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CN115172500B - A laser battery component - Google Patents

A laser battery component Download PDF

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CN115172500B
CN115172500B CN202210817562.XA CN202210817562A CN115172500B CN 115172500 B CN115172500 B CN 115172500B CN 202210817562 A CN202210817562 A CN 202210817562A CN 115172500 B CN115172500 B CN 115172500B
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CN115172500A (en
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张无迪
高鹏
王赫
姜明序
倪旺
王宇
赵一聪
孟占昆
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CETC 18 Research Institute
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    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10FINORGANIC SEMICONDUCTOR DEVICES SENSITIVE TO INFRARED RADIATION, LIGHT, ELECTROMAGNETIC RADIATION OF SHORTER WAVELENGTH OR CORPUSCULAR RADIATION
    • H10F19/00Integrated devices, or assemblies of multiple devices, comprising at least one photovoltaic cell covered by group H10F10/00, e.g. photovoltaic modules
    • H10F19/90Structures for connecting between photovoltaic cells, e.g. interconnections or insulating spacers
    • H10F19/902Structures for connecting between photovoltaic cells, e.g. interconnections or insulating spacers for series or parallel connection of photovoltaic cells
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10FINORGANIC SEMICONDUCTOR DEVICES SENSITIVE TO INFRARED RADIATION, LIGHT, ELECTROMAGNETIC RADIATION OF SHORTER WAVELENGTH OR CORPUSCULAR RADIATION
    • H10F77/00Constructional details of devices covered by this subclass
    • H10F77/30Coatings
    • H10F77/306Coatings for devices having potential barriers
    • H10F77/311Coatings for devices having potential barriers for photovoltaic cells
    • H10F77/315Coatings for devices having potential barriers for photovoltaic cells the coatings being antireflective or having enhancing optical properties

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Abstract

本发明公开了一种激光电池组件,属于光伏电池技术领域,包括:绝缘衬底、M个激光电池单元、隔离槽、绝缘层、桥联电极。激光电池单元包括下电极,电池外延有源层,上电极,减反射结构。隔离槽将激光电池单元分离,绝缘层将激光电池单元侧壁绝缘钝化,桥联电极将相邻激光电池单元上下电极连接,实现相邻激光电池单元电学连接,将M个激光电池单元依次串联。该结构激光电池组件在远距离高功率的激光无线传能应用中,可兼顾电池效率与适用性。

The invention discloses a laser battery assembly, which belongs to the technical field of photovoltaic cells and comprises: an insulating substrate, M laser battery units, an isolation groove, an insulating layer, and a bridging electrode. The laser battery unit includes a lower electrode, a battery epitaxial active layer, an upper electrode, and an anti-reflection structure. The isolation groove separates the laser battery units, the insulating layer insulates and passivates the side walls of the laser battery units, and the bridging electrodes connect the upper and lower electrodes of adjacent laser battery units to realize the electrical connection of adjacent laser battery units, and connect M laser battery units in series. . In the application of long-distance high-power laser wireless energy transmission, the structural laser battery assembly can take into account battery efficiency and applicability.

Description

一种激光电池组件A laser battery component

技术领域technical field

本发明属于光伏电池技术领域,具体涉及一种激光电池组件。The invention belongs to the technical field of photovoltaic cells, and in particular relates to a laser cell assembly.

背景技术Background technique

激光无线传能具有传输能量密度大、传输及转换效率高、能量综合利用率高、系统体积小、供能场景受限小等优势,非常适用于空间环境应用。高轨空间飞行器的太阳电池阵实现太阳能转换为电能,电能再转换为激光,借助激光电池实现激光对其他空间飞行器或临近空间无人机供能。激光电池是无线传能系统激光接收端最重要的组成部分。激光电池组件的光电转换效率直接决定着无线传能系统的整体传输效率。Laser wireless energy transmission has the advantages of high transmission energy density, high transmission and conversion efficiency, high energy comprehensive utilization rate, small system size, and limited energy supply scenarios. It is very suitable for space environment applications. The solar cell array of the high-orbit spacecraft realizes the conversion of solar energy into electrical energy, and then converts the electrical energy into laser. With the help of laser batteries, the laser can supply energy to other spacecraft or near-space drones. The laser battery is the most important part of the laser receiving end of the wireless energy transmission system. The photoelectric conversion efficiency of the laser battery module directly determines the overall transmission efficiency of the wireless energy transfer system.

远距离高功率的激光无线传能,要保证实际应用中激光电池组件较高的光电转换效率,对激光电池组件提出了更为苛刻的要求,包括:大尺寸、高电压和对激光光强与入射角变化适应性强。对于单结III-V族半导体激光电池,其在高功率激光照射下,会产生很大的工作电流,过大的电流在电路中会引起更高的能量损耗,从而降低激光电池组件的光电转换效率。一般会采取串联子电池的方法提升电池电压,进而减小电池输出电流。Long-distance and high-power laser wireless energy transmission, in order to ensure the high photoelectric conversion efficiency of laser battery components in practical applications, puts forward more stringent requirements for laser battery components, including: large size, high voltage and the relationship between laser light intensity and Strong adaptability to incident angle changes. For a single-junction III-V semiconductor laser cell, it will generate a large operating current under high-power laser irradiation. Excessive current will cause higher energy loss in the circuit, thereby reducing the photoelectric conversion of the laser cell component. efficiency. Generally, the method of connecting sub-batteries in series is adopted to increase the battery voltage, thereby reducing the battery output current.

