CN108690733A - Gel detergent for kitchen use - Google Patents
Gel detergent for kitchen use Download PDFInfo
- Publication number
- CN108690733A CN108690733A CN201810179918.5A CN201810179918A CN108690733A CN 108690733 A CN108690733 A CN 108690733A CN 201810179918 A CN201810179918 A CN 201810179918A CN 108690733 A CN108690733 A CN 108690733A
- Authority
- CN
- China
- Prior art keywords
- ether
- kitchen use
- glycol
- detergent
- gel detergent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/008—Polymeric surface-active agents
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/28—Sulfonation products derived from fatty acids or their derivatives, e.g. esters, amides
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/72—Ethers of polyoxyalkylene glycols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/83—Mixtures of non-ionic with anionic compounds
- C11D1/831—Mixtures of non-ionic with anionic compounds of sulfonates with ethers of polyoxyalkylenes without phosphates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/0008—Detergent materials or soaps characterised by their shape or physical properties aqueous liquid non soap compositions
- C11D17/003—Colloidal solutions, e.g. gels; Thixotropic solutions or pastes
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/044—Hydroxides or bases
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2068—Ethers
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/22—Carbohydrates or derivatives thereof
- C11D3/222—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/33—Amino carboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3757—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Engineering & Computer Science (AREA)
- Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- Inorganic Chemistry (AREA)
- Dispersion Chemistry (AREA)
- Molecular Biology (AREA)
- Detergent Compositions (AREA)
Abstract
The invention discloses a kind of gel detergents for kitchen use, contain following components:Surfactant, chelating agent, alcohol ethers solvent, rheology modifier, pH adjusting agent, water.The raw materials used safety and environmental protection of the detergent, low to skin irritatin, not damaged to metal glass surface, cleaning effect is good.
Description
Technical field
The invention belongs to household cleaners technical field more particularly to a kind of gel detergents for kitchen use.
Background technology
The detergent of kitchen degreasing sold on the market at present, principle are a large amount of sodium hydroxide of addition mostly and molten
Agent and oil response generally reach the clean purpose of greasy dirt for 13 or more in pH, belong to high ph-values type detergent, and traditional
The detergent of kitchen degreasing is mostly liquid spray shape or the detergent of foam-like.
Wherein, the foam-like nozzle of detergent show bubble belongs to the packaging material applied in recent years, and the packaging material is by using spy
Show bubble after fixed technology makes conventional detergents be sprayed by nozzle has preferable attachment compared to traditional spray head
Power, but use the packaging material of the technology still undesirable applied to high dip face or the faster acting surface of air flowing, while this
The manufacturing requirements of class A foam A shape nozzle is high, expensive.
The detergent of above-mentioned kitchen degreasing has the disadvantage that:1, the pH value of detergent is high, high pH big to skin damage
The detergent of value system also has corrosiveness for materials such as glass, metals;2, oil is contacted again after such detergent being sprayed
Dirty surface, adhesive force is poor, and time of contact is short, especially for the acting surface that angle of inclination is larger, under the effect of gravity can
It falls quickly, cleaning effect is poor;Although the detergent of foam type improves to some extent compared with spray-like detergent, cleaning dynamics is still not
It is highly desirable;3, drop of the aerosol type of such detergent after atomization is easy sucking respiratory tract, influences health.
And gelatinous product viscosity is high, anelasticity is high, can be used for improving the cleaning effect of detergent.
In conclusion how pH is low, gelatinous performance combine develop it is a kind of it is non-stimulated, cleaning effect is good
Detergent for kitchen use is the key point of the present invention.
Invention content
In view of the problems of the above-mentioned prior art, the purpose of the present invention is to propose to a kind of gel detergents for kitchen use.
The raw materials used safety and environmental protection of the detergent, low to skin irritatin, cleaning effect is good.
The purpose of the present invention will be achieved by the following technical programs:
A kind of gel detergent for kitchen use, contains following components:Surfactant, chelating agent, alcohol ethers solvent, rheology
Modifying agent, pH adjusting agent, water.
Above-mentioned gel detergent for kitchen use, wherein the component containing following mass percent:Surfactant 1-
10%, chelating agent 1-5%, alcohol ethers solvent 1-15%, rheology modifier 1-10%, pH adjusting agent 0.1-5%, surplus are
Water.
Above-mentioned gel detergent for kitchen use, wherein the surfactant is selected from isomer fatty acids fat ethyl sulfonation
Object, octyl phenol polyoxyethylene ether or alkyl phenol polyoxyethylene ether it is any or combinations thereof.
