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CN114551335A - Semiconductor structure and forming method thereof - Google Patents

Semiconductor structure and forming method thereof Download PDF

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Publication number
CN114551335A
CN114551335A CN202011334080.6A CN202011334080A CN114551335A CN 114551335 A CN114551335 A CN 114551335A CN 202011334080 A CN202011334080 A CN 202011334080A CN 114551335 A CN114551335 A CN 114551335A
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opening
layer
forming
conductive
semiconductor structure
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刘睿
陈蓉峰
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Semiconductor Manufacturing International Shanghai Corp
Semiconductor Manufacturing International Beijing Corp
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Semiconductor Manufacturing International Beijing Corp
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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L21/00Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
    • H01L21/70Manufacture or treatment of devices consisting of a plurality of solid state components formed in or on a common substrate or of parts thereof; Manufacture of integrated circuit devices or of parts thereof
    • H01L21/71Manufacture of specific parts of devices defined in group H01L21/70
    • H01L21/768Applying interconnections to be used for carrying current between separate components within a device comprising conductors and dielectrics
    • H01L21/76801Applying interconnections to be used for carrying current between separate components within a device comprising conductors and dielectrics characterised by the formation and the after-treatment of the dielectrics, e.g. smoothing
    • H01L21/76802Applying interconnections to be used for carrying current between separate components within a device comprising conductors and dielectrics characterised by the formation and the after-treatment of the dielectrics, e.g. smoothing by forming openings in dielectrics
    • H01L21/76816Aspects relating to the layout of the pattern or to the size of vias or trenches
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L21/00Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
    • H01L21/70Manufacture or treatment of devices consisting of a plurality of solid state components formed in or on a common substrate or of parts thereof; Manufacture of integrated circuit devices or of parts thereof
    • H01L21/71Manufacture of specific parts of devices defined in group H01L21/70
    • H01L21/768Applying interconnections to be used for carrying current between separate components within a device comprising conductors and dielectrics
    • H01L21/76801Applying interconnections to be used for carrying current between separate components within a device comprising conductors and dielectrics characterised by the formation and the after-treatment of the dielectrics, e.g. smoothing
    • H01L21/76829Applying interconnections to be used for carrying current between separate components within a device comprising conductors and dielectrics characterised by the formation and the after-treatment of the dielectrics, e.g. smoothing characterised by the formation of thin functional dielectric layers, e.g. dielectric etch-stop, barrier, capping or liner layers
    • H01L21/76831Applying interconnections to be used for carrying current between separate components within a device comprising conductors and dielectrics characterised by the formation and the after-treatment of the dielectrics, e.g. smoothing characterised by the formation of thin functional dielectric layers, e.g. dielectric etch-stop, barrier, capping or liner layers in via holes or trenches, e.g. non-conductive sidewall liners
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L21/00Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
    • H01L21/70Manufacture or treatment of devices consisting of a plurality of solid state components formed in or on a common substrate or of parts thereof; Manufacture of integrated circuit devices or of parts thereof
    • H01L21/71Manufacture of specific parts of devices defined in group H01L21/70
    • H01L21/768Applying interconnections to be used for carrying current between separate components within a device comprising conductors and dielectrics
    • H01L21/76838Applying interconnections to be used for carrying current between separate components within a device comprising conductors and dielectrics characterised by the formation and the after-treatment of the conductors
    • H01L21/76841Barrier, adhesion or liner layers
    • H01L21/7685Barrier, adhesion or liner layers the layer covering a conductive structure
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L21/00Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
    • H01L21/70Manufacture or treatment of devices consisting of a plurality of solid state components formed in or on a common substrate or of parts thereof; Manufacture of integrated circuit devices or of parts thereof
    • H01L21/71Manufacture of specific parts of devices defined in group H01L21/70
    • H01L21/768Applying interconnections to be used for carrying current between separate components within a device comprising conductors and dielectrics
    • H01L21/76838Applying interconnections to be used for carrying current between separate components within a device comprising conductors and dielectrics characterised by the formation and the after-treatment of the conductors
    • H01L21/76877Filling of holes, grooves or trenches, e.g. vias, with conductive material
    • H01L21/76879Filling of holes, grooves or trenches, e.g. vias, with conductive material by selective deposition of conductive material in the vias, e.g. selective C.V.D. on semiconductor material, plating

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  • Internal Circuitry In Semiconductor Integrated Circuit Devices (AREA)

Abstract

一种半导体结构及其形成方法,包括:衬底,衬底包括基底和器件结构;位于器件结构上的导电层;位于导电层上的复合层,复合层包括第一膜层;位于衬底上的介质层,介质层内具有第一开口;位于第一膜层内的第二开口,第二开口的侧壁相对于第一开口的侧壁凹陷;位于第一开口和第二开口内的导电插塞。通过第二开口的侧壁相对于第一开口的侧壁凹陷,在平坦化处理形成导电插塞的过程中,能够有效增加平坦化处理溶液的流经路径,进而减小平坦化处理溶液对导电层的刻蚀损伤;另外,还可以使得导电插塞在第二开口内的生长受到限制,进而使得导电插塞在第二开口形成的结构更为致密,进一步的减小平坦化处理溶液流向导电层造成损伤。

Figure 202011334080

A semiconductor structure and a method for forming the same, comprising: a substrate, the substrate comprising a base and a device structure; a conductive layer on the device structure; a composite layer on the conductive layer, the composite layer comprising a first film layer; on the substrate The dielectric layer has a first opening in the dielectric layer; the second opening is located in the first film layer, and the sidewall of the second opening is recessed relative to the sidewall of the first opening; the conductive layer located in the first opening and the second opening plug. Since the sidewall of the second opening is recessed relative to the sidewall of the first opening, during the planarization process to form the conductive plug, the flow path of the planarization solution can be effectively increased, thereby reducing the electrical conductivity of the planarization solution. In addition, the growth of the conductive plug in the second opening can be restricted, so that the structure formed by the conductive plug in the second opening is more dense, and the flow of the planarization solution to the conductive plug is further reduced. layer damage.

Figure 202011334080

Description

半导体结构及其形成方法Semiconductor structure and method of forming the same

技术领域technical field

本发明涉及半导体制造技术领域,尤其涉及一种半导体结构及其形成方法。The present invention relates to the technical field of semiconductor manufacturing, and in particular, to a semiconductor structure and a method for forming the same.

背景技术Background technique

随着集成电路的制作向超大规模集成电路发展,集成电路内部的电路密度越来越大,所包含的元件数量也越来越多,这种发展使得晶圆表面无法提供足够的面积来制作所需的互连线。As the production of integrated circuits develops to VLSI, the circuit density inside the integrated circuit is getting larger and larger, and the number of components included is also increasing. This development makes the surface of the wafer unable to provide enough area to make the required interconnection.

为了满足元件缩小后的互连线需求,两层及两层以上的多层金属互连线的设计成为超大规模集成电路技术所通常采用的一种方法。目前,不同金属层或者金属层与衬底中的器件之间的导通,是通过金属层与金属层之间或者金属层与衬底之间的介质层中的导电插塞来实现的。In order to meet the requirements of interconnect lines after shrinking components, the design of multi-layer metal interconnect lines with two or more layers has become a method commonly used in VLSI technology. At present, the conduction between different metal layers or between the metal layers and the devices in the substrate is realized through conductive plugs in the dielectric layer between the metal layers and the metal layers or between the metal layers and the substrate.

