CN108393077A - A kind of preparation method of high efficiency absorbent-type dephosphorization agent - Google Patents
A kind of preparation method of high efficiency absorbent-type dephosphorization agent Download PDFInfo
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- CN108393077A CN108393077A CN201810262519.5A CN201810262519A CN108393077A CN 108393077 A CN108393077 A CN 108393077A CN 201810262519 A CN201810262519 A CN 201810262519A CN 108393077 A CN108393077 A CN 108393077A
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/10—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/28—Treatment of water, waste water, or sewage by sorption
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/52—Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities
- C02F1/5236—Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities using inorganic agents
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2101/00—Nature of the contaminant
- C02F2101/10—Inorganic compounds
- C02F2101/105—Phosphorus compounds
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Abstract
The present invention relates to material for water treatment preparing technical fields, and in particular to a kind of preparation method of high efficiency absorbent-type dephosphorization agent.The present invention is using sepiolite as adsorption substrates, aqueous deposit and modified mixed-powder are as accelerating agent, and it is aided with absolute ethyl alcohol etc. and high usage absorbent-type dephosphorization agent is prepared, using sepiolite as raw material modified meerschaum powder is obtained by processing, seventy flavors pearl pill and sodium carbonate are mixed, and lanthanum carbonate is prepared under the action of polyethylene glycol, adsorption substrates coated with lanthanum carbonate have adsorption capacity, the dephosphorization rate of dephosphorization agent is improved again, by scallop shell and molybdenum disulfide mixed grinding at mixed-powder, mixed-powder is modified using silane coupling agent, improve the caking property between mixed-powder and adsorption substrates, phosphate reaction in the free calcium ion and sewage generated in scallop shell generates di calcium precipitate, further increase the dephosphorization rate of dephosphorization agent, it is with a wide range of applications.
Description
Technical field
The present invention relates to material for water treatment preparing technical fields, and in particular to a kind of preparation of high efficiency absorbent-type dephosphorization agent
Method.
Background technology
Phosphorus is the one of the chief elements of life to be maintained in earth system, and constitute organism and participate in metabolic processes
Essential element.But body eutrophication is may result in if phosphorus content is more than 20mg/L in water body, causes algae a large amount of
Breeding, being decomposed after frond death can make water body generate musty and stink, influence the existence of the aquatiles such as fish.
Phosphorus-containing wastewater main source is：1, Phos waste water can be divided into according to the existing forms of phosphorus（Phosphate, polyphosphoric acid
Salt）And organism P wastewater（Organic phosphorus compound is mixed in water）；2, Cataloguing In Source mostlys come from various detergent, phosphatization
The excretion etc. of waste water, the production process of agricultural fertilizer and human body.
The phosphorus in waste water is mainly removed by chemical coacervating precipitation method and bioanalysis at present.Bioanalysis such as A/O, A2/O, UCT
Technique is mainly suitable for processing low concentration and organic phosphorus-containing wastewater.Chemical method mainly has coagulant sedimentation, crystallisation, ion to hand over
The techniques such as absorption method, electrodialysis, reverse osmosis are changed, are mainly suitable for processing inorganic states phosphorus-containing wastewater, chemical precipitation method is due to dephosphorizing rate
It is high and become common dephosphorization method.The discharge index of phosphorus is very low, and level-one A scale values are 0.5 mg/litre, so many sewage pass through
All be difficult to after the biochemical treatment stage it is up to standard, this be many units with dephosphorization agent come the reason of supplementing dephosphorization.