Above-mentioned gel detergent for kitchen use, wherein the chelating agent is selected from disodium ethylene diamine tetraacetate, ethylenediamine tetraacetic
Four sodium of acetic acid or glutamic acid diacetic acid sodium are any or combinations thereof.
Above-mentioned gel detergent for kitchen use, wherein the alcohol ethers solvent is selected from E series alcohol ether solvents or/and P systems
Row alcohol ether solvents.
Above-mentioned gel detergent for kitchen use, wherein the E series alcohol ether solvents are passed through by core of ethylene oxide
Ring-opening reaction prepares, including diethylene glycol dimethyl ether, triethylene glycol methyl ether, diethylene glycol ether, tri ethylene glycol ethyl ether, second two
Alcohol propyl ether, butyl glycol ether, butyl, triethylene glycol butyl ether;The P series alcohol ether solvents are using propylene oxide as core
The heart is prepared by ring-opening reaction, including propylene glycol monomethyl ether, propylene glycol propyl ether, propandiol butyl ether, dipropylene glycol methyl ether, dipropyl
Glycol propyl ether, dipropylene, tripropylene glycol methyl ether, tripropylene glycol butyl ether, dimethyl ether.
Above-mentioned gel detergent for kitchen use, wherein the rheology modifier be selected from carbomer, acrylic acid (ester) class/
C10-30 alkylol acrylamide acid esters cross-linked polymer, xanthan gum.
Above-mentioned gel detergent for kitchen use, wherein the pH adjusting agent is selected from citric acid, sodium hydroxide, hydroxide
It is any or combinations thereof in potassium, triethanolamine or hydrochloric acid.
Compared with prior art, a kind of gel detergent for kitchen use provided by the invention, what is reached has the technical effect that:1)
The formula system entirety pH value of the present invention is low, not damaged to metal glass surface 9 hereinafter, low to skin irritatin, compared to
Traditional healthier safety of detergent for kitchen use;2) rheology modifier in the present invention can shear the high detergent of viscosity
It is thinning, convenient for spraying, and after spraying can fast quick-recovery be in the gel with certain viscosity, it is for kitchen use clear compared to traditional
Clean dose can be to avoid respiratory tract, while gel strong adhesive force be sucked, and action time is longer, and traditional detergent for kitchen use is usual
It to be liquid, is easily lost in, especially acts on high obliquity or inverted greasy dirt face, product are more easy to run off, cleaning effect
Difference;3) materials safety of the invention environmental protection, relative to traditional product to more environment-friendly;4) detergent of the invention, which uses, appoints
It is good that the conventional nozzle of meaning can be realized adhesive force, is suitably applied high dip face or air flows faster acting surface, to nozzle
Requirement it is low, reduce the application cost of detergent, preparation method is simple, meets the needs of users.
Below just in conjunction with the embodiments, the embodiment of the present invention is described in further detail, so that technical solution is more
It should be readily appreciated that, grasp.
Specific implementation mode
Below by specific embodiment, the present invention will be described, but the present invention is not limited thereto.In following embodiments
The experimental method is unless otherwise specified conventional method;The reagent and material unless otherwise specified can be from business
Approach obtains, and following example is not to limit the scope of the claims of the present invention, all equivalence enforcements without departing from carried out by the present invention
Or change, it is intended to be limited solely by the scope of this patent.
Embodiment 1
Gel detergent for kitchen use:By weight percentage, isomer fatty acids fat ethyl sulfonated bodies 5%;Glutamic acid two
Sodium acetate 4.5%;Butyl 5%;Potassium hydroxide 0.75%;Carbomer 1.5%;83.25% is water.
Preparation method is:Water 83.25%, carbomer 1.5% is added, stirring and dissolving is uniform;Glutamic acid diacetic acid sodium is added
4.5%, isomer fatty acids fat ethyl sulfonated bodies 5%, butyl 5%, stirring and dissolving is uniform;With potassium hydroxide 0.75%
Adjust pH to 6.8-7.2, viscosity 2000-6000mPaS.