目前通过选择性钨生长工艺制成的导电插塞能够有效的增大导电插塞的体积,进而增大导电插塞底部的接触面积,以此实现减小接触电阻的目的。At present, the conductive plug made by the selective tungsten growth process can effectively increase the volume of the conductive plug, thereby increasing the contact area of the bottom of the conductive plug, so as to achieve the purpose of reducing the contact resistance.

然而,现有技术中采用选择性钨生长工艺制成的导电插塞性能有待提高。However, the performance of the conductive plug made by the selective tungsten growth process in the prior art needs to be improved.

发明内容SUMMARY OF THE INVENTION

本发明解决的技术问题是提供一种半导体结构及其形成方法,能够有效的提升最终形成的半导体结构的性能。The technical problem solved by the present invention is to provide a semiconductor structure and a method for forming the same, which can effectively improve the performance of the finally formed semiconductor structure.

为解决上述问题,本发明提供一种半导体结构,包括:衬底,所述衬底包括基底以及位于所述基底上的器件结构;位于所述器件结构上的导电层;位于所述导电层上的至少一层复合层,所述复合层包括位于所述导电层上的第一膜层;位于所述衬底上的介质层,所述介质层覆盖所述器件结构和所述复合层,所述介质层内具有第一开口;位于所述第一膜层内的第二开口,所述第二开口的侧壁相对于所述第一开口的侧壁凹陷;位于所述第一开口和所述第二开口内的导电插塞。In order to solve the above problems, the present invention provides a semiconductor structure, comprising: a substrate, the substrate includes a base and a device structure located on the base; a conductive layer located on the device structure; located on the conductive layer At least one composite layer of the device, the composite layer includes a first film layer on the conductive layer; a dielectric layer on the substrate, the dielectric layer covers the device structure and the composite layer, so The dielectric layer has a first opening; a second opening located in the first film layer, the sidewall of the second opening is recessed relative to the sidewall of the first opening; located between the first opening and the the conductive plug in the second opening.

可选的,所述复合层还包括:位于所述第一膜层上的阻挡层,所述阻挡层内具有第三开口,所述第二开口的侧壁相对于所述第三开口的侧壁凹陷,所述导电插塞还位于所述第三开口内。Optionally, the composite layer further includes: a barrier layer on the first film layer, the barrier layer has a third opening, and the sidewall of the second opening is opposite to the side of the third opening The wall is recessed, and the conductive plug is also located in the third opening.

可选的,所述复合层还包括:位于所述阻挡层上的第二膜层,所述第二膜层内具有第四开口,所述第四开口的侧壁相对于所述第三开口的侧壁凹陷,所述导电插塞还位于所述第四开口内。Optionally, the composite layer further includes: a second film layer on the barrier layer, the second film layer has a fourth opening, and the sidewall of the fourth opening is opposite to the third opening The sidewall is recessed, and the conductive plug is also located in the fourth opening.

可选的,所述第一膜层和所述阻挡层的材料不相同;所述第二膜层和所述阻挡层的材料不相同。Optionally, the materials of the first film layer and the barrier layer are different; the materials of the second film layer and the barrier layer are different.

可选的,所述第一膜层的材料包括氮化铝;所述第二膜层的材料包括氮化铝。Optionally, the material of the first film layer includes aluminum nitride; the material of the second film layer includes aluminum nitride.

可选的,所述阻挡层的材料包括掺碳的氮化硅。Optionally, the material of the barrier layer includes carbon-doped silicon nitride.

可选的,所述导电插塞的材料包括钨。Optionally, the material of the conductive plug includes tungsten.

可选的,所述导电层的材料包括钴。Optionally, the material of the conductive layer includes cobalt.

可选的,所述器件结构包括晶体管结构。Optionally, the device structure includes a transistor structure.

可选的,所述晶体管结构包括:位于所述基底上的栅极结构;位于所述栅极结构两侧所述基底内的源漏掺杂层。Optionally, the transistor structure includes: a gate structure on the substrate; and source and drain doped layers in the substrate on both sides of the gate structure.

可选的,所述导电层位于所述源漏掺杂层或所述栅极结构上。Optionally, the conductive layer is located on the source-drain doped layer or the gate structure.

相应的,本发明的技术方案还提供了一种半导体结构的形成方法,包括:提供衬底,所述衬底包括基底以及位于所述基底上的器件结构;在所述器件结构上形成导电层;在所述导电层上形成至少一层复合层,所述复合层包括位于所述导电层上的第一膜层;在所述衬底上形成介质层,所述介质层覆盖所述器件结构和所述复合层,所述介质层内具有第一开口;在所述第一膜层内形成第二开口,所述第二开口的侧壁相对于所述第一开口的侧壁凹陷。在所述第一开口和所述第二开口内形成导电插塞。Correspondingly, the technical solution of the present invention also provides a method for forming a semiconductor structure, including: providing a substrate, the substrate comprising a base and a device structure on the base; forming a conductive layer on the device structure forming at least one composite layer on the conductive layer, the composite layer comprising a first film layer located on the conductive layer; forming a dielectric layer on the substrate, the dielectric layer covering the device structure and the composite layer, the dielectric layer has a first opening; a second opening is formed in the first film layer, and the sidewall of the second opening is recessed relative to the sidewall of the first opening. Conductive plugs are formed in the first opening and the second opening.

可选的,所述复合层还包括:位于所述第一膜层上的阻挡层,所述阻挡层内具有第三开口,所述第二开口的侧壁相对于所述第三开口的侧壁凹陷,所述导电插塞还位于所述第三开口内。Optionally, the composite layer further includes: a barrier layer on the first film layer, the barrier layer has a third opening, and the sidewall of the second opening is opposite to the side of the third opening The wall is recessed, and the conductive plug is also located in the third opening.

可选的,所述复合层还包括:位于所述阻挡层上的第二膜层,所述第二膜层内具有第四开口,所述第四开口的侧壁相对于所述第三开口的侧壁凹陷,所述导电插塞还位于所述第四开口内。Optionally, the composite layer further includes: a second film layer on the barrier layer, the second film layer has a fourth opening, and the sidewall of the fourth opening is opposite to the third opening The sidewall is recessed, and the conductive plug is also located in the fourth opening.

可选的,所述第一膜层和所述阻挡层的材料不相同;所述第二膜层和所述阻挡层的材料不相同。Optionally, the materials of the first film layer and the barrier layer are different; the materials of the second film layer and the barrier layer are different.

可选的,所述第一膜层的材料包括氮化铝;所述第二膜层的材料包括氮化铝。Optionally, the material of the first film layer includes aluminum nitride; the material of the second film layer includes aluminum nitride.

可选的,所述阻挡层的材料包括掺碳的氮化硅。Optionally, the material of the barrier layer includes carbon-doped silicon nitride.

可选的,所述第二开口的形成工艺包括各向同性的湿法刻蚀工艺。Optionally, the formation process of the second opening includes an isotropic wet etching process.

可选的,所述第四开口的形成工艺包括各向同性的湿法刻蚀工艺。Optionally, the formation process of the fourth opening includes an isotropic wet etching process.