Dephosphorization agent be to sewage carry out biochemical treatment after still cannot be up to standard when supplement medicament, function is in coagulation turbidity removing
While remove total phosphorus, achieve the purpose that qualified discharge.Original sub-block flow is had no need to change in operation, need not add large size
Water treatment building, it is simple and easy to do, it is economical and practical, it can get significant social and economic benefit.Currently, most of dephosphorization agent with
Inorganic molysite, aluminium salt, calcium salt or iron aluminium calcium and magnesium compound based on, form metal phosphate precipitation, pass through the side of spoil disposal
Formula removes, and phosphor-removing effect is good, but the dosage of product is big, utilization rate is low, sludge output is big, easily causes pipe-line equipment blocking.Largely
The additive of metal object is unfavorable for biosystem growth, is unfavorable for sludge incineration or compost disposition, is easy to form secondary pollution, together
When also increase processing cost.
Therefore, secondary pollution is not generated in there is an urgent need for a kind of phosphor-removing effects of research and development good, recyclable recycling, preparation process
Sewage dephosphorization agent.
Invention content
The technical problems to be solved by the invention：Low for calcium content in dephosphorization agent common at present, specific surface area is smaller,
Alkalinity cannot be satisfied the needs of partial crystallization reaction, and relatively low to the removal rate of phosphor in sewage, can not meet the defect of market demands, carries
A kind of preparation method of high efficiency absorbent-type dephosphorization agent is supplied.
In order to solve the above technical problems, the present invention is using technical solution as described below：
A kind of preparation method of high efficiency absorbent-type dephosphorization agent, it is characterised in that specifically preparation process is：
（1）It weighs and crosses 80 mesh sieve after 65~70g sepiolites are ground, collect sieving sepiolite powder, then the sepiolite that will be sieved
Powder and deionized water mixing are impregnated, and after settling, filtering removal sediment obtains filtrate, and filtrate is placed in baking oven and is done
It is dry, obtain dried object；
（2）Continue dried object and mixed in hydrochloric acid being placed in beaker and stir, be dried after stirring, drying is placed in Muffle furnace
Roasting, cooling discharging obtain modified meerschaum powder；
（3）It weighs 3~5g seventy flavors pearl pills and stirring and dissolving in 180~200mL distilled water is poured into the mixing of 1~2g polyethylene glycol,
Lysate is obtained, then 0.8~1.0mL sodium carbonate liquors are added dropwise into lysate and are mixed, obtains aqueous deposit, control contains
Water deposit pH is 8.1~8.6, continues to stir, and finally modified meerschaum powder and aqueous deposit are mixed, centrifugation point
From, removal water phase, isolated loaded article；
（4）Scallop shell and molybdenum disulfide are mixed to be placed in grinder after grinding and cross 80 mesh sieve, collects sieving mixed-powder, incited somebody to action
It sieves mixed-powder and silane resin acceptor kh-550 is mixed, obtain mixture, continue that mixture quality is added into mixture
The Yoghourt of 8% glucose and mixture quality 0.5%, is fitted into fermentation tank, is sealed by fermentation, and after fermentation, takes out fermentation production
Object, as modified mixed-powder；
（5）Loaded article, modified mixed-powder and absolute ethyl alcohol are mixed, obtain stirred suspension, then by stirred suspension
It is placed in ultrasonic wave separating apparatus and is ultrasonically treated with lauryl sodium sulfate mixing, supersound process is placed in baking oven dry, cooling
Discharging is to get high efficiency absorbent-type dephosphorization agent.
Step（1）The time that grinds is 10~12min, the mass ratio of be sieved sepiolite powder and deionized water
It is 1：3, soaking time is 24~32min, and drying temperature is 75~85 DEG C, and drying time is 30~32min.
Step（2）The solid-liquid mass ratio of the dried object and a concentration of 0.8mol/L hydrochloric acid is 1：20, whipping temp is
80~85 DEG C, mixing time be 12~16h, drying time be 2~4h, calcination temperature be 400~420 DEG C, roasting time be 1~
2h。
Step（3）The stirring and dissolving rotating speed is 200~240r/min, and the stirring and dissolving time is 32~40min, carbonic acid
A concentration of 1mol/L of sodium solution, mixing time are 20~24min, and whipping temp is 45~50 DEG C, continues mixing time
For 1~2h, the mass ratio of modified meerschaum powder and aqueous deposit is 3：1, the mixing time is 45~60min.