The formula system pH of the present embodiment is 7.0, stands transparent gel, is sheared when by the fog-spray nozzle of any conventional
It is thinning, it is sprayed in misty, fast quick-recovery is in gel behind contact greasy dirt face, is firmly adsorbed in greasy dirt face, when gelatinous clear
Clean dose, with after the haptoreaction of greasy dirt face, can directly be rinsed with water totally.And present invention drop in atomization process is heavier, no
It is easy to wave, respiratory tract can be inhaled into avoid gel cleanser for kitchen use, influence health.Kitchen provided in this embodiment
It is environment-friendly materials with the formula material of detergent, the higher requirement of the sector can be met.The gel cleanser of the present embodiment
Drop is formed after atomization, is easy to spray, and restores to be in gel shape when contacting greasy dirt face, adhesive force is larger, through routine experiment side
Method detection can stop 5-8 minutes in the vertical surface of acting surface, and detergency reaches wanting for traditional oil smoke net products detergency
It asks.
Embodiment 2
Gel detergent for kitchen use:By weight percentage, isomer fatty acids fat ethyl sulfonated bodies 1.5%;Octyl phenol
Polyoxyethylene ether 3%;Disodium ethylene diamine tetraacetate 4%;Butyl 4%;Potassium hydroxide 0.49%;Carbomer 1%;The Chinese
Raw rubber 0.5%;Water 85.51%.
Preparation method is:Water 85.51%, carbomer 1%, xanthan gum 0.5% is added, stirring and dissolving is uniform;Second two is added
Amine tetraacethyl disodium 4%, isomer fatty acids fat ethyl sulfonated bodies 1.5%, butyl 4%, stirring and dissolving is uniform;Use hydrogen
Potassium oxide 0.49% adjusts pH to 7.0-7.5, viscosity 5000-10000mPaS.
The formula system pH of the present embodiment is 7.2, stands transparent gel, is sheared when by the fog-spray nozzle of any conventional
It is thinning, it is sprayed in misty, restores to be in gel behind contact greasy dirt face, be firmly adsorbed in greasy dirt face, compared in atomization process
It is heavier in 1 drop of embodiment, it can use, can be influenced to avoid respiratory tract is inhaled into the faster place of speed air flow
Health.The formula material cost of the detergent for kitchen use of the present embodiment is opposite relatively inexpensive with embodiment 1 simultaneously, has price
Advantage.Drop is formed after the gel atomization of the present embodiment, is easy to spray, restores to be in gel shape, adhesive force when contacting greasy dirt face
It is larger, it can be stopped 7-15 minutes in the vertical surface of acting surface through the detection of conventional experimental method, detergency reaches traditional oils
The requirement of cigarette net products detergency.
Embodiment 3
Gel detergent for kitchen use:By weight percentage, octyl phenol polyoxyethylene ether 3%;Ethylenediamine tetra-acetic acid two
Sodium 4%;Butyl 4%;Potassium hydroxide 0.55%;Carbomer 1%;Xanthan gum 0.5%;Water 86.95%.
Preparation method is:Water 86.95%, carbomer 1%, xanthan gum 0.5% is added, stirring and dissolving is uniform;Second two is added
Amine tetraacethyl disodium 4%, octyl phenol polyoxyethylene ether 3%, butyl 4%, stirring and dissolving is uniform;Use potassium hydroxide
0.55% adjusts pH to 7.0-7.5, viscosity 2000-5000mPaS.
The formula system pH of the present embodiment is 8.5, stands transparent gel, by fog-spray nozzle shear shinning, in mist
It sprays, fast quick-recovery is in gel behind contact greasy dirt face, greasy dirt face is firmly adsorbed in, when gelatinous detergent and greasy dirt face
After haptoreaction, can directly it be rinsed with water clean.The detergent for kitchen use of the present embodiment is compared to embodiment 1,2, this implementation
The formula system pH of example is slightly higher, but still far below the pH value of market conventional kitchen detergent, it is substantially non-stimulated to skin, and
And system cost is more economical, has price advantage.The gel cleanser of the present embodiment forms drop after atomization, is easy to spray
Go out, restore to be in gel shape when contacting greasy dirt face, adhesive force is larger, and the vertical surface in acting surface is detected through conventional experimental method
It can stop 5-10 minutes, detergency improves 50-100% than traditional oil smoke net products.
Embodiment 4
Gel detergent for kitchen use:By weight percentage, isomer fatty acids fat ethyl sulfonated bodies 5%;Glutamic acid two
Sodium acetate 4.5%;Butyl 5%;Potassium hydroxide 0.3%;Acrylic acid (ester) class/C10-30 alkylol acrylamide acid esters crosslinking
Polymer 2%;Water 83.2%.