可选的,所述第三开口的形成工艺包括各向异性的干法刻蚀工艺。Optionally, the formation process of the third opening includes an anisotropic dry etching process.

可选的,所述导电插塞的形成的方法包括:采用金属选择性生长工艺在所述第一开口、第二开口、第三开口以及第四开口内、以及在所述介质层的顶部表面形成初始导电插塞;对所述初始导电插塞进行平坦化处理,直至暴露出所述介质层的顶部表面为止,形成所述导电插塞。Optionally, the method for forming the conductive plug includes: using a metal selective growth process in the first opening, the second opening, the third opening and the fourth opening, and on the top surface of the dielectric layer forming initial conductive plugs; performing planarization treatment on the initial conductive plugs until the top surface of the dielectric layer is exposed, and forming the conductive plugs.

可选的,所述导电插塞的材料包括钨。Optionally, the material of the conductive plug includes tungsten.

可选的,所述平坦化处理的工艺包括化学机械打磨工艺。Optionally, the planarization process includes a chemical mechanical polishing process.

可选的,所述导电层的材料包括钴。Optionally, the material of the conductive layer includes cobalt.

可选的,所述器件结构包括晶体管结构。Optionally, the device structure includes a transistor structure.

可选的,所述晶体管结构包括:位于所述基底上的栅极结构;位于所述栅极结构两侧所述基底内的源漏掺杂层。Optionally, the transistor structure includes: a gate structure on the substrate; and source and drain doped layers in the substrate on both sides of the gate structure.

可选的,所述导电层位于所述源漏掺杂层或所述栅极结构上。Optionally, the conductive layer is located on the source-drain doped layer or the gate structure.

与现有技术相比,本发明的技术方案具有以下优点:Compared with the prior art, the technical solution of the present invention has the following advantages:

在本发明的技术方案的结构中,通过位于所述第一膜层内的第二开口,所述第二开口的侧壁相对于所述第一开口的侧壁凹陷。在后续通过平坦化处理形成所述导电插塞的过程中,能够有效增加平坦化处理溶液的流经路径,进而减小平坦化处理溶液对所述导电层的刻蚀损伤;另外,由于所述第二开口的侧壁相对于所述第一开口的侧壁凹陷,使得所述导电插塞在所述第二开口内的生长受到限制,进而使得所述导电插塞在所述第二开口形成的结构更为致密,进一步的减小平坦化处理溶液流向所述导电层,进而减小了平坦化处理溶液对所述导电层的刻蚀损伤。In the structure of the technical solution of the present invention, through the second opening located in the first film layer, the sidewall of the second opening is recessed relative to the sidewall of the first opening. In the subsequent process of forming the conductive plug through the planarization treatment, the flow path of the planarization treatment solution can be effectively increased, thereby reducing the etching damage to the conductive layer caused by the planarization treatment solution; The sidewall of the second opening is recessed relative to the sidewall of the first opening, so that the growth of the conductive plug in the second opening is limited, so that the conductive plug is formed in the second opening The structure is more compact, which further reduces the flow of the planarization treatment solution to the conductive layer, thereby reducing the etching damage of the planarization treatment solution to the conductive layer.

进一步,所述复合层还包括:位于所述第一膜层上的阻挡层,所述阻挡层内具有第三开口,所述第二开口的侧壁相对于所述第三开口的侧壁凹陷。通过所述阻挡层进一步的增加了平坦化处理溶液的流经路径,进而减小平坦化处理溶液对所述导电层的刻蚀损伤。Further, the composite layer further includes: a barrier layer on the first film layer, the barrier layer has a third opening therein, and the sidewall of the second opening is recessed relative to the sidewall of the third opening . The barrier layer further increases the flow path of the planarization treatment solution, thereby reducing the etching damage to the conductive layer caused by the planarization treatment solution.

进一步,所述复合层还包括:位于所述阻挡层上的第二膜层,所述第二膜层内具有第四开口,所述第四开口的侧壁相对于所述第三开口的侧壁凹陷,所述导电插塞还位于所述第四开口内。通过所述第二膜层进一步的增加了平坦化处理溶液的流经路径,进而减小平坦化处理溶液对所述导电层的刻蚀损伤。另外,由于所述第四开口的侧壁相对于所述第三开口的侧壁凹陷,使得所述导电插塞在所述第四开口内的生长受到限制,进而使得所述导电插塞在所述第四开口形成的结构更为致密,进一步的减小平坦化处理溶液流向所述导电层,进而减小了平坦化处理溶液对所述导电层的刻蚀损伤。Further, the composite layer further includes: a second film layer on the barrier layer, the second film layer has a fourth opening, and the side wall of the fourth opening is opposite to the side of the third opening The wall is recessed, and the conductive plug is also located in the fourth opening. The second film layer further increases the flow path of the planarization treatment solution, thereby reducing the etching damage of the planarization treatment solution to the conductive layer. In addition, since the sidewall of the fourth opening is recessed relative to the sidewall of the third opening, the growth of the conductive plug in the fourth opening is limited, so that the conductive plug is located in the fourth opening. The structure formed by the fourth opening is more compact, which further reduces the flow of the planarization treatment solution to the conductive layer, thereby reducing the etching damage to the conductive layer caused by the planarization treatment solution.

在本发明的技术方案的形成方法中,通过在所述第一膜层内形成第二开口,所述第二开口的侧壁相对于所述第一开口的侧壁凹陷。在后续通过平坦化处理形成所述导电插塞的过程中,能够有效增加平坦化处理溶液的流经路径,进而减小平坦化处理溶液对所述导电层的刻蚀损伤;另外,由于所述第二开口的侧壁相对于所述第一开口的侧壁凹陷,使得所述导电插塞在所述第二开口内的生长受到限制,进而使得所述导电插塞在所述第二开口形成的结构更为致密,进一步的减小平坦化处理溶液流向所述导电层,进而减小了平坦化处理溶液对所述导电层的刻蚀损伤。In the formation method of the technical solution of the present invention, by forming the second opening in the first film layer, the side wall of the second opening is recessed relative to the side wall of the first opening. In the subsequent process of forming the conductive plug through the planarization treatment, the flow path of the planarization treatment solution can be effectively increased, thereby reducing the etching damage to the conductive layer caused by the planarization treatment solution; The sidewall of the second opening is recessed relative to the sidewall of the first opening, so that the growth of the conductive plug in the second opening is limited, so that the conductive plug is formed in the second opening The structure is more compact, which further reduces the flow of the planarization treatment solution to the conductive layer, thereby reducing the etching damage of the planarization treatment solution to the conductive layer.

进一步,所述复合层还包括:位于所述第一膜层上的阻挡层,所述阻挡层内具有第三开口,所述第二开口的侧壁相对于所述第三开口的侧壁凹陷。通过所述阻挡层进一步的增加了平坦化处理溶液的流经路径,进而减小平坦化处理溶液对所述导电层的刻蚀损伤。Further, the composite layer further includes: a barrier layer on the first film layer, the barrier layer has a third opening therein, and the sidewall of the second opening is recessed relative to the sidewall of the third opening . The barrier layer further increases the flow path of the planarization treatment solution, thereby reducing the etching damage to the conductive layer caused by the planarization treatment solution.

