[go: up one dir, main page]

CN109281225A - 具有多价金属离子的乳胶调配物 - Google Patents

具有多价金属离子的乳胶调配物 Download PDF

Info

Publication number
CN109281225A
CN109281225A CN201810776623.6A CN201810776623A CN109281225A CN 109281225 A CN109281225 A CN 109281225A CN 201810776623 A CN201810776623 A CN 201810776623A CN 109281225 A CN109281225 A CN 109281225A
Authority
CN
China
Prior art keywords
structural unit
weight percent
monomer
carboxylic acid
weight
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201810776623.6A
Other languages
English (en)
Inventor
B·L·麦卡洛特
J·A·罗珀三世
K·罗斯
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Dow Global Technologies LLC
Rohm and Haas Co
Original Assignee
Dow Global Technologies LLC
Rohm and Haas Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Dow Global Technologies LLC, Rohm and Haas Co filed Critical Dow Global Technologies LLC
Publication of CN109281225A publication Critical patent/CN109281225A/zh
Pending legal-status Critical Current

Links

Classifications

    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00—Coated paper; Coating material
    • D21H19/10—Coatings without pigments
    • D21H19/14—Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12
    • D21H19/20—Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12 comprising macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F265/00—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00
    • C08F265/04—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00 on to polymers of esters
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B27/10—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of paper or cardboard
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F20/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
    • C08F20/02—Monocarboxylic acids having less than ten carbon atoms, Derivatives thereof
    • C08F20/10—Esters
    • C08F20/12—Esters of monohydric alcohols or phenols
    • C08F20/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
    • C08F20/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F212/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
    • C08F212/02—Monomers containing only one unsaturated aliphatic radical
    • C08F212/04—Monomers containing only one unsaturated aliphatic radical containing one ring
    • C08F212/06—Hydrocarbons
    • C08F212/08—Styrene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/04—Acids; Metal salts or ammonium salts thereof
    • C08F220/06—Acrylic acid; Methacrylic acid; Metal salts or ammonium salts thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J3/00—Processes of treating or compounding macromolecular substances
    • C08J3/02—Making solutions, dispersions, lattices or gels by other methods than by solution, emulsion or suspension polymerisation techniques
    • C08J3/03—Making solutions, dispersions, lattices or gels by other methods than by solution, emulsion or suspension polymerisation techniques in aqueous media
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J3/00—Processes of treating or compounding macromolecular substances
    • C08J3/02—Making solutions, dispersions, lattices or gels by other methods than by solution, emulsion or suspension polymerisation techniques
    • C08J3/03—Making solutions, dispersions, lattices or gels by other methods than by solution, emulsion or suspension polymerisation techniques in aqueous media
    • C08J3/05—Making solutions, dispersions, lattices or gels by other methods than by solution, emulsion or suspension polymerisation techniques in aqueous media from solid polymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/24—Acids; Salts thereof
    • C08K3/26—Carbonates; Bicarbonates
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
    • C08L51/003—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to macromolecular compounds obtained by reactions only involving unsaturated carbon-to-carbon bonds
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/20—Macromolecular organic compounds
    • D21H17/33—Synthetic macromolecular compounds
    • D21H17/34—Synthetic macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/60—Waxes
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/63—Inorganic compounds
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00—Coated paper; Coating material
    • D21H19/10—Coatings without pigments
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00—Coated paper; Coating material
    • D21H19/36—Coatings with pigments
    • D21H19/44—Coatings with pigments characterised by the other ingredients, e.g. the binder or dispersing agent
    • D21H19/56—Macromolecular organic compounds or oligomers thereof obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D21H19/58—Polymers or oligomers of diolefins, aromatic vinyl monomers or unsaturated acids or derivatives thereof
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00—Coated paper; Coating material
    • D21H19/36—Coatings with pigments
    • D21H19/44—Coatings with pigments characterised by the other ingredients, e.g. the binder or dispersing agent
    • D21H19/64—Inorganic compounds
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
    • D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
    • D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
    • D21H21/16—Sizing or water-repelling agents
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
    • D21H21/50—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by form
    • D21H21/52—Additives of definite length or shape
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H27/00—Special paper not otherwise provided for, e.g. made by multi-step processes
    • D21H27/10—Packing paper
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2800/00—Copolymer characterised by the proportions of the comonomers expressed
    • C08F2800/20—Copolymer characterised by the proportions of the comonomers expressed as weight or mass percentages
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2325/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Derivatives of such polymers
    • C08J2325/02—Homopolymers or copolymers of hydrocarbons
    • C08J2325/04—Homopolymers or copolymers of styrene
    • C08J2325/08—Copolymers of styrene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2433/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers
    • C08J2433/02—Homopolymers or copolymers of acids; Metal or ammonium salts thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2433/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers
    • C08J2433/04—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers esters
    • C08J2433/06—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers esters of esters containing only carbon, hydrogen, and oxygen, the oxygen atom being present only as part of the carboxyl radical
    • C08J2433/08—Homopolymers or copolymers of acrylic acid esters
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2433/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers
    • C08J2433/04—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers esters
    • C08J2433/06—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers esters of esters containing only carbon, hydrogen, and oxygen, the oxygen atom being present only as part of the carboxyl radical
    • C08J2433/10—Homopolymers or copolymers of methacrylic acid esters
    • C08J2433/12—Homopolymers or copolymers of methyl methacrylate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C08K2003/2244—Oxides; Hydroxides of metals of zirconium
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C08K2003/2296—Oxides; Hydroxides of metals of zinc

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Dispersion Chemistry (AREA)
  • Paper (AREA)
  • Paints Or Removers (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Graft Or Block Polymers (AREA)