Preparation method is:Water 83.2%, acrylic acid (ester) class/C10-30 alkylol acrylamide acid esters cross-linked polymer 2% is added,
Stirring and dissolving is uniform;Glutamic acid diacetic acid sodium 4.5%, isomer fatty acids fat ethyl sulfonated bodies 5%, butyl is added
5%, stirring and dissolving is uniform;PH to 6.8-7.2, viscosity 2000-5000mPaS are adjusted with potassium hydroxide 0.3%.
The formula system pH of the present embodiment is 7.0, stands transparent gel, is sheared when by the fog-spray nozzle of any conventional
It is thinning, it is sprayed in misty, wherein acrylic acid (ester) class/C10-30 alkylol acrylamide acid esters cross-linked polymers that the present embodiment uses
Compared with the carbomer that embodiment 1,2,3 uses, when very fast quick-recovery is firmly adsorbed in gel after contacting greasy dirt face
Behind greasy dirt face, with greasy dirt face haptoreaction, can directly it be rinsed with water clean.The present embodiment in atomization process drop compared with
Weight, it is not easy to wave, health can be influenced to avoid respiratory tract is inhaled into.Detergent for kitchen use provided in this embodiment
Formula material is environment-friendly materials, can meet the higher requirement of the sector.The gel cleanser of the present embodiment shape after atomization
At drop, it is easy to spray, restores to be in gel shape when contacting greasy dirt face, adhesive force is larger, is making through the detection of conventional experimental method
It can be stopped 5-10 minutes with the vertical surface in face, detergency improves 20% or more than traditional oil smoke net products.
Embodiment 5
Gel detergent for kitchen use:By weight percentage, isomer fatty acids fat ethyl sulfonated bodies 8%;Glutamic acid two
Sodium acetate 4.5%;Butyl 5%;Potassium hydroxide 0.28%;Acrylic acid (ester) class/C10-30 alkylol acrylamide acid esters is handed over
Linked polymer 2%;Water 80.22%.
Preparation method is:Water 80.38%, acrylic acid (ester) class/C10-30 alkylol acrylamide acid esters cross-linked polymers is added
2%, stirring and dissolving is uniform;Glutamic acid diacetic acid sodium 4.5%, isomer fatty acids fat ethyl sulfonated bodies 8%, diethylene glycol fourth is added
Ether 5%, stirring and dissolving is uniform;PH to 5.8-6.2, viscosity 2000-5000mPaS are adjusted with potassium hydroxide 0.28%.
The formula system pH of the present embodiment is 6.0, stands transparent gel, is sheared when by the fog-spray nozzle of any conventional
It is thinning, it is sprayed in misty, wherein acrylic acid (ester) class/C10-30 alkylol acrylamide acid esters cross-linked polymers that the present embodiment uses
Compared with the carbomer that embodiment 1,2,3 uses, when very fast quick-recovery is firmly adsorbed in gel after contacting greasy dirt face
Behind greasy dirt face, with greasy dirt face haptoreaction, can directly it be rinsed with water clean.The present embodiment in atomization process drop compared with
Weight, it is not easy to wave, health can be influenced to avoid respiratory tract is inhaled into.Detergent for kitchen use provided in this embodiment
Formula material is environment-friendly materials, can meet the higher requirement of the sector.
The gel cleanser of the present embodiment forms drop after atomization, is easy to spray, and restores to be in Gel when contacting greasy dirt face
Curry shape, adhesive force is larger, can stop 5-10 minutes in the vertical surface of acting surface through the detection of conventional experimental method, detergency
Reach the requirement of traditional oil smoke net products detergency.
Test example 1
A. detergency test
Method:With reference to QBT4348"Kitchen cleaning agent of grease stain"The requirement of standard appendix A, weighs 200g samples and is placed in 35 DEG C of water
In bath, ready dirty piece is clipped in pendulum and is washed on frame, so that greasy dirt is impregnated 10min in sample solution completely, then put and wash 5min, so
30s is washed with clear water pendulum afterwards, test piece is removed and is weighed after dry 40min in 120 DEG C of baking ovens, calculate detergency.
Specimen sample:Kitchen gel cleanser prepared by embodiment 1-5, comparative example 1:Commercially available kitchen cleaning agent A.
It the results are shown in Table 1.
B. corrosion resistance is tested
With reference to QBT 4348"Kitchen cleaning agent of grease stain"Standard requirement, using sample stoste 150ml, heating water bath makes temperature
It for (25 ± 2) DEG C, is taken out after 30min is impregnated in two pieces of duralumin (LY12) test pieces wherein, (pendulum is washed 10 times) is rinsed with distilled water,
Dehydration and hot wind sense of touch, calculate etching extent, it is desirable that etching extent≤100mg after weighing in absolute ethyl alcohol.