进一步,所述复合层还包括:位于所述阻挡层上的第二膜层,所述第二膜层内具有第四开口,所述第四开口的侧壁相对于所述第三开口的侧壁凹陷,所述导电插塞还位于所述第四开口内。通过所述第二膜层进一步的增加了平坦化处理溶液的流经路径,进而减小平坦化处理溶液对所述导电层的刻蚀损伤。另外,由于所述第四开口的侧壁相对于所述第三开口的侧壁凹陷,使得所述导电插塞在所述第四开口内的生长受到限制,进而使得所述导电插塞在所述第四开口形成的结构更为致密,进一步的减小平坦化处理溶液流向所述导电层,进而减小了平坦化处理溶液对所述导电层的刻蚀损伤。Further, the composite layer further includes: a second film layer on the barrier layer, the second film layer has a fourth opening, and the side wall of the fourth opening is opposite to the side of the third opening The wall is recessed, and the conductive plug is also located in the fourth opening. The second film layer further increases the flow path of the planarization treatment solution, thereby reducing the etching damage of the planarization treatment solution to the conductive layer. In addition, since the sidewall of the fourth opening is recessed relative to the sidewall of the third opening, the growth of the conductive plug in the fourth opening is limited, so that the conductive plug is located in the fourth opening. The structure formed by the fourth opening is more compact, which further reduces the flow of the planarization treatment solution to the conductive layer, thereby reducing the etching damage to the conductive layer caused by the planarization treatment solution.

附图说明Description of drawings

图1至图2是一种半导体结构的结构示意图;1 to 2 are schematic structural diagrams of a semiconductor structure;

图3至图10是本发明半导体结构形成方法实施例各步骤结构示意图。FIG. 3 to FIG. 10 are schematic structural diagrams of each step in an embodiment of the method for forming a semiconductor structure of the present invention.

具体实施方式Detailed ways

正如背景技术所述,现有技术中采用选择性钨生长工艺制成的导电插塞性能有待提高。以下将结合附图进行具体说明。As mentioned in the background art, the performance of the conductive plug made by the selective tungsten growth process in the prior art needs to be improved. The following will be described in detail with reference to the accompanying drawings.

请参考图1,提供衬底,所述衬底包括基底100以及位于所述基底100上的器件结构101;在所述器件结构101上形成导电层102;在所述衬底上形成介质层103,所述介质层103覆盖所述器件结构101和所述导电层102;在所述介质层103内形成导电开口104,所述导电开口104暴露出所述导电层102的部分顶部表面。Referring to FIG. 1, a substrate is provided, the substrate includes a base 100 and a device structure 101 on the base 100; a conductive layer 102 is formed on the device structure 101; a dielectric layer 103 is formed on the substrate , the dielectric layer 103 covers the device structure 101 and the conductive layer 102 ; a conductive opening 104 is formed in the dielectric layer 103 , and the conductive opening 104 exposes part of the top surface of the conductive layer 102 .

请参考图2,在所述导电开口104内和所述介质层103的顶部表面形成初始导电插塞(未图示);对所述初始导电插塞进行平坦化处理,直至暴露出所述介质层103的顶部表面为止,形成导电插塞105。Referring to FIG. 2, initial conductive plugs (not shown) are formed in the conductive openings 104 and on the top surface of the dielectric layer 103; the initial conductive plugs are planarized until the dielectric is exposed Up to the top surface of layer 103, conductive plugs 105 are formed.

在本实施例中,通过金属钨的选择性生长形成所述初始导电插塞,然而,由于钨仅能够在金属表面上进行生长,因此形成的初始导电插塞与所述导电开口104的侧壁之间的结合性并不是很好,使得初始导电插塞与所述导电开口的侧壁之间存在缝隙,在对所述初始导电插塞进行平化学机械掩膜的坦化的过程中,所使用的研磨碱性溶液会顺着所述导电开口104的侧壁流向所述导电层102,进而对所述导电层102造成一定的损伤,使得所述导电层102与所述导电插塞105的接触性降低,甚至会造成导电插塞105与所述导电层102完全不接触的问题(如图2中A部分所示),进而使得最终形成的半导体结构的性能降低。In this embodiment, the initial conductive plug is formed by selective growth of metal tungsten. However, since tungsten can only grow on the metal surface, the formed initial conductive plug is connected to the sidewall of the conductive opening 104 . The bonding between them is not very good, so that there is a gap between the initial conductive plug and the side wall of the conductive opening. The grinding alkaline solution used will flow to the conductive layer 102 along the sidewall of the conductive opening 104 , thereby causing certain damage to the conductive layer 102 , so that the conductive layer 102 and the conductive plug 105 are separated. The reduced contact may even lead to the problem that the conductive plug 105 is not in contact with the conductive layer 102 at all (as shown in part A in FIG. 2 ), thereby reducing the performance of the finally formed semiconductor structure.

在此基础上,本发明提供一种半导体结构及其形成方法,通过在所述第一膜层内形成第二开口,所述第二开口的侧壁相对于所述第一开口的侧壁凹陷。在后续通过平坦化处理形成所述导电插塞的过程中,能够有效增加平坦化处理溶液的流经路径,进而减小平坦化处理溶液对所述导电层的刻蚀损伤;另外,由于所述第二开口的侧壁相对于所述第一开口的侧壁凹陷,使得所述导电插塞在所述第二开口内的生长受到限制,进而使得所述导电插塞在所述第二开口形成的结构更为致密,进一步的减小平坦化处理溶液流向所述导电层,进而减小了平坦化处理溶液对所述导电层的刻蚀损伤。On this basis, the present invention provides a semiconductor structure and a method for forming the same. By forming a second opening in the first film layer, the sidewall of the second opening is recessed relative to the sidewall of the first opening. . In the subsequent process of forming the conductive plug through the planarization treatment, the flow path of the planarization treatment solution can be effectively increased, thereby reducing the etching damage to the conductive layer caused by the planarization treatment solution; The sidewall of the second opening is recessed relative to the sidewall of the first opening, so that the growth of the conductive plug in the second opening is limited, so that the conductive plug is formed in the second opening The structure is more compact, which further reduces the flow of the planarization treatment solution to the conductive layer, thereby reducing the etching damage of the planarization treatment solution to the conductive layer.

为使本发明的上述目的、特征和优点能够更为明显易懂,下面结合附图对本发明的具体实施例做详细地说明。In order to make the above objects, features and advantages of the present invention more clearly understood, the specific embodiments of the present invention will be described in detail below with reference to the accompanying drawings.

图3至图10是本发明实施例的一种半导体结构的形成过程的结构示意图。3 to 10 are schematic structural diagrams of a process of forming a semiconductor structure according to an embodiment of the present invention.

请参考图3,提供衬底,所述衬底包括基底200以及位于所述基底200上的器件结构201。Referring to FIG. 3 , a substrate is provided, and the substrate includes a base 200 and a device structure 201 on the base 200 .

在本实施例中,所述基底200具有若干相互分立的鳍部(未标示),以及位于覆盖部分所述鳍部的隔离层(未标示),所述隔离层的顶部表面低于所述鳍部的顶部表面。在其他实施例中,所述基底还可以具有若干有源区,相邻的所述有源区之间具有隔离层。In this embodiment, the substrate 200 has a plurality of fins (not shown) separated from each other, and an isolation layer (not shown) covering part of the fins, and the top surface of the isolation layer is lower than the fins top surface of the part. In other embodiments, the substrate may further have several active regions, and an isolation layer is provided between adjacent active regions.