Abstract

具有多价金属离子的乳胶调配物。本发明涉及组合物和通过将所述组合物施涂于纸张而制备的一种制品。所述组合物包含具有硬相和软相的丙烯酸或苯乙烯丙烯酸聚合物颗粒的水分散体，其中两种相均包含特定酸单体的结构单元。所述组合物进一步包括相对于羧酸基团的亚化学计量含量的Zn++或Zr++++。所述组合物适用作赋予抗粘连性和抗粘着性的纸张上涂料。

Description

具有多价金属离子的乳胶调配物
背景技术
碳氟化合物已被用于纸张的处理，以生产用于包括快餐食品包装、微波爆米花包装和烘焙食品包装的广泛应用的耐油脂(oil and grease resistant，OGR)等级的纸张。然而，各种政府机构正在强制限制使用碳氟化合物，从而需要替代的阻隔材料。碳氟化合物替代方案的挑战之一是保持这些碳氟化合物中固有的低粘连性，而不降低阻隔性能。
WO 2009/142739教示了具有交联剂如锌或锆和至少2重量百分比的高纵横比剥离纳米填料的纸张涂料组合物。这种纳米填料颗粒的加入被描述为对耐油性、耐油脂性和抗粘连性的改进至关重要；然而，纳米填料的存在对于需要折皱或折叠的包装应用而言可能是有害的。
因此，找到包括碳氟化合物的调配物或需要高纵横比纳米填料以获得耐油性、耐油脂性和抗粘连性的调配物的环境上可接受的替代方案将会是纸张涂料领域中的进步。
发明内容
第一方面，本发明通过提供一种包含平均粒度在80nm至500nm范围内的聚合物颗粒的水分散体的组合物来满足本领域的需要；其中聚合物颗粒包含Tg大于50℃的第一相和Tg小于35℃的第二相；其中第一相与第二相的重量比在5∶95至50∶50范围内；
其中所述第一相包含：
a)90至99重量百分比的第一烯属不饱和非离子单体的结构单元；和b)1至10重量百分比的第一羧酸单体的结构单元；以所述第一烯属不饱和非离子单体和所述第一羧酸单体的结构单元的重量计；
其中所述第二相包含：
a)90至98重量百分比的第二非离子烯属不饱和单体的结构单元；和b)2至10重量百分比的第二羧酸单体的结构单元，以所述第二非离子烯属不饱和单体和所述第二羧酸单体的重量计；
其中所述聚合物颗粒占所述组合物的35至50重量百分比；
其中以所述聚合物颗粒的重量计，所述组合物进一步包含0.05至5重量百分比的Zn++或Zr++++离子，其中羧酸单体的结构单元与Zn++离子的摩尔比在7∶1至2∶1范围内，并且羧酸单体的结构单元与Zr++++离子的摩尔比在3.5∶1至1∶1范围内。
另一方面，本发明是一种制品，包含由包含Tg大于50℃的第一域和Tg小于35℃的第二域的膜叠加的纸张衬底；其中第一域与第二域的重量比在5∶95至50∶50范围内；
其中所述第一域包含90至99重量百分比的第一烯属不饱和非离子单体的结构单元；和b)1至10重量百分比的第一羧酸单体的结构单元；以所述第一烯属不饱和非离子单体和所述第一羧酸单体的结构单元的重量计；
其中所述第二域包含：
a)90至98重量百分比的第二烯属不饱和非离子单体的结构单元；和b)2至10重量百分比的第二羧酸单体的结构单元，以所述第二非离子烯属不饱和单体和所述第二羧酸单体的重量计；
其中以单体的结构单元的重量计，所述膜进一步包含0.05至5重量百分比的Zn++或Zr++++离子，其中甲基丙烯酸和丙烯酸的总结构单元与Zn++离子的摩尔比在7∶1到2∶1范围内；并且所述羧酸单体的结构单元与Zr++++离子的摩尔比在3.5∶1至1∶1范围内；
其中所述膜的涂布重量厚度在1至20g/m2范围内。
本发明的组合物和制品通过提供一种环境上可接受的纸张涂料调配物来满足本领域的需要，所述纸张涂料调配物赋予涂料以良好的耐油性、耐油脂性和抗粘连性。
具体实施方式
第一方面，本发明是一种组合物，包含平均粒度在80nm至500nm范围内的聚合物颗粒的水分散体；其中聚合物颗粒包含Tg大于50℃的第一相和Tg小于35℃的第二相；其中第一相与第二相的重量比在5∶95至50∶50范围内；
其中所述第一相包含：
a)90至99重量百分比的第一烯属不饱和非离子单体的结构单元；和b)1至10重量百分比的第一羧酸单体的结构单元；以所述第一烯属不饱和非离子单体和所述第一羧酸单体的结构单元的重量计；
其中所述第二相包含：
a)90至98重量百分比的第二非离子烯属不饱和单体的结构单元；和b)2至10重量百分比的第二羧酸单体的结构单元，以所述第二非离子烯属不饱和单体和所述第二羧酸单体的重量计；
其中所述聚合物颗粒占所述组合物的35至50重量百分比；
其中以所述聚合物颗粒的重量计，所述组合物进一步包含0.05至5重量百分比的Zn++或Zr++++离子，其中羧酸单体的结构单元与Zn++离子的摩尔比在7∶1至2∶1范围内，并且羧酸单体的结构单元与Zr++++离子的摩尔比在3.5∶1至1∶1范围内。
如本文所用，平均粒度是指由Brookhaven BI-90Plus粒度分析仪测定的聚合物粒子的粒度。优选地，聚合物颗粒的平均粒度在100nm至300nm范围内。