传统激光电池子电池的串联结构有横向和纵向两种。但横向串联结构子电池间存在分割区域,这减小了电池的有效发电面积。而纵向串联结构,只能针对单一激光强度,来优化每结子电池的吸收厚度。光强和入射角变化都会影响其效率,而且纵向结数越多影响越大。因此传统结构的激光电池无法适应远距离高功率的激光无线传能需求。There are two types of series structures of traditional laser battery sub-cells: horizontal and vertical. However, there is a partition area between the sub-cells in the horizontal series structure, which reduces the effective power generation area of the battery. However, the longitudinal series structure can only optimize the absorption thickness of each sub-cell for a single laser intensity. Variations in light intensity and incident angle will affect its efficiency, and the greater the number of longitudinal knots, the greater the impact. Therefore, laser batteries with traditional structures cannot meet the needs of long-distance and high-power laser wireless energy transmission.

发明内容Contents of the invention

本发明为解决公知技术中存在的技术问题,提供一种激光电池组件,能够同时满足远距离高功率的激光无线传能中,对激光电池组件的大尺寸、高电压和对激光光强与入射角变化适应性强的三项需求,电池有效受光面积更大,电池串联电阻更小,光电转换效率更高。In order to solve the technical problems in the known technology, the present invention provides a laser battery assembly, which can simultaneously meet the needs of large size, high voltage and laser light intensity and incident laser energy transmission in long-distance high-power laser wireless energy transmission. The three requirements of strong adaptability to angle changes, the effective light-receiving area of the battery is larger, the series resistance of the battery is smaller, and the photoelectric conversion efficiency is higher.

本发明的目的是提供一种激光电池组件,包括:绝缘衬底、M个激光电池单元、隔离槽、绝缘层、桥联电极,其中:M为大于0的自然数。The object of the present invention is to provide a laser battery assembly, including: an insulating substrate, M laser battery units, an isolation groove, an insulating layer, and a bridging electrode, wherein: M is a natural number greater than 0.

所述激光电池单元包括下电极、电池外延有源层、上电极、减反射结构。The laser battery unit includes a lower electrode, a battery epitaxial active layer, an upper electrode, and an anti-reflection structure.

所述隔离槽将相邻激光电池单元分离,所述绝缘层将所述激光电池单元侧壁绝缘钝化,所述桥联电极将相邻所述激光电池单元上下电极连接,实现相邻激光电池单元电学连接,将所述M个激光电池单元依次串联。The isolation groove separates the adjacent laser battery units, the insulating layer insulates and passivates the side walls of the laser battery units, and the bridging electrodes connect the upper and lower electrodes of the adjacent laser battery units to realize the The units are electrically connected, and the M laser battery units are sequentially connected in series.

优选地,所述绝缘衬底的材料为氧化硅、聚酰亚胺、石英中的一种。Preferably, the material of the insulating substrate is one of silicon oxide, polyimide, and quartz.

优选地,M个激光电池单元的面积相同。Preferably, the areas of the M laser battery units are the same.

作为一种可选结构,所述电池外延有源层为GaAs基电池有源层,由下向上包括:p型电极接触层、第一结Ga(In)As子电池、隧穿结、第二结Ga(In)As子电池和n型电极接触层。As an optional structure, the battery epitaxial active layer is a GaAs-based battery active layer, which includes from bottom to top: a p-type electrode contact layer, a first junction Ga(In)As subcell, a tunnel junction, a second Junction Ga(In)As subcell and n-type electrode contact layer.

优选地,所述第一结Ga(In)As子电池由下向上包括:GaInP背场、Gax1In1-x1As基区、Gax1In1-x1As发射区、GaInP窗口层,其中0.8≤x1≤1。Preferably, the first junction Ga(In)As subcell includes from bottom to top: a GaInP back field, a Ga x1 In 1-x1 As base region, a Ga x1 In 1-x1 As emitter region, and a GaInP window layer, wherein 0.8 ≤x1≤1.

优选地,所述第二结Ga(In)As子电池由下向上包括:GaInP背场、Gax2In1-x2As基区、Gax2In1-x2As发射区、GaInP窗口层,其中0.8≤x2≤1。Preferably, the second junction Ga(In)As subcell includes from bottom to top: a GaInP back field, a Gax2 In 1-x2 As base region, a Gax2 In 1-x2 As emitter region, and a GaInP window layer, wherein 0.8 ≤x2≤1.

优选地,所述p型电极接触层为p型GaAs层,掺杂浓度为1×1018~1×1019cm-3,厚度为100~200nm。Preferably, the p-type electrode contact layer is a p-type GaAs layer with a doping concentration of 1×10 18 -1×10 19 cm -3 and a thickness of 100-200 nm.

优选地,所述GaInP背场为p型掺杂,掺杂浓度为1×1017~1×1018cm-3,厚度为50~400nm。Preferably, the GaInP back field is p-type doped with a doping concentration of 1×10 17 to 1×10 18 cm -3 and a thickness of 50 to 400 nm.

优选地,所述GaInP窗口层为n型掺杂,掺杂浓度为1×1017~1×1018cm-3,厚度为50~400nm。Preferably, the GaInP window layer is n-type doped with a doping concentration of 1×10 17 to 1×10 18 cm -3 and a thickness of 50 to 400 nm.