在本实施例中,所述器件结构201包括晶体管结构,所述晶体管结构包括:位于所述基底上的栅极结构(未标示),所述栅极结构横跨所述鳍部,且所述栅极结构覆盖所述鳍部的部分侧壁和顶部表面;位于所述栅极结构两侧所述基底内的源漏掺杂层(未标示)。In this embodiment, the device structure 201 includes a transistor structure including: a gate structure (not labeled) on the substrate, the gate structure spans the fin, and the The gate structure covers part of the sidewalls and the top surface of the fin; source and drain doped layers (not marked) in the substrate on both sides of the gate structure.

请参考图4,在所述器件结构201上形成导电层202。Referring to FIG. 4 , a conductive layer 202 is formed on the device structure 201 .

在本实施例中,所述导电层202位于所述源漏掺杂层上。在其他实施例中,所述导电层还可以位于所述栅极结构上。In this embodiment, the conductive layer 202 is located on the source and drain doped layers. In other embodiments, the conductive layer may also be located on the gate structure.

在本实施例中,所述导电层202的材料采用钴。In this embodiment, the material of the conductive layer 202 is cobalt.

请参考图5,在所述导电层202上形成至少一层复合层,所述复合层包括位于所述导电层202上的第一膜层203。Referring to FIG. 5 , at least one composite layer is formed on the conductive layer 202 , and the composite layer includes a first film layer 203 on the conductive layer 202 .

在本实施例中,所述复合层还包括:位于所述第一膜层203上的阻挡层204。In this embodiment, the composite layer further includes: a barrier layer 204 located on the first film layer 203 .

在本实施例中,所述复合层还包括:位于所述阻挡层204上的第二膜层205。In this embodiment, the composite layer further includes: a second film layer 205 located on the barrier layer 204 .

在本实施例中,所述第一膜层203和所述阻挡层204的材料不相同;所述第二膜层205和所述阻挡层204的材料不相同。通过选择不同的材料,在后续刻蚀过程中,增大不同膜层之间的刻蚀选择比,减小对其他膜层的损伤。In this embodiment, the materials of the first film layer 203 and the barrier layer 204 are different; the materials of the second film layer 205 and the barrier layer 204 are different. By selecting different materials, in the subsequent etching process, the etching selectivity ratio between different film layers is increased, and the damage to other film layers is reduced.

在本实施例中,所述第一膜层203的材料包括氮化铝;所述第二膜层205的材料包括氮化铝。In this embodiment, the material of the first film layer 203 includes aluminum nitride; the material of the second film layer 205 includes aluminum nitride.

在本实施例中,所述阻挡层204的材料包括掺碳的氮化硅。In this embodiment, the material of the barrier layer 204 includes carbon-doped silicon nitride.

请参考图6,在形成所述复合层之后,在所述衬底上形成介质层206,所述介质层206覆盖所述器件结构201和所述复合层,所述介质层206内具有第一开口207。Referring to FIG. 6 , after the composite layer is formed, a dielectric layer 206 is formed on the substrate, the dielectric layer 206 covers the device structure 201 and the composite layer, and the dielectric layer 206 has a first Opening 207.

在本实施例中,所述介质层206的形成方法包括:在所述复合层上形成初始介质层(未图示);在所述初始介质层上形成图形化层(未图示),所述图形化层暴露出部分所述初始介质层的顶部表面;以所述图形化层为掩膜刻蚀所述初始介质层,直至暴露出所述复合的顶部表面为止,形成所述介质层206。In this embodiment, the method for forming the dielectric layer 206 includes: forming an initial dielectric layer (not shown) on the composite layer; forming a patterned layer (not shown) on the initial dielectric layer, so that The patterned layer exposes part of the top surface of the initial dielectric layer; the initial dielectric layer is etched with the patterned layer as a mask until the top surface of the composite is exposed, forming the dielectric layer 206 .

在本实施例中,所述介质层206的材料采用氧化硅;在其他实施例中,所述介质层的材料还可以为低K介质材料(低K介质材料指相对介电常数低于3.9的介质材料)或超低K介质材料(超低K介质材料指相对介电常数低于2.5的介质材料)。In this embodiment, the material of the dielectric layer 206 is silicon oxide; in other embodiments, the material of the dielectric layer may also be a low-K dielectric material (low-K dielectric material refers to a material with a relative permittivity lower than 3.9). dielectric material) or ultra-low-K dielectric material (ultra-low-K dielectric material refers to a dielectric material with a relative permittivity lower than 2.5).

在形成所述介质层206之后,还包括:在所述第一膜层203内形成第二开口,所述第二开口的侧壁相对于所述第一开口207的侧壁凹陷;在所述阻挡层204内形成第三开口,所述第二开口的侧壁相对于所述第三开口的侧壁凹陷;在所述第二膜层205内形成第四开口,所述第四开口的侧壁相对于所述第三开口的侧壁凹陷。具体形成过程请参考图7至图9。After forming the dielectric layer 206, the method further includes: forming a second opening in the first film layer 203, and the sidewall of the second opening is recessed relative to the sidewall of the first opening 207; A third opening is formed in the barrier layer 204, and the sidewall of the second opening is recessed relative to the sidewall of the third opening; a fourth opening is formed in the second film layer 205, and the sidewall of the fourth opening is The wall is recessed relative to the side wall of the third opening. Please refer to FIG. 7 to FIG. 9 for the specific forming process.

请参考图7,以所述介质层206为掩膜刻蚀所述第二膜层205,在所述第二膜层205内形成所述第四开口208。Referring to FIG. 7 , the second film layer 205 is etched using the dielectric layer 206 as a mask, and the fourth opening 208 is formed in the second film layer 205 .

在本实施例中,所述第四开口208的形成工艺包括各向同性的湿法刻蚀工艺。In this embodiment, the formation process of the fourth opening 208 includes an isotropic wet etching process.

请参考图8,以所述介质层206和第二膜层205为掩膜刻蚀所述阻挡层204,在所述阻挡层204内形成所述第三开口209。Referring to FIG. 8 , the barrier layer 204 is etched using the dielectric layer 206 and the second film layer 205 as masks, and the third opening 209 is formed in the barrier layer 204 .

在本实施例中,所述第三开口209的形成工艺包括各向异性的干法刻蚀工艺。In this embodiment, the formation process of the third opening 209 includes an anisotropic dry etching process.

请参考图9,以所述介质层206、第二膜层205以及阻挡层204为掩膜刻蚀所述第一膜层203,在所述第一膜层203内形成所述第二开口210。Referring to FIG. 9 , the first film layer 203 is etched using the dielectric layer 206 , the second film layer 205 and the barrier layer 204 as masks, and the second opening 210 is formed in the first film layer 203 .

在本实施例中,所述第二开口210的形成工艺包括各向同性的湿法刻蚀工艺。In this embodiment, the formation process of the second opening 210 includes an isotropic wet etching process.