如本文所用，Tg是指由Fox方程计算的特定相的玻璃化转变温度(glasstransition temperature)。聚合物颗粒的第一相在环境温度下不成膜，其中第二相优选在环境温度下成膜。优选地，第一相的Tg大于60℃，更优选大于80℃，并且第二相的Tg优选不大于25℃，更优选不大于15℃，并且最优选不大于10℃。
第一相包含一种或多种高Tg单体的结构单元，即烯属不饱和非离子单体的结构单元，其均聚物具有由Fox方程计算的Tg大于50℃，优选大于60℃，并且更优选大于80℃。适合的高Tg单体的实例包括苯乙烯(均聚物的计算Tg＝100℃)、甲基丙烯酸甲酯(均聚物的计算Tg＝105℃)、甲基丙烯酸乙酯(均聚物的计算Tg＝65℃)、甲基丙烯酸叔丁酯(均聚物的计算Tg＝118℃)、丙烯酰胺(均聚物的计算Tg＝165℃)、丙烯腈(均聚物的计算Tg＝125℃)、2-乙烯基吡啶(均聚物的计算Tg＝104℃)、4-乙烯基吡啶(均聚物的计算Tg＝142℃)、甲基丙烯酸环己酯(均聚物的计算Tg＝92℃)、甲基丙烯酸异冰片酯(均聚物的计算Tg＝110℃)和氯乙烯(均聚物的计算Tg＝81℃)。优选地，第一相包含甲基丙烯酸甲酯或苯乙烯或其组合的结构单元。
第一相进一步包含第一羧酸单体的结构单元，第一羧酸单体的实例包括丙烯酸、甲基丙烯酸和衣康酸，其中甲基丙烯酸是优选的。
第一相还可以包括低Tg单体的结构单元，即烯属不饱和单体的结构单元，其均聚物的Tg小于35℃，条件是第一相的计算Tg大于50℃。低Tg单体的实例包括丙烯酸酯单体如丙烯酸甲酯(均聚物的计算Tg＝10℃)、丙烯酸乙酯(均聚物的计算Tg＝-24℃)、丙烯酸正丁酯(均聚物的计算Tg＝-54℃)、丙烯酸-2-丁酯(均聚物的计算Tg＝-26℃)、丙烯酸-2-乙基己酯(均聚物的计算Tg＝-50℃)以及乙酸乙烯酯(均聚物的计算Tg＝30℃)和偏二氯乙烯(均聚物的计算Tg＝-18℃)。
以第一烯属不饱和单体和第一羧酸单体的结构单元的重量计，第一相优选包含92，更优选94重量百分比，至优选98，更优选至96重量百分比的第一烯属不饱和单体的结构单元；并且以第一单体和甲基丙烯酸的结构单元的重量计，优选2，更优选3，并且最优选4重量百分比，至8，更优选至7，并且最优选至6重量百分比的甲基丙烯酸的结构单元。
以低Tg丙烯酸酯单体、第二非离子烯属不饱和单体和羧酸单体的结构单元的重量计，第二相优选包含60，更优选65，并且最优选70重量百分比至优选90，更优选至85，并且最优选80重量百分比的低Tg丙烯酸酯单体的结构单元；优选5，更优选10，并且最优选15重量百分比，至优选35，更优选30，并且最优选25重量百分比的除低Tg丙烯酸酯单体以外的烯属不饱和第二单体的结构单元；并且优选2，更优选3，并且最优选4重量百分比，至优选10，更优选8，并且最优选至6重量百分比的羧酸单体的结构单元。
优选地，第二相包含a)一种或多种选自由丙烯酸甲酯、丙烯酸乙酯、丙烯酸丁酯和丙烯酸-2-乙基己酯组成的组的丙烯酸酯单体的结构单元；b)选自由苯乙烯和甲基丙烯酸甲酯组成的组的第二烯属不饱和非离子单体的结构单元；和c)丙烯酸的结构单元。第一相与第二相的重量比优选为10：90至35：65，更优选至30：70。
以聚合物颗粒的重量计，羧酸单体的结构单元，优选第一相中丙烯酸的结构单元和第二相中甲基丙烯酸的结构单元的总和优选不大于10，更优选不大于7，并且最优选不大于5重量百分比，并且优选不小于2，更优选不小于3重量百分比。
以聚合物颗粒的重量计，Zn++离子的浓度优选0.1，更优选0.2，更优选0.5，并且最优选0.8重量百分比，优选至4，更优选至3，并且最优选至2重量百分比。基于聚合物颗粒的重量，Zr++++离子的浓度优选0.05，更优选0.1，并且最优选0.5重量百分比，优选至2，更优选至1.5，并且最优选至1重量百分比。第一和第二羧酸单体的结构单元，优选第一相中甲基丙烯酸的结构单元和第二相中丙烯酸的结构单元与Zn++离子的摩尔比优选5∶1，并且更优选4.5∶1，至优选2.5∶1，并且更优选至3∶1。第一和第二羧酸单体的总结构单元，优选第一相中甲基丙烯酸的结构单元和第二相中丙烯酸的结构单元与Zr++++离子的摩尔比优选3∶1，并且更优选2∶1，至优选1.2∶1，并且更优选至1.5∶1。如本文所用，术语“Zn++或Zr++++离子的浓度”是指以干聚合物颗粒的重量计，锌或锆化合物中锌或锆的重量百分比浓度。
本发明的组合物可以通过首先通过多级乳液聚合工艺，优选2级工艺，如本领域所公知的那些合成聚合物颗粒(乳胶)的水分散体来方便地制备，接着将乳胶与分别产生Zn++或Zr++++离子的锌化合物或锆化合物混合。锌和锆化合物的实例包括碳酸锌铵、氧化锌、硬脂酸锌、碳酸锆铵、氧化锆和硬脂酸锆。锌化合物是优选的并且碳酸锌铵和氧化锌是优选的锌化合物。
