂,防止所述催化剂堵住所述曝气管41。In this embodiment, referring to the accompanying drawings 2 or 3 of the specification, an air inlet pipe 4 is provided at the center of the bottom surface inside the tower body 1, and the air inlet pipe 4 communicates with one end of the ozone pipe 2, and the outer wall of the air inlet pipe 4 A plurality of aeration pipes 41 are communicated, and the outer wall of the bottom of the air intake pipe 4 is fixedly connected with a plurality of discharge pipes 43, and the discharge pipe 43 communicates with the interior of the air intake pipe 4, and the inner wall of the lower part of the air intake pipe 4 A filter screen 42 is fixedly connected, and the filter screen 42 is used to filter the catalyst to prevent the catalyst from blocking the aeration pipe 41 .

工作时,进气管4包括曝气管41、过滤网42、排料管43,塔体1内部的底面中心位置设有进气管4,进气管4与臭氧管2的一端连通,进气管4外壁连通有多个曝气管41,进气管4底部的外壁固连多个排料管43,且排料管43与进气管4内部连通,进气管4下部的内壁固连有过滤网42,工作人员将臭氧与臭氧催化剂一起从臭氧管2排入进气管4,进气管4内的过滤网42阻止臭氧催化剂通过,使其从排料口排出至废水中,防止臭氧催化剂堵住曝气管41,经过过滤网42的臭氧气体往进气管4上方移动,在进气管4的侧壁上的曝气管中排出到废水中,经过曝气管出来的臭氧气体搅动水流,保证了臭氧与废水的充分反应。During work, the air intake pipe 4 comprises an aeration pipe 41, a filter screen 42, and a discharge pipe 43. The central position of the bottom surface of the tower body 1 is provided with an air intake pipe 4. The air intake pipe 4 communicates with one end of the ozone pipe 2, and the outer wall of the air intake pipe 4 Connected with a plurality of aeration pipes 41, the outer wall of the bottom of the intake pipe 4 is fixedly connected with a plurality of discharge pipes 43, and the discharge pipe 43 communicates with the inside of the intake pipe 4, and the inner wall of the lower part of the intake pipe 4 is fixedly connected with a filter screen 42. Personnel discharge the ozone and the ozone catalyst from the ozone pipe 2 into the intake pipe 4, and the filter screen 42 in the intake pipe 4 prevents the ozone catalyst from passing through, so that it is discharged into the waste water from the discharge port, preventing the ozone catalyst from blocking the aeration pipe 41 , the ozone gas through the filter screen 42 moves to the top of the intake pipe 4, and is discharged into the waste water in the aeration pipe on the side wall of the air intake pipe 4, and the ozone gas that comes out through the aeration pipe stirs the water flow, ensuring the separation of ozone and waste water. fully responsive.

本实施例中,参照说明书附图6,所述过滤网42底部端面中心位置向下鼓起。In this embodiment, referring to Fig. 6 of the specification, the center position of the bottom end surface of the filter 42 bulges downward.

工作时,臭氧带动臭氧催化剂一同进入进气管,过滤网42底部端面中心位置向下鼓起,臭氧催化剂达到过滤网42位置时向下鼓起的过滤网42将臭氧催化剂向四周分离,臭氧从过滤网42中部进入固定管45和转动管44,,防止臭氧催化剂堵住过滤网42,保证了臭氧与废水的充分反应。During work, ozone drives the ozone catalyst to enter the intake pipe together, and the central position of the end face of the filter screen 42 bottom bulges downward. The middle part of the net 42 enters the fixed pipe 45 and the rotating pipe 44 to prevent the ozone catalyst from blocking the filter screen 42 and ensure the sufficient reaction of the ozone and waste water.

实施例5;Embodiment 5;

与实施例4区别在于:The difference with embodiment 4 is:

本实施例中,参照说明书附图6,所述排料管43开口方向斜向上。In this embodiment, referring to the accompanying drawing 6 of the specification, the opening direction of the discharge pipe 43 is obliquely upward.

