CN107624762A - Bromine cyanogen insect amide opens up film oil-suspending agent - Google Patents
Bromine cyanogen insect amide opens up film oil-suspending agent Download PDFInfo
- Publication number
- CN107624762A CN107624762A CN201710944897.7A CN201710944897A CN107624762A CN 107624762 A CN107624762 A CN 107624762A CN 201710944897 A CN201710944897 A CN 201710944897A CN 107624762 A CN107624762 A CN 107624762A
- Authority
- CN
- China
- Prior art keywords
- oil
- insect amide
- cyanogen insect
- bromine cyanogen
- suspending agent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 241000238631 Hexapoda Species 0.000 title claims abstract description 109
- 150000001408 amides Chemical class 0.000 title claims abstract description 101
- YBOFEONRFJMHND-UHFFFAOYSA-N [Br].N#CC#N Chemical compound [Br].N#CC#N YBOFEONRFJMHND-UHFFFAOYSA-N 0.000 title claims abstract description 86
- 239000000375 suspending agent Substances 0.000 title claims abstract description 86
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 40
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Chemical compound BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 claims abstract description 32
- JMANVNJQNLATNU-UHFFFAOYSA-N oxalonitrile Chemical compound N#CC#N JMANVNJQNLATNU-UHFFFAOYSA-N 0.000 claims abstract description 32
- -1 Lauryl Alcohol ester Chemical class 0.000 claims abstract description 21
- 125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims abstract description 17
- 229910052794 bromium Inorganic materials 0.000 claims abstract description 16
- OHBRHBQMHLEELN-UHFFFAOYSA-N acetic acid;1-butoxybutane Chemical compound CC(O)=O.CCCCOCCCC OHBRHBQMHLEELN-UHFFFAOYSA-N 0.000 claims abstract description 12
- 239000012752 auxiliary agent Substances 0.000 claims abstract description 11
- ULWHHBHJGPPBCO-UHFFFAOYSA-N propane-1,1-diol Chemical class CCC(O)O ULWHHBHJGPPBCO-UHFFFAOYSA-N 0.000 claims abstract description 11
- DOIRQSBPFJWKBE-UHFFFAOYSA-N dibutyl phthalate Chemical compound CCCCOC(=O)C1=CC=CC=C1C(=O)OCCCC DOIRQSBPFJWKBE-UHFFFAOYSA-N 0.000 claims abstract description 8
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 24
- 239000003063 flame retardant Substances 0.000 claims description 21
- 238000000034 method Methods 0.000 claims description 20
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 claims description 16
- 150000004945 aromatic hydrocarbons Chemical group 0.000 claims description 9
- QPUYECUOLPXSFR-UHFFFAOYSA-N 1-methylnaphthalene Chemical compound C1=CC=C2C(C)=CC=CC2=C1 QPUYECUOLPXSFR-UHFFFAOYSA-N 0.000 claims description 8
- 235000015112 vegetable and seed oil Nutrition 0.000 claims description 7
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims description 6
- 230000000740 bleeding effect Effects 0.000 claims description 6
- 239000011574 phosphorus Substances 0.000 claims description 6
- 229910052698 phosphorus Inorganic materials 0.000 claims description 6
- 239000010773 plant oil Substances 0.000 claims description 6
- 239000008158 vegetable oil Substances 0.000 claims description 6
- OOCMUZJPDXYRFD-UHFFFAOYSA-L calcium;2-dodecylbenzenesulfonate Chemical compound [Ca+2].CCCCCCCCCCCCC1=CC=CC=C1S([O-])(=O)=O.CCCCCCCCCCCCC1=CC=CC=C1S([O-])(=O)=O OOCMUZJPDXYRFD-UHFFFAOYSA-L 0.000 claims description 5
- 239000004359 castor oil Substances 0.000 claims description 5
- 235000019438 castor oil Nutrition 0.000 claims description 5
- QYDYPVFESGNLHU-UHFFFAOYSA-N elaidic acid methyl ester Natural products CCCCCCCCC=CCCCCCCCC(=O)OC QYDYPVFESGNLHU-UHFFFAOYSA-N 0.000 claims description 5
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 claims description 5
- QYDYPVFESGNLHU-KHPPLWFESA-N methyl oleate Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OC QYDYPVFESGNLHU-KHPPLWFESA-N 0.000 claims description 5
- 229940073769 methyl oleate Drugs 0.000 claims description 5
- 239000004094 surface-active agent Substances 0.000 claims description 5
- 238000009835 boiling Methods 0.000 claims description 4
- 235000012424 soybean oil Nutrition 0.000 claims description 4
- 239000003549 soybean oil Substances 0.000 claims description 4
- DMAXMXPDVWTIRV-UHFFFAOYSA-N 2-(2-phenylethyl)phenol Chemical compound OC1=CC=CC=C1CCC1=CC=CC=C1 DMAXMXPDVWTIRV-UHFFFAOYSA-N 0.000 claims description 3
- LVGKNOAMLMIIKO-UHFFFAOYSA-N Elaidinsaeure-aethylester Natural products CCCCCCCCC=CCCCCCCCC(=O)OCC LVGKNOAMLMIIKO-UHFFFAOYSA-N 0.000 claims description 3
- 239000001293 FEMA 3089 Substances 0.000 claims description 3
- 125000002877 alkyl aryl group Chemical group 0.000 claims description 3
- 229910052799 carbon Inorganic materials 0.000 claims description 3
- 235000012343 cottonseed oil Nutrition 0.000 claims description 3
- 239000002385 cottonseed oil Substances 0.000 claims description 3
- LVGKNOAMLMIIKO-QXMHVHEDSA-N ethyl oleate Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OCC LVGKNOAMLMIIKO-QXMHVHEDSA-N 0.000 claims description 3
- 229940093471 ethyl oleate Drugs 0.000 claims description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N nitrogen Substances N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 3
- 229940051841 polyoxyethylene ether Drugs 0.000 claims description 3
- 229920000056 polyoxyethylene ether Polymers 0.000 claims description 3
- 229920002503 polyoxyethylene-polyoxypropylene Polymers 0.000 claims description 3
- GYICYQJEVCIYJY-UHFFFAOYSA-N thiophen-1-ylidenemethanone Chemical compound O=C=S1C=CC=C1 GYICYQJEVCIYJY-UHFFFAOYSA-N 0.000 claims description 3
- 241001272567 Hominoidea Species 0.000 claims description 2
- 229910052736 halogen Inorganic materials 0.000 claims description 2
- 150000002367 halogens Chemical group 0.000 claims description 2
- 229910052757 nitrogen Inorganic materials 0.000 claims description 2
- XZZNDPSIHUTMOC-UHFFFAOYSA-N triphenyl phosphate Chemical compound C=1C=CC=CC=1OP(OC=1C=CC=CC=1)(=O)OC1=CC=CC=C1 XZZNDPSIHUTMOC-UHFFFAOYSA-N 0.000 claims description 2
- 235000013311 vegetables Nutrition 0.000 claims 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 22
- 239000003814 drug Substances 0.000 abstract description 21
- 239000000203 mixture Substances 0.000 abstract description 14
- 238000009472 formulation Methods 0.000 abstract description 13
- 239000007788 liquid Substances 0.000 abstract description 3
- 239000012466 permeate Substances 0.000 abstract description 2
- 238000012360 testing method Methods 0.000 description 42
- 239000003595 mist Substances 0.000 description 26
- 239000002609 medium Substances 0.000 description 24