本发明的组合物优选包含基本上不存在的纳米填料，特别是纵横比大于20的纳米填料。纳米填料是指剥离或部分剥离的天然或合成层状硅酸盐，如蒙脱土、膨润土、高岭石、高岭土、云母、锂蒙脱石、锌蒙脱石、含氟锂蒙脱石、皂石、绿坡缕石、海泡石、贝得石、三八面体伊利石、绿脱石、钒锌石、硅镁石、蛭石、埃洛石、滑石、叶蜡石、坡缕石、伊利石、金云母、黑云母、绿泥石、珍珠陶土、地开石、硫镍石(suconite)、麦羟硅钠石、水羟硅钠石、合成锂皂石性能添加剂、带云母和合成氟云母。如本文所用，“基本上不存在的纳米填料”是指以聚合物颗粒和纳米填料的重量计，小于5，优选小于1.8，更优选小于1，更优选小于0.5，并且最优选0重量百分比的纳米填料。
已经发现排除或基本上排除这些纳米填料改进了最终涂料的柔性，其在需要折叠或折皱的柔性包装中特别有用。与WO 2009/142739的教示相反，已经发现，不需要纳米填料以获得改进的耐油性、耐油脂性和抗粘连性，条件是聚合物颗粒含有规定范围内的软相和硬相并且金属阳离子以相对于羧酸基团等于或低于化学计量含量而存在。
本发明的组合物可以进一步包括选自由以下组成的组的一种或多种成分：流变改性剂；分散剂；其它颜料如TiO2、碳酸钙和粘土；消泡剂；中和剂；表面活性剂；溶剂；附加粘合剂；聚结剂；杀生物剂；不透明聚合物；着色剂；水溶性聚合物如淀粉、聚(乙烯醇)、聚(乙烯-共-乙烯醇)和聚(亚烷基二醇)；增塑剂和蜡。
另一方面，本发明是一种制品，包含由包含Tg大于50℃的第一域和Tg小于35℃的第二域的膜叠加的纸张衬底；其中第一域与第二域的重量比在5：95，优选10：90至50：50，优选至35∶65，更优选至30∶70范围内。
第一域优选包含90，更优选92，并且最优选94重量百分比，至优选99，更优选至98，并且最优选至96重量百分比的第一烯属不饱和非离子单体(其为苯乙烯或甲基丙烯酸甲酯或其组合)的结构单元；和b)1至10重量百分比的羧酸单体，优选甲基丙烯酸的结构单元；以第一单体和羧酸单体的结构单元的重量计。
第二域优选包含：a)60，更优选65，并且最优选70重量百分比至优选90，更优选至85，并且最优选至80重量百分比的丙烯酸酯(其为丙烯酸甲酯、丙烯酸乙酯、丙烯酸丁酯或丙烯酸-2-乙基己酯或其组合)的结构单元；b)优选5，更优选10，并且最优选15重量百分比至优选35，更优选至30，并且最优选至25重量百分比的第二烯属不饱和非离子单体(其为苯乙烯或甲基丙烯酸甲酯或其组合)的结构单元；和c)2至10重量百分比的第二羧酸单体，优选丙烯酸的结构单元；以丙烯酸酯、第二烯属不饱和非离子单体和羧酸单体的重量计。
以单体的结构单元的重量计，膜进一步包含0.05，优选0.2，更优选0.5，并且最优选0.8重量百分比，至5，优选至4，更优选至3，并且最优选至2重量百分比的Zn++或Zr++++离子。第一和第二羧酸单体的结构单元，优选第一域中甲基丙烯酸和丙烯酸的结构单元与Zn++离子的摩尔比在7∶1，优选5∶1，并且更优选4.5∶1，至2∶1，优选至2.5∶1，并且更优选至3∶1范围内；并且第一和第二羧酸单体的结构单元，优选第一域中甲基丙烯酸的结构单元和第二结构域中丙烯酸的结构单元与Zr++++离子的摩尔比在3.5∶1，优选3∶1，并且更优选2.5∶1至1∶1，优选至1.2∶1，并且更优选至1.5∶1范围内。
其中膜的涂布重量厚度在1，优选2，并且更优选3，至20，优选至15，并且更优选至10g/m2范围内。
实例
中间实例1-制备具有15重量％硬相的粘合剂
通过混合去离子水(334.4g)、Polystep B5N表面活性剂(5.16g)、丙烯酸丁酯(538.0g)、苯乙烯(148.2g)和丙烯酸(34.2g)制备单体乳液1(ME1)。通过混合去离子水(56.0g)、Polystep B5N表面活性剂(0.84g)、甲基丙烯酸(8.3g)和甲基丙烯酸甲酯(118.3g)制备单体乳液2(ME2)。
配备有机械搅拌器、温度计、冷凝器、加热套和温度控制器的3L反应器以去离子水(306.0g)填充并且在N2下加热到76℃。然后将Polystep B5N表面活性剂(1.84g)加入反应器中，接着依次是ME1(42.4g)在水(20.0g)中的一部分，然后是过硫酸铵(1.68g)在水(14g)中的溶液。
初始放热后，将反应温度保持在84℃下；将共馈引发剂溶液(1.62g过硫酸铵在44.0g去离子水中)以0.16克/分钟的速率馈送到反应器中并且以3.5克/分钟的速率馈送ME1。10分钟后，将共馈引发剂馈送速率增加到0.32克/分钟并且将ME1馈送速率增加到7.0克/分钟。当共馈和ME1添加完成时，将反应保持在84℃下15分钟，然后冷却到71℃。
通过添加漏斗将ME2加入反应器中，接着依次添加叔丁基过氧化氢的水溶液(t-BHP，0.68g，70％水溶液)和去离子水(6.0g)，然后是七水合硫酸亚铁的水溶液(0.4g，1％水溶液)，并且然后是异抗坏血酸(isoascorbic acid(IAA)，0.34g)和去离子水(14.0g)。以绝热方式保持反应直至反应放热完成，其后将反应冷却到50℃。以0.38克/分钟的速率加入t-BHP(1.34g，70％水溶液)在DI水(12.0g)中的溶液和IAA(0.67g)在去离子水(12.0g)中的溶液。馈送添加完成后，缓慢加入氢氧化铵(9.9g，28％水溶液)在去离子水(40.0g)中的溶液。将反应冷却至室温并通过100目筛过滤。最终的分散体具有44.0重量百分比的固体含量和pH 6.4。