Step（4）The mass ratio of the scallop shell and molybdenum disulfide is 1：4, milling time is 5~7min, sieving mixing
The mass ratio of powder and silane resin acceptor kh-550 is 5：1, the mixing time is 10~12min, and fermentation temperature is 37~42
DEG C, fermentation time is 9~11 days.
Step（5）The mass ratio of the loaded article, modified mixed-powder and absolute ethyl alcohol is 5：3：1, when mixing
Between be 16~20min, the mass ratio of stirred suspension and lauryl sodium sulfate is 5：1, be ultrasonically treated frequency be 24~
30kHz, sonification power are 160~200W, and sonication treatment time is 1~2h, and drying temperature is 96~100 DEG C, when dry
Between be 35~45min.
Compared with other methods, advantageous effects are the present invention：
（1）Using sepiolite as adsorption substrates, aqueous deposit and modified mixed-powder are aided with anhydrous the present invention as accelerating agent
High usage absorbent-type dephosphorization agent is prepared in ethyl alcohol etc., grinds sepiolite to obtain sepiolite powder first, by itself and hydrochloric acid
It is mixed, and acidification reaction occurs and obtains acidulants, then acidulants are roasted to obtain modified meerschaum powder, due to sea
Afrodite makes its Si-O-Mg-O-Si key become two Si-O keys through acid processing, that is, the structure of " unlimited " state occurs, at this time
Inner passage is connected to, and surface area increases, while micropore being made to develop into mesoporous, and pore ratio is reduced, and mesopore ratio increases, to
The adsorptivity and dephosphorization rate of dephosphorization agent are improved, then seventy flavors pearl pill and sodium carbonate are mixed, and in the work of polyethylene glycol
Lanthanum carbonate is prepared under, lanthanum carbonate is then supported on adsorption substrates surface so that adsorption substrates surface forms more
Activated centre, these activated centres are to PO4 3-There is larger adsorption capacity, improves the dephosphorization rate of dephosphorization agent again, in addition poly- second two
Alcohol is a kind of nontoxic surfactant, carries a large amount of hydroxyl and ehter bond, can form one layer of polymeric on lanthanum carbonate surface
Layer makes the active material of substrate surface be controlled, is conducive to the adsorptivity of dephosphorization agent to control the type looks and grain size of lanthanum carbonate
It is improved；
（2）The present invention by scallop shell and molybdenum disulfide mixed grinding at mixed-powder, using silane coupling agent to mixed-powder into
Row is modified, itself and glucose and Yoghourt co-fermentation are made it have breakdown of glucose at macromolecular carbohydrate using microorganism
Viscosity improves the caking property between mixed-powder and adsorption substrates, and wherein molybdenum disulfide has and stratiform knot as graphite-like
Structure, and sulphur atom is negative divalent in molybdenum disulfide molecule, so that molybdenum disulfide is had higher chemism, promotes containing carbonic acid
The scallop shell of calcium and the combination of adsorption substrates, and since phosphorus contained in sewage is most of with phosphate radical, hydrogen phosphate, di(2-ethylhexyl)phosphate
The form of hydrogen radical plasma exists, and the calcium carbonate contained in scallop shell dissolves in acid condition, generates largely free calcium
Ion, calcium ion generate di calcium precipitate with the phosphate reaction in sewage, further increase the dephosphorization rate of dephosphorization agent, have
Have wide practical use.
