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CN111118711A - Alginate fiber health-care antibacterial fabric and manufacturing method thereof - Google Patents

Alginate fiber health-care antibacterial fabric and manufacturing method thereof Download PDF

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Publication number
CN111118711A
CN111118711A CN201910849255.8A CN201910849255A CN111118711A CN 111118711 A CN111118711 A CN 111118711A CN 201910849255 A CN201910849255 A CN 201910849255A CN 111118711 A CN111118711 A CN 111118711A
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China
Prior art keywords
fiber
fabric
alginate
chitosan grafted
layer
Prior art date
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Pending
Application number
CN201910849255.8A
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Chinese (zh)
Inventor
刘琼
何立锋
刘浪
刘冰
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Ningbo Daqian Textile Co Ltd
Original Assignee
Ningbo Daqian Textile Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ningbo Daqian Textile Co Ltd filed Critical Ningbo Daqian Textile Co Ltd
Priority to CN201910849255.8A priority Critical patent/CN111118711A/en
Publication of CN111118711A publication Critical patent/CN111118711A/en
Pending legal-status Critical Current

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Classifications

    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04BKNITTING
    • D04B1/00Weft knitting processes for the production of fabrics or articles not dependent on the use of particular machines; Fabrics or articles defined by such processes
    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04BKNITTING
    • D04B1/00Weft knitting processes for the production of fabrics or articles not dependent on the use of particular machines; Fabrics or articles defined by such processes
    • D04B1/14Other fabrics or articles characterised primarily by the use of particular thread materials
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/01Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
    • D06M15/03Polysaccharides or derivatives thereof
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M16/00Biochemical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. enzymatic
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/64General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing low-molecular-weight organic compounds without sulfate or sulfonate groups
    • D06P1/651Compounds without nitrogen
    • D06P1/65106Oxygen-containing compounds
    • D06P1/65118Compounds containing hydroxyl groups
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P3/00Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
    • D06P3/58Material containing hydroxyl groups
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/02Natural fibres, other than mineral fibres
    • D06M2101/04Vegetal fibres
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2201/00Cellulose-based fibres, e.g. vegetable fibres
    • D10B2201/01Natural vegetable fibres
    • D10B2201/02Cotton
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2401/00Physical properties
    • D10B2401/13Physical properties anti-allergenic or anti-bacterial
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2403/00Details of fabric structure established in the fabric forming process
    • D10B2403/01Surface features
    • D10B2403/011Dissimilar front and back faces
    • D10B2403/0114Dissimilar front and back faces with one or more yarns appearing predominantly on one face, e.g. plated or paralleled yarns

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Biochemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Microbiology (AREA)
  • Woven Fabrics (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)

Abstract

The invention relates to a alginate fiber health-care bacteriostatic fabric and a manufacturing method thereof. The preparation method comprises the following steps: dyeing chitosan grafted alginate fiber, blending the chitosan grafted alginate fiber and bamboo charcoal fiber, weaving the fabric, and performing enzyme bath post-treatment. According to the alginate fiber health-care antibacterial fabric, chitosan grafted alginate fibers are coated with a certain amount of chitosan on the surfaces, so that the chitosan grafted alginate fibers have good hygroscopicity and antibacterial property, and are non-toxic, harmless, high in safety and biodegradable; the heat-moisture comfortable layer woven by the moisture-absorbing and sweat-releasing fiber yarns and the cotton fiber yarns has heat-moisture comfort and skin-friendly property.