工作时,臭氧催化剂在增压后的臭氧的作用下经过过滤网42从弧形管道的排料口排出,使臭氧催化剂平滑的排出,防止臭氧催化剂在排料口堵住,保证了臭氧与废水的充分反应。When working, the ozone catalyst is discharged from the discharge port of the arc-shaped pipe through the filter screen 42 under the action of the pressurized ozone, so that the ozone catalyst is discharged smoothly, preventing the ozone catalyst from being blocked at the discharge port, and ensuring the ozone and waste water adequate response.

本实施例中,参照说明书附图6,所述进气管4上包括多个转动管44和多个固定管45,多个所述固定管45通过多个U型杆48固连,所述转动管44位于所述两个固定管45之间,所述转动管44与所述固定管45的下端面设有环形T型槽49,所述转动管44与所述固定管45的上端面设有环形T型块47,所述环形T型块47与相近的所述环形T型槽49转动密封连接。In this embodiment, referring to the accompanying drawing 6 of the specification, the intake pipe 4 includes a plurality of rotating pipes 44 and a plurality of fixed pipes 45, and the plurality of fixed pipes 45 are fixedly connected by a plurality of U-shaped rods 48, and the rotating The pipe 44 is located between the two fixed pipes 45, the lower end surfaces of the rotating pipe 44 and the fixed pipe 45 are provided with an annular T-shaped groove 49, and the upper end surfaces of the rotating pipe 44 and the fixed pipe 45 are provided with An annular T-shaped block 47 is provided, and the annular T-shaped block 47 is in rotation and sealing connection with the adjacent said annular T-shaped groove 49 .

工作时,进气管4包括曝气管41、过滤网42、排料管43、转动管44、固定管45、环形T型块47、U型杆48、环形T型槽49,排料管43底部与塔体1内部的地面固连,工作人员在转动管44与固定管45的下端面设有环形T型槽49,转动管44与固定管45的上端面设有环形T型块47,环形T型块47与环形T型槽49转动密封连接,使转动管44与固定管45之间通过环形T型块47达到密封效果,防止废水从转动管44与固定管45连接面之间进入进气管4内部,造成废水在进气管4内部下落,降低臭氧气体在进气管4内的运动速度,随着时间增加,进入进气管4内的废水逐渐增加会堵住进气管4内部,使臭氧气体无法通过曝气管41排出,因此防止废水进气管为必要的,所以该结构提高了设备的实用性,且工作人员将多个固定管45通过U型杆48连接,使固定管45重力产生的压力作用不会影响到转动管44上,从而减小转动杆44转动时的摩擦力,提高了该设备的实用性。During work, the intake pipe 4 comprises an aeration pipe 41, a filter screen 42, a discharge pipe 43, a rotating pipe 44, a fixed pipe 45, an annular T-shaped block 47, a U-shaped bar 48, an annular T-shaped groove 49, and a discharge pipe 43 The bottom is fixedly connected to the ground inside the tower body 1, and the staff is provided with an annular T-shaped groove 49 on the lower end surface of the rotating pipe 44 and the fixed pipe 45, and an annular T-shaped block 47 is provided on the upper end surface of the rotating pipe 44 and the fixed pipe 45, The annular T-shaped block 47 is connected with the annular T-shaped groove 49 in a rotating and sealed manner, so that the sealing effect is achieved between the rotating pipe 44 and the fixed pipe 45 through the annular T-shaped block 47, preventing waste water from entering between the connecting surface of the rotating pipe 44 and the fixed pipe 45 The interior of the intake pipe 4 causes waste water to fall inside the intake pipe 4, reducing the movement speed of the ozone gas in the intake pipe 4. As time increases, the waste water entering the intake pipe 4 gradually increases and will block the inside of the intake pipe 4, making the ozone The gas cannot be discharged through the aeration pipe 41, so it is necessary to prevent the waste water intake pipe, so this structure improves the practicability of the equipment, and the staff connects a plurality of fixed pipes 45 through U-shaped rods 48, so that the gravity of the fixed pipes 45 generates The pressure effect of the pressure will not affect the rotating tube 44, thereby reducing the frictional force when the rotating rod 44 rotates, and improving the practicability of the device.