Specific implementation mode
It weighs after 65~70g sepiolites grind 10~12min and crosses 80 mesh sieve, collect sieving sepiolite powder, then will
Sieving sepiolite powder and deionized water are 1 in mass ratio：24~32min is impregnated in 3 mixing, after settling, filtering removal precipitation
Object obtains filtrate, and filtrate is placed in baking oven, and dry 30~32min at being 75~85 DEG C in temperature obtains dried object；After
Continuous by dried object and a concentration of 0.8mol/L hydrochloric acid is 1 by solid-liquid mass ratio：20 mixing are placed in beaker, are 80~85 in temperature
12~16h is stirred at DEG C, 2~4h is dried after stirring, and drying is placed in Muffle furnace, is roasted at being 400~420 DEG C in temperature
1~2h is burnt, cooling discharging obtains modified meerschaum powder；It weighs 3~5g seventy flavors pearl pills and the mixing of 1~2g polyethylene glycol is fallen
Enter in 180~200mL distilled water, 32~40min of stirring and dissolving under conditions of rotating speed is 200~240r/min is dissolved
Liquid, then into lysate, 20~24min is mixed in the sodium carbonate liquor of a concentration of 1mol/L of 0.8~1.0mL of dropwise addition, is contained
Water deposit, control aqueous deposit pH is 8.1~8.6, and temperature continues 1~2h of stirring under conditions of being maintained at 45~50 DEG C,
It is finally 3 in mass ratio by modified meerschaum powder and aqueous deposit：1 is mixed 45~60min, centrifuges, removal
Water phase, isolated loaded article；It is 1 in mass ratio：4 scallop shell and molybdenum disulfide are mixed be placed in grinding 5 in grinder~
80 mesh sieve is crossed after 7min, collects sieving mixed-powder, is 5 in mass ratio by sieving mixed-powder and silane resin acceptor kh-550：1
10~12min is mixed, obtains mixture, continues glucose and compounding substances that mixture quality 8% is added into mixture
The Yoghourt of amount 0.5%, is fitted into fermentation tank, sealing and fermenting 9~11 days under conditions of temperature is 37~42 DEG C, after fermentation,
Tunning is taken out, as modified mixed-powder；It is 5 in mass ratio：3：1 by loaded article, modified mixed-powder and absolute ethyl alcohol
16~20min is mixed, obtains stirred suspension, then by stirred suspension and lauryl sodium sulfate is 5 in mass ratio：1
Mixing be placed in ultrasonic wave separating apparatus, under conditions of frequency is 24~30kHz, power is 160~200W be ultrasonically treated 1~
2h, supersound process are placed in baking oven, and dry 35~45min at being 96~100 DEG C in temperature, cooling discharging is to get high efficiency
Absorbent-type dephosphorization agent.
Example 1
It weighs after 65g sepiolites grind 10min and crosses 80 mesh sieve, collect sieving sepiolite powder, then the sepiolite powder that will be sieved
End and deionized water are 1 in mass ratio：24min is impregnated in 3 mixing, and after settling, filtering removal sediment obtains filtrate, and will
Filtrate is placed in baking oven, and dry 30min at being 75 DEG C in temperature obtains dried object；Continue dried object and a concentration of 0.8mol/
L hydrochloric acid is 1 by solid-liquid mass ratio：20 mixing are placed in beaker, stir 12h at being 80 DEG C in temperature, 2h is dried after stirring,
Drying is placed in Muffle furnace, roasts 1~2h at being 400 DEG C in temperature, cooling discharging obtains modified meerschaum powder；It weighs
3g seventy flavors pearl pills and the mixing of 1g polyethylene glycol are poured into 180mL distilled water, are stirred under conditions of rotating speed is 200r/min molten
32min is solved, lysate is obtained, then the sodium carbonate liquor mixing of a concentration of 1mol/L of 0.8mL is added dropwise into lysate
20min obtains aqueous deposit, and control aqueous deposit pH is 8.1, and temperature continues to stir 1h under conditions of being maintained at 45 DEG C,
It is finally 3 in mass ratio by modified meerschaum powder and aqueous deposit：1 is mixed 45min, centrifuges, and removes water phase,
Isolated loaded article；It is 1 in mass ratio：4 are placed in scallop shell and molybdenum disulfide mixing in grinder excessively 80 after grinding 5min
Mesh sieves, and collects sieving mixed-powder, is 5 in mass ratio by sieving mixed-powder and silane resin acceptor kh-550：1 is mixed
10min obtains mixture, continues the acid that the glucose and mixture quality 0.5% of mixture quality 8% are added into mixture
Milk is fitted into fermentation tank, is sealed by fermentation under conditions of temperature is 37 DEG C 9 days, after fermentation, is taken out tunning, as
Modified mixed-powder；It is 5 in mass ratio：3：16min is mixed in loaded article, modified mixed-powder and absolute ethyl alcohol by 1, is obtained
Stirred suspension, then by stirred suspension and lauryl sodium sulfate be 5 in mass ratio：1 mixing is placed in ultrasonic wave separating apparatus,
1h is ultrasonically treated under conditions of frequency is 24kHz, power is 160W, supersound process is placed in baking oven, is 96 DEG C in temperature
Lower dry 35min, cooling discharging is to get high efficiency absorbent-type dephosphorization agent.