Description

Alginate fiber health-care antibacterial fabric and manufacturing method thereof
Technical Field
The invention relates to the field of fabrics, in particular to a seaweed fiber health-care antibacterial fabric and a manufacturing method thereof.
Background
With the continuous development of economy and the gradual improvement of living standard, consumers have generated great changes to the consumption concept of knitted clothes, and besides the wearing performance requirements of warm keeping, ventilation, comfort and the like, health care fabrics with the functions of antibiosis, heat and humidity comfort are also pursued.
Sodium alginate is a polysaccharide carbohydrate extracted from brown algae such as herba Zosterae Marinae or Sargassum, and is composed of B-D-mannuronic acid and a-L-guluronic acid, and can be made into fiber by wet spinning. Chitosan is the most basic and important derivative of chitin, and has excellent performances of biodegradability, antibiosis, corrosion prevention and the like. The chitosan grafted alginate fiber is a functional fiber with good antibacterial property. How to utilize sodium alginate and chitosan as raw materials to prepare the antibacterial, heat-moisture comfortable health care fabric is a technical problem to be solved by technicians in the field.
Disclosure of Invention
In order to overcome the defects of the prior art, the invention provides the alginate fiber health-care antibacterial fabric and the manufacturing method thereof.
In order to achieve the purpose, the invention adopts the following technical scheme:
the invention provides a seaweed fiber health-care bacteriostatic fabric which comprises a bacteriostatic layer and a heat-moisture comfortable layer, wherein the bacteriostatic layer is formed by weaving seaweed fibers and bamboo charcoal fiber blended yarns, and the heat-moisture comfortable layer is formed by weaving moisture-absorbing sweat-releasing fiber yarns and cotton fiber yarns.
The second aspect of the invention provides a method for manufacturing a seaweed fiber health-care bacteriostatic fabric, which comprises the following steps:
(1) dyeing chitosan grafted alginate fibers: immersing the chitosan grafted alginate fiber into a dyeing tank, wherein a dyeing solution in the dyeing tank consists of ethanol and dye, and the chitosan grafted alginate fiber is dehydrated, oiled and dried after being subjected to bath in the dyeing tank to obtain the colored chitosan grafted alginate fiber;
(2) blending chitosan grafted alginate fibers and bamboo charcoal fibers: blending chitosan grafted alginate fibers and bamboo charcoal fibers and spirally twisting to form blended yarns;
(3) the weaving process comprises the following steps: weaving a double-layer fabric with a heat and humidity comfort layer on the front side and an antibacterial layer on the back side by adopting a double-rib type composite tissue structure compounded by a variable weft plain needle and a tucking coil;
(4) enzyme bath post-treatment: and (3) washing the double-layer fabric for 60-80min by adopting an enzyme bath at the water temperature of 80-100 ℃.
Further, in the step (1), the purity of ethanol in the staining solution is 99%.
Further, in the step (1), the dye in the dyeing solution is a reactive, direct, disperse, neutral dye, an animal or plant pigment or various pigments.
Further, in the step (2), the twist direction of the blended yarn is "Z" or "S".
Further, in the step (3), a double-sided circular knitting machine with the machine number of 24G and the simple diameter of 762mm and 72F is used for weaving the fabric.
Further, in the step (4), the enzyme in the enzyme bath is a refined enzyme, and the weight parts are 3-5; the hydrogen peroxide in the enzyme bath is 30 percent of hydrogen peroxide, and the weight portion is 5 to 8.
Compared with the prior art, the invention has the following advantages:
according to the alginate fiber health-care antibacterial fabric, the surface of the alginate fiber is coated with a certain amount of chitosan, so that the alginate fiber health-care antibacterial fabric has good hygroscopicity and antibacterial property, and is non-toxic, harmless, high in safety and biodegradable; the heat-moisture comfortable layer woven by the moisture-absorbing sweat-discharging fiber yarns and the cotton fiber yarns has heat-moisture comfort and skin-friendly property.