Specimen sample:Kitchen gel cleanser prepared by embodiment 1-5, comparative example 1:Commercially available kitchen cleaning agent.As a result
It is shown in Table 1.
The test result of 1 embodiment 1-5 of table, 1 detergency of comparative example, corrosion resistance
C. acute skin irritation is tested
Given the test agent:Kitchen gel cleanser prepared by embodiment 1-5, comparative example 1:Commercially available kitchen cleaning agent.
Experimental animal
The male rabbit 36 of adult, health, skin zero damage is chosen, point 6 groups, respectively 1 group of embodiment, embodiment 2
Group, 3 groups of embodiment, 4 groups of embodiment, 5 groups of embodiment, 1 group of comparative example, every group 6.
Male rabbit selects conventional feed to feed, free water according to national corresponding regulation.
Method:
1) normal raising 3d before experiment, and before the test about for 24 hours, experimental animal back backbone diamond wool is cut, it can not
Damage epidermis, the left and right each about 2cm × 3cm of unhairing range;
2) 0.5 ± 0.0002g of tested material is taken to be coated directly on skin, then with two layers of gauze (2.5cm × 2.5cm) and one
Layer glassine paper covering, then fixed with medical proof fabric and bandage, other side skin is as a contrast;Using blocking test, application
Time is 4h, cleans residual tested material with warm water after the test;
3) 1h after removing tested material, for 24 hours the position dermoreaction of observation smearing, dermoreaction scoring is carried out by table 2, with
The average value of tested rabbit integral carries out overall merit, according to 1h, respectively observes time point top mean value for 24 hours, judges skin by table 3
Skin stimulus intensity.
Evaluation of result:Daily every animal average integral is calculated according to the following formula, skin irritatin intensity, knot are judged with table 3
Fruit is shown in Table 4.
2 skin wound repair of table scores
3 skin irritatin strength grading of table
4 embodiment 1-5 of table, comparative example 1 are to Rabbits with Acute skin irritation test result
As shown in Table 4, gel detergent for kitchen use of the invention is to no skin irritation.
Test example 2
Gel detergent for kitchen use prepared by embodiment 1-5 proves through conventional heat-resisting low temperature resistant test, kitchen of the invention
Room not stratified, viscosity stablization with gel detergent.
Several preferred embodiments of the present invention have shown and described in above description, but as previously described, it should be understood that the present invention
Be not limited to form disclosed herein, be not to be taken as excluding other embodiments, and can be used for various other combinations,
Modification and environment, and the above teachings or related fields of technology or knowledge can be passed through in the scope of the invention is set forth herein
It is modified.And changes and modifications made by those skilled in the art do not depart from the spirit and scope of the present invention, then it all should be in this hair
In the protection domain of bright appended claims.
Claims (8)
1. a kind of gel detergent for kitchen use, which is characterized in that contain following components:Surfactant, chelating agent, alcohol ethers
Solvent, rheology modifier, pH adjusting agent, water.
2. gel detergent for kitchen use according to claim 1, which is characterized in that the group containing following mass percent
Point:Surfactant 1-10%, chelating agent 1-5%, alcohol ethers solvent 1-15%, rheology modifier 1-10%, pH adjusting agent
0.1-5%, surplus are water.
3. gel detergent for kitchen use according to claim 1, which is characterized in that the surfactant is selected from isomery
Fatty acid ester ethyl sulfonated bodies, octyl phenol polyoxyethylene ether or alkyl phenol polyoxyethylene ether it is any or combinations thereof.
4. gel detergent for kitchen use according to claim 1, which is characterized in that the chelating agent is selected from ethylenediamine tetraacetic
Acetic acid disodium, tetrasodium ethylenediamine tetraacetate or glutamic acid diacetic acid sodium are any or combinations thereof.
5. gel detergent for kitchen use according to claim 1, which is characterized in that the alcohol ethers solvent is selected from E systems
Row alcohol ether solvents or/and P series alcohol ether solvents.
6. gel detergent for kitchen use according to claim 1, which is characterized in that the E series alcohol ether solvents be with
Ethylene oxide is prepared for core by ring-opening reaction, including diethylene glycol dimethyl ether, triethylene glycol methyl ether, diethylene glycol second
Ether, tri ethylene glycol ethyl ether, glycol propyl ether, butyl glycol ether, butyl, triethylene glycol butyl ether;The P series alcohol ether
Solvent is prepared by ring-opening reaction using propylene oxide as core, including propylene glycol monomethyl ether, propylene glycol propyl ether, propylene glycol fourth
Ether, dipropylene glycol methyl ether, dipropylene glycol propyl ether, dipropylene, tripropylene glycol methyl ether, tripropylene glycol butyl ether, dipropylene glycol
Dimethyl ether.