在本实施例中,通过在所述第一膜层203内形成第二开口210,所述第二开口210的侧壁相对于所述第一开口207的侧壁凹陷。在后续通过平坦化处理形成所述导电插塞的过程中,能够有效增加平坦化处理溶液的流经路径,进而减小平坦化处理溶液对所述导电层的刻蚀损伤;另外,由于所述第二开口210的侧壁相对于所述第一开口207的侧壁凹陷,使得所述导电插塞在所述第二开口210内的生长受到限制,进而使得所述导电插塞在所述第二开口210形成的结构更为致密,进一步的减小平坦化处理溶液流向所述导电层202,进而减小了平坦化处理溶液对所述导电层202的刻蚀损伤。In this embodiment, by forming the second opening 210 in the first film layer 203 , the sidewall of the second opening 210 is recessed relative to the sidewall of the first opening 207 . In the subsequent process of forming the conductive plug through the planarization treatment, the flow path of the planarization treatment solution can be effectively increased, thereby reducing the etching damage to the conductive layer caused by the planarization treatment solution; The sidewall of the second opening 210 is recessed relative to the sidewall of the first opening 207 , so that the growth of the conductive plug in the second opening 210 is restricted, so that the conductive plug is in the first opening 210 . The structure formed by the two openings 210 is more compact, which further reduces the flow of the planarization treatment solution to the conductive layer 202, thereby reducing the etching damage to the conductive layer 202 caused by the planarization treatment solution.

通过所述阻挡层204进一步的增加了平坦化处理溶液的流经路径,进而减小平坦化处理溶液对所述导电层202的刻蚀损伤。The barrier layer 204 further increases the flow path of the planarization solution, thereby reducing the etching damage to the conductive layer 202 caused by the planarization solution.

通过所述第二膜层205进一步的增加了平坦化处理溶液的流经路径,进而减小平坦化处理溶液对所述导电层的刻蚀损伤。另外,由于所述第四开口208的侧壁相对于所述第三开口209的侧壁凹陷,使得所述导电插塞在所述第四开口208内的生长受到限制,进而使得所述导电插塞在所述第四开口208形成的结构更为致密,进一步的减小平坦化处理溶液流向所述导电层202,进而减小了平坦化处理溶液对所述导电层202的刻蚀损伤。The second film layer 205 further increases the flow path of the planarization treatment solution, thereby reducing the etching damage of the planarization treatment solution to the conductive layer. In addition, since the sidewall of the fourth opening 208 is recessed relative to the sidewall of the third opening 209 , the growth of the conductive plug in the fourth opening 208 is restricted, thereby making the conductive plug The structure formed by plugging in the fourth opening 208 is more compact, which further reduces the flow of the planarization treatment solution to the conductive layer 202 , and further reduces the etching damage to the conductive layer 202 caused by the planarization treatment solution.

请参考图10,在所述第一开口207和所述第二开口210内形成导电插塞211。Referring to FIG. 10 , conductive plugs 211 are formed in the first opening 207 and the second opening 210 .

在本实施例中,所述导电插塞211还位于所述第三开口209和所述第四开口208内。In this embodiment, the conductive plug 211 is also located in the third opening 209 and the fourth opening 208 .

在本实施例中,所述导电插塞211的形成的方法包括:采用金属选择性生长工艺在所述第一开口207、第二开口210、第三开口209以及第四开口208内、以及在所述介质层206的顶部表面形成初始导电插塞(未图示);对所述初始导电插塞进行平坦化处理,直至暴露出所述介质层206的顶部表面为止,形成所述导电插塞211。In this embodiment, the method for forming the conductive plug 211 includes: adopting a metal selective growth process in the first opening 207 , the second opening 210 , the third opening 209 and the fourth opening 208 , and in the An initial conductive plug (not shown) is formed on the top surface of the dielectric layer 206; the initial conductive plug is planarized until the top surface of the dielectric layer 206 is exposed, and the conductive plug is formed 211.

在本实施例中,所述导电插塞211的材料包括钨。In this embodiment, the material of the conductive plug 211 includes tungsten.

在本实施例中,所述平坦化处理的工艺包括化学机械打磨工艺。In this embodiment, the planarization process includes a chemical mechanical polishing process.

相应的,本发明实施例还提供了一种半导体结构,请继续参考图10,包括:衬底,所述衬底包括基底200以及位于所述基底200上的器件结构201;位于所述器件结构201上的导电层202;位于所述导电层202上的至少一层复合层,所述复合层包括位于所述导电层202上的第一膜层203;位于所述衬底上的介质层206,所述介质层206覆盖所述器件结构201和所述复合层,所述介质层206内具有第一开口207;位于所述第一膜层203内的第二开口210,所述第二开口210的侧壁相对于所述第一开口207的侧壁凹陷;位于所述第一开口207和所述第二开口210内的导电插塞211。Correspondingly, an embodiment of the present invention further provides a semiconductor structure, please continue to refer to FIG. 10 , including: a substrate, the substrate includes a base 200 and a device structure 201 located on the base 200; Conductive layer 202 on 201; at least one composite layer on the conductive layer 202, the composite layer including a first film layer 203 on the conductive layer 202; dielectric layer 206 on the substrate , the dielectric layer 206 covers the device structure 201 and the composite layer, the dielectric layer 206 has a first opening 207; the second opening 210 located in the first film layer 203, the second opening The side wall of 210 is recessed relative to the side wall of the first opening 207 ; the conductive plugs 211 are located in the first opening 207 and the second opening 210 .

在本实施例中,通过位于所述第一膜层203内的第二开口210,所述第二开口210的侧壁相对于所述第一开口207的侧壁凹陷。在后续通过平坦化处理形成所述导电插塞211的过程中,能够有效增加平坦化处理溶液的流经路径,进而减小平坦化处理溶液对所述导电层的刻蚀损伤;另外,由于所述第二开口210的侧壁相对于所述第一开口207的侧壁凹陷,使得所述导电插塞211在所述第二开口210内的生长受到限制,进而使得所述导电插塞211在所述第二开口210形成的结构更为致密,进一步的减小平坦化处理溶液流向所述导电层202,进而减小了平坦化处理溶液对所述导电层202的刻蚀损伤。In this embodiment, the sidewall of the second opening 210 is recessed relative to the sidewall of the first opening 207 through the second opening 210 in the first film layer 203 . In the subsequent process of forming the conductive plug 211 through the planarization treatment, the flow path of the planarization treatment solution can be effectively increased, thereby reducing the etching damage to the conductive layer by the planarization treatment solution; The sidewall of the second opening 210 is recessed relative to the sidewall of the first opening 207 , so that the growth of the conductive plug 211 in the second opening 210 is restricted, so that the conductive plug 211 is The structure formed by the second opening 210 is more compact, which further reduces the flow of the planarization treatment solution to the conductive layer 202, thereby reducing the etching damage to the conductive layer 202 caused by the planarization treatment solution.

在本实施例中,所述复合层还包括:位于所述第一膜层203上的阻挡层204,所述阻挡层204内具有第三开口209,所述第二开口210的侧壁相对于所述第三开口209的侧壁凹陷,所述导电插塞211还位于所述第三开口209内。通过所述阻挡层204进一步的增加了平坦化处理溶液的流经路径,进而减小平坦化处理溶液对所述导电层202的刻蚀损伤。In this embodiment, the composite layer further includes: a barrier layer 204 located on the first film layer 203, the barrier layer 204 has a third opening 209 inside, and the sidewall of the second opening 210 is opposite to The sidewall of the third opening 209 is recessed, and the conductive plug 211 is also located in the third opening 209 . The barrier layer 204 further increases the flow path of the planarization solution, thereby reducing the etching damage to the conductive layer 202 caused by the planarization solution.