- 235000019198 oils Nutrition 0.000 description 20
- 230000000694 effects Effects 0.000 description 17
- 239000003921 oil Substances 0.000 description 17
- 238000002360 preparation method Methods 0.000 description 16
- 230000002265 prevention Effects 0.000 description 16
- 230000003449 preventive effect Effects 0.000 description 16
- 230000000857 drug effect Effects 0.000 description 15
- 239000000575 pesticide Substances 0.000 description 12
- 239000007921 spray Substances 0.000 description 12
- 241000985245 Spodoptera litura Species 0.000 description 10
- 230000000295 complement effect Effects 0.000 description 10
- 238000010790 dilution Methods 0.000 description 9
- 239000012895 dilution Substances 0.000 description 9
- 241000196324 Embryophyta Species 0.000 description 8
- 239000002872 contrast media Substances 0.000 description 8
- 241000607479 Yersinia pestis Species 0.000 description 7
- 230000008569 process Effects 0.000 description 7
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 6
- 241000346285 Ostrinia furnacalis Species 0.000 description 6
- 244000061458 Solanum melongena Species 0.000 description 6
- 235000002597 Solanum melongena Nutrition 0.000 description 6
- 238000004364 calculation method Methods 0.000 description 6
- 238000005516 engineering process Methods 0.000 description 6
- 238000011835 investigation Methods 0.000 description 6
- 230000002045 lasting effect Effects 0.000 description 6
- 239000000463 material Substances 0.000 description 6
- 238000011177 media preparation Methods 0.000 description 6
- 239000000047 product Substances 0.000 description 6
- 239000000779 smoke Substances 0.000 description 6
- 238000010998 test method Methods 0.000 description 6
- 241000526125 Diaphorina citri Species 0.000 description 5
- 241000208125 Nicotiana Species 0.000 description 5
- 235000002637 Nicotiana tabacum Nutrition 0.000 description 5
- 239000004480 active ingredient Substances 0.000 description 5
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N dimethylmethane Natural products CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 5
- 239000001294 propane Substances 0.000 description 5
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 4
- 241001414989 Thysanoptera Species 0.000 description 4
- 201000010099 disease Diseases 0.000 description 4
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 4
- 239000002270 dispersing agent Substances 0.000 description 4
- 239000002612 dispersion medium Substances 0.000 description 4
- REOJLIXKJWXUGB-UHFFFAOYSA-N mofebutazone Chemical group O=C1C(CCCC)C(=O)NN1C1=CC=CC=C1 REOJLIXKJWXUGB-UHFFFAOYSA-N 0.000 description 4
- 238000003860 storage Methods 0.000 description 4
- AXTGDCSMTYGJND-UHFFFAOYSA-N 1-dodecylazepan-2-one Chemical group CCCCCCCCCCCCN1CCCCCC1=O AXTGDCSMTYGJND-UHFFFAOYSA-N 0.000 description 3
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- IAZDPXIOMUYVGZ-UHFFFAOYSA-N Dimethylsulphoxide Chemical compound CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 description 3
- 241000510199 Helicoverpa assulta Species 0.000 description 3
- QYKIQEUNHZKYBP-UHFFFAOYSA-N Vinyl ether Chemical compound C=COC=C QYKIQEUNHZKYBP-UHFFFAOYSA-N 0.000 description 3
- NBLKSVZGIFWHQH-UHFFFAOYSA-N [O].C(CCCCCCCC)C1=C(C=CC=C1)O Chemical compound [O].C(CCCCCCCC)C1=C(C=CC=C1)O NBLKSVZGIFWHQH-UHFFFAOYSA-N 0.000 description 3
- 230000007547 defect Effects 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 239000008041 oiling agent Substances 0.000 description 3
- 230000035699 permeability Effects 0.000 description 3
- 239000004576 sand Substances 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- 239000002904 solvent Substances 0.000 description 3
- DURPTKYDGMDSBL-UHFFFAOYSA-N 1-butoxybutane Chemical compound CCCCOCCCC DURPTKYDGMDSBL-UHFFFAOYSA-N 0.000 description 2
- KXDAEFPNCMNJSK-UHFFFAOYSA-N Benzamide Chemical compound NC(=O)C1=CC=CC=C1 KXDAEFPNCMNJSK-UHFFFAOYSA-N 0.000 description 2
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- 235000019484 Rapeseed oil Nutrition 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 238000001514 detection method Methods 0.000 description 2
- 238000009792 diffusion process Methods 0.000 description 2
- 239000000839 emulsion Substances 0.000 description 2
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 2
- 239000002917 insecticide Substances 0.000 description 2
- 238000009533 lab test Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 230000000361 pesticidal effect Effects 0.000 description 2
- 239000002798 polar solvent Substances 0.000 description 2
- 230000000391 smoking effect Effects 0.000 description 2
- 238000005507 spraying Methods 0.000 description 2
- 230000007480 spreading Effects 0.000 description 2
- 238000003892 spreading Methods 0.000 description 2
- 239000004551 spreading oil Substances 0.000 description 2
- 239000000725 suspension Substances 0.000 description 2
- OCJBOOLMMGQPQU-UHFFFAOYSA-N 1,4-dichlorobenzene Chemical group ClC1=CC=C(Cl)C=C1 OCJBOOLMMGQPQU-UHFFFAOYSA-N 0.000 description 1
- PWRBCZZQRRPXAB-UHFFFAOYSA-N 3-chloropyridine Chemical compound ClC1=CC=CN=C1 PWRBCZZQRRPXAB-UHFFFAOYSA-N 0.000 description 1
- 241001124076 Aphididae Species 0.000 description 1
- 241001367049 Autographa Species 0.000 description 1
- ONFABMBOOPWBRD-UHFFFAOYSA-N C(CCCCCCCC)C1=C(C=CC=C1)O.C=C.[O] Chemical compound C(CCCCCCCC)C1=C(C=CC=C1)O.C=C.[O] ONFABMBOOPWBRD-UHFFFAOYSA-N 0.000 description 1
- 244000025254 Cannabis sativa Species 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- 241000254173 Coleoptera Species 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- 241000254171 Curculionidae Species 0.000 description 1
- 239000005889 Cyantraniliprole Substances 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 241000594036 Liriomyza Species 0.000 description 1
- 240000007594 Oryza sativa Species 0.000 description 1
- 235000007164 Oryza sativa Nutrition 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 235000004443 Ricinus communis Nutrition 0.000 description 1
- YSMRWXYRXBRSND-UHFFFAOYSA-N TOTP Chemical compound CC1=CC=CC=C1OP(=O)(OC=1C(=CC=CC=1)C)OC1=CC=CC=C1C YSMRWXYRXBRSND-UHFFFAOYSA-N 0.000 description 1
- 241000482268 Zea mays subsp. mays Species 0.000 description 1
- 125000002252 acyl group Chemical group 0.000 description 1
- 238000012271 agricultural production Methods 0.000 description 1
- 239000003905 agrochemical Substances 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 125000003236 benzoyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C(*)=O 0.000 description 1