Example 2
It weighs after 67g sepiolites grind 11min and crosses 80 mesh sieve, collect sieving sepiolite powder, then the sepiolite powder that will be sieved
End and deionized water are 1 in mass ratio：28min is impregnated in 3 mixing, and after settling, filtering removal sediment obtains filtrate, and will
Filtrate is placed in baking oven, and dry 31min at being 80 DEG C in temperature obtains dried object；Continue dried object and a concentration of 0.8mol/
L hydrochloric acid is 1 by solid-liquid mass ratio：20 mixing are placed in beaker, stir 18h at being 83 DEG C in temperature, 3h is dried after stirring,
Drying is placed in Muffle furnace, roasts 1.5h at being 410 DEG C in temperature, cooling discharging obtains modified meerschaum powder；Weigh 4g
Seventy flavors pearl pill and the mixing of 1.5g polyethylene glycol are poured into 190mL distilled water, are stirred under conditions of rotating speed is 220r/min molten
36min is solved, lysate is obtained, then the sodium carbonate liquor mixing of a concentration of 1mol/L of 0.9mL is added dropwise into lysate
23min obtains aqueous deposit, and control aqueous deposit pH is 8.3, and temperature continues to stir under conditions of being maintained at 47 DEG C
Modified meerschaum powder and aqueous deposit are finally 3 in mass ratio by 1.5h：1 is mixed 53min, centrifuges, removal
Water phase, isolated loaded article；It is 1 in mass ratio：4 are placed in scallop shell and molybdenum disulfide mixing in grinder after grinding 6min
80 mesh sieve is crossed, sieving mixed-powder is collected, is 5 in mass ratio by sieving mixed-powder and silane resin acceptor kh-550：1 mixing is stirred
11min is mixed, mixture is obtained, continues the acid that the glucose and mixture quality 0.5% of mixture quality 8% are added into mixture
Milk is fitted into fermentation tank, is sealed by fermentation under conditions of temperature is 40 DEG C 10 days, after fermentation, is taken out tunning, as
Modified mixed-powder；It is 5 in mass ratio：3：18min is mixed in loaded article, modified mixed-powder and absolute ethyl alcohol by 1, is obtained
Stirred suspension, then by stirred suspension and lauryl sodium sulfate be 5 in mass ratio：1 mixing is placed in ultrasonic wave separating apparatus,
1.5h is ultrasonically treated under conditions of frequency is 26kHz, power is 180W, supersound process is placed in baking oven, is 98 in temperature
Dry 40min at DEG C, cooling discharging is to get high efficiency absorbent-type dephosphorization agent.