中间比较实例1-制备无硬相粘合剂
所述程序基本上如实例1中所述进行，除了排除第二单体乳液。最终分散体具有42.8％的固体含量和pH 6.1。
中间实例2-制备碳酸锌铵溶液
在容器中将氧化锌(50.3g)、碳酸氢铵(62.7g)、氢氧化铵(83.4g，28％NH3水)和去离子水(285.0g)混合30分钟。得到透明的碳酸锌铵溶液并且发现每克溶液含有1.28mmolZn。
实例1-制备分散体与Zn添加剂的混合物
将中间实例1的聚合物分散体(200g，每克聚合物0.66mmol总羧酸单体，58.1mmol羧酸基团)加入玻璃罐中。使用顶置式混合器，将碳酸锌铵溶液(13.6g，17.4mmol Zn)逐滴加入分散体中，接着是氢氧化铵(0.9g，28％NH3水)和去离子水(9.3g)以将最终pH调节至8.3并将最终固体调节至40.6重量百分比。
比较实例1-制备分散体与化学计量过量的Zn的混合物
将中间实例1的聚合物分散体(250g，每克聚合物0.66mmol羧酸单体，72.6mmol羧酸基团)加入玻璃罐中。使用顶置式混合器，将碳酸锌铵溶液(35.5g，45.4mmol Zn)逐滴加入分散体中以将最终pH调节至8.9并将最终固体含量调节为39.4重量百分比。
比较实例2-制备pH和固体经调节的分散体，不添加Zn
通过添加氢氧化铵(2.9g，28％NH3水)和去离子水(17.4g)调节中间实例1的pH和固体含量至最终pH 8.6和40.0重量百分比的最终固体。
比较实例3-制备无硬相分散体和Zn的混合物
将中间比较实例1的聚合物分散体(200g，每克聚合物0.65mmol总羧酸单体，57.2mmol羧酸基团)加入玻璃罐中。使用顶置式混合器，将碳酸锌铵溶液(13g，16.6mmolZn)逐滴加入分散体中，接着是DI水(5.7g)以将最终pH调节至8.4并将最终固体调节至39.7重量百分比。
调配实例
通过将来自实例1的一部分分散体(147.4g)与去离子水(5.06g)混合，接着用顶置台式混合器添加ACRYSOLTM ASE-60流变改性剂(3.00g，陶氏化学公司(Dow ChemicalCompany)或其附属公司的商标)来制备固体含量38.8％的调配物1。将混合物在室温下搅拌20分钟，此时使用Brookfield粘度计读取调配物的粘度为100rpm下678.8厘泊。
所有调配物都调节至38.5-39.0％固体和100rpm下650至700cP的Brookfield粘度。
涂布样品制备
使用配备有绕线棒的RK自动涂布机在机器方向上向空纸片(60g/m2)施涂调配物以实现指定的涂布重量(6至10g/m2)。通过冲出烘干的涂布纸(80℃ 2分钟)的固定面积并减去衬底的基重来确定涂布重量。从至少三个冲出区域的平均值来确定涂布重量。在测试前，根据TAPPI T 402标准条件将涂布纸在受控温度室中调整至少4小时。
涂布纸的试剂盒测试：
根据TAPPI T 559cm-12测试涂布衬底的耐油脂性。将由蓖麻油、甲苯和庚烷的混合物组成的制备好的试剂盒溶液逐滴施加到涂布样品上。15s后，注意到溶剂渗入涂料的任何突破，并将溶液从衬底上擦除。对于特定试剂盒溶液而言，对衬底的任何变色或外观变化都被认为是失败的。为通过测试的最高编号的试剂盒溶液分配分数。(0-12，其中12是最好的。)
涂布纸的粘连测试：
使用金属、弹簧加压压缩装置测试涂布衬底的粘连。将1.5″×2.75″涂布衬底的样品在装置上的金属板之间涂布-至-涂布或涂布-至-未涂布地放置。将弹簧压缩以向衬底施加50psi压力，并且将整个装置放入60℃的烘箱中1h。1h后，将装置从烘箱中取出并允许在室温下冷却30分钟。小心取出并拉开冷却的衬底；根据以下等级，评定每个接触面的抗粘连性：
1＝衬底没有阻力地破裂
2＝分离衬底所需的最小力；随着分离的可听见的杂音
3＝分离片材所需的恒定力；大致类似于便利贴
4＝观察到的最小量的纤维撕裂
5＝片材完全粘结在一起；观察到显著的纤维撕裂
粘性测试程序
使用自动摩擦计测量每个涂层的粘性；摩擦计和测试方法描述于Kalihari，V等，《科学仪器评论(Rev.Sci.Instrum.)》84,035104，(2013))中。在这种情况下，在最大法向载荷100g下使用3/8英寸不锈钢球作为探针。在缩回期间测量表面粘着力并记录为缩回期间出现的最大力。使用双面胶带将涂布纸粘附到玻璃板上，并对涂布纸的不同位置上的每个样品进行3次测量，将其平均并用于计算测量的标准偏差。
表1说明聚合物硬相和Zn浓度对抗粘连性和粘性的影响。在表中，％Zn中和是指Zn++的摩尔除以总羧酸基团的摩尔乘以200。硬相组分％是指硬相的重量百分比占总聚合物的百分数。稳定性通过添加流变改性剂5分钟内调配物不存在凝固来定义。
表1-作为硬相和Zn浓度的函数的抗粘连性
数据显示，当聚合物颗粒包含硬相时并且当调配物含有少于Zn添加剂的化学计量量时，粘连和粘性得到改进。对于含有化学计量过量的Zn的调配物不能测量粘连，因为调配物在加入流变改性剂后迅速凝固。