优选地,所述Gax1In1-x1As基区为p型掺杂,掺杂浓度为1×1016~1×1018cm-3,厚度为1000~5000nm。Preferably, the Ga x1 In 1-x1 As base region is p-type doped with a doping concentration of 1×10 16 to 1×10 18 cm -3 and a thickness of 1000 to 5000 nm.

优选地,所述Gax1In1-x1As发射区为n型掺杂,掺杂浓度为1×1017~1×1019cm-3,厚度为100~500nm。Preferably, the Ga x1 In 1-x1 As emission region is n-type doped with a doping concentration of 1×10 17 to 1×10 19 cm -3 and a thickness of 100 to 500 nm.

优选地,所述Gax2In1-x2As基区为p型掺杂,掺杂浓度为1×1016~1×1018cm-3,厚度为1000~5000nm。Preferably, the Ga x2 In 1-x2 As base region is p-type doped with a doping concentration of 1×10 16 to 1×10 18 cm -3 and a thickness of 1000 to 5000 nm.

优选地,所述Gax2In1-x2As发射区为n型掺杂,掺杂浓度为1×1017~1×1019cm-3,厚度为100~500nm。Preferably, the Ga x2 In 1-x2 As emission region is n-type doped with a doping concentration of 1×10 17 to 1×10 19 cm -3 and a thickness of 100 to 500 nm.

优选地,所述隧穿结包括:n型GaAs层与p型GaAs层,掺杂浓度为1×1019~1×1021cm-3,厚度为10~100nm。Preferably, the tunnel junction includes: an n-type GaAs layer and a p-type GaAs layer, the doping concentration is 1×10 19 -1×10 21 cm -3 , and the thickness is 10-100 nm.

优选地,所述n型电极接触层为n型GaAs层,掺杂浓度为1×1018~1×1019cm-3,厚度为100~200nm。Preferably, the n-type electrode contact layer is an n-type GaAs layer with a doping concentration of 1×10 18 to 1×10 19 cm -3 and a thickness of 100 to 200 nm.

作为另一种可选结构,所述电池外延有源层为InP基电池有源层,由下向上包括:p型电极接触层、第一结GaInAsP子电池、隧穿结、第二结GaInAsP子电池和n型电极接触层。As another optional structure, the battery epitaxial active layer is an InP-based battery active layer, which includes from bottom to top: p-type electrode contact layer, first junction GaInAsP sub-cell, tunnel junction, second junction GaInAsP sub-cell battery and n-type electrode contact layer.

优选地,所述第一结GaInAsP子电池由下向上包括:InP背场、Gay1In1-y1Asz1P1-z1基区、Gay1In1-y1Asz1P1-z1发射区、InP窗口层,其中0≤y1≤0.5,0≤z1≤1。Preferably, the first junction GaInAsP subcell includes from bottom to top: an InP back field, a Ga y1 In 1-y1 As z1 P 1-z1 base region, a Ga y1 In 1-y1 As z1 P 1-z1 emitter region, InP window layer, where 0≤y1≤0.5, 0≤z1≤1.

优选地,所述第二结GaInAsP子电池由下向上包括:InP背场、Gay2In1-y2Asz2P1-z2基区、Gay2In1-y2Asz2P1-z2发射区、InP窗口层,其中0≤y2≤0.5,0≤z2≤1。Preferably, the second junction GaInAsP sub-cell includes from bottom to top: InP back field, Ga y2 In 1-y2 As z2 P 1-z2 base region, Ga y2 In 1-y2 As z2 P 1-z2 emission region, InP window layer, where 0≤y2≤0.5, 0≤z2≤1.

优选地,所述p型电极接触层为p型GaInAs层,掺杂浓度为1×1018~1×1019cm-3,厚度为100~200nm。Preferably, the p-type electrode contact layer is a p-type GaInAs layer with a doping concentration of 1×10 18 -1×10 19 cm -3 and a thickness of 100-200 nm.

优选地,所述InP背场为p型掺杂,掺杂浓度为1×1017~1×1018cm-3,厚度为50~400nm。Preferably, the InP back field is p-type doped with a doping concentration of 1×10 17 to 1×10 18 cm -3 and a thickness of 50 to 400 nm.

优选地,所述InP窗口层为n型掺杂,掺杂浓度为1×1017~1×1018cm-3,厚度为50~400nm。Preferably, the InP window layer is n-type doped with a doping concentration of 1×10 17 to 1×10 18 cm -3 and a thickness of 50 to 400 nm.

优选地,所述Gay1In1-y1Asz1P1-z1基区为p型掺杂,掺杂浓度为1×1016~1×1018cm-3,厚度为1000~5000nm。Preferably, the Ga y1 In 1-y1 As z1 P 1-z1 base region is p-type doped with a doping concentration of 1×10 16 to 1×10 18 cm -3 and a thickness of 1000 to 5000 nm.

优选地,所述Gay1In1-y1Asz1P1-z1发射区为n型掺杂,掺杂浓度为1×1017~1×1019cm-3,厚度为100~500nm。Preferably, the Ga y1 In 1-y1 As z1 P 1-z1 emitting region is n-type doped, with a doping concentration of 1×10 17 to 1×10 19 cm -3 and a thickness of 100 to 500 nm.