Example 3
It weighs after 70g sepiolites grind 12min and crosses 80 mesh sieve, collect sieving sepiolite powder, then the sepiolite powder that will be sieved
End and deionized water are 1 in mass ratio：32min is impregnated in 3 mixing, and after settling, filtering removal sediment obtains filtrate, and will
Filtrate is placed in baking oven, and dry 32min at being 85 DEG C in temperature obtains dried object；Continue dried object and a concentration of 0.8mol/
L hydrochloric acid is 1 by solid-liquid mass ratio：20 mixing are placed in beaker, stir 16h at being 85 DEG C in temperature, 4h is dried after stirring,
Drying is placed in Muffle furnace, roasts 2h at being 420 DEG C in temperature, cooling discharging obtains modified meerschaum powder；Weigh 5g seven
Water lanthanum chloride and the mixing of 2g polyethylene glycol are poured into 200mL distilled water, stirring and dissolving under conditions of rotating speed is 240r/min
40min obtains lysate, then the sodium carbonate liquor mixing 24min of a concentration of 1mol/L of 1.0mL is added dropwise into lysate,
Aqueous deposit is obtained, control aqueous deposit pH is 8.6, and temperature continues to stir 2h under conditions of being maintained at 50 DEG C, finally will
Modified meerschaum powder and aqueous deposit are 3 in mass ratio：1 is mixed 60min, centrifuges, and removes water phase, detaches
To loaded article；It is 1 in mass ratio：4 scallop shell and molybdenum disulfide are mixed be placed in grinder grind 7min after cross 80 mesh sieve, receive
Sieving mixed-powder and silane resin acceptor kh-550 are 5 in mass ratio by collection sieving mixed-powder：1 is mixed 12min, obtains
To mixture, continues the Yoghourt that the glucose and mixture quality 0.5% of mixture quality 8% are added into mixture, be packed into hair
In fermentation tank, it is sealed by fermentation under conditions of temperature is 42 DEG C 11 days, after fermentation, takes out tunning, as modified mixing
Powder；It is 5 in mass ratio：3：20min is mixed in loaded article, modified mixed-powder and absolute ethyl alcohol by 1, obtains stirring suspension
Liquid, then by stirred suspension and lauryl sodium sulfate be 5 in mass ratio：1 mixing is placed in ultrasonic wave separating apparatus, is in frequency
30kHz, power are ultrasonically treated 2h under conditions of being 200W, supersound process is placed in baking oven, dry at being 100 DEG C in temperature
45min, cooling discharging is to get high efficiency absorbent-type dephosphorization agent.
Comparative example
With the dephosphorization agent of Fuyang City company production as a comparison case to high efficiency absorbent-type dephosphorization agent produced by the present invention and right
Dephosphorization agent in ratio is detected, and testing result is as shown in table 1：
In same water head site while 4 parts of 100mL water samples are taken, be separately added into prepared by the present invention of phase homogenous quantities into water sample removes
Phosphorus agent and comparative example dephosphorization agent, it is spare.Using volume for 250mL conical flask as reactor, then by above-mentioned spare water sample（pH
It is 7.6~7.8）It pours into above-mentioned conical flask, conical flask is put into oscillation absorption 30min in complete warm shaking table, temperature is set in shaking table
It it is 25 DEG C, rotating speed is set as 200r/min, finally takes conical flask supernatant liquor, uses ammonium molybdate spectrophotometric method（GB11893-89）It surveys
Determine COD contents, calculates COD removal rates；NH3-N contents are surveyed, NH3-N removal rates are calculated；Total phosphorus content is surveyed, the removal of total phosphorus is calculated
Rate.
1 performance measurement result of table
According to data in table 1 it is found that high efficiency absorbent-type dephosphorization agent produced by the present invention, has excellent Nitrogen/Phosphorus Removal,
It is not easy to form secondary pollution, hence it is evident that be better than comparative example, have broad prospects.