Claims (10)

1.一种组合物，包含平均粒度在80nm至500nm范围内的聚合物颗粒的水分散体；其中所述聚合物颗粒包含Tg大于50℃的第一相和Tg小于35℃的第二相；其中所述第一相与所述第二相的重量比在5∶95至50∶50范围内；
其中所述第一相包含：
a)90至99重量百分比的第一烯属不饱和非离子单体的结构单元；和b)1至10重量百分比的第一羧酸单体的结构单元；以所述第一烯属不饱和非离子单体和所述第一羧酸单体的结构单元的重量计；
其中所述第二相包含：
a)90至98重量百分比的第二非离子烯属不饱和单体的结构单元；和b)2至10重量百分比的第二羧酸单体的结构单元，以所述第二非离子烯属不饱和单体和所述第二羧酸单体的重量计；
其中所述聚合物颗粒占所述组合物的35至50重量百分比；
其中以所述聚合物颗粒的重量计，所述组合物进一步包含0.05至5重量百分比的Zn++或Zr++++离子，其中所述羧酸单体的结构单元与Zn++离子的摩尔比在7∶1至2∶1范围内，并且所述羧酸单体的结构单元与Zr++++离子的摩尔比在3.5∶1至1∶1范围内。
2.根据权利要求1所述的组合物，其中以所述聚合物颗粒的重量计，所述组合物包含0.2至4重量百分比的Zn++离子，其中所述聚合物颗粒中所述第一和第二羧酸单体的结构单元与Zn++离子的摩尔比在5∶1至2.5∶1范围内。
3.根据权利要求2所述的组合物，其中所述第一相包含92至98重量百分比的所述第一烯属不饱和非离子单体的结构单元和2至8重量百分比的所述第一羧酸单体的结构单元；其中所述第二相包含60至90重量百分比的低Tg丙烯酸酯的结构单元、5至35重量百分比的除丙烯酸酯以外的第二烯属不饱和单体的结构单元和2至10重量百分比的所述第二羧酸单体的结构单元，以所述丙烯酸酯、所述第二烯属不饱和单体和所述第二羧酸单体的重量计。
4.根据权利要求3所述的组合物，其中所述第一相包含94至96重量百分比的所述第一烯属不饱和非离子单体的结构单元和4至6重量百分比的所述第一羧酸单体的结构单元；其中所述第一烯属不饱和非离子单体是苯乙烯或甲基丙烯酸甲酯或其组合；并且其中所述第一羧酸单体是甲基丙烯酸；
其中所述第二相包含65至85重量百分比的所述低Tg丙烯酸酯的结构单元；10至30个所述第二烯属不饱和单体的结构单元；和3至6重量百分比的所述第二羧酸单体的结构单元；其中所述丙烯酸酯是丙烯酸乙酯、丙烯酸丁酯或丙烯酸-2-乙基己酯；所述第二烯属不饱和单体是苯乙烯或甲基丙烯酸甲酯或其组合；并且其中所述第一羧酸单体是丙烯酸；
其中所述第一相与所述第二相的重量比为10∶90至35∶65。
5.根据权利要求1所述的组合物，其中第一羧酸单体是甲基丙烯酸并且所述第二羧酸单体是丙烯酸，其中以所述聚合物颗粒的重量计，丙烯酸和甲基丙烯酸的结构单元的总和不大于5重量百分比，并且不小于3重量百分比，并且其中以所述聚合物颗粒的重量计，Zn++离子的浓度为0.2至2重量百分比；其中所述聚合物颗粒的平均粒度在100nm至300nm范围内。
6.根据权利要求5所述的组合物，其中所述Zn++离子由碳酸锌铵或氧化锌产生，其中以所述聚合物颗粒的重量计，所述Zn++离子的浓度在0.8至2重量百分比范围内；其中甲基丙烯酸和丙烯酸的总结构单元与所述Zn++离子的摩尔比为4.5∶1至3∶1；并且其中所述组合物进一步包含流变改性剂。
7.根据权利要求1至6中任一项所述的组合物，其包含基本上不存在的纳米填料。
8.根据权利要求1至6中任一项所述的组合物，其包含基本上不存在的纵横比大于20∶1的纳米填料。
9.根据权利要求8所述的组合物，其包含小于1.8重量百分比的所述纳米填料。
10.一种制品，包含由包含Tg大于50℃的第一域和Tg小于35℃的第二区域的膜叠加的纸张衬底；其中所述第一域与所述第二域的所述重量比在5∶95至50∶50范围内；
其中所述第一域包含90至99重量百分比的第一烯属不饱和非离子单体的结构单元；和b)1至10重量百分比的第一羧酸单体的结构单元；以所述第一烯属不饱和非离子单体和所述第一羧酸单体的结构单元的重量计；
其中所述第二域包含：
a)90至98重量百分比的第二烯属不饱和非离子单体的结构单元；和b)2至10重量百分比的第二羧酸单体的结构单元，以所述第二非离子烯属不饱和单体和所述第二羧酸单体的重量计；
其中以所述单体的结构单元的重量计，所述膜进一步包含0.05至5重量百分比的Zn++或Zr++++离子，其中所述甲基丙烯酸和丙烯酸的总结构单元与Zn++离子的摩尔比在7∶1到2∶1范围内；并且所述羧酸单体的结构单元与Zr++++离子的摩尔比在3.5∶1至1∶1范围内；
其中所述膜的涂布重量厚度在1至20g/m2范围内。
CN201810776623.6A 2017-07-21 2018-07-16 具有多价金属离子的乳胶调配物 Pending CN109281225A (zh)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US201762535298P 2017-07-21 2017-07-21
US62/535298 2017-07-21