优选地,所述Gay2In1-y2Asz2P1-z2基区为p型掺杂,掺杂浓度为1×1016~1×1018cm-3,厚度为1000~5000nm。Preferably, the Ga y2 In 1-y2 As z2 P 1-z2 base region is p-type doped, with a doping concentration of 1×10 16 to 1×10 18 cm -3 and a thickness of 1000 to 5000 nm.

优选地,所述Gay2In1-y2Asz2P1-z2发射区为n型掺杂,掺杂浓度为1×1017~1×1019cm-3,厚度为100~500nm。Preferably, the Ga y2 In 1-y2 As z2 P 1-z2 emitting region is n-type doped, with a doping concentration of 1×10 17 to 1×10 19 cm -3 and a thickness of 100 to 500 nm.

优选地,所述隧穿结包括:n型InP层与p型InP层,掺杂浓度为1×1019~1×1021cm-3,厚度为10~100nm。Preferably, the tunnel junction includes: an n-type InP layer and a p-type InP layer, the doping concentration is 1×10 19 -1×10 21 cm -3 , and the thickness is 10-100 nm.

优选地,所述n型电极接触层为n型GaInAs层,掺杂浓度为1×1018~1×1019cm-3,厚度为100~200nm。Preferably, the n-type electrode contact layer is an n-type GaInAs layer with a doping concentration of 1×10 18 to 1×10 19 cm -3 and a thickness of 100 to 200 nm.

优选地,所述上电极与桥联电极的材料为Au/Ge/Ag,厚度为2~5μm;所述下电极的材料为Ti/Pd/Au/Ge/Au,厚度为4~8μm。Preferably, the material of the upper electrode and the bridging electrode is Au/Ge/Ag, with a thickness of 2-5 μm; the material of the lower electrode is Ti/Pd/Au/Ge/Au, with a thickness of 4-8 μm.

优选地,所述绝缘层为聚酰亚胺胶。Preferably, the insulating layer is polyimide glue.

优选地,所述减反射结构由下向上包括:氧化钛/氧化硅减反射膜、纳米阵列陷光结构。Preferably, the anti-reflection structure includes from bottom to top: titanium oxide/silicon oxide anti-reflection film, nano-array light-trapping structure.

本发明具有的有益效果是:The beneficial effects that the present invention has are:

1、本发明将传统激光电池子电池横向串联与纵向串联两种技术路径结合,发明了纵向2结内级联结构激光电池组件。纵向2结结构对激光光强与入射角变化适应性较强,横向内级联串联结构有效提升电池电压,电池组件整体在保证高电压同时,减少了因隔离槽造成的电池有效面积损失。在远距离高功率的激光无线传能应用中,可兼顾电池效率与适用性。1. The present invention combines the two technical paths of horizontal series connection and vertical series connection of traditional laser battery sub-cells, and invents a vertical 2-junction cascade structure laser battery assembly. The vertical 2-junction structure has strong adaptability to changes in laser light intensity and incident angle, and the horizontal cascaded series structure effectively increases the battery voltage. The battery module as a whole ensures high voltage while reducing the effective area loss of the battery caused by the isolation groove. In long-distance high-power laser wireless energy transmission applications, battery efficiency and applicability can be considered.

2、在减反射膜上制作纳米阵列结构,陷光结构可延长光子光学路径,增强激光斜入射情况减反射效果,增强激光电池组件在无线传能应用中的适用性。2. Fabricate a nano-array structure on the anti-reflection film. The light-trapping structure can extend the photon optical path, enhance the anti-reflection effect in the case of oblique laser incidence, and enhance the applicability of laser battery components in wireless energy transfer applications.

附图说明Description of drawings

图1为本发明优选实施例中激光电池组件的剖面结构示意图。Fig. 1 is a schematic cross-sectional structure diagram of a laser cell assembly in a preferred embodiment of the present invention.

图2为本发明优选实施例中激光电池组件的俯视面结构示意图。Fig. 2 is a schematic top view of the laser cell assembly in a preferred embodiment of the present invention.

图3为本发明优选实施例中激光电池组件外延有源层的剖面结构示意图。Fig. 3 is a schematic cross-sectional structure diagram of the epitaxial active layer of the laser cell assembly in the preferred embodiment of the present invention.

图中:In the picture:

100、绝缘衬底;100. Insulating substrate;

200、下电极;200, lower electrode;

300、电池外延有源层;300. Cell epitaxial active layer;

310、p型电极接触层;310. P-type electrode contact layer;

320、第一结Ga(In)As子电池或第一结GaInAsP子电池;320. A first junction Ga(In)As subcell or a first junction GaInAsP subcell;

321、GaInP背场或InP背场;321. GaInP back field or InP back field;

322、Gax1In1-x1As基区或Gay1In1-y1Asz1P1-z1基区;322. Ga x1 In 1-x1 As base region or Ga y1 In 1-y1 As z1 P 1-z1 base region;

323、Gax1In1-x1As发射区或Gay1In1-y1Asz1P1-z1发射区;323. Ga x1 In 1-x1 As emission area or Ga y1 In 1-y1 As z1 P 1-z1 emission area;

324、GaInP窗口层或InP窗口层;324. GaInP window layer or InP window layer;

330、隧穿结;330. Tunneling junction;