在本实施例中,所述复合层还包括:位于所述阻挡层204上的第二膜层205,所述第二膜层205内具有第四开口208,所述第四开口208的侧壁相对于所述第三开口209的侧壁凹陷,所述导电插塞211还位于所述第四开口208内。通过所述第二膜层205进一步的增加了平坦化处理溶液的流经路径,进而减小平坦化处理溶液对所述导电层202的刻蚀损伤。另外,由于所述第四开口208的侧壁相对于所述第三开口209的侧壁凹陷,使得所述导电插塞211在所述第四开口208内的生长受到限制,进而使得所述导电插塞211在所述第四开口208形成的结构更为致密,进一步的减小平坦化处理溶液流向所述导电层202,进而减小了平坦化处理溶液对所述导电层202的刻蚀损伤。In this embodiment, the composite layer further includes: a second film layer 205 located on the barrier layer 204 , the second film layer 205 has a fourth opening 208 inside, and the sidewall of the fourth opening 208 Relative to the sidewall of the third opening 209 , the conductive plug 211 is also located in the fourth opening 208 . The second film layer 205 further increases the flow path of the planarization treatment solution, thereby reducing the etching damage of the planarization treatment solution to the conductive layer 202 . In addition, since the sidewall of the fourth opening 208 is recessed relative to the sidewall of the third opening 209 , the growth of the conductive plug 211 in the fourth opening 208 is limited, thereby making the conductive plug 211 limited. The structure formed by the plug 211 in the fourth opening 208 is more compact, which further reduces the flow of the planarization treatment solution to the conductive layer 202, thereby reducing the etching damage of the planarization treatment solution to the conductive layer 202 .

在本实施例中,所述第一膜层203和所述阻挡层204的材料不相同;所述第二膜层205和所述阻挡层204的材料不相同。In this embodiment, the materials of the first film layer 203 and the barrier layer 204 are different; the materials of the second film layer 205 and the barrier layer 204 are different.

在本实施例中,所述第一膜层203的材料包括氮化铝;所述第二膜层205的材料包括氮化铝。In this embodiment, the material of the first film layer 203 includes aluminum nitride; the material of the second film layer 205 includes aluminum nitride.

在本实施例中,所述阻挡层204的材料包括掺碳的氮化硅。In this embodiment, the material of the barrier layer 204 includes carbon-doped silicon nitride.

在本实施例中,所述导电插塞211的材料包括钨。In this embodiment, the material of the conductive plug 211 includes tungsten.

在本实施例中,所述导电层202的材料包括钴。In this embodiment, the material of the conductive layer 202 includes cobalt.

在本实施例中,所述器件结构201包括晶体管结构。In this embodiment, the device structure 201 includes a transistor structure.

在本实施例中,所述晶体管结构包括:位于所述基底200上的栅极结构;位于所述栅极结构两侧所述基底内的源漏掺杂层。In this embodiment, the transistor structure includes: a gate structure on the substrate 200 ; source and drain doped layers in the substrate on both sides of the gate structure.

在本实施例中,所述导电层202位于所述源漏掺杂层。在其他实施例中,所述导电层还可以位于所述栅极结构上。In this embodiment, the conductive layer 202 is located in the source-drain doped layer. In other embodiments, the conductive layer may also be located on the gate structure.

虽然本发明披露如上,但本发明并非限定于此。任何本领域技术人员,在不脱离本发明的精神和范围内,均可作各种更动与修改,因此本发明的保护范围应当以权利要求所限定的范围为准。Although the present invention is disclosed above, the present invention is not limited thereto. Any person skilled in the art can make various changes and modifications without departing from the spirit and scope of the present invention. Therefore, the protection scope of the present invention should be based on the scope defined by the claims.

Claims (27)