Detailed Description
The present invention will now be described in detail and specifically with reference to the following examples so as to provide a better understanding of the present invention, but the following examples are not intended to limit the scope of the present invention.
Example 1
The alginate fiber health-care antibacterial fabric comprises an antibacterial layer and a heat-moisture comfortable layer, wherein the antibacterial layer is woven by alginate fiber and bamboo charcoal fiber blended yarns, and the heat-moisture comfortable layer is woven by moisture-absorbing sweat-releasing fiber yarns and cotton fiber yarns.
The manufacturing method of the alginate fiber health-care bacteriostatic fabric comprises the following steps:
(1) dyeing chitosan grafted alginate fibers: immersing the chitosan grafted alginate fiber into a dyeing tank, wherein a dyeing solution in the dyeing tank consists of ethanol and dye, and the chitosan grafted alginate fiber is dehydrated, oiled and dried after being subjected to bath in the dyeing tank to obtain the colored chitosan grafted alginate fiber;
further, the dye in the dyeing solution is active, direct, disperse, neutral dye or animal and plant pigment or various pigments;
(2) blending chitosan grafted alginate fibers and bamboo charcoal fibers: the chitosan grafted alginate fiber and the bamboo charcoal fiber are blended and spirally twisted to form blended yarn, wherein the twisting direction of the blended yarn is Z or S;
(3) the weaving process comprises the following steps: the moisture-absorbing and sweat-releasing fiber yarns, the warp yarns and the weft yarns of the cotton fiber yarns are interwoven to be used as the front surface of the fabric, the blended yarns of the alginate fibers and the bamboo charcoal fibers are used as the back surface, the interlock type composite organizational structure formed by combining the variable weft plain knitting and the tuck coils is adopted, and the double-layer fabric with the hot and wet comfortable layer on the front surface and the antibacterial layer on the back surface is woven, so that the fabric has good moisture absorption performance, and meanwhile, the chitosan grafted alginate fiber surface is coated with certain chitosan, so the fabric also has excellent antibacterial performance; the fabric is woven by using a double-sided circular knitting machine with the machine number of 24G, the simple diameter of 762mm and the simple diameter of 72F;
(4) enzyme bath post-treatment: and (3) washing the double-layer fabric for 60min by adopting an enzyme bath at the water temperature of 80 ℃.
Further, the enzyme in the enzyme bath is refined enzyme, and the weight part of the refined enzyme is 3-5; the hydrogen peroxide in the enzyme bath is 30 percent hydrogen peroxide, and the weight portion is 5 to 8.
Example 2
The alginate fiber health-care antibacterial fabric comprises an antibacterial layer and a heat-moisture comfortable layer, wherein the antibacterial layer is woven by alginate fiber and bamboo charcoal fiber blended yarns, and the heat-moisture comfortable layer is woven by moisture-absorbing sweat-releasing fiber yarns and cotton fiber yarns.
The manufacturing method of the alginate fiber health-care bacteriostatic fabric comprises the following steps:
(1) dyeing chitosan grafted alginate fibers: immersing the chitosan grafted alginate fiber into a dyeing tank, wherein a dyeing solution in the dyeing tank consists of ethanol and dye, and the chitosan grafted alginate fiber is dehydrated, oiled and dried after being subjected to bath in the dyeing tank to obtain the colored chitosan grafted alginate fiber;
further, the dye in the dyeing solution is active, direct, disperse, neutral dye or animal and plant pigment or various pigments;