331、n型GaAs或n型InP;331. n-type GaAs or n-type InP;

332、p型GaAs或p型InP;332. p-type GaAs or p-type InP;

340、第二结Ga(In)As子电池或第二结GaInAsP子电池;340. A second junction Ga(In)As subcell or a second junction GaInAsP subcell;

341、GaInP背场或InP背场;341. GaInP back field or InP back field;

342、Gax2In1-x2As基区或Gay2In1-y2Asz2P1-z2基区;342. Ga x2 In 1-x2 As base region or Ga y2 In 1-y2 As z2 P 1-z2 base region;

343、Gax2In1-x2As发射区或Gay2In1-y2Asz2P1-z2发射区;343. Ga x2 In 1-x2 As emission area or Ga y2 In 1-y2 As z2 P 1-z2 emission area;

344、GaInP窗口层或InP窗口层;344. GaInP window layer or InP window layer;

350、n型电极接触层350. n-type electrode contact layer

400、上电极400. Upper electrode

500、减反射结构500. Anti-reflection structure

600、绝缘层600, insulating layer

700、桥联电极700. Bridge electrode

具体实施方式Detailed ways

下面将结合本申请实施例中的附图,对本申请实施例中的技术方案进行详细说明,以期能进一步了解本发明的发明内容。In the following, the technical solutions in the embodiments of the present application will be described in detail in combination with the drawings in the embodiments of the present application, so as to further understand the content of the present invention.

显然,所描述的实施例仅是本发明一部分实施例,而不是全部的实施例。基于本发明中的技术方案,本领域普通技术人员在没有做出创造性劳动前提下所获得的所有其他实施例,都属于本发明保护的范围。Apparently, the described embodiments are only some of the embodiments of the present invention, but not all of them. Based on the technical solutions in the present invention, all other embodiments obtained by persons of ordinary skill in the art without making creative efforts belong to the protection scope of the present invention.

在本发明的描述中,需要理解的是,术语“上”、“下”等指示的方位或位置关系为基于附图所示的方位或位置关系,使用“第一”、“第二”等词语来限定零部件,仅是为了便于描述本发明和简化描述,不能理解为对本发明的限制。In the description of the present invention, it should be understood that the orientation or positional relationship indicated by the terms "upper", "lower", etc. is based on the orientation or positional relationship shown in the drawings, and the use of "first", "second", etc. Words used to define components are only for the convenience of describing the present invention and simplifying the description, and should not be construed as limiting the present invention.

本发明的目的是提供一种激光电池组件,如图1、2所示,包括:绝缘衬底100、9个激光电池单元、隔离槽、绝缘层600、桥联电极700。The object of the present invention is to provide a laser battery assembly, as shown in FIGS. 1 and 2 , including: an insulating substrate 100 , 9 laser battery units, isolation grooves, an insulating layer 600 , and a bridging electrode 700 .

激光电池单元包括下电极200,电池外延有源层300,上电极400,减反射结构500。The laser battery unit includes a lower electrode 200 , a battery epitaxial active layer 300 , an upper electrode 400 , and an anti-reflection structure 500 .

隔离槽将相邻激光电池单元分离,绝缘层600将激光电池单元侧壁绝缘钝化,桥联电极700将相邻激光电池单元上下电极连接,实现相邻激光电池单元电学连接,将9个激光电池单元依次串联。The isolation groove separates the adjacent laser battery units, the insulating layer 600 insulates and passivates the side walls of the laser battery units, and the bridging electrode 700 connects the upper and lower electrodes of the adjacent laser battery units to realize the electrical connection of the adjacent laser battery units. The battery cells are serially connected in series.

其中:绝缘衬底100的材料为氧化硅、聚酰亚胺、石英中的一种。Wherein: the material of the insulating substrate 100 is one of silicon oxide, polyimide, and quartz.

每个激光电池单元的面积相同。Each laser cell has the same area.

实施例一,一种用于接收780~850nm波段的GaAs基激光电池组件结构如下:Embodiment 1, the structure of a GaAs-based laser cell assembly for receiving the 780-850nm band is as follows:

如图3所示,电池外延有源层300为GaAs基电池有源层,由下向上包括:p型电极接触层310、第一结Ga(In)As子电池320、隧穿结330、第二结Ga(In)As子电池340、n型电极接触层350。As shown in FIG. 3 , the battery epitaxial active layer 300 is a GaAs-based battery active layer, which includes from bottom to top: a p-type electrode contact layer 310, a first junction Ga(In)As subcell 320, a tunnel junction 330, a second junction A two-junction Ga(In)As sub-cell 340 and an n-type electrode contact layer 350 .

其中:第一结Ga(In)As子电池320由下向上包括:GaInP背场321、Gax1In1-x1As基区322、Gax1In1-x1As发射区323、GaInP窗口层324,其中0.8≤x1≤1。Wherein: the first junction Ga(In)As sub-cell 320 includes from bottom to top: GaInP back field 321, Ga x1 In 1-x1 As base region 322, Ga x1 In 1-x1 As emission region 323, GaInP window layer 324, where 0.8≤x1≤1.