Claims (6)
1. a kind of preparation method of high efficiency absorbent-type dephosphorization agent, it is characterised in that specifically preparation process is：
（1）It weighs and crosses 80 mesh sieve after 65~70g sepiolites are ground, collect sieving sepiolite powder, then the sepiolite that will be sieved
Powder and deionized water mixing are impregnated, and after settling, filtering removal sediment obtains filtrate, and filtrate is placed in baking oven and is done
It is dry, obtain dried object；
（2）Continue dried object and mixed in hydrochloric acid being placed in beaker and stir, be dried after stirring, drying is placed in Muffle furnace
Roasting, cooling discharging obtain modified meerschaum powder；
（3）It weighs 3~5g seventy flavors pearl pills and stirring and dissolving in 180~200mL distilled water is poured into the mixing of 1~2g polyethylene glycol,
Lysate is obtained, then 0.8~1.0mL sodium carbonate liquors are added dropwise into lysate and are mixed, obtains aqueous deposit, control contains
Water deposit pH is 8.1~8.6, continues to stir, and finally modified meerschaum powder and aqueous deposit are mixed, centrifugation point
From, removal water phase, isolated loaded article；
（4）Scallop shell and molybdenum disulfide are mixed to be placed in grinder after grinding and cross 80 mesh sieve, collects sieving mixed-powder, incited somebody to action
It sieves mixed-powder and silane resin acceptor kh-550 is mixed, obtain mixture, continue that mixture quality is added into mixture
The Yoghourt of 8% glucose and mixture quality 0.5%, is fitted into fermentation tank, is sealed by fermentation, and after fermentation, takes out fermentation production
Object, as modified mixed-powder；
（5）Loaded article, modified mixed-powder and absolute ethyl alcohol are mixed, obtain stirred suspension, then by stirred suspension
It is placed in ultrasonic wave separating apparatus and is ultrasonically treated with lauryl sodium sulfate mixing, supersound process is placed in baking oven dry, cooling
Discharging is to get high efficiency absorbent-type dephosphorization agent.
2. a kind of preparation method of high efficiency absorbent-type dephosphorization agent according to claim 1, it is characterised in that：Step（1）
Described grinds the time as 10~12min, and the mass ratio of sieving sepiolite powder and deionized water is 1：3, soaking time
For 24~32min, drying temperature is 75~85 DEG C, and drying time is 30~32min.
3. a kind of preparation method of high efficiency absorbent-type dephosphorization agent according to claim 1, it is characterised in that：Step（2）
The solid-liquid mass ratio of the dried object and a concentration of 0.8mol/L hydrochloric acid is 1：20, whipping temp is 80~85 DEG C, when stirring
Between be 12~16h, drying time be 2~4h, calcination temperature be 400~420 DEG C, roasting time be 1~2h.
4. a kind of preparation method of high efficiency absorbent-type dephosphorization agent according to claim 1, it is characterised in that：Step（3）
The stirring and dissolving rotating speed be 200~240r/min, the stirring and dissolving time be 32~40min, sodium carbonate liquor it is a concentration of
1mol/L, mixing time are 20~24min, and whipping temp is 45~50 DEG C, and continuation mixing time is 1~2h, modified sea
The mass ratio of afrodite powder and aqueous deposit is 3：1, the mixing time is 45~60min.
5. a kind of preparation method of high efficiency absorbent-type dephosphorization agent according to claim 1, it is characterised in that：Step（4）
The mass ratio of the scallop shell and molybdenum disulfide is 1：4, milling time is 5~7min, and be sieved mixed-powder and silane coupled
The mass ratio of agent KH-550 is 5：1, the mixing time is 10~12min, and fermentation temperature is 37~42 DEG C, fermentation time 9
~11 days.
6. a kind of preparation method of high efficiency absorbent-type dephosphorization agent according to claim 1, it is characterised in that：Step（5）
The mass ratio of the loaded article, modified mixed-powder and absolute ethyl alcohol is 5：3：1, the mixing time is 16~20min, is stirred
The mass ratio for mixing suspension and lauryl sodium sulfate is 5：1, supersound process frequency is 24~30kHz, and sonification power is
160~200W, sonication treatment time are 1~2h, and drying temperature is 96~100 DEG C, and drying time is 35~45min.