本实施例中,参照说明书附图6,所述转动管44内壁固连有多个扇叶46,所述曝气管41位于所述转动管44的外壁。In this embodiment, referring to FIG. 6 of the specification, a plurality of fan blades 46 are fixedly connected to the inner wall of the rotating tube 44 , and the aeration tube 41 is located on the outer wall of the rotating tube 44 .

工作时,进气管4包括曝气管41、过滤网42、排料管43、转动管44、固定管45、扇叶46、环形T型块47、U型杆48、环形T型槽49,曝气管41位于转动管44的外壁,且曝气管41与转动管44内部连通,进入进气管4内的臭氧带动转动管44内壁固连的扇叶46转动,使转动管44进行转动,同时转动管44带动曝气管41对废水进行搅拌,同时曝气管41产生的气泡也能够对废水产生一定的扰流作用,使臭氧催化剂在塔体1内不断运动,增加臭氧催化剂在塔体1内的混合程度,提高了臭氧的利用率。During work, the intake pipe 4 comprises an aeration pipe 41, a filter screen 42, a discharge pipe 43, a rotating pipe 44, a fixed pipe 45, a fan blade 46, an annular T-shaped block 47, a U-shaped bar 48, and an annular T-shaped groove 49, The aeration pipe 41 is located on the outer wall of the rotating pipe 44, and the aeration pipe 41 communicates with the inside of the rotating pipe 44. The ozone entering the intake pipe 4 drives the fan blade 46 fixedly connected to the inner wall of the rotating pipe 44 to rotate, so that the rotating pipe 44 rotates. At the same time, the rotating tube 44 drives the aeration tube 41 to stir the wastewater, and the air bubbles produced by the aeration tube 41 can also have a certain disturbance to the wastewater, so that the ozone catalyst is constantly moving in the tower body 1, increasing the ozone catalyst in the tower body. The degree of mixing within 1 improves the utilization rate of ozone.

Claims (10)