Publications (1)

Publication Number Publication Date
CN109281225A true CN109281225A (zh) 2019-01-29

Family

ID=63144799

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201810776623.6A Pending CN109281225A (zh) 2017-07-21 2018-07-16 具有多价金属离子的乳胶调配物

Country Status (8)

Country Link
US (1) US10683396B2 (zh)
EP (1) EP3431283B1 (zh)
JP (1) JP7353023B2 (zh)
KR (1) KR102604519B1 (zh)
CN (1) CN109281225A (zh)
BR (1) BR102018014552B1 (zh)
CA (1) CA3011684A1 (zh)
FI (1) FI3431283T3 (zh)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2020242473A1 (en) * 2019-05-30 2020-12-03 Hewlett-Packard Development Company, L.P. Inkjet ink for textile printing

Citations (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0173300A1 (en) * 1984-08-29 1986-03-05 National Starch and Chemical Corporation Aqueous surfactant-free base coating for metallized paper
US4980411A (en) * 1988-01-15 1990-12-25 Basf Aktiengesellschaft Binders for non-tacky, non-soiling, flexible coatings
CN1233260A (zh) * 1996-09-09 1999-10-27 巴斯福股份公司 聚合物水分散体的制备方法
CN1236380A (zh) * 1996-09-06 1999-11-24 奥里卡澳大利亚有限公司 防污的水性涂料组合物
US6255381B1 (en) * 1995-11-27 2001-07-03 Korea Research Institute Of Chemical Technology Process for manufacturing an acrylic antislipping agent composed of small amounts of solid content
US20040065425A1 (en) * 2002-10-07 2004-04-08 Kemira Chemicals, Inc. Latex paper sizing composition
TW201249876A (en) * 2011-06-15 2012-12-16 Rohm & Haas Microdomained emulsion polymers
US20130171346A1 (en) * 2009-06-04 2013-07-04 Basf Se Fluorinated core-shell-polymers and process for preparing same
US20140251563A1 (en) * 2011-11-09 2014-09-11 Basf Se Use in paper coatings of a mixture of a secondary polymeric dispersion and of a primary dispersion of an emulsion polymer
JP2016203982A (ja) * 2015-04-15 2016-12-08 東洋インキＳｃホールディングス株式会社 食品包装シート用コート剤および食品包装シート
CN106536577A (zh) * 2014-06-20 2017-03-22 陶氏环球技术有限责任公司 多阶段乳胶聚合物、其方法以及由其制得的涂料组合物

Family Cites Families (23)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA1117677A (en) * 1977-03-17 1982-02-02 David R. Gehman Internally plasticized polymer latex
DE3443964A1 (de) 1984-12-01 1986-06-12 Basf Ag, 6700 Ludwigshafen Verfahren zur herstellung von polymer-dispersionen, die blockfeste filme bilden
US4894397A (en) * 1988-04-21 1990-01-16 S. C. Johnson & Son, Inc. Stable emulsion polymers and methods of preparing same
US5081166A (en) * 1988-04-21 1992-01-14 S. C. Johnson & Son, Inc. Process for producing a stabilized latex emulsion adhesive
CA2071756A1 (en) * 1991-07-03 1993-01-04 Rohm And Haas Company Multi-staged binder for use in elastomeric coatings, caulks, and sealants
JP3963498B2 (ja) * 1996-04-11 2007-08-22 ローム アンド ハース カンパニー エマルションポリマー組成物
US5776619A (en) 1996-07-31 1998-07-07 Fort James Corporation Plate stock
AU2003203420B2 (en) * 2002-04-09 2008-12-11 Rohm And Haas Company Aqueous polymer blend composition
EP1366828A1 (en) 2002-05-31 2003-12-03 Rohm And Haas Company Multi-layer coating composition and method of preparation
MXPA03006208A (es) 2002-07-25 2004-12-07 Rohm & Haas Composiciones con respuesta activada.
AU2004200432A1 (en) * 2003-02-13 2004-09-02 Rohm And Haas Company Aqueous composition and method of preparing nonyellowing coating therefrom
JP3776421B2 (ja) 2003-09-08 2006-05-17 大王製紙株式会社 耐水耐油紙
FR2870454B1 (fr) * 2004-05-19 2006-08-25 Oreal Film de vernis a ongles aqueux
US20070219307A1 (en) * 2006-03-17 2007-09-20 Yong Yang Emulsion polymer blend coating compositions and methods for increasing chalky substrate adhesion
WO2009142739A1 (en) 2008-05-23 2009-11-26 Dow Global Technologies Inc. Paper coating composition having nanofiller
JP6190724B2 (ja) * 2011-03-02 2017-08-30 ダウ グローバル テクノロジーズ エルエルシー コーティング組成物およびそれから作製された物品
JP2013035600A (ja) 2011-07-14 2013-02-21 Osaka Insatsu Ink Seizo Kk 食品用包装紙
CN107163198B (zh) * 2012-02-10 2019-11-22 阿科玛股份有限公司 在零或低voc涂料组合物中有用的聚合物胶乳粘合剂
JP2015155582A (ja) 2014-02-21 2015-08-27 王子ホールディングス株式会社 ヒートシール性を有する撥水耐油紙及びその製造方法
US9670621B2 (en) 2015-02-11 2017-06-06 Westrock Mwv, Llc Compostable paperboard with oil, grease, and moisture resistance
US9863094B2 (en) 2015-02-11 2018-01-09 Westrock Mwv, Llc Printable compostable paperboard
US10703928B2 (en) * 2016-04-04 2020-07-07 Rohm And Haas Company Aqueous coating compositions having low or zero VOCs and comprising encapsulated or polymer adsorbed pigments and letdown binders
AU2017204813B2 (en) * 2016-08-08 2021-09-09 Rohm And Haas Company Paint composition