- 150000001734 carboxylic acid salts Chemical class 0.000 description 1
- 238000012512 characterization method Methods 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 235000019504 cigarettes Nutrition 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- DVBUIBGJRQBEDP-UHFFFAOYSA-N cyantraniliprole Chemical compound CNC(=O)C1=CC(C#N)=CC(C)=C1NC(=O)C1=CC(Br)=NN1C1=NC=CC=C1Cl DVBUIBGJRQBEDP-UHFFFAOYSA-N 0.000 description 1
- 239000008367 deionised water Substances 0.000 description 1
- 229910021641 deionized water Inorganic materials 0.000 description 1
- 229940117389 dichlorobenzene Drugs 0.000 description 1
- LQZZUXJYWNFBMV-UHFFFAOYSA-N dodecan-1-ol Chemical compound CCCCCCCCCCCCO LQZZUXJYWNFBMV-UHFFFAOYSA-N 0.000 description 1
- 239000002552 dosage form Substances 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 230000032050 esterification Effects 0.000 description 1
- 238000005886 esterification reaction Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 239000002360 explosive Substances 0.000 description 1
- 235000019197 fats Nutrition 0.000 description 1
- 238000003682 fluorination reaction Methods 0.000 description 1
- 239000004519 grease Substances 0.000 description 1
- 238000005286 illumination Methods 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 231100001231 less toxic Toxicity 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 239000005022 packaging material Substances 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 238000006303 photolysis reaction Methods 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 230000000452 restraining effect Effects 0.000 description 1
- 235000009566 rice Nutrition 0.000 description 1
- 230000001932 seasonal effect Effects 0.000 description 1
- DCKVNWZUADLDEH-UHFFFAOYSA-N sec-butyl acetate Chemical compound CCC(C)OC(C)=O DCKVNWZUADLDEH-UHFFFAOYSA-N 0.000 description 1
- 239000008159 sesame oil Substances 0.000 description 1
- 235000011803 sesame oil Nutrition 0.000 description 1
- CMXPERZAMAQXSF-UHFFFAOYSA-M sodium;1,4-bis(2-ethylhexoxy)-1,4-dioxobutane-2-sulfonate;1,8-dihydroxyanthracene-9,10-dione Chemical compound [Na+].O=C1C2=CC=CC(O)=C2C(=O)C2=C1C=CC=C2O.CCCCC(CC)COC(=O)CC(S([O-])(=O)=O)C(=O)OCC(CC)CCCC CMXPERZAMAQXSF-UHFFFAOYSA-M 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
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- 238000012546 transfer Methods 0.000 description 1
- 230000005945 translocation Effects 0.000 description 1
- PTVDYMGQGCNETM-UHFFFAOYSA-N trityl 2-methylprop-2-enoate Chemical compound C=1C=CC=CC=1C(C=1C=CC=CC=1)(OC(=O)C(=C)C)C1=CC=CC=C1 PTVDYMGQGCNETM-UHFFFAOYSA-N 0.000 description 1
- 235000019871 vegetable fat Nutrition 0.000 description 1
- 238000009423 ventilation Methods 0.000 description 1
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- 238000009736 wetting Methods 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
- 229920001285 xanthan gum Polymers 0.000 description 1
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention provides a kind of bromine cyanogen insect amide to open up film oil-suspending agent, including bromine cyanogen insect amide 1%~40% by weight, and film forming agent is 1%~30%, and auxiliary agent 2%~25%, oiliness decentralized medium complements to 100%.Wherein, the film forming agent includes the one or more in Lauryl Alcohol ester, octadecyl alcolol, propane diols phenylate, dibutyl phthalate and monobutyl ether acetate.Bromine cyanogen insect amide exhibition film oil-suspending agent of the invention, is built upon on the basis of oil-suspending agent formulation, after crop or evil thing contact, is adhered to crop or evil thing surface, due to there is the presence of film forming agent, permeates rapidly and internally rapidly, play a part of preventing and treating；Simple to operate, labor intensity is small, and cost is low, can increase substantially efficiency, reduces agricultural cost.Good with traditional film forming agent film-formation result, medicament, also can preferable spread in micro- water or water shortage environment so that exhibition film oil-suspending agent shows have more preferable bioactivity to contrast formulation oil-suspending agent in the spread excellent performance of paddy field liquid level.
Description
Technical field
The invention belongs to pesticide field, and in particular to a kind of bromine cyanogen insect amide opens up film oil-suspending agent.
Background technology
At present, industrial crops insect is prevented and treated in agricultural planting and generally uses conventional spray-on process.Conventional spray-on process is by agricultural chemicals
Preparation is diluted with water certain concentration, and Target crops or evil thing are sprayed with conventional nebulizers (including manual and power spraye)
Mist prevents and treats the method for pest and disease damage.Some defects be present in this application method：
(1) conventional spray-on process pharmacy effect is poor.Because conventional spray-on process using the formulation of medicament is usually missible oil, water
Agent, wettable powder, suspending agent, aqueous emulsion etc., certain defect on be present, causing preventive effect poor.On the one hand, due to adding
Enter a large amount of water dilutions, the concentration of decoction is very low, and surface tension is often larger, viscous on having the crop or target surface of wax coat
Attached property, wetability, permeability are poor, it is difficult into crop and target body；On the other hand, illumination, high temperature, drying nature
In environment, the water in decoction is easy to evaporate, and causes medicament to remain in crop surface, easy photodissociation, and decoction dry after by
Easily come off and fail from crop in poor adhesion；3rd, the mist droplet particle size routinely sprayed is larger, up to 200~600 μm, leads
The decoction for causing to be sprayed onto on crop or target surface is easily because poor adhesion is lost in；4th, conventional spraying droplet, which is difficult to reach, to be made
Inside thing leaf back and crown canopy, medicament is caused can not effectively to contact harmful thing and work.
(2) conventional spray-on process labor intensity is high, and work efficiency is low.Labor intensity is big, and generally work efficiency is only 2~5 mus/day per capita,
It is difficult to the needs for meeting large-scale planting.
(3) conventional spray-on process preventing and treating pest and disease damage needs a large amount of water dilution medicaments, and usual water consumption is up to 450~900L/hm2,
In drought and water-scarce area, the difficult restraining factors for turning into the prevention and control of plant diseases, pest control of water intaking.
(4) agricultural production is seasonal obvious, and pest and disease damage is often in short time outburst, it is necessary to which a large amount of manpowers are prevented and treated, often
Rule spray-on process requirement has substantial amounts of labour to complete dispenser.
Bromine cyanogen insect amide, English name：cyantraniliprole；Molecular formula：C19H14BrClN6O2；Chemical name：3-
Bromo- N- [4- chloro-2-methyls -6- [(methyl-carbamoyl) benzene] -1- (3- chloropyridine -2- bases) -1H- pyrazoles -5- formamides；Knot
Structure formula：
Bromine cyanogen insect amide, it is second benzamide insecticides, while be also first to prevent and treat biting mouthparts
Insect and can preventing and treating pierce-suck type, file suction and more spectral pattern insecticides of lapping mouthparts insect.Its insect prevention spectrum for aleyrodid, aphid,
The preventing and treating of the primary pests such as thrips, wood louse, Liriomyza, beetle, weevil and lepidopterous larvae and reach outstanding to cauline leaf and fruit
Protection.
The formulations of pesticide develop novel dosage forms film-spreading oil solution at this stage, are to be furnished with to have water surface diffusant in common finish
Special auxiliary agent film forming agent, impose on the water surface formed film finish, applied in a manner of spilling drop, easily.With reference to the medicine of active compound
Manage characteristic and molecular characterization, water surface diffusion agent molecule and active ingredient non-covalent intermolecular key are formed house and formed a kind of new
Pesticidal preparations.Using that need not add water during the medicine or mix soil, without any plant protection apparatus, decoction is directly dripped in paddy field can be fast
Speed uniformly spreads full field, forms medicine film layer, and reaches pest control purpose along the rice basal part of stem liter 20cm that climb.With height
The features such as effect, long-acting, less toxic, safe, easy to use, dart transfer.
Thermal fog, pesticide active ingredient is dissolved in the solvent with appropriate flash-point and viscosity, then adds other compositions
It is modulated into the preparation of certain specification.When in use, by means of fog machine, this preparation is quantitatively sent in fireworks pipe, with height
The thermal current mixing of warm high speed is sprayed into air, forms micron-sized mist or cigarette.
Existing bromine cyanogen insect amide product is mainly dispersible oil-suspending agent oil-suspending agent OD, suspension emulsion SE, suspending agent SC.It is logical
Cross be watered dilution after spray pesticide, and the exhibition film oil-suspending agent of bromine cyanogen insect amide both at home and abroad there is not been reported, also without report use
Hot mist machine applies bromine cyanogen insect amide preparation such as bromine cyanogen insect amide exhibition film oil-suspending agent or bromine cyanogen insect amide SE report, in addition, existing
Have in technology, film-spreading oil solution or thermal fog require that active ingredient is dissolved in preparation system, and the two is often molten using polarity
Agent such as DMF, DMSO, especially for this active ingredient being not readily dissolved in general non-polar solven of bromine cyanogen insect amide, a side
Partial solvent is unfriendly to environment in these polar solvents of face, and on the other hand, polar solvent often destroys film forming agent institute into oil film
Continuity, limitation film forming agent technology promotes the use.
The content of the invention
In view of this, it is an object of the invention to be permeability and local Uptake and translocation ability of the enhancing medicament to blade,
The product is prevented and treated a variety of different types of insects, while overcome work efficiency present on conventional spray techniques prevention and controls
Low, the defects of labor intensity is big, water requirement is big and current exhibition film oil-suspending agent product resistance is strong and the technical solution that proposes,
A kind of bromine cyanogen insect amide exhibition film oil-suspending agent is provided.
I.e. the first object of the present invention is to provide a kind of bromine cyanogen insect amide exhibition film oil-suspending agent, including following components：With
Weight meter bromine cyanogen insect amide 1%~40%, film forming agent are 1%~30%, and auxiliary agent 2%~25%, oiliness decentralized medium complements to
100%.
Preferably, in bromine cyanogen insect amide of the present invention opens up film oil-suspending agent, the film forming agent includes Lauryl Alcohol
One or more in ester, octadecyl alcolol, propane diols phenylate, dibutyl phthalate and monobutyl ether acetate.
Preferably, bromine cyanogen insect amide of the present invention open up film oil-suspending agent in, the auxiliary agent include surfactant,
Bleeding agent and fire retardant.
Preferably, in bromine cyanogen insect amide of the present invention opens up film oil-suspending agent, the surfactant is selected from fat
Alcohol APEO, APES, phenethyl phenol polyethenoxy ether, alkylaryl polyoxyethylene polyoxypropylene ether again,
One or more kinds of combinations of castor oil polyoxyethylene ether, calcium dodecyl benzene sulfonate etc..
Preferably, in bromine cyanogen insect amide of the present invention opens up film oil-suspending agent, the bleeding agent is selected from azone, thiophene
Ketone, the one or more kinds of combinations for oozing T soon.
Preferably, in bromine cyanogen insect amide of the present invention opens up film oil-suspending agent, it is fire-retardant that the fire retardant is selected from halogen system
Agent, phosphorus flame retardant, nitrogenated flame retardant, phosphorus-halogenated flame retardant, the one or more of phosphorus-nitrogenated flame retardant, wherein the phosphorus
The preferred triphenyl phosphate of flame retardant.
Preferably, in bromine cyanogen insect amide of the present invention opens up film oil-suspending agent, the oiliness decentralized medium is aromatic hydrocarbons
Class oiliness decentralized medium or plant oil oiliness decentralized medium.
Preferably, in bromine cyanogen insect amide of the present invention opens up film oil-suspending agent, the aromatic hydrocarbons oiliness decentralized medium
For C10 aromatic hydrocarbons, o-dichlorohenzene or methyl naphthalene；The plant oil oiliness decentralized medium is soybean oil, cottonseed oil, rapeseed oil, castor
Sesame oil, turpentine oil or esterified vegetable oil, wherein the esterified vegetable oil is methyl oleate or ethyl oleate.
Preferably, in bromine cyanogen insect amide of the present invention opens up film oil-suspending agent, the oiliness decentralized medium is boiling point
Higher than the oiliness decentralized medium that 160 DEG C, flash-point are higher than 60 DEG C.
Another object of the present invention is the preparation method for providing above-mentioned bromine cyanogen insect amide exhibition film oil-suspending agent, and methods described is
Bromine cyanogen insect amide and film forming agent, oiliness decentralized medium, auxiliary agent are sufficiently stirred dissolving, it is well mixed to form.
Traditional film forming agent is generally vegetable fat or is nonpolar mineral grease, into oil film when the advantage is that pure material
Preferably, but exist exhibition film speed it is slow, rely on water environment the problems such as.The present invention compared with prior art, the present invention have with
Lower advantage：
The bromine cyanogen insect amide exhibition film oil-suspending agent of 1 present invention, is built upon on the basis of oil-suspending agent formulation, with higher boiling
Oily oiliness decentralized medium be pesticide activity component decentralized medium, add appropriate film forming agent, help oiliness decentralized medium and help
A kind of special finish that agent is configured to.And in use, preparation is sent in smoke pipe by hot mist machine, with high temperature and high speed
Thermal current mixing is sprayed into air, forms 0.1~10 μm of droplet, and diffusion diffuses in field, after crop or evil thing contact,
Crop or evil thing surface are adhered to, due to there is the presence of film forming agent, permeates rapidly and internally rapidly, plays a part of preventing and treating.
2nd, work efficiency is high.Hot mist machine dispenser can be used in the bromine cyanogen insect amide exhibition film oil-suspending agent of the present invention, simple to operate, work
Intensity is small, and cost is low, can increase substantially efficiency, improves work efficiency decades of times, reduces agricultural cost.
3rd, quick-acting is good, and preventive effect protrudes.The droplet of the bromine cyanogen insect amide exhibition film oil-suspending agent of the present invention is superfine, in crop
The long period is diffused, makes insect and crop " immersion " in medicine mist.The oiliness decentralized medium for opening up film oil-suspending agent is oiliness oiliness
Decentralized medium, and add special wetting penetrant, and added with film forming agent, decoction to the adhesion permeability of insect and crop very
By force, once with contacting pests, whole body surface is just sprawled rapidly, and then penetrates into vivo and plays effect, substantially increases medicament
To the prevention effect of insect.
3rd, flash-point is high, job safety.The exhibition film oil-suspending agent of the present invention uses high-flash oiliness decentralized medium to add for material
Add special fire retardant, product flash-point is high, is not easy to catch fire in use, high to people and crop safety.
4th, heretofore described film forming agent is good compared to traditional film forming agent film-formation result, spread of the medicament in paddy field liquid level
Excellent performance, also can preferable spread in micro- water or water shortage environment so that exhibition film oil-suspending agent is shown to contrasting formulation oil-suspending agent
There is more preferable bioactivity.
Embodiment
In one embodiment of the invention, there is provided a kind of bromine cyanogen insect amide opens up film oil-suspending agent, including following components：
Bromine cyanogen insect amide 1%~40% by weight, film forming agent are 1%~30%, and auxiliary agent 2%~25%, oiliness decentralized medium is supplied
To 100%.
Preferably, in another embodiment, the film forming agent includes Lauryl Alcohol ester, octadecyl alcolol, third
One or more in glycol phenylate, dibutyl phthalate and monobutyl ether acetate.
Preferably, in another embodiment, the auxiliary agent includes surfactant, bleeding agent and fire-retardant
Agent.
Preferably, in another embodiment, the surfactant is selected from AEO, alkyl
Phenol polyethenoxy ether, phenethyl phenol polyethenoxy ether, alkylaryl polyoxyethylene polyoxypropylene ether again, castor oil polyoxyethylene ether,
One or more kinds of combinations of calcium dodecyl benzene sulfonate etc..
Preferably, in another embodiment, the bleeding agent is selected from azone, thiophene ketone, one kind for oozing T soon or one
The combination of the kind above.
Preferably, in another embodiment, the fire retardant is selected from halogenated flame retardant, phosphorus flame retardant, nitrogen
Flame retardant, phosphorus-halogenated flame retardant, the one or more of phosphorus-nitrogenated flame retardant, wherein the preferred phosphoric acid of the phosphorus flame retardant
Triphenylmethyl methacrylate.
Preferably, in another embodiment, the oiliness decentralized medium be aromatic hydrocarbons oiliness decentralized medium or
Plant oil oiliness decentralized medium.
Preferably, in another embodiment, the aromatic hydrocarbons oiliness decentralized medium is C10 aromatic hydrocarbons, adjacent dichloro
Benzene or methyl naphthalene；The plant oil oiliness decentralized medium is soybean oil, cottonseed oil, rapeseed oil, castor oil, turpentine oil or esterification
Vegetable oil, wherein the esterified vegetable oil is methyl oleate or ethyl oleate.
Preferably, in another embodiment, the oiliness decentralized medium is boiling point higher than 160 DEG C, flash-point height
In 60 DEG C of oiliness decentralized medium.
In further embodiment of the present invention, the preparation method of above-mentioned bromine cyanogen insect amide exhibition film oil-suspending agent, institute are also provided
It is that bromine cyanogen insect amide and film forming agent, oiliness decentralized medium, auxiliary agent are sufficiently stirred into dissolving to state method, well mixed to form.
Preferably, pass through below to use influence of the film forming agent to bromine cyanogen insect amide medicament to test in the embodiment of the present invention
Subsequent embodiment discovery propane diols phenylate, Lauryl Alcohol ester+octadecyl alcolol, Lauryl Alcohol ester+octadecyl alcolol+propane diols phenylate, 12
Carbon alcohol ester+octadecyl alcolol+propane diols phenylate+monobutyl ether acetate, octadecyl alcolol+propane diols phenylate, octadecyl alcolol+propane diols phenylate+butyl ether
Acetate, propane diols phenylate+monobutyl ether acetate resultant effect best results.It is highly preferred that propane diols phenylate, butyl ether are combined below
Acetate, Lauryl Alcohol ester+octadecyl alcolol+propane diols phenylate+monobutyl ether acetate, propane diols phenylate+monobutyl ether acetate have preferably
Practice is worth.
Film forming agent influences on medicament scalability
Note：Data above is 5 measurement average values.Different lowercase letters after same row average value are in P=0.05
The horizontal significance of difference.+ and-represent assessment grade, spreading rate and the spreading area significance of difference for " a or b " remember "+",
Otherwise "-" is remembered.
Below in conjunction with the embodiment in the present invention, the technical scheme in the present invention is clearly and completely described.It is aobvious
So, described embodiment is only part of the embodiment of the present invention, rather than whole embodiments.Based on the reality in the present invention
Example is applied, the every other embodiment that those of ordinary skill in the art are obtained under the premise of creative work is not made, is all belonged to
In the scope of protection of the invention.
Embodiment 1：1% bromine cyanogen insect amide opens up the formula and preparation technology of film oil-suspending agent
Formula：Bromine cyanogen insect amide 1kg, methyl oleate 5kg, nonyl phenol oxygen vinethene 8kg, AEO 2kg,
Lauryl Alcohol ester 3kg, propane diols phenylate 3kg, monobutyl ether acetate 5kg, white oil complement to 100kg.
Preparation technology：In the mixing kettle of belt stirrer, first with bromine cyanogen insect amide, methyl oleate, nonyl phenol oxygen vinethene,
Lauryl Alcohol ester, propane diols phenylate, monobutyl ether acetate and white oil, after being thoroughly mixed, husky mill are pumped into sand mill, sand is milled to
Behind granular size D90≤5 μm, exhibition film exhibition film oil-suspending agent is produced.
According to preparation technology same as Example 1, following examples are prepared.
Embodiment 2：5% bromine cyanogen insect amide opens up film oil-suspending agent
Formula：Bromine cyanogen insect amide 5kg, nonyl phenol oxygen vinethene 4kg, AEO 3kg, octadecyl alcolol 3kg, third
Glycol phenylate 3kg, monobutyl ether acetate 5kg, white oil complement to 100kg.
Embodiment 3：8% bromine cyanogen insect amide opens up film oil-suspending agent
Formula：Bromine cyanogen insect amide 8kg, nonyl phenol oxygen ethene polyethenoxy ether 4kg, AEO 2kg, 12
Carbon alcohol ester 3kg, octadecyl alcolol 2kg, propane diols phenylate 5kg, monobutyl ether acetate 5kg, sec-Butyl Acetate complement to 100kg.
Embodiment 4：10% bromine cyanogen insect amide opens up film oil-suspending agent
Formula：Bromine cyanogen insect amide 10kg, AEO yuban 4kg, NPE
2kg, Lauryl Alcohol ester 2kg, octadecyl alcolol 3kg, propane diols phenylate 5kg, monobutyl ether acetate 2kg, white oil complement to 100kg.
Embodiment 5：15% bromine cyanogen insect amide opens up film oil-suspending agent
Formula：Bromine cyanogen insect amide 15kg, AEO yuban 5kg, NPE
1kg, octadecyl alcolol 2kg, Lauryl Alcohol ester 3kg, monobutyl ether acetate 5kg, white oil complement to 100kg.
Embodiment 6：20% bromine cyanogen insect amide opens up film oil-suspending agent
Formula：Bromine cyanogen insect amide 20kg, AEO 3kg, NPE 3kg, octadecyl alcolol
5kg, monobutyl ether acetate 3kg, solvent naphtha complement to 100kg.
Embodiment 7：30% bromine cyanogen insect amide opens up film oil-suspending agent
Formula：Bromine cyanogen insect amide 30kg, AEO 3kg, octadecyl alcolol 5kg, Lauryl Alcohol ester 3kg, white oil
Complement to 100kg.
Embodiment 8：40% bromine cyanogen insect amide opens up film oil-suspending agent
Formula：Bromine cyanogen insect amide 40kg, AEO 12kg, NPE 5kg, octadecyl alcolol
0.5kg, monobutyl ether acetate 3kg, white oil complement to 100kg.
Comparison medicament 1：20% bromine cyanogen insect amide SC
Bromine cyanogen insect amide 20kg, polymerization of carboxylic acid salt 3kg, phosphate 5kg, xanthans 0.2kg, KF88 0.02kg, water are supplied
To 100kg.After above-mentioned material is well mixed, material particles D90≤10 μm are milled to through sand, produce the suspension of 20% bromine cyanogen insect amide
Agent.
Contrast agent 2:5% bromine cyanogen insect amide missible oil
Formula：Bromine cyanogen insect amide 5kg, T 3kg, AEO 8kg, calcium dodecyl benzene sulfonate 1kg are oozed soon,
DMF 15kg, dimethylbenzene complement to 100kg.After above-mentioned material is well mixed, active ingredient bromine cyanogen worm is treated
Acid amides dissolving is complete, during oil-based liquid clear, produces 5% chlorine worm benzoyl missible oil.
Contrast agent 3:5% bromine cyanogen insect amide oil-suspending agent
Bromine cyanogen insect amide 5kg, azone 2kg, AEO 6kg, calcium dodecyl benzene sulfonate 3kg, tricresyl phosphate
Phenyl ester 4kg, soybean oil 15kg, methyl naphthalene complement to 100kg.
Application Example
Beneficial effects of the present invention are further illustrated by following field test.
Test example 1：Prevent and treat the field test of big shed eggplant prodenia litura.
Bromine cyanogen insect amide of the present invention is opened up into film oil-suspending agent and carries out the oblique of preventing and treating big shed eggplant with 20% bromine cyanogen insect amide SC
Autographa spp field control effectiveness test.Test method：The hot mist machine dispenser of film oil-suspending agent is opened up, closed greenhouse is opened after 30 minutes after dispenser
Canopy is divulged information；20% bromine cyanogen insect amide SC is compared after being watered dilution with conventional manual sprayer spray pesticide.Each plot area
For 200m2, it is repeated 4 times, 3 days after medicine, investigates preventive effect within 15 days.Investigation drug effect method be：Each cell by east, south, west, north,
In take 5 points, every singling investigates 2 plants, records prodenia litura quantity, calculates prevention effect.Calculation formula is as follows：
Borer population × 100 ... .. (1) before prevention effect (%)=(borer population after borer population-dispenser before dispenser) ÷ dispensers
Result of the test is shown in Table 1.
Table 1 prevents and treats the field test results of greenhouse prodenia litura
Table of field test results is bright:Bromine cyanogen insect amide exhibition film oil-suspending agent compares conventional formulation to the preventive effect of greenhouse prodenia litura
Suspending agent compares drug effect more carefully, and lasting effect is longer.
Test example 2：Prevent and treat the field test of diaphorina citri.
Bromine cyanogen insect amide of the present invention is opened up into film oil-suspending agent and 20% bromine cyanogen insect amide SC prevent and treat the field of diaphorina citri
Between the test of pesticide effectiveness.Test method：Open up the hot mist machine dispenser of film oil-suspending agent；20% bromine cyanogen insect amide SC uses routine after being watered dilution
Hand sprayer spray pesticide compares.Each plot area is 200m2, it is repeated 4 times, 3 days after medicine, investigates preventive effect within 15 days.Adjust
The method for looking into drug effect is：Each cell by east, south, west, north, in take 5 points, every singling investigates 2 plants, records diaphorina citri number
Amount, calculate prevention effect.Calculation formula is as follows：
Borer population × 100 ... .. (1) before prevention effect (%)=(borer population after borer population-dispenser before dispenser) ÷ dispensers
Result of the test is shown in Table 2.
Table 2 prevents and treats the field test results of diaphorina citri
Table of field test results is bright:Bromine cyanogen insect amide opens up film oil-suspending agent and the preventive effect of diaphorina citri is suspended than conventional formulation
Agent is good, and lasting effect is longer.
Test example 3：Prevent and treat the field test of corn borer.
Bromine cyanogen insect amide of the present invention is opened up into film oil-suspending agent and 20% bromine cyanogen insect amide SC prevent and treat the field of corn borer
The test of pesticide effectiveness.Test method：Open up the hot mist machine dispenser of film oil-suspending agent；20% bromine cyanogen insect amide SC is watered after dilution with conventional hand
Dynamic sprayer spray pesticide compares.Each plot area is 200m2, it is repeated 4 times, 3 days after medicine, investigates preventive effect within 15 days.Investigation
The method of drug effect is：Each cell by east, south, west, north, in take 5 points, every singling investigates 2 plants, records corn borer quantity,
Calculate prevention effect.Calculation formula is as follows：
Borer population × 100 ... .. (1) before prevention effect (%)=(borer population after borer population-dispenser before dispenser) ÷ dispensers
Result of the test is shown in Table 3.
Table 3 prevents and treats the field test results of corn borer
Table of field test results is bright:Bromine cyanogen insect amide opens up film oil-suspending agent to the preventive effect of corn borer than conventional formulation such as missible oil
It is good with suspending agent, and lasting effect is longer, and also confirm that in terms of drug effect is improved, has the preparation of oiliness dispersant media in addition, such as
Exhibition film oil-suspending agent and EC, drug effect are higher than aqueous dispersion medium preparation, such as SC.
Test example 4：Prevent and treat the field test of cotton cotton thrips.
Bromine cyanogen insect amide of the present invention is opened up into film oil-suspending agent and 5% bromine cyanogen insect amide EC and 20% bromine cyanogen insect amide SC is carried out
Prevent and treat the field control effectiveness test of Cotton Fields cotton thrips.Test method：Open up the hot mist machine dispenser of film oil-suspending agent；5% bromine cyanogen worm acyl
Amine EC uses conventional manual sprayer spray pesticide after being watered dilution；Clear water compares.Each plot area is 200m2, repeat 4
It is secondary, 3 days after medicine, investigate preventive effect within 15 days.Investigation drug effect method be：Each cell by east, south, west, north, in take 5 points, every point
Singling investigates 2 plants, records corn borer quantity, calculates prevention effect.Calculation formula is as follows：
Borer population × 100 ... .. (1) before prevention effect (%)=(borer population after borer population-dispenser before dispenser) ÷ dispensers
Result of the test is shown in Table 4.
Table 4 prevents and treats the field test results of cotton cotton thrips
Table of field test results is bright:Bromine cyanogen insect amide opens up film oil-suspending agent to the preventive effect conventional formulation of corn field corn borer such as
Missible oil and suspending agent are good, and lasting effect is longer, and also confirm that in terms of drug effect is improved, has the system of oiliness dispersant media in addition
Agent, such as open up film oil-suspending agent and EC, drug effect are higher than aqueous dispersion medium preparation, such as SC.
Test example 5：Prevent and treat the field test of big shed eggplant prodenia litura.
Bromine cyanogen insect amide of the present invention is opened up into film oil-suspending agent and 5% bromine cyanogen insect amide EC and 20% bromine cyanogen insect amide SC is carried out
Prevent and treat the field control effectiveness test of big shed eggplant prodenia litura.Test method：The hot mist machine dispenser of film oil-suspending agent is opened up, it is close after dispenser
Canopy ventilation is opened after closing greenhouse 30 minutes；20% bromine cyanogen insect amide WG uses conventional manual sprayer spray pesticide after being watered dilution；Clearly
Water compares.Each plot area is 200m2, it is repeated 4 times, 3 days after medicine, investigates preventive effect within 15 days.Investigation drug effect method be：Often
Individual cell by east, south, west, north, in take 5 points, every singling investigates 2 plants, records prodenia litura quantity, calculates prevention effect.
Calculation formula is as follows：
Borer population × 100 ... .. (1) before prevention effect (%)=(borer population after borer population-dispenser before dispenser) ÷ dispensers
Result of the test is shown in Table 5.
Table 5 prevents and treats the field test results of big shed eggplant prodenia litura
Table of field test results is bright:It is more conventional than preventive effect to the preventive effect of greenhouse prodenia litura that bromine cyanogen insect amide opens up film oil-suspending agent
Preparation such as missible oil and suspending agent are good, and lasting effect is longer, also confirm that in addition in terms of drug effect is improved, there is oiliness dispersant media
Preparation, such as open up film oil-suspending agent and EC, drug effect and be higher than aqueous dispersion medium preparation, such as SC.
Test example 6：Prevent and treat the field test of tobacco oriental tobacco budworm.
Bromine cyanogen insect amide of the present invention is opened up into film oil-suspending agent and 5% bromine cyanogen insect amide EC and 20% bromine cyanogen insect amide SC is carried out
Prevent and treat the field control effectiveness test of tobacco oriental tobacco budworm.Test method：Open up the hot mist machine dispenser of film oil-suspending agent；20% bromine cyanogen insect amide
WG uses conventional manual sprayer spray pesticide after being watered dilution；Clear water compares.Each plot area is 200m2, it is repeated 4 times,
3 days after medicine, investigate preventive effect within 15 days.Investigation drug effect method be：Each cell by east, south, west, north, in take 5 points, every is fixed
2 plants of strain investigation, records tobacco smoke green grass or young crops borer population amount, calculates prevention effect.Calculation formula is as follows：
Borer population × 100 ... .. (1) before prevention effect (%)=(borer population after borer population-dispenser before dispenser) ÷ dispensers
(treatment region Revision insect recluced rate) × 100
Result of the test is shown in Table 6.
Table 6 prevents and treats the field test results of big shed eggplant prodenia litura
Table of field test results is bright:Bromine cyanogen insect amide exhibition film oil-suspending agent compares preventive effect routine to the preventive effect of tobacco oriental tobacco budworm
Preparation such as missible oil and suspending agent are good, and lasting effect is longer, also confirm that in addition in terms of drug effect is improved, there is oiliness dispersant media
Preparation, such as open up film oil-suspending agent and EC, drug effect and be higher than aqueous dispersion medium preparation, such as SC.Test example 6：Prevent and treat tobacco smoke
The field test of blue or green worm.
Laboratory test 1：Thermal fog smoking property is tested.
Hot mist machine explosive barrel is contained into deionized water 2kg, Sample Reagents 1kg, is stirred, and opens hot mist machine, and observation sprays heat
Mistiness degree, thick fog grade is evaluated, and observe during spraying hot mist whether have Ignition Phenomena.
Thick fog grade：
It is excellent ----hot mist is white dense smoke mist
It is good ----hot mist is blue dense smoke mist
In ----hot mist is light blue smog
Difference ----hot mist smoke dance is off and on
It the results are shown in Table 7
Table 7, bromine cyanogen insect amide exhibition film oil-suspending agent smoking property result of the test
From table 7 we it is concluded that, spray inventive samples using hot mist machine, send hot mist and be significantly better than contrast agent 2.
In the difference of the invention for being flash-point in flash-point difference with conventional missible oil sample contrast agent 2.Additionally, due to the flash-point of contrast agent 2
It is low, when hot mist machine sprays sample, there is the phenomenon caught fire.The low characteristic of flash-point, also conventional missible oil product is not applied to
Spray and use in hot mist machine.
Laboratory test 2：Normal temperature stores stability test
Sample preparation：Prepare sample on December 14th, 2015, each example weight is 1 kilogram, content before detection storage, normal temperature
It is stored in the room that keeps sample.
Sample is sealed in peace amber bottle and project team finally determines that vial, fluorination bottle, barrier three kinds of materials of bottle can conducts
In the packaging material of product.
Content after detection storage on December 14th, 2016, calculates resolution ratio
It the results are shown in Table 8,
The bromine cyanogen insect amide storage at normal temperature of table 8 is reported
| Sample | Pacify amber bottle | Vial | It is fluorinated bottle | Obstruct bottle |
| Embodiment 1 | 1.1 | 1.9 | 2.5 | 1.4 |
| Embodiment 2 | 3.0 | 2.8 | 1.9 | 2.8 |
| Embodiment 3 | 2.5 | 2.6 | 1.8 | 2.9 |
| Embodiment 4 | 1.1 | 2.1 | 2.1 | 2.8 |
| Embodiment 5 | 1.3 | 2.8 | 2.1 | 1.7 |
| Embodiment 6 | 2.3 | 1.3 | 1.6 | 2.7 |
| Embodiment 7 | 2.1 | 1.6 | 1.4 | 2.7 |
| Embodiment 8 | 1.2 | 2.9 | 1.2 | 2.6 |
| Contrast agent 1 | 1.9 | 2.9 | 2.1 | 1.3 |
| Contrast agent 2 | 12.7 | 13.3 | 13.7 | 14.4 |
| Contrast agent 3 | 2.1 | 3.0 | 2.2 | 1.6 |
Result of the test shows, bromine cyanogen insect amide opens up film oil-suspending agent and keeps stable after storage at normal temperature December, and stability connects
Conventional formulation suspending agent is bordering on, it is much more stable than conventional formulation missible oil.
Described above is only the preferred embodiment of the present invention, it is noted that for the ordinary skill people of the art
For member, under the premise without departing from the principles of the invention, some improvements and modifications can also be made, these improvements and modifications also should
It is considered as protection scope of the present invention.
Claims (10)
1. a kind of bromine cyanogen insect amide opens up film oil-suspending agent, it is characterised in that including following components：Bromine cyanogen insect amide by weight
1%~40%, film forming agent is 1%~30%, and auxiliary agent 2%~25%, oiliness decentralized medium complements to 100%.
2. bromine cyanogen insect amide according to claim 1 opens up film oil-suspending agent, it is characterised in that the film forming agent includes 12
One or more in carbon alcohol ester, octadecyl alcolol, propane diols phenylate, dibutyl phthalate and monobutyl ether acetate.
3. bromine cyanogen insect amide according to claim 1 opens up film oil-suspending agent, it is characterised in that the auxiliary agent is lived including surface
Property agent, bleeding agent and fire retardant.
4. bromine cyanogen insect amide according to claim 1 opens up film oil-suspending agent, it is characterised in that the surfactant is selected from
AEO, APES, phenethyl phenol polyethenoxy ether, alkylaryl polyoxyethylene polyoxypropylene
One or more kinds of combinations of ether, castor oil polyoxyethylene ether, calcium dodecyl benzene sulfonate etc..
5. bromine cyanogen insect amide according to claim 1 opens up film oil-suspending agent, it is characterised in that the bleeding agent is selected from nitrogen
Ketone, thiophene ketone, the one or more kinds of combinations for oozing T soon.
6. bromine cyanogen insect amide according to claim 1 opens up film oil-suspending agent, it is characterised in that the fire retardant is selected from halogen system
Fire retardant, phosphorus flame retardant, nitrogenated flame retardant, phosphorus-halogenated flame retardant, the one or more of phosphorus-nitrogenated flame retardant, wherein institute
State the preferred triphenyl phosphate of phosphorus flame retardant.
7. bromine cyanogen insect amide according to claim 1 opens up film oil-suspending agent, it is characterised in that the oiliness decentralized medium is
Aromatic hydrocarbons oiliness decentralized medium or plant oil oiliness decentralized medium.
8. bromine cyanogen insect amide according to claim 7 opens up film oil-suspending agent, it is characterised in that the aromatic hydrocarbons oiliness is disperseed
Medium is C10 aromatic hydrocarbons, o-dichlorohenzene or methyl naphthalene；The plant oil oiliness decentralized medium is soybean oil, cottonseed oil, vegetable seed
Oil, castor oil, turpentine oil or esterified vegetable oil, wherein the esterified vegetable oil is methyl oleate or ethyl oleate.
9. bromine cyanogen insect amide according to claim 7 opens up film oil-suspending agent, it is characterised in that the oiliness decentralized medium is
Boiling point is higher than 60 DEG C of oiliness decentralized medium higher than 160 DEG C, flash-point.
10. a kind of method of the bromine cyanogen insect amide exhibition film oil-suspending agent prepared described in claim 1~9 any one, its feature
Be, methods described is that bromine cyanogen insect amide and film forming agent, oiliness decentralized medium, auxiliary agent are sufficiently stirred into dissolving, it is well mixed and
Into.
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108124864A (en) * | 2018-02-07 | 2018-06-08 | 郑州农达生化制品有限公司 | A kind of stable type compound sodium nitrophenolate and preparation method thereof |
| CN114246186A (en) * | 2021-12-22 | 2022-03-29 | 天津市汉邦植物保护剂有限责任公司 | Dispersible oil suspending agent containing kojic acid and cyantraniliprole as well as preparation method and application thereof |
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| CN102669105A (en) * | 2012-06-11 | 2012-09-19 | 联保作物科技有限公司 | Insecticide composition and preparation of insecticide composition |
| CN106489929A (en) * | 2016-08-31 | 2017-03-15 | 江西天人生态股份有限公司 | A kind of exhibition film oil-suspending agent and its application in terms of preventing and treating crops sucking pest |
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Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102669105A (en) * | 2012-06-11 | 2012-09-19 | 联保作物科技有限公司 | Insecticide composition and preparation of insecticide composition |
| CN106489929A (en) * | 2016-08-31 | 2017-03-15 | 江西天人生态股份有限公司 | A kind of exhibition film oil-suspending agent and its application in terms of preventing and treating crops sucking pest |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108124864A (en) * | 2018-02-07 | 2018-06-08 | 郑州农达生化制品有限公司 | A kind of stable type compound sodium nitrophenolate and preparation method thereof |
| CN114246186A (en) * | 2021-12-22 | 2022-03-29 | 天津市汉邦植物保护剂有限责任公司 | Dispersible oil suspending agent containing kojic acid and cyantraniliprole as well as preparation method and application thereof |
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