第二结Ga(In)As子电池340由下向上包括:GaInP背场341、Gax2In1-x2As基区342、Gax2In1-x2As发射区343、GaInP窗口层344,其中0.8≤x2≤1。The second junction Ga(In)As subcell 340 includes from bottom to top: GaInP back field 341, Ga x2 In 1-x2 As base region 342, Ga x2 In 1-x2 As emission region 343, GaInP window layer 344, wherein 0.8 ≤x2≤1.

p型电极接触层310为p型GaAs层,掺杂浓度为1×1018~1×1019cm-3,厚度为100~200nm。The p-type electrode contact layer 310 is a p-type GaAs layer with a doping concentration of 1×10 18 to 1×10 19 cm −3 and a thickness of 100 to 200 nm.

GaInP背场321、341为p型掺杂,掺杂浓度为1×1017~1×1018cm-3,厚度为50~400nm。The GaInP back fields 321 and 341 are p-type doped with a doping concentration of 1×10 17 to 1×10 18 cm −3 and a thickness of 50 to 400 nm.

GaInP窗口层324、344为n型掺杂,掺杂浓度为1×1017~1×1018cm-3,厚度为50~400nm。The GaInP window layers 324 and 344 are n-type doped with a doping concentration of 1×10 17 to 1×10 18 cm −3 and a thickness of 50 to 400 nm.

Gax1In1-x1As基区322为p型掺杂,掺杂浓度为1×1016~1×1018cm-3,厚度为1000~5000nm。The Ga x1 In 1-x1 As base region 322 is p-type doped, the doping concentration is 1×10 16 ˜1×10 18 cm −3 , and the thickness is 1000˜5000 nm.

Gax1In1-x1As发射区323为n型掺杂,掺杂浓度为1×1017~1×1019cm-3,厚度为100~500nm。The Ga x1 In 1-x1 As emission region 323 is n-type doped, the doping concentration is 1×10 17 ˜1×10 19 cm −3 , and the thickness is 100˜500 nm.

Gax2In1-x2As基区342为p型掺杂,掺杂浓度为1×1016~1×1018cm-3,厚度为1000~5000nm。The Ga x2 In 1-x2 As base region 342 is p-type doped, the doping concentration is 1×10 16 ˜1×10 18 cm −3 , and the thickness is 1000˜5000 nm.

Gax2In1-x2As发射区343为n型掺杂,掺杂浓度为1×1017~1×1019cm-3,厚度为100~500nm。The Ga x2 In 1-x2 As emission region 343 is n-type doped, the doping concentration is 1×10 17 ˜1×10 19 cm −3 , and the thickness is 100˜500 nm.

隧穿结包括:n型GaAs层334与p型GaAs层332,掺杂浓度为1×1019~1×1021cm-3,厚度为10~100nm。The tunnel junction includes: an n-type GaAs layer 334 and a p-type GaAs layer 332 with a doping concentration of 1×10 19 ˜1×10 21 cm −3 and a thickness of 10˜100 nm.

n型电极接触层350为n型GaAs层,掺杂浓度为1×1018~1×1019cm-3,厚度为100~200nm。The n-type electrode contact layer 350 is an n-type GaAs layer with a doping concentration of 1×10 18 to 1×10 19 cm −3 and a thickness of 100 to 200 nm.

上电极400与桥联电极700材料为Au/Ge/Ag,厚度为2~5μm;下电极200材料为Ti/Pd/Au/Ge/Au,厚度为4~8μm。The material of the upper electrode 400 and the bridging electrode 700 is Au/Ge/Ag, with a thickness of 2-5 μm; the material of the lower electrode 200 is Ti/Pd/Au/Ge/Au, with a thickness of 4-8 μm.

绝缘层600为聚酰亚胺胶。The insulating layer 600 is polyimide glue.

减反射结构500由下向上包括:氧化钛/氧化硅减反射膜、纳米阵列陷光结构。The anti-reflection structure 500 includes from bottom to top: titanium oxide/silicon oxide anti-reflection film, nano-array light trapping structure.

实施例二,一种用于接收950~1600nm波段的InP基激光电池组件结构如下:Embodiment 2, the structure of an InP-based laser cell assembly for receiving the 950-1600nm band is as follows:

如图3所示,电池外延有源层300为InP基电池有源层,由下向上包括:p型电极接触层310、第一结GaInAsP子电池320、隧穿结330、第二结GaInAsP子电池340、n型电极接触层350。As shown in FIG. 3 , the battery epitaxial active layer 300 is an InP-based battery active layer, which includes from bottom to top: a p-type electrode contact layer 310, a first junction GaInAsP sub-cell 320, a tunnel junction 330, a second junction GaInAsP sub-cell. Battery 340 , n-type electrode contact layer 350 .

其中,第一结GaInAsP子电池320由下向上包括:InP背场321、Gay1In1-y1Asz1P1-z1基区基区322、Gay1In1-y1Asz1P1-z1基区发射区323、InP窗口层324,其中0≤y1≤0.5,0≤z1≤1。Wherein, the first junction GaInAsP sub-cell 320 includes from bottom to top: InP back field 321, Ga y1 In 1-y1 As z1 P 1-z1 base area 322, Ga y1 In 1-y1 As z1 P 1-z1 base area Emitting region 323, InP window layer 324, where 0≤y1≤0.5, 0≤z1≤1.