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109569552A (en) * | 2018-12-13 | 2019-04-05 | 北京林业大学 | A kind of magnetic/non magnetic lanthanum carbonate sodium dephosphorization adsorbent and its synthetic method |
| CN111841497A (en) * | 2020-07-30 | 2020-10-30 | 盐城工学院 | A kind of modified loofah-based biomass carbon and its preparation method and application |
| CN113813916A (en) * | 2021-09-17 | 2021-12-21 | 交通运输部天津水运工程科学研究所 | Salt-tolerant deep phosphorus removal agent and preparation method thereof |
| CN117582938A (en) * | 2023-12-04 | 2024-02-23 | 西安益维普泰环保股份有限公司 | Wastewater organophosphorus remover and preparation method thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1688511A (en) * | 2002-08-14 | 2005-10-26 | 爱尔达纳米材料公司 | Rare earth metal compounds, methods of making, and methods of using the same |
| CN101691275A (en) * | 2009-08-31 | 2010-04-07 | 河北工业大学 | Method for preparing nano mineral fiber |
| CN204474346U (en) * | 2015-02-10 | 2015-07-15 | 济宁金水科技有限公司 | A kind of shell particles auxiliary dephosphorization device |
| CN107321299A (en) * | 2017-08-30 | 2017-11-07 | 河北工业大学 | The preparation method of molybdenum disulfide and scpiolitc nanofiber composite adsorbing material |
-
2018
- 2018-03-28 CN CN201810262519.5A patent/CN108393077A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1688511A (en) * | 2002-08-14 | 2005-10-26 | 爱尔达纳米材料公司 | Rare earth metal compounds, methods of making, and methods of using the same |
| CN101691275A (en) * | 2009-08-31 | 2010-04-07 | 河北工业大学 | Method for preparing nano mineral fiber |
| CN204474346U (en) * | 2015-02-10 | 2015-07-15 | 济宁金水科技有限公司 | A kind of shell particles auxiliary dephosphorization device |
| CN107321299A (en) * | 2017-08-30 | 2017-11-07 | 河北工业大学 | The preparation method of molybdenum disulfide and scpiolitc nanofiber composite adsorbing material |
Non-Patent Citations (1)
| Title |
|---|
| 解佳烨: "碳酸镧纳米晶的制备及其磷结合效果的评价研究", 《中国优秀硕士学位论文全文数据库 工程科技Ⅰ辑》 * |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109569552A (en) * | 2018-12-13 | 2019-04-05 | 北京林业大学 | A kind of magnetic/non magnetic lanthanum carbonate sodium dephosphorization adsorbent and its synthetic method |
| CN109569552B (en) * | 2018-12-13 | 2021-10-26 | 北京林业大学 | Magnetic/non-magnetic lanthanum sodium carbonate phosphorus removal adsorbent and synthesis method thereof |
| CN111841497A (en) * | 2020-07-30 | 2020-10-30 | 盐城工学院 | A kind of modified loofah-based biomass carbon and its preparation method and application |
| CN113813916A (en) * | 2021-09-17 | 2021-12-21 | 交通运输部天津水运工程科学研究所 | Salt-tolerant deep phosphorus removal agent and preparation method thereof |
| CN113813916B (en) * | 2021-09-17 | 2024-02-02 | 交通运输部天津水运工程科学研究所 | Salt-tolerant deep dephosphorizing agent and preparation method thereof |
| CN117582938A (en) * | 2023-12-04 | 2024-02-23 | 西安益维普泰环保股份有限公司 | Wastewater organophosphorus remover and preparation method thereof |
| CN117582938B (en) * | 2023-12-04 | 2024-12-31 | 西安益维普泰环保股份有限公司 | A wastewater organic phosphorus remover and preparation method thereof |
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