(2) blending chitosan grafted alginate fibers and bamboo charcoal fibers: the chitosan grafted alginate fiber and the bamboo charcoal fiber are blended and spirally twisted to form blended yarn, wherein the twisting direction of the blended yarn is Z or S;
(3) the weaving process comprises the following steps: the moisture-absorbing and sweat-releasing fiber yarns, the warp yarns and the weft yarns of the cotton fiber yarns are interwoven to be used as the front surface of the fabric, the blended yarns of the alginate fibers and the bamboo charcoal fibers are used as the back surface, the interlock type composite organizational structure formed by combining the variable weft plain knitting and the tuck coils is adopted, and the double-layer fabric with the hot and wet comfortable layer on the front surface and the antibacterial layer on the back surface is woven, so that the fabric has good moisture absorption performance, and meanwhile, the chitosan grafted alginate fiber surface is coated with certain chitosan, so the fabric also has excellent antibacterial performance; the fabric is woven by using a double-sided circular knitting machine with the machine number of 24G, the simple diameter of 762mm and the simple diameter of 72F;
(4) enzyme bath post-treatment: and (3) washing the double-layer fabric for 70min by adopting an enzyme bath at the water temperature of 90 ℃.
Further, the enzyme in the enzyme bath is refined enzyme, and the weight part of the refined enzyme is 3-5; the hydrogen peroxide in the enzyme bath is 30 percent hydrogen peroxide, and the weight portion is 5 to 8.
Example 3
The alginate fiber health-care antibacterial fabric comprises an antibacterial layer and a heat-moisture comfortable layer, wherein the antibacterial layer is woven by alginate fiber and bamboo charcoal fiber blended yarns, and the heat-moisture comfortable layer is woven by moisture-absorbing sweat-releasing fiber yarns and cotton fiber yarns.
The manufacturing method of the alginate fiber health-care bacteriostatic fabric comprises the following steps:
(1) dyeing chitosan grafted alginate fibers: immersing the chitosan grafted alginate fiber into a dyeing tank, wherein a dyeing solution in the dyeing tank consists of ethanol and dye, and the chitosan grafted alginate fiber is dehydrated, oiled and dried after being subjected to bath in the dyeing tank to obtain the colored chitosan grafted alginate fiber;
(2) blending chitosan grafted alginate fibers and bamboo charcoal fibers: the chitosan grafted alginate fiber and the bamboo charcoal fiber are blended and spirally twisted to form blended yarn, wherein the twisting direction of the blended yarn is Z or S;
(3) the weaving process comprises the following steps: the moisture-absorbing and sweat-releasing fiber yarns, the warp yarns and the weft yarns of the cotton fiber yarns are interwoven to be used as the front surface of the fabric, the blended yarns of the alginate fibers and the bamboo charcoal fibers are used as the back surface, the interlock type composite organizational structure formed by combining the variable weft plain knitting and the tuck coils is adopted, and the double-layer fabric with the hot and wet comfortable layer on the front surface and the antibacterial layer on the back surface is woven, so that the fabric has good moisture absorption performance, and meanwhile, the chitosan grafted alginate fiber surface is coated with certain chitosan, so the fabric also has excellent antibacterial performance; the fabric is woven by using a double-sided circular knitting machine with the machine number of 24G, the simple diameter of 762mm and the simple diameter of 72F;
(4) enzyme bath post-treatment: and (3) carrying out enzyme bath on the double-layer feed water for 80min at the water temperature of 100 ℃.
Further, the enzyme in the enzyme bath is refined enzyme, and the weight part of the refined enzyme is 3-5; the hydrogen peroxide in the enzyme bath is 30 percent hydrogen peroxide, and the weight portion is 5 to 8.
While the invention has been described with reference to a preferred embodiment, it will be understood by those skilled in the art that various changes in form and detail may be made therein without departing from the spirit and scope of the invention.