7. gel detergent for kitchen use according to claim 1, which is characterized in that the rheology modifier is selected from card wave
Nurse, acrylic acid (ester) class/C10-30 alkylol acrylamide acid esters cross-linked polymer, xanthan gum.
8. gel detergent for kitchen use according to claim 1, which is characterized in that the pH adjusting agent is selected from lemon
It is any or combinations thereof in acid, sodium hydroxide, potassium hydroxide, triethanolamine or hydrochloric acid.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810179918.5A CN108690733A (en) | 2018-03-05 | 2018-03-05 | Gel detergent for kitchen use |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810179918.5A CN108690733A (en) | 2018-03-05 | 2018-03-05 | Gel detergent for kitchen use |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN108690733A true CN108690733A (en) | 2018-10-23 |
Family
ID=63844465
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201810179918.5A Pending CN108690733A (en) | 2018-03-05 | 2018-03-05 | Gel detergent for kitchen use |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN108690733A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112094704A (en) * | 2020-10-15 | 2020-12-18 | 北京佰易和环保工程有限公司 | Cleaning gel for kitchen fume exhaust facility and fume exhaust pipeline |
| CN113717587A (en) * | 2021-09-02 | 2021-11-30 | 李超 | Decolorizing gel for TPE and silica gel products and preparation method thereof |
-
2018
- 2018-03-05 CN CN201810179918.5A patent/CN108690733A/en active Pending
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112094704A (en) * | 2020-10-15 | 2020-12-18 | 北京佰易和环保工程有限公司 | Cleaning gel for kitchen fume exhaust facility and fume exhaust pipeline |
| CN113717587A (en) * | 2021-09-02 | 2021-11-30 | 李超 | Decolorizing gel for TPE and silica gel products and preparation method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN104263566B (en) | A kind of stain removal bactericidal multifunctional cleaning cream and preparation method thereof | |
| CN106398887B (en) | Multipurpose high-efficiency environment-protecting clean liquid and preparation method thereof | |
| CN101953660B (en) | Automotive glass antifogging cleaning wet tissue and preparation method thereof | |
| CN106148030B (en) | Kitchen wet paper immersion and the preparation method and application thereof | |
| CN105125128A (en) | Glass anti-fog wet wipes and production method thereof | |
| CN108690733A (en) | Gel detergent for kitchen use | |
| JP3617613B2 (en) | Liquid detergent composition | |
| US8658630B2 (en) | Allergen depressant and depression method | |
| CN103320238B (en) | Water-based cleaning agent with weak acidity for removing thick oil dirt, and preparation method thereof | |
| CN106379000A (en) | Disposable high-efficiency environment-friendly car cleaning wipe, high-efficiency environment-friendly waterless car cleaning wet wipe and preparation methods thereof | |
| CN109646327A (en) | A kind of moisturiser and preparation method thereof with liquid crystal structure | |
| CN106967529B (en) | A kind of mildly inirritative dish washing detergent and preparation method thereof | |
| TW201542235A (en) | Skin cleanser composition | |
| CN112375632B (en) | Environment-friendly bio-based cleaning aerosol and preparation method thereof | |
| CN100360632C (en) | Multifunctional long-effect environmental protective glass antifogging defrosting agent | |
| CN108130221B (en) | Foam cleaning agent | |
| JP2015525310A (en) | Processed nonwoven fabric containing functional additives and method for producing the processed nonwoven fabric | |
| CN106947635B (en) | Car washing liquid and preparation method thereof and car-washing method | |
| JP7381693B2 (en) | cleaning products | |
| JP4044080B2 (en) | Allergen remover | |
| CN103849496B (en) | A kind of adhesive sticker removing residual glue stain cleanser and production technology thereof | |
| CN108179430B (en) | A kind of auto parts cleaning agent and preparation method thereof | |
| WO2022077953A1 (en) | Detergent and preparation method therefor | |
| CN108251851A (en) | A kind of stainless steel surface environment-friendly cleaning agent | |
| JP4043011B2 (en) | Wet wiper |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20181023 |
|
| RJ01 | Rejection of invention patent application after publication |