第二结GaInAsP子电池340由下向上包括:InP背场341、Gay2In1-y2Asz2P1-z2基区342、Gay2In1-y2Asz2P1-z2发射区343、InP窗口层344,其中0≤y2≤0.5,0≤z2≤1。The second junction GaInAsP sub-cell 340 includes from bottom to top: InP back field 341, Ga y2 In 1-y2 As z2 P 1-z2 base region 342, Ga y2 In 1-y2 As z2 P 1-z2 emitter region 343, InP The window layer 344, where 0≤y2≤0.5, 0≤z2≤1.

p型电极接触层310为p型InP层,掺杂浓度为1×1018~1×1019cm-3,厚度为100~200nm。The p-type electrode contact layer 310 is a p-type InP layer with a doping concentration of 1×10 18 to 1×10 19 cm −3 and a thickness of 100 to 200 nm.

InP背场321、341为p型掺杂,掺杂浓度为1×1017~1×1018cm-3,厚度为50~400nm。The InP back fields 321 and 341 are p-type doped, the doping concentration is 1×10 17 ˜1×10 18 cm −3 , and the thickness is 50˜400 nm.

InP窗口层324、344为n型掺杂,掺杂浓度为1×1017~1×1018cm-3,厚度为50~400nm。The InP window layers 324 and 344 are n-type doped, the doping concentration is 1×10 17 ˜1×10 18 cm −3 , and the thickness is 50˜400 nm.

Gay1In1-y1Asz1P1-z1基区322为p型掺杂,掺杂浓度为1×1016~1×1018cm-3,厚度为1000~5000nm。The Ga y1 In 1-y1 As z1 P 1-z1 base region 322 is p-type doped, the doping concentration is 1×10 16 ˜1×10 18 cm −3 , and the thickness is 1000˜5000 nm.

Gay1In1-y1Asz1P1-z1发射区323为n型掺杂,掺杂浓度为1×1017~1×1019cm-3,厚度为100~500nm。The Ga y1 In 1-y1 As z1 P 1-z1 emission region 323 is n-type doped, the doping concentration is 1×10 17 ˜1×10 19 cm −3 , and the thickness is 100˜500 nm.

Gay2In1-y2Asz2P1-z2基区342为p型掺杂,掺杂浓度为1×1016~1×1018cm-3,厚度为1000~5000nm。The Ga y2 In 1-y2 As z2 P 1-z2 base region 342 is p-type doped, the doping concentration is 1×10 16 ˜1×10 18 cm −3 , and the thickness is 1000˜5000 nm.

Gay2In1-y2Asz2P1-z2发射区343为n型掺杂,掺杂浓度为1×1017~1×1019cm-3,厚度为100~500nm。The Ga y2 In 1-y2 As z2 P 1-z2 emission region 343 is n-type doped, the doping concentration is 1×10 17 ˜1×10 19 cm −3 , and the thickness is 100˜500 nm.

隧穿结包括:n型InP层334与p型InP层332,掺杂浓度为1×1019~1×1021cm-3,厚度为10~100nm。The tunnel junction includes: an n-type InP layer 334 and a p-type InP layer 332 with a doping concentration of 1×10 19 ˜1×10 21 cm −3 and a thickness of 10˜100 nm.

n型电极接触层350为n型GaInAs层,掺杂浓度为1×1018~1×1019cm-3,厚度为100~200nm。The n-type electrode contact layer 350 is an n-type GaInAs layer with a doping concentration of 1×10 18 to 1×10 19 cm −3 and a thickness of 100 to 200 nm.

上电极400与桥联电极700材料为Au/Ge/Ag,厚度为2~5μm;下电极200材料为Ti/Pd/Au/Ge/Au,厚度为4~8μm。The material of the upper electrode 400 and the bridging electrode 700 is Au/Ge/Ag, with a thickness of 2-5 μm; the material of the lower electrode 200 is Ti/Pd/Au/Ge/Au, with a thickness of 4-8 μm.

绝缘层600为聚酰亚胺胶。The insulating layer 600 is polyimide glue.

减反射结构500由下向上包括:氧化钛/氧化硅减反射膜、纳米阵列陷光结构。The anti-reflection structure 500 includes from bottom to top: titanium oxide/silicon oxide anti-reflection film, nano-array light trapping structure.

以上所述仅是对本发明的较佳实施例而已,并非对本发明作任何形式上的限制,凡是依据本发明的技术实质对以上实施例所做的任何简单修改,等同变化与修饰,均属于本发明技术方案的范围内。The above descriptions are only preferred embodiments of the present invention, and are not intended to limit the present invention in any form. Any simple modifications made to the above embodiments according to the technical essence of the present invention, equivalent changes and modifications, all belong to this invention. within the scope of the technical solution of the invention.

Claims (6)