1. A coal chemical industry advanced wastewater treatment CoSD reaction tower comprises:
a tower body (1);
one end of the ozone pipe (2) is communicated with the bottom of the tower body (1);
the feeding pipe (3) is positioned on one side far away from the tower body (1), and an opening in the bottom of the feeding pipe (3) is communicated with the outer wall of the ozone pipe (2);
the ozone booster pump (21) is positioned on one side far away from the tower body (1), and a first air inlet (212) of the ozone booster pump (21) is communicated with the other end of the ozone pipe (2);
the ozone generator (22) is positioned at one side close to the ozone booster pump (21), and a third air outlet (221) of the ozone generator (22) is communicated with a first air inlet (212) of the ozone booster pump (21);
it is characterized by also comprising:
a feed unit (31), the feed unit (31) being located within the feed pipe (3) for controlling the feeding of ozone catalyst.
2. The coal chemical industry wastewater advanced treatment CoSD reaction tower according to claim 1, characterized in that: feed unit (31) includes motor (311), electric putter (312), check valve (313), feed inlet (314), piston (315), motor (311) are located inlet pipe (3) top, motor (311) are used for the drive electric putter (312), electric putter (312) are located inside inlet pipe (3), the one end of electric putter (312) has linked firmly piston (315), piston (315) with inlet pipe (3) inner wall sliding connection, check valve (313) are located the lower extreme opening of inlet pipe (3), feed inlet (314) with inlet pipe (3) upper portion outer wall intercommunication.
3. The coal chemical industry wastewater advanced treatment CoSD reaction tower according to claim 1, characterized in that: the feeding unit (31) comprises an air pump (321), a feeding cover (322) and a one-way valve (313); air pump (321) are located tower body (1) with between inlet pipe (3) just No. two air inlets (325) of air pump (321) with inlet pipe (3) lateral wall intercommunication, feeding lid (322) with inlet pipe (3) top is connected, is used for control gaseous circulation in trachea (33).
4. The coal chemical industry wastewater advanced treatment CoSD reaction tower according to claim 3, characterized in that: the lateral wall intercommunication of inlet pipe (3) has the one end of trachea (33), the other end of trachea (33) with ozone pipe (2) intercommunication, be equipped with control valve (331) in trachea (33), ozone detector (323) are installed to inlet pipe (3) inner wall.
5. The coal chemical industry wastewater advanced treatment CoSD reaction tower according to claim 4, characterized in that: no. two gas outlets (326) of air pump (321) with tower body (1) outer wall passes through outlet duct (327) intercommunication, install vacuum relief valve (324) on feeding lid (322).
6. The coal chemical industry wastewater advanced treatment CoSD reaction tower according to claim 4, characterized in that: tower body (1) inside bottom surface central point puts and is equipped with intake pipe (4), intake pipe (4) with the one end intercommunication of ozone pipe (2), intake pipe (4) outer wall intercommunication has a plurality of aeration pipe (41), the outer wall of intake pipe (4) bottom links firmly a plurality of row and expects pipe (43), just arrange material pipe (43) with intake pipe (4) inside intercommunication, intake pipe (4) lower part's inner wall has linked firmly filter screen (42), filter screen (42) are used for filtering the catalyst, prevent the catalyst blocks up aeration pipe (41).
7. The coal chemical industry wastewater advanced treatment CoSD reaction tower according to claim 6, characterized in that: the center of the end face of the bottom of the filter screen (42) is bulged downwards.
8. The coal chemical industry wastewater advanced treatment CoSD reaction tower according to claim 6 or 7, characterized in that: the opening direction of the discharge pipe (43) is inclined upwards.
9. The coal chemical industry wastewater advanced treatment CoSD reaction tower according to claim 6, characterized in that: intake pipe (4) are gone up including a plurality of rotating tubes (44) and a plurality of fixed pipe (45), and are a plurality of fixed pipe (45) link firmly through a plurality of U type poles (48), rotating tube (44) are located between two fixed pipe (45), rotating tube (44) with the lower terminal surface of fixed pipe (45) is equipped with annular T type groove (49), rotating tube (44) with the up end of fixed pipe (45) is equipped with annular T type piece (47), annular T type piece (47) and close annular T type groove (49) rotate sealing connection.
10. The coal chemical industry wastewater advanced treatment CoSD reaction tower according to claim 9, wherein: the inner wall of the rotating pipe (44) is fixedly connected with a plurality of fan blades (46), and the aeration pipe (46) is positioned on the outer wall of the rotating pipe (44).
CN202210752389.XA 2022-06-28 2022-06-28 A CoSD reaction tower for deep treatment of coal chemical wastewater Active CN115520953B (en)

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CN112759064A (en) * 2021-01-04 2021-05-07 华东理工大学 Ozone catalytic oxidation system and treatment method of coal chemical industry concentrated solution
CN214031786U (en) * 2020-12-22 2021-08-24 宋振鑫 A chemical addition device for oil field chemical flooding
CN214528292U (en) * 2020-12-26 2021-10-29 苏州聚智同创环保科技有限公司 Ozone catalytic oxidation processing system
CN216538166U (en) * 2021-11-23 2022-05-17 山东瑞迪恩环保科技有限公司 Chemical agent agitator tank

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH10305287A (en) * 1997-05-02 1998-11-17 Kubota Corp Ozone catalytic reactor
CN102849875A (en) * 2012-10-12 2013-01-02 中国矿业大学(北京) System for deep treatment of coking wastewater by means of catalytic ozonation-ceramic membrane filtration
CN108946914A (en) * 2018-07-24 2018-12-07 石宏扬 A kind of coal chemical industrial waste water advanced treating CoSD reaction tower
CN111470582A (en) * 2020-06-23 2020-07-31 山东龙安泰环保科技有限公司 Ozone bubble generating device for catalytic oxidation sewage treatment
CN214031786U (en) * 2020-12-22 2021-08-24 宋振鑫 A chemical addition device for oil field chemical flooding
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CN216538166U (en) * 2021-11-23 2022-05-17 山东瑞迪恩环保科技有限公司 Chemical agent agitator tank

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