1.一种半导体结构,其特征在于,包括:1. a semiconductor structure, is characterized in that, comprises: 衬底,所述衬底包括基底以及位于所述基底上的器件结构;a substrate, the substrate comprising a base and a device structure on the base; 位于所述器件结构上的导电层;a conductive layer on the device structure; 位于所述导电层上的至少一层复合层,所述复合层包括位于所述导电层上的第一膜层;at least one composite layer on the conductive layer, the composite layer including a first film layer on the conductive layer; 位于所述衬底上的介质层,所述介质层覆盖所述器件结构和所述复合层,所述介质层内具有第一开口;a dielectric layer on the substrate, the dielectric layer covering the device structure and the composite layer, and a first opening is provided in the dielectric layer; 位于所述第一膜层内的第二开口,所述第二开口的侧壁相对于所述第一开口的侧壁凹陷;a second opening located in the first film layer, the sidewall of the second opening is recessed relative to the sidewall of the first opening; 位于所述第一开口和所述第二开口内的导电插塞。conductive plugs located within the first opening and the second opening. 2.如权利要求1所述半导体结构,其特征在于,所述复合层还包括:位于所述第一膜层上的阻挡层,所述阻挡层内具有第三开口,所述第二开口的侧壁相对于所述第三开口的侧壁凹陷,所述导电插塞还位于所述第三开口内。2 . The semiconductor structure according to claim 1 , wherein the composite layer further comprises: a barrier layer located on the first film layer, the barrier layer has a third opening therein, and the second opening has a third opening. 3 . The side wall is recessed relative to the side wall of the third opening, and the conductive plug is also located in the third opening. 3.如权利要求2所述半导体结构,其特征在于,所述复合层还包括:位于所述阻挡层上的第二膜层,所述第二膜层内具有第四开口,所述第四开口的侧壁相对于所述第三开口的侧壁凹陷,所述导电插塞还位于所述第四开口内。3 . The semiconductor structure of claim 2 , wherein the composite layer further comprises: a second film layer located on the barrier layer, the second film layer has a fourth opening therein, and the fourth film layer is 3 . The sidewall of the opening is recessed relative to the sidewall of the third opening, and the conductive plug is also located in the fourth opening. 4.如权利要求3所述半导体结构,其特征在于,所述第一膜层和所述阻挡层的材料不相同;所述第二膜层和所述阻挡层的材料不相同。4 . The semiconductor structure of claim 3 , wherein the materials of the first film layer and the barrier layer are different; and the materials of the second film layer and the barrier layer are different. 5 . 5.如权利要求4所述半导体结构,其特征在于,所述第一膜层的材料包括氮化铝;所述第二膜层的材料包括氮化铝。5 . The semiconductor structure of claim 4 , wherein the material of the first film layer comprises aluminum nitride; the material of the second film layer comprises aluminum nitride. 6 . 6.如权利要求4所述半导体结构,其特征在于,所述阻挡层的材料包括掺碳的氮化硅。6. The semiconductor structure of claim 4, wherein the material of the barrier layer comprises carbon-doped silicon nitride. 7.如权利要求1所述半导体结构,其特征在于,所述导电插塞的材料包括钨。7. The semiconductor structure of claim 1, wherein the material of the conductive plug comprises tungsten. 8.如权利要求1所述半导体结构,其特征在于,所述导电层的材料包括钴。8. The semiconductor structure of claim 1, wherein the material of the conductive layer comprises cobalt. 9.如权利要求1所述半导体结构,其特征在于,所述器件结构包括晶体管结构。9. The semiconductor structure of claim 1, wherein the device structure comprises a transistor structure. 10.如权利要求9所述半导体结构,其特征在于,所述晶体管结构包括:位于所述基底上的栅极结构;位于所述栅极结构两侧所述基底内的源漏掺杂层。10 . The semiconductor structure of claim 9 , wherein the transistor structure comprises: a gate structure on the substrate; and source-drain doped layers in the substrate on both sides of the gate structure. 11 . 11.如权利要求10所述半导体结构,其特征在于,所述导电层位于所述源漏掺杂层或所述栅极结构上。11. The semiconductor structure of claim 10, wherein the conductive layer is located on the source-drain doped layer or the gate structure. 12.一种半导体结构的形成方法,其特征在于,包括:12. A method for forming a semiconductor structure, comprising: 提供衬底,所述衬底包括基底以及位于所述基底上的器件结构;providing a substrate including a base and a device structure on the base; 在所述器件结构上形成导电层;forming a conductive layer on the device structure; 在所述导电层上形成至少一层复合层,所述复合层包括位于所述导电层上的第一膜层;forming at least one composite layer on the conductive layer, the composite layer comprising a first film layer on the conductive layer; 在所述衬底上形成介质层,所述介质层覆盖所述器件结构和所述复合层,所述介质层内具有第一开口;forming a dielectric layer on the substrate, the dielectric layer covering the device structure and the composite layer, and a first opening is formed in the dielectric layer; 在所述第一膜层内形成第二开口,所述第二开口的侧壁相对于所述第一开口的侧壁凹陷。A second opening is formed in the first film layer, and the sidewall of the second opening is recessed relative to the sidewall of the first opening. 在所述第一开口和所述第二开口内形成导电插塞。Conductive plugs are formed in the first opening and the second opening. 13.如权利要求12所述半导体结构的形成方法,其特征在于,所述复合层还包括:位于所述第一膜层上的阻挡层,所述阻挡层内具有第三开口,所述第二开口的侧壁相对于所述第三开口的侧壁凹陷,所述导电插塞还位于所述第三开口内。13 . The method for forming a semiconductor structure according to claim 12 , wherein the composite layer further comprises: a barrier layer located on the first film layer, the barrier layer has a third opening in the barrier layer, and the first film layer is 13 . The sidewalls of the second openings are recessed relative to the sidewalls of the third opening, and the conductive plug is also located in the third opening. 14.如权利要求13所述半导体结构的形成方法,其特征在于,所述复合层还包括:位于所述阻挡层上的第二膜层,所述第二膜层内具有第四开口,所述第四开口的侧壁相对于所述第三开口的侧壁凹陷,所述导电插塞还位于所述第四开口内。14 . The method for forming a semiconductor structure according to claim 13 , wherein the composite layer further comprises: a second film layer located on the barrier layer, the second film layer having a fourth opening therein, 14 . The side wall of the fourth opening is recessed relative to the side wall of the third opening, and the conductive plug is also located in the fourth opening. 15.如权利要求14所述半导体结构的形成方法,其特征在于,所述第一膜层和所述阻挡层的材料不相同;所述第二膜层和所述阻挡层的材料不相同。15 . The method for forming a semiconductor structure according to claim 14 , wherein the materials of the first film layer and the barrier layer are different; and the materials of the second film layer and the barrier layer are different. 16 . 16.如权利要求15所述半导体结构的形成方法,其特征在于,所述第一膜层的材料包括氮化铝;所述第二膜层的材料包括氮化铝。16. The method for forming a semiconductor structure according to claim 15, wherein the material of the first film layer comprises aluminum nitride; the material of the second film layer comprises aluminum nitride. 17.如权利要求15所述半导体结构的形成方法,其特征在于,所述阻挡层的材料包括掺碳的氮化硅。17 . The method for forming a semiconductor structure according to claim 15 , wherein the material of the barrier layer comprises carbon-doped silicon nitride. 18 . 18.如权利要求12所述半导体结构的形成方法,其特征在于,所述第二开口的形成工艺包括各向同性的湿法刻蚀工艺。18. The method for forming a semiconductor structure according to claim 12, wherein the forming process of the second opening comprises an isotropic wet etching process. 19.如权利要求14所述半导体结构的形成方法,其特征在于,所述第四开口的形成工艺包括各向同性的湿法刻蚀工艺。19 . The method for forming a semiconductor structure according to claim 14 , wherein the forming process of the fourth opening comprises an isotropic wet etching process. 20 . 20.如权利要求13所述半导体结构的形成方法,其特征在于,所述第三开口的形成工艺包括各向异性的干法刻蚀工艺。20 . The method for forming a semiconductor structure according to claim 13 , wherein the formation process of the third opening comprises an anisotropic dry etching process. 21 . 21.如权利要求14所述半导体结构的形成方法,其特征在于,所述导电插塞的形成的方法包括:采用金属选择性生长工艺在所述第一开口、第二开口、第三开口以及第四开口内、以及在所述介质层的顶部表面形成初始导电插塞;对所述初始导电插塞进行平坦化处理,直至暴露出所述介质层的顶部表面为止,形成所述导电插塞。21. The method for forming a semiconductor structure according to claim 14, wherein the method for forming the conductive plug comprises: adopting a metal selective growth process on the first opening, the second opening, the third opening and the forming initial conductive plugs in the fourth opening and on the top surface of the dielectric layer; performing a planarization process on the initial conductive plugs until the top surface of the dielectric layer is exposed to form the conductive plugs . 22.如权利要求12所述半导体结构的形成方法,其特征在于,所述导电插塞的材料包括钨。22. The method for forming a semiconductor structure according to claim 12, wherein the material of the conductive plug comprises tungsten. 23.如权利要求21所述半导体结构的形成方法,其特征在于,所述平坦化处理的工艺包括化学机械打磨工艺。23. The method for forming a semiconductor structure according to claim 21, wherein the planarization process comprises a chemical mechanical polishing process. 24.如权利要求12所述半导体结构的形成方法,其特征在于,所述导电层的材料包括钴。24. The method for forming a semiconductor structure according to claim 12, wherein the material of the conductive layer comprises cobalt. 25.如权利要求12所述半导体结构的形成方法,其特征在于,所述器件结构包括晶体管结构。25. The method of forming a semiconductor structure of claim 12, wherein the device structure comprises a transistor structure. 26.如权利要求25所述半导体结构的形成方法,其特征在于,所述晶体管结构包括:位于所述基底上的栅极结构;位于所述栅极结构两侧所述基底内的源漏掺杂层。26. The method for forming a semiconductor structure according to claim 25, wherein the transistor structure comprises: a gate structure located on the substrate; source-drain dopant located in the substrate on both sides of the gate structure Miscellaneous layers. 27.如权利要求26所述半导体结构的形成方法,其特征在于,所述导电层位于所述源漏掺杂层或所述栅极结构上。27. The method for forming a semiconductor structure according to claim 26, wherein the conductive layer is located on the source-drain doped layer or the gate structure.
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