Patent Citations (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0173300A1 (en) * 1984-08-29 1986-03-05 National Starch and Chemical Corporation Aqueous surfactant-free base coating for metallized paper
US4980411A (en) * 1988-01-15 1990-12-25 Basf Aktiengesellschaft Binders for non-tacky, non-soiling, flexible coatings
US6255381B1 (en) * 1995-11-27 2001-07-03 Korea Research Institute Of Chemical Technology Process for manufacturing an acrylic antislipping agent composed of small amounts of solid content
CN1236380A (zh) * 1996-09-06 1999-11-24 奥里卡澳大利亚有限公司 防污的水性涂料组合物
CN1233260A (zh) * 1996-09-09 1999-10-27 巴斯福股份公司 聚合物水分散体的制备方法
US20040065425A1 (en) * 2002-10-07 2004-04-08 Kemira Chemicals, Inc. Latex paper sizing composition
US20130171346A1 (en) * 2009-06-04 2013-07-04 Basf Se Fluorinated core-shell-polymers and process for preparing same
TW201249876A (en) * 2011-06-15 2012-12-16 Rohm & Haas Microdomained emulsion polymers
US20140251563A1 (en) * 2011-11-09 2014-09-11 Basf Se Use in paper coatings of a mixture of a secondary polymeric dispersion and of a primary dispersion of an emulsion polymer
CN106536577A (zh) * 2014-06-20 2017-03-22 陶氏环球技术有限责任公司 多阶段乳胶聚合物、其方法以及由其制得的涂料组合物
JP2016203982A (ja) * 2015-04-15 2016-12-08 東洋インキＳｃホールディングス株式会社 食品包装シート用コート剤および食品包装シート

Also Published As

Publication number Publication date
FI3431283T3 (fi) 2024-01-24
JP2019023280A (ja) 2019-02-14
US10683396B2 (en) 2020-06-16
EP3431283A1 (en) 2019-01-23
JP7353023B2 (ja) 2023-09-29
BR102018014552A2 (pt) 2019-03-12
US20190023853A1 (en) 2019-01-24
KR102604519B1 (ko) 2023-11-21
EP3431283B1 (en) 2024-01-03
KR20190010447A (ko) 2019-01-30
CA3011684A1 (en) 2019-01-21
BR102018014552B1 (pt) 2023-04-04

Similar Documents

Publication Publication Date Title
EP1948707B1 (de) Silan-modifizierte polyvinylalkohole
CN109563360A (zh) 液态防水涂料
EP2057202A1 (de) Vernetzbare reaktive silikonorganocopolymere sowie verfahren zu deren herstellung und deren verwendung
EP2675850B1 (de) Modifizierte kompositpartikel
US20090312494A1 (en) Method for preparing a grafted copolymer by polyunsaturated fatty acids, copolymer grafted by polyunsaturated fatty acids obtainable by said method and uses thereof
AU2099600A (en) Filler-containing polymer dispersion, method for its production and its use
DE19733157A1 (de) Vernetzbare, in Wasser redispergierbare Pulverzusammensetzung
JP6466660B2 (ja) 塗料組成物、塗膜、及び、塗膜の製造方法
CN106164100B (zh) 乳液型树脂组合物及其制造方法
CN109281225A (zh) 具有多价金属离子的乳胶调配物
WO2008017671A1 (de) Selbstdispergierbare silikoncopolymerisate und verfahren zu deren herstellung und deren verwendung
CN106189469A (zh) 具有低或零voc并包含囊封或聚合物吸附的颜料和下降粘合剂的水性涂料组合
EP1620271B1 (de) Verwendung einer pulverförmigen zusammensetzung für die beschichtung von tintenstrahl-aufzeichnungsmaterialien
WO2011003864A1 (de) Kaltsiegelbare, durch emulsionspolymerisation in gegenwart von ethylen/(meth)acrylsäure copolymer hergestellte polymerdispersion
EP1812478B1 (de) Silan-modifizierte polyvinylalkohole
JP5466044B2 (ja) 紙塗工用共重合体ラテックス及び紙塗工用組成物
CN102911302B (zh) 乙酸乙烯酯类单体乳液活性聚合反应方法
EP2111419A2 (de) Radikalisches polymerisationsverfahren
JPS63254116A (ja) 高分子エマルジヨンの製造方法
JP2879121B2 (ja) 共重合体ラテックスの製造法
Temelkaya Bilgin Synthesis and characterization of water-based acrylic polymers for pressure-sensitive adhesive applications via mini-emulsion polymerization
DE10321941B4 (de) Verwendung einer pulverförmigen Beschichtungsmittel-Zusammensetzung
JPS62258738A (ja) 水性エマルジヨン型エアゾ−ル組成物
WO2008122297A1 (en) Adhesive composition comprising a filler-containing polymer dispersion, method for its production and its use
JP2002212205A (ja) 共重合体ラテックスおよび紙塗工用組成物

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination