CN107653671A - A kind of environment protection type multifunctional scouring agent and preparation method - Google Patents
A kind of environment protection type multifunctional scouring agent and preparation method Download PDFInfo
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- CN107653671A CN107653671A CN201710654915.8A CN201710654915A CN107653671A CN 107653671 A CN107653671 A CN 107653671A CN 201710654915 A CN201710654915 A CN 201710654915A CN 107653671 A CN107653671 A CN 107653671A
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/53—Polyethers
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/07—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with halogens; with halogen acids or salts thereof; with oxides or oxyacids of halogens or salts thereof
- D06M11/11—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with halogens; with halogen acids or salts thereof; with oxides or oxyacids of halogens or salts thereof with halogen acids or salts thereof
- D06M11/13—Ammonium halides or halides of elements of Groups 1 or 11 of the Periodic Table
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/07—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with halogens; with halogen acids or salts thereof; with oxides or oxyacids of halogens or salts thereof
- D06M11/11—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with halogens; with halogen acids or salts thereof; with oxides or oxyacids of halogens or salts thereof with halogen acids or salts thereof
- D06M11/155—Halides of elements of Groups 2 or 12 of the Periodic Table
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- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/144—Alcohols; Metal alcoholates
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- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/165—Ethers
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- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/184—Carboxylic acids; Anhydrides, halides or salts thereof
- D06M13/207—Substituted carboxylic acids, e.g. by hydroxy or keto groups; Anhydrides, halides or salts thereof
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/46—Compounds containing quaternary nitrogen atoms
- D06M13/463—Compounds containing quaternary nitrogen atoms derived from monoamines
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Abstract
The present invention provides a kind of environment protection type multifunctional scouring agent and preparation method thereof.The environment protection type multifunctional scouring agent of the present invention is free of the banned substance such as APES class and adsorbable organic halogenes class, soluble in water, acidproof, alkaline-resisting, resistance to hard water, low bubble, is easy to use.The environment protection type multifunctional scouring agent of the present invention integrates infiltration, emulsification, chelating, scattered, stabilized hydrogen peroxide, becomes simplified as pre-treating technology, rationalizes, economization, and energy-conserving and environment-protective.The environment protection type multifunctional scouring agent of the present invention has major transformation meaning to traditional handicraft, the technique of cotton and its blend fabric is widely portable to, routine can be carried out and move back/boil/bleaching process, can also carry out short route cold batching process, it can reach good desizing rate, whiteness and capillary effect.In addition, the environment protection type multifunctional scouring agent of the present invention also has sequestering power, the metal ion in work bath can be chelated, prevents metal ion from being had an impact to pre-treatment, dyeing, is advantageous to improve product quality.
Description
Technical field
The present invention relates to a kind of environment protection type multifunctional scouring agent of technical field of textile printing and preparation method.
Background technology
Concise is very important process in pretreating technology for printing and dyeing, it is therefore intended that removes impurities in cotton fiber, such as
Oil stain stain on the slurry and fabric not eliminated in cotton seed hulls, cotton wax, pectin, protein, desizing process etc..Nearly 20 years
Come, with the popularization of the high Efficient Short Process Pretreatments such as alkali oxygen-bath, cold pad--batch, improve refining speed, save energy consumption, reduce
Water consumption, shortening technological process etc. turns into urgent problem, it is necessary to seek infiltration rapidly, emulsifying ability is strong, sequestering power is strong,
Detergency height, high temperature resistant, resistance to concentrated base, resistance to hard water, low bubble, the high-efficiency multi-function scouring agent that biological degradability is good, safe and non-toxic, portion
Division multi-functional scouring agent it is also desirable to have bleaching function.Reach above-mentioned performance and requirement, a variety of surfactants and other nothings
Machine and the multi-functional scouring agent of organic additive compounding arise at the historic moment.
With the development of science and technology and the progressively reinforcement of people's environmental consciousness, requirement of the World Textile market to Green Textiles
More and more high, ISO14000 and Oeko TEX standard 100 promulgation promotes dyeing to develop green scouring agent.
But many kinds contain APEO in scouring agent in the market, due to APEO carcinogenicity, teratogenesis and the mutagens opposite sex, state
APEO and the preparation or formula that are made from it are disabled in the market of border, then, on domestic and international market, the scouring agent of environment-friendly type is not
Section city.
Environment protection type multifunctional scouring agent represents following developing direction of scouring agent, meets people to environmental protection and efficiently
Concise needs.Find and environment protection type multifunctional scouring agent of the exploitation without banned substance and with excellent pre-treatment effect turns into
The important development direction of field of printing and dyeing.
The content of the invention
It is an object of the invention to provide a kind of environment protection type multifunctional scouring agent and preparation method, to solve above-mentioned background skill
The problem of being proposed in art.
To achieve the above object, the present invention provides following technical scheme：
A kind of environment protection type multifunctional scouring agent, according to parts by weight, is prepared from the following components：Isomerous tridecanol polyoxy
The 20-25 parts of vinethene 1309,13 carbon isomery alcohol ether TO-15 5-8 parts, C12-14 fatty alcohols (7EO) 10-20 parts, ethylene glycol list
Butyl ether 1-3 parts, sodium gluconate 0.5-3 parts, dodecyl benzyl dimethyl ammonium chloride 5-15 parts, sodium chloride 1-3 parts, magnesium chloride
3-5 parts, citric acid 2-4 parts, deionized water 40-60 parts.
Preferably, a kind of environment protection type multifunctional scouring agent, according to parts by weight, is prepared from the following components：Isomery ten
The 22-24 parts of triol APEO 1309,13 carbon isomery alcohol ether TO-15 6-8 parts, C12-14 fatty alcohols (7EO) 12-28 parts,
Ethylene glycol monobutyl ether 1.5-2.5 parts, sodium gluconate 1-3 parts, dodecyl benzyl dimethyl ammonium chloride 5-13 parts, sodium chloride
1.5-2.5 parts, magnesium chloride 3.5-5 parts, citric acid 2.5-4 parts, deionized water 42-58 parts.
Preferably, a kind of environment protection type multifunctional scouring agent, according to parts by weight, is prepared from the following components：Isomery ten
1,309 23 parts of triol APEO, 13 7 parts of carbon isomery alcohol ether TO-15,20 parts of C12-14 fatty alcohols (7EO), ethylene glycol list
2 parts of butyl ether, 2 parts of sodium gluconate, 9 parts of dodecyl benzyl dimethyl ammonium chloride, 2 parts of sodium chloride, 4 parts of magnesium chloride, citric acid 3
Part, 50 parts of deionized water.
Preferably, a kind of environment protection type multifunctional scouring agent, according to parts by weight, is prepared from the following components：Isomery ten
1,309 25 parts of triol APEO, 13 8 parts of carbon isomery alcohol ether TO-15,20 parts of C12-14 fatty alcohols (7EO), ethylene glycol list
3 parts of butyl ether, 3 parts of sodium gluconate, 15 parts of dodecyl benzyl dimethyl ammonium chloride, 3 parts of sodium chloride, 5 parts of magnesium chloride, citric acid
4 parts, 60 parts of deionized water.
Preferably, a kind of environment protection type multifunctional scouring agent, according to parts by weight, is prepared from the following components：Isomery ten
1,309 20 parts of triol APEO, 13 5 parts of carbon isomery alcohol ether TO-15,10 parts of C12-14 fatty alcohols (7EO), ethylene glycol list
1 part of butyl ether, 0.5 part of sodium gluconate, 5 parts of dodecyl benzyl dimethyl ammonium chloride, 1 part of sodium chloride, 3 parts of magnesium chloride, lemon
Sour 2 parts, 40 parts of deionized water.
Preferably, a kind of environment protection type multifunctional scouring agent, according to parts by weight, is prepared from the following components：Isomery ten
1,309 24 parts of triol APEO, 13 6 parts of carbon isomery alcohol ether TO-15,18 parts of C12-14 fatty alcohols (7EO), ethylene glycol list
1.5 parts of butyl ether, 2 parts of sodium gluconate, 8 parts of dodecyl benzyl dimethyl ammonium chloride, 1.5 parts of sodium chloride, 3.5 parts of magnesium chloride,
3.5 parts of citric acid, 45 parts of deionized water.
Preferably, the C12-14 fatty alcohols are C12-14 natural fatty alcohols, fatty alcohol (C12-C14 mixes alcohol), Malaysia palm fibre
It is one or two kinds of in palmitic acid kernel oil and fat fat alcohol C12-C14 alcohol.
Preferably, a kind of preparation method of environment protection type multifunctional scouring agent, is comprised the following steps that：
(1) deionized water 40-60 parts are added in the reactor of cleaning, are warming up to 70-80 DEG C, it is different to add 5-8 13 carbon of part
Structure alcohol ether isomery alcohol TO-15 and isomerous tridecanol polyoxyethylene ether 1309, under 200-800 revs/min of rotating speed, stir 15-30
Minute to substantially uniformity；
(2) 10-20 part C12-14 fatty alcohols (7EO) are added, under 500-600 revs/min of rotating speed, stirring 5-10 minutes are extremely
Substantially uniformity；
(3) 5-15 part dodecyl benzyl dimethyl ammonium chlorides are added, under 200-800 revs/min of rotating speed, stir 10-
20 minutes to being completely dissolved；
(4) 1-3 part sodium chloride is added, under 200-800 revs/min of rotating speed, mixing speed slowly raises, and stirs 10-20
Minute to being completely dissolved；
(5) add 0.5-3 parts sodium gluconate and 3-5 part magnesium chlorides, under 200-800 revs/min of rotating speed, stir 10-
20 minutes to being completely dissolved；
(6) 1-3 part ethylene glycol monobutyl ethers are added, under 200-800 revs/min of rotating speed, stirring 10-20 minutes are to completely molten
Solution
(7) with 2-4 part lemon acid for adjusting pH value to 3-4, under 500-800 revs/min of rotating speed, stir 10 minutes；
(8) blowing, finished product are filtered.
Compared with prior art, the beneficial effects of the invention are as follows：
1st, environment protection type multifunctional scouring agent of the present invention integrates infiltration, emulsification, chelating, scattered, stabilized hydrogen peroxide, before making
Handling process becomes simplified as, rationalized, economization and energy-conserving and environment-protective.
2nd, isomerous tridecanol polyoxyethylene ether, C12-14 fatty alcohols (7EO) used in environment protection type multifunctional scouring agent of the present invention
With the synergy of dodecyl benzyl dimethyl ammonium chloride, there is splendid concise impurity elimination effect, excellent desizing rate and good
Good capillary effect.
3rd, sodium gluconate used in environment protection type multifunctional scouring agent of the present invention can play the effect of chelating agent, effectively inhale
Heavy metal ion in attached chelating working solution or fiber, while magnesium chloride collaboration stably controls decomposing hydrogen dioxide solution, to reach excellent
Different capillary effect and whiteness
4th, the low bubble of environment protection type multifunctional scouring agent of the present invention, energy-conservation, environmental protection be not phosphorous without APEO.
Embodiment
The invention discloses a kind of environment protection type multifunctional scouring agent, according to parts by weight, it is prepared from the following components：It is different
The 20-25 parts of structure tridecanol polyoxyethylene ether 1309,13 carbon isomery alcohol ether TO-15 5-8 parts, C12-14 fatty alcohols (7EO) 10-20
Part, ethylene glycol monobutyl ether 1-3 parts, sodium gluconate 0.5-3 parts, dodecyl benzyl dimethyl ammonium chloride 5-15 parts, sodium chloride
1-3 parts, magnesium chloride 3-5 parts, citric acid 2-4 parts, deionized water 40-60 parts.
Preferably, a kind of environment protection type multifunctional scouring agent, according to parts by weight, is prepared from the following components：Isomery ten
The 22-24 parts of triol APEO 1309,13 carbon isomery alcohol ether TO-15 6-8 parts, C12-14 fatty alcohols (7EO) 12-28 parts,
Ethylene glycol monobutyl ether 1.5-2.5 parts, sodium gluconate 1-3 parts, dodecyl benzyl dimethyl ammonium chloride 5-13 parts, sodium chloride
1.5-2.5 parts, magnesium chloride 3.5-5 parts, citric acid 2.5-4 parts, deionized water 42-58 parts.
Preferably, a kind of environment protection type multifunctional scouring agent, according to parts by weight, is prepared from the following components：Isomery ten
1,309 23 parts of triol APEO, 13 7 parts of carbon isomery alcohol ether TO-15,20 parts of C12-14 fatty alcohols (7EO), ethylene glycol list
2 parts of butyl ether, 2 parts of sodium gluconate, 9 parts of dodecyl benzyl dimethyl ammonium chloride, 2 parts of sodium chloride, 4 parts of magnesium chloride, citric acid 3
Part, 50 parts of deionized water.
Preferably, a kind of environment protection type multifunctional scouring agent, according to parts by weight, is prepared from the following components：Isomery ten
1,309 25 parts of triol APEO, 13 8 parts of carbon isomery alcohol ether TO-15,20 parts of C12-14 fatty alcohols (7EO), ethylene glycol list
3 parts of butyl ether, 3 parts of sodium gluconate, 15 parts of dodecyl benzyl dimethyl ammonium chloride, 3 parts of sodium chloride, 5 parts of magnesium chloride, citric acid
4 parts, 60 parts of deionized water.
Preferably, a kind of environment protection type multifunctional scouring agent, according to parts by weight, is prepared from the following components：Isomery ten
1,309 20 parts of triol APEO, 13 5 parts of carbon isomery alcohol ether TO-15,10 parts of C12-14 fatty alcohols (7EO), ethylene glycol list
1 part of butyl ether, 0.5 part of sodium gluconate, 5 parts of dodecyl benzyl dimethyl ammonium chloride, 1 part of sodium chloride, 3 parts of magnesium chloride, lemon
Sour 2 parts, 40 parts of deionized water.
Preferably, a kind of environment protection type multifunctional scouring agent, according to parts by weight, is prepared from the following components：Isomery ten
1,309 24 parts of triol APEO, 13 6 parts of carbon isomery alcohol ether TO-15,18 parts of C12-14 fatty alcohols (7EO), ethylene glycol list
1.5 parts of butyl ether, 2 parts of sodium gluconate, 8 parts of dodecyl benzyl dimethyl ammonium chloride, 1.5 parts of sodium chloride, 3.5 parts of magnesium chloride,
3.5 parts of citric acid, 45 parts of deionized water.
Preferably, the C12-14 fatty alcohols are C12-14 natural fatty alcohols, fatty alcohol (C12-C14 mixes alcohol), Malaysia palm fibre
It is one or two kinds of in palmitic acid kernel oil and fat fat alcohol C12-C14 alcohol.
Preferably, a kind of preparation method of environment protection type multifunctional scouring agent, is comprised the following steps that：
(1) deionized water 40-60 parts are added in the reactor of cleaning, are warming up to 70-80 DEG C, it is different to add 5-8 13 carbon of part
Structure alcohol ether isomery alcohol TO-15 and isomerous tridecanol polyoxyethylene ether 1309, under 200-800 revs/min of rotating speed, stir 15-30
Minute to substantially uniformity；
(2) 10-20 part C12-14 fatty alcohols (7EO) are added, under 500-600 revs/min of rotating speed, stirring 5-10 minutes are extremely
Substantially uniformity；
(3) 5-15 part dodecyl benzyl dimethyl ammonium chlorides are added, under 200-800 revs/min of rotating speed, stir 10-
20 minutes to being completely dissolved；
(4) 1-3 part sodium chloride is added, under 200-800 revs/min of rotating speed, mixing speed slowly raises, and stirs 10-20
Minute to being completely dissolved；
(5) add 0.5-3 parts sodium gluconate and 3-5 part magnesium chlorides, under 200-800 revs/min of rotating speed, stir 10-
20 minutes to being completely dissolved；
(6) 1-3 part ethylene glycol monobutyl ethers are added, under 200-800 revs/min of rotating speed, stirring 10-20 minutes are to completely molten
Solution；
(7) with 2-4 part lemon acid for adjusting pH value to 3-4, under 500-800 revs/min of rotating speed, stir 10 minutes；
(8) blowing, finished product are filtered.
Compared with prior art, the beneficial effects of the invention are as follows：
1st, environment protection type multifunctional scouring agent of the present invention integrates infiltration, emulsification, chelating, scattered, stabilized hydrogen peroxide, before making
Handling process becomes simplified as, rationalized, economization and energy-conserving and environment-protective.
2nd, isomerous tridecanol polyoxyethylene ether, C12-14 fatty alcohols (7EO) used in environment protection type multifunctional scouring agent of the present invention
With the synergy of dodecyl benzyl dimethyl ammonium chloride, there is splendid concise impurity elimination effect, excellent desizing rate and good
Good capillary effect.
3rd, sodium gluconate used in environment protection type multifunctional scouring agent of the present invention can play the effect of chelating agent, effectively inhale
Heavy metal ion in attached chelating working solution or fiber, while magnesium chloride collaboration stably controls decomposing hydrogen dioxide solution, to reach excellent
Different capillary effect and whiteness
4th, the low bubble of environment protection type multifunctional scouring agent of the present invention, energy-conservation, environmental protection be not phosphorous without APEO.
Embodiment 1
The invention discloses a kind of environment protection type multifunctional scouring agent, according to parts by weight, it is prepared from the following components：It is different
1,309 23 parts of structure tridecanol polyoxyethylene ether, 13 7 parts of carbon isomery alcohol ether TO-15,20 parts of C12-14 fatty alcohols (7EO), second two
2 parts of alcohol monobutyl ether, 2 parts of sodium gluconate, 9 parts of dodecyl benzyl dimethyl ammonium chloride, 2 parts of sodium chloride, 4 parts of magnesium chloride, lemon
Lemon acid 3 parts, 50 parts of deionized water.
Present invention also offers a kind of above-mentioned preparation method of environment protection type multifunctional scouring agent, comprise the following steps that：
(1) 50 parts of deionized water is added in the reactor of cleaning, is warming up to 75 DEG C, it is different to add 7 part of 13 carbon isomery alcohol ether
Structure alcohol TO-15 and 23 parts of isomerous tridecanol polyoxyethylene ethers 1309, under 800 revs/min of rotating speed, stirring 25 minutes is to complete
Uniformly；
(2) 20 parts of C12-14 fatty alcohols (7EO) are added, under 550 revs/min of rotating speed, stirring 8 minutes to substantially uniformity；
(3) 9 parts of dodecyl benzyl dimethyl ammonium chlorides are added, under 600 revs/min of rotating speed, stirring 20 minutes is to complete
Fully dissolved；
(4) 2 parts of sodium chloride are added, under 400 revs/min of rotating speed, mixing speed slowly raises, and stirring 15 minutes is to complete
Dissolving；
(5) add 2 parts of sodium gluconates and 4 parts of magnesium chlorides, under 200-800 revs/min of rotating speed, stir 10-20 minutes
To being completely dissolved；
(6) 1-3 part ethylene glycol monobutyl ethers are added, under 320 revs/min of rotating speed, stirring 16 minutes is to being completely dissolved
(7) with 3 parts of lemon acid for adjusting pH value to 3-4, under 700 revs/min of rotating speed, stir 10 minutes；
(8) blowing, finished product are filtered.
Embodiment 2
The invention discloses a kind of environment protection type multifunctional scouring agent, according to parts by weight, it is prepared from the following components：It is different
1,309 25 parts of structure tridecanol polyoxyethylene ether, 13 8 parts of carbon isomery alcohol ether TO-15,20 parts of C12-14 fatty alcohols (7EO), second two
3 parts of alcohol monobutyl ether, 3 parts of sodium gluconate, 15 parts of dodecyl benzyl dimethyl ammonium chloride, 3 parts of sodium chloride, 5 parts of magnesium chloride, lemon
Lemon acid 4 parts, 60 parts of deionized water.
Present invention also offers a kind of above-mentioned preparation method of environment protection type multifunctional scouring agent, comprise the following steps that：
(1) 60 parts of deionized water is added in the reactor of cleaning, is warming up to 70-80 DEG C, adds 8 part of 13 carbon isomery alcohol ether
Under the rotating speed of isomery alcohol TO-15 and 25 parts of 1309,800 revs/min of isomerous tridecanol polyoxyethylene ethers, stirring 25 minutes is to complete
Uniformly；
(2) 20 parts of C12-14 fatty alcohols (7EO) are added, under 600 revs/min of rotating speed, stirring 10 minutes to substantially uniformity；
(3) 15 parts of dodecyl benzyl dimethyl ammonium chlorides are added, under 700 revs/min of rotating speed, stirring 15 minutes is to complete
Fully dissolved；
(4) 3 parts of sodium chloride are added, under 600 revs/min of rotating speed, mixing speed slowly raises, and stirring 20 minutes is to complete
Dissolving；
(5) 3 parts of sodium gluconates and 5 parts of magnesium chlorides are added, under 800 revs/min of rotating speed, stirring 20 minutes is to completely molten
Solution；
(6) 3 parts of ethylene glycol monobutyl ethers are added, under 800 revs/min of rotating speed, stirring 20 minutes is to being completely dissolved
(7) with 4 parts of lemon acid for adjusting pH value to 3-4, under 800 revs/min of rotating speed, stir 10 minutes；
(8) blowing, finished product are filtered.
Embodiment 3
The invention discloses a kind of environment protection type multifunctional scouring agent, according to parts by weight, it is prepared from the following components：It is different
1,309 20 parts of structure tridecanol polyoxyethylene ether, 13 5 parts of carbon isomery alcohol ether TO-15,10 parts of C12-14 fatty alcohols (7EO), second two
1 part of alcohol monobutyl ether, 0.5 part of sodium gluconate, 5 parts of dodecyl benzyl dimethyl ammonium chloride, 1 part of sodium chloride, 3 parts of magnesium chloride,
2 parts of citric acid, 40 parts of deionized water.
Present invention also offers a kind of above-mentioned preparation method of environment protection type multifunctional scouring agent, specific preparation method is：
(1) 40 parts of deionized water is added in the reactor of cleaning, is warming up to 70 DEG C, it is different to add 5 part of 13 carbon isomery alcohol ether
Under the rotating speed of structure alcohol TO-15 and 20 parts of 1309,200 revs/min of isomerous tridecanol polyoxyethylene ethers, 15 minutes are stirred to completely
It is even；
(2) 10 parts of C12-14 fatty alcohols (7EO) are added, under 500 revs/min of rotating speed, stirring 10 minutes to substantially uniformity；
(3) 5 parts of dodecyl benzyl dimethyl ammonium chlorides are added, under 200 revs/min of rotating speed, stirring 20 minutes is to complete
Fully dissolved；
(4) 1 part of sodium chloride is added, under 200 revs/min of rotating speed, mixing speed slowly raises, and stirring 20 minutes is to complete
Dissolving；
(5) 0.5 part of sodium gluconate and 3 parts of magnesium chlorides are added, under 600 revs/min of rotating speed, stirring 10 minutes is to complete
Dissolving；
(6) 1 part of ethylene glycol monobutyl ether is added, under 600 revs/min of rotating speed, stirring 10 minutes is to being completely dissolved
(7) with 2 parts of lemon acid for adjusting pH value to 3-4, under 500 revs/min of rotating speed, stir 10 minutes；
(8) blowing, finished product are filtered.
Embodiment 4
The invention discloses a kind of environment protection type multifunctional scouring agent, according to parts by weight, it is prepared from the following components：It is different
1,309 24 parts of structure tridecanol polyoxyethylene ether, 13 6 parts of carbon isomery alcohol ether TO-15,18 parts of C12-14 fatty alcohols (7EO), second two
1.5 parts of alcohol monobutyl ether, 2 parts of sodium gluconate, 8 parts of dodecyl benzyl dimethyl ammonium chloride, 1.5 parts of sodium chloride, magnesium chloride 3.5
Part, 3.5 parts of citric acid, 45 parts of deionized water.
Present invention also offers a kind of above-mentioned preparation method of environment protection type multifunctional scouring agent, comprise the following steps that：
(1) 45 parts of deionized water is added in the reactor of cleaning, is warming up to 76 DEG C, it is different to add 6 part of 13 carbon isomery alcohol ether
Under the rotating speed of structure alcohol TO-15 and 24 parts of 1309,600 revs/min of isomerous tridecanol polyoxyethylene ethers, 30 minutes are stirred to completely
It is even；
(2) 18 parts of C12-14 fatty alcohols (7EO) are added, under 540 revs/min of rotating speed, stirring 10 minutes to substantially uniformity；
(3) 8 parts of dodecyl benzyl dimethyl ammonium chlorides are added, under 500 revs/min of rotating speed, stirring 20 minutes is to complete
Fully dissolved；
(4) 1.5 parts of sodium chloride are added, under 600 revs/min of rotating speed, mixing speed slowly raises, and stirring 18 minutes is to complete
Fully dissolved；
(5) 2 parts of sodium gluconates and 3.5 parts of magnesium chlorides are added, under 600 revs/min of rotating speed, stirring 13 minutes is to complete
Dissolving；
(6) 1.5 parts of ethylene glycol monobutyl ethers are added, under 400 revs/min of rotating speed, stirring 15 minutes is to being completely dissolved
(7) with 3.5 parts of lemon acid for adjusting pH value to 3-4, under 650 revs/min of rotating speed, stir 10 minutes；
(8) blowing, finished product are filtered.
Although an embodiment of the present invention has been shown and described, for the ordinary skill in the art, can be with
A variety of changes, modification can be carried out to these embodiments, replace without departing from the principles and spirit of the present invention by understanding
And modification, the scope of the present invention is defined by the appended.
Claims (8)
- A kind of 1. environment protection type multifunctional scouring agent, it is characterised in that:According to parts by weight, it is prepared from the following components：Isomery The 20-25 parts of tridecanol polyoxyethylene ether 1309,13 carbon isomery alcohol ether TO-15 5-8 parts, C12-14 fatty alcohols (7EO) 10-20 Part, ethylene glycol monobutyl ether 1-3 parts, sodium gluconate 0.5-3 parts, dodecyl benzyl dimethyl ammonium chloride 5-15 parts, sodium chloride 1-3 parts, magnesium chloride 3-5 parts, citric acid 2-4 parts, deionized water 40-60 parts.
- A kind of 2. environment protection type multifunctional scouring agent according to claim 1, it is characterised in that：According to parts by weight, by with Lower component is prepared：The 22-24 parts of isomerous tridecanol polyoxyethylene ether 1309,13 carbon isomery alcohol ether TO-15 6-8 parts, C12- 14 fatty alcohols (7EO) 12-28 parts, ethylene glycol monobutyl ether 1.5-2.5 parts, sodium gluconate 1-3 parts, dodecyl dimethyl benzyl Ammonium chloride 5-13 parts, sodium chloride 1.5-2.5 parts, magnesium chloride 3.5-5 parts, citric acid 2.5-4 parts, deionized water 42-58 parts.
- A kind of 3. environment protection type multifunctional scouring agent according to claim 1, it is characterised in that：According to parts by weight, by with Lower component is prepared：1,309 23 parts of isomerous tridecanol polyoxyethylene ether, 13 7 parts of carbon isomery alcohol ether TO-15, C12-14 fat 20 parts of alcohol (7EO), 2 parts of ethylene glycol monobutyl ether, 2 parts of sodium gluconate, 9 parts of dodecyl benzyl dimethyl ammonium chloride, sodium chloride 2 Part, 4 parts of magnesium chloride, 3 parts of citric acid, 50 parts of deionized water.
- A kind of 4. environment protection type multifunctional scouring agent according to claim 1, it is characterised in that：According to parts by weight, by with Lower component is prepared：1,309 25 parts of isomerous tridecanol polyoxyethylene ether, 13 8 parts of carbon isomery alcohol ether TO-15, C12-14 fat 20 parts of alcohol (7EO), 3 parts of ethylene glycol monobutyl ether, 3 parts of sodium gluconate, 15 parts of dodecyl benzyl dimethyl ammonium chloride, sodium chloride 3 parts, 5 parts of magnesium chloride, 4 parts of citric acid, 60 parts of deionized water.
- A kind of 5. environment protection type multifunctional scouring agent according to claim 1, it is characterised in that：According to parts by weight, by with Lower component is prepared：1,309 20 parts of isomerous tridecanol polyoxyethylene ether, 13 5 parts of carbon isomery alcohol ether TO-15, C12-14 fat 10 parts of alcohol (7EO), 1 part of ethylene glycol monobutyl ether, 0.5 part of sodium gluconate, 5 parts of dodecyl benzyl dimethyl ammonium chloride, chlorination 1 part of sodium, 3 parts of magnesium chloride, 2 parts of citric acid, 40 parts of deionized water.
- A kind of 6. environment protection type multifunctional scouring agent according to claim 1, it is characterised in that：According to parts by weight, by with Lower component is prepared：1,309 24 parts of isomerous tridecanol polyoxyethylene ether, 13 6 parts of carbon isomery alcohol ether TO-15, C12-14 fat 18 parts of alcohol (7EO), 1.5 parts of ethylene glycol monobutyl ether, 2 parts of sodium gluconate, 8 parts of dodecyl benzyl dimethyl ammonium chloride, chlorination 1.5 parts of sodium, 3.5 parts of magnesium chloride, 3.5 parts of citric acid, 45 parts of deionized water.
- 7. environment protection type multifunctional scouring agent according to claim 1, it is characterised in that：The C12-14 fatty alcohols are C12- It is one or two kinds of in 14 natural fatty alcohols, fatty alcohol (C12-C14 mixes alcohol), Malaysia palm kernel oil fatty alcohol C12-C14 alcohol.
- 8. the preparation method of any described a kind of environment protection type multifunctional scouring agent in a kind of 1-7 using the claims, its It is characterised by：Comprise the following steps that：(1) deionized water 40-60 parts are added in the reactor of cleaning, are warming up to 70-80 DEG C, add the carbon isomery alcohol of 5-8 parts 13 Ether isomery alcohol TO-15 and isomerous tridecanol polyoxyethylene ether 1309, under 200-800 revs/min of rotating speed, stir 15-30 minutes To substantially uniformity；(2) 10-20 part C12-14 fatty alcohols (7EO) are added, under 500-600 revs/min of rotating speed, stirring 5-10 minutes are to complete Uniformly；(3) 5-15 part dodecyl benzyl dimethyl ammonium chlorides are added, under 200-800 revs/min of rotating speed, 10-20 points of stirring Clock is to being completely dissolved；(4) 1-3 part sodium chloride is added, under 200-800 revs/min of rotating speed, mixing speed slowly raises, and stirs 10-20 minutes To being completely dissolved；(5) 0.5-3 parts sodium gluconate and 3-5 part magnesium chlorides are added, under 200-800 revs/min of rotating speed, 10-20 points of stirring Clock is to being completely dissolved；(6) 1-3 part ethylene glycol monobutyl ethers are added, under 200-800 revs/min of rotating speed, stirring 10-20 minutes are to being completely dissolved；(7) with 2-4 part lemon acid for adjusting pH value to 3-4, under 500-800 revs/min of rotating speed, stir 10 minutes；(8) blowing, finished product are filtered.
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| CN109056319A (en) * | 2018-07-18 | 2018-12-21 | 珠海华大浩宏化工有限公司 | A kind of environmental protection knitting open-width scouring agent and preparation method thereof |
| CN114369954A (en) * | 2021-12-30 | 2022-04-19 | 桐乡市恒隆化工有限公司 | Preparation method of antifreezing emulsifier for spinning sizing |
| CN115262247A (en) * | 2022-08-24 | 2022-11-01 | 张家港市德宝化工有限公司 | Polyester cotton tooling fabric and one-step dyeing process thereof |
| CN115928427A (en) * | 2022-12-26 | 2023-04-07 | 绍兴海成化工有限公司 | Scouring agent and preparation method and application thereof |
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