Claims (7)

1. The alginate fiber health-care antibacterial fabric comprises an antibacterial layer and a heat-moisture comfortable layer, and is characterized in that the antibacterial layer is woven by alginate fiber and bamboo charcoal fiber blended yarns, and the heat-moisture comfortable layer is woven by moisture-absorbing sweat-releasing fiber yarns and cotton fiber yarns.
2. The manufacturing method of the alginate fiber health-care bacteriostatic fabric according to claim 1, which is characterized by comprising the following steps:
(1) dyeing chitosan grafted alginate fibers: immersing the chitosan grafted alginate fiber into a dyeing tank, wherein a dyeing solution in the dyeing tank consists of ethanol and dye, and the chitosan grafted alginate fiber is dehydrated, oiled and dried after being subjected to bath in the dyeing tank to obtain the colored chitosan grafted alginate fiber;
(2) blending chitosan grafted alginate fibers and bamboo charcoal fibers: blending chitosan grafted alginate fibers and bamboo charcoal fibers and spirally twisting to form blended yarns;
(3) the weaving process comprises the following steps: weaving a double-layer fabric with a heat and humidity comfort layer on the front side and an antibacterial layer on the back side by adopting a double-rib type composite tissue structure compounded by a variable weft plain needle and a tucking coil;
(4) enzyme bath post-treatment: and (3) washing the double-layer fabric for 60-80min by adopting an enzyme bath at the water temperature of 80-100 ℃.
3. The method according to claim 2, wherein the purity of ethanol in the staining solution in the step (1) is 99%.
4. The process according to claim 2, wherein in the step (1), the dye in the dyeing liquid is a reactive, direct, disperse, neutral dye, an animal or plant pigment, or any of various pigments.
5. The method of manufacturing of claim 2 wherein in step (2) the twist direction of said blended yarn is either "Z" or "S".
6. The manufacturing method according to claim 2, wherein in the step (3), a double-sided circular knitting machine with the machine number of 24G and the simple diameter of 762mm and 72F is used for weaving the fabric.
7. The process according to claim 2, wherein in the step (4), the enzyme in the enzyme bath is a refined enzyme in an amount of 3 to 5 parts by weight; the hydrogen peroxide in the enzyme bath is 30 percent of hydrogen peroxide, and the weight portion is 5 to 8.
CN201910849255.8A 2019-09-09 2019-09-09 Alginate fiber health-care antibacterial fabric and manufacturing method thereof Pending CN111118711A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
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Application Number Priority Date Filing Date Title
CN201910849255.8A CN111118711A (en) 2019-09-09 2019-09-09 Alginate fiber health-care antibacterial fabric and manufacturing method thereof

Publications (1)

Publication Number Publication Date
CN111118711A true CN111118711A (en) 2020-05-08

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Citations (9)

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Publication number Priority date Publication date Assignee Title
CN1844516A (en) * 2006-03-10 2006-10-11 青岛即发集团股份有限公司 A kind of colored chitosan fiber production technology by dyeing tank method
CN1940153A (en) * 2006-09-21 2007-04-04 青岛大学 Chitose graft alginate fibre, its production and use
CN103465537A (en) * 2013-09-24 2013-12-25 昆山市周市镇吉盛服装厂 Moisture-absorption anti-bacterial knitted fabric
CN104060367A (en) * 2014-06-03 2014-09-24 南通纺科纺织科技有限公司 Hygroscopic air permeable double layer fabric
CN205005951U (en) * 2015-09-14 2016-02-03 朱玉珍 Antibiotic moisture absorbable and breathable sportswear
CN105696176A (en) * 2014-11-25 2016-06-22 江阴市长泾花园毛纺织有限公司 Wool-algae fiber dual-face high-grade T-shirt fabric and technology for producing same
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CN108517614A (en) * 2018-04-13 2018-09-11 相里海霞 A kind of seaweed fiber fabric
CN211522481U (en) * 2019-09-09 2020-09-18 宁波大千纺织品有限公司 Alginate fiber health-care antibacterial fabric

Patent Citations (9)

* Cited by examiner, † Cited by third party
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CN1940153A (en) * 2006-09-21 2007-04-04 青岛大学 Chitose graft alginate fibre, its production and use
CN103465537A (en) * 2013-09-24 2013-12-25 昆山市周市镇吉盛服装厂 Moisture-absorption anti-bacterial knitted fabric
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CN105696176A (en) * 2014-11-25 2016-06-22 江阴市长泾花园毛纺织有限公司 Wool-algae fiber dual-face high-grade T-shirt fabric and technology for producing same
CN106183210A (en) * 2015-04-30 2016-12-07 江苏双山集团股份有限公司 A kind of perspiratory and antibacterial fabric and production technology thereof
CN205005951U (en) * 2015-09-14 2016-02-03 朱玉珍 Antibiotic moisture absorbable and breathable sportswear
CN108517614A (en) * 2018-04-13 2018-09-11 相里海霞 A kind of seaweed fiber fabric
CN211522481U (en) * 2019-09-09 2020-09-18 宁波大千纺织品有限公司 Alginate fiber health-care antibacterial fabric

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