1. A laser cell assembly, comprising: the device comprises an insulating substrate, M laser battery units, an isolation groove, an insulating layer and a bridging electrode; wherein: m is a natural number greater than 0;
the laser battery unit comprises a lower electrode, a battery epitaxial active layer, an upper electrode and an antireflection structure;
the isolation groove separates adjacent laser battery cells, the side wall of each laser battery cell is insulated and passivated by the insulating layer, the upper electrode and the lower electrode of each adjacent laser battery cell are connected by the bridging electrode, the adjacent laser battery cells are electrically connected, and M laser battery cells are sequentially connected in series;
the battery epitaxial active layer is a GaAs-based battery active layer and comprises the following components from bottom to top: a p-type electrode contact layer, a first junction Ga (In) As subcell, a tunneling junction, a second junction Ga (In) As subcell, and an n-type electrode contact layer;
the first junction Ga (In) As subcell comprises from bottom to top: gaInP back field, ga x1 In 1-x1 As base region, ga x1 In 1-x1 An As emission region and a GaInP window layer, wherein x1 is more than or equal to 0.8 and less than or equal to 1;
the second junctionThe Ga (In) As subcell comprises from bottom to top: gaInP back field, ga x2 In 1-x2 As base region, ga x2 In 1-x2 An As emission region and a GaInP window layer, wherein x2 is more than or equal to 0.8 and less than or equal to 1;
the p-type electrode contact layer is a p-type GaAs layer with doping concentration of 1×10 18 ~1×10 19 cm -3 The thickness is 100-200 nm;
the GaInP back field is p-type doped with doping concentration of 1×10 17 ~1×10 18 cm -3 The thickness is 50-400 nm;
the GaInP window layer is doped with n type with doping concentration of 1×10 17 ~1×10 18 cm -3 The thickness is 50-400 nm;
the Ga x1 In 1-x1 The As base region is doped with p type, and the doping concentration is 1 multiplied by 10 16 ~1×10 18 cm -3 The thickness is 1000-5000 nm;
the Ga x1 In 1-x1 The As emitting region is n-type doped with doping concentration of 1×10 17 ~1×10 19 cm -3 The thickness is 100-500 nm;
the Ga x2 In 1-x2 The As base region is doped with p type, and the doping concentration is 1 multiplied by 10 16 ~1×10 18 cm -3 The thickness is 1000-5000 nm;
the Ga x2 In 1-x2 The As emitting region is n-type doped with doping concentration of 1×10 17 ~1×10 19 cm -3 The thickness is 100-500 nm;
the tunneling junction includes: n-type GaAs and p-type GaAs layers with doping concentrations of 1×10 19 ~1×10 21 cm -3 The thickness is 10-100 nm;
the n-type electrode contact layer is an n-type GaAs layer with doping concentration of 1×10 18 ~1×10 19 cm -3 The thickness is 100-200 nm;
or, the battery epitaxial active layer is an InP-based battery active layer, which comprises from bottom to top: a p-type electrode contact layer, a first junction GaInAsP subcell, a tunneling junction, a second junction GaInAsP subcell, and an n-type electrode contact layer;
the first junction GaInAsP subcell includes from bottom to top: inP back surface field, ga y1 In 1-y1 As z1 P 1-z1 Base region, ga y1 In 1- y1 As z1 P 1-z1 An emission region and an InP window layer, wherein y1 is more than or equal to 0 and less than or equal to 0.5, and z1 is more than or equal to 0 and less than or equal to 1;
the second junction GaInAsP subcell includes from bottom to top: inP back surface field, ga y2 In 1-y2 As z2 P 1-z2 Base region, ga y2 In 1- y2 As z2 P 1-z2 An emission region and an InP window layer, wherein y2 is more than or equal to 0 and less than or equal to 0.5, and z2 is more than or equal to 0 and less than or equal to 1;
the p-type electrode contact layer is a p-type GaInAs layer with doping concentration of 1×10 18 ~1×10 19 cm -3 The thickness is 100-200 nm;
the InP back field is p-type doped with doping concentration of 1×10 17 ~1×10 18 cm -3 The thickness is 50-400 nm;
the InP window layer is n-type doped with doping concentration of 1×10 17 ~1×10 18 cm -3 The thickness is 50-400 nm;
the Ga y1 In 1-y1 As z1 P 1-z1 The base region is doped with p-type material with doping concentration of 1×10 16 ~1×10 18 cm -3 The thickness is 1000-5000 nm;
the Ga y1 In 1-y1 As z1 P 1-z1 The emitter region is doped n-type with doping concentration of 1×10 17 ~1×10 19 cm -3 The thickness is 100-500 nm;
the Ga y2 In 1-y2 As z2 P 1-z2 The base region is doped with p-type material with doping concentration of 1×10 16 ~1×10 18 cm -3 The thickness is 1000-5000 nm;
the Ga y2 In 1-y2 As z2 P 1-z2 The emitter region is doped n-type with doping concentration of 1×10 17 ~1×10 19 cm -3 The thickness is 100-500 nm;
the tunneling junction includes: n-type InP and p-type InPA layer with a doping concentration of 1X 10 19 ~1×10 21 cm -3 The thickness is 10-100 nm;
the n-type electrode contact layer is an n-type GaInAs layer with doping concentration of 1×10 18 ~1×10 19 cm -3 The thickness is 100-200 nm.
2. The laser cell assembly of claim 1, wherein: the insulating substrate is made of one of silicon oxide, polyimide and quartz.
3. The laser cell assembly of claim 1, wherein: the areas of the M laser battery cells are the same.
4. The laser cell assembly of claim 1, wherein: the upper electrode and the bridging electrode are made of Au/Ge/Ag, and the thickness is 2-5 mu m; the lower electrode is made of Ti/Pd/Au/Ge/Au, and the thickness is 4-8 mu m.
5. The laser cell assembly of claim 1, wherein: the insulating layer is polyimide glue.
6. The laser cell assembly of claim 1, wherein: the anti-reflection structure comprises from bottom to top: titanium oxide/silicon oxide antireflection film and nano array light trapping structure.
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