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CN107505575A - A kind of fast evaluation method of retired electrokinetic cell - Google Patents

A kind of fast evaluation method of retired electrokinetic cell Download PDF

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Publication number
CN107505575A
CN107505575A CN201710679940.1A CN201710679940A CN107505575A CN 107505575 A CN107505575 A CN 107505575A CN 201710679940 A CN201710679940 A CN 201710679940A CN 107505575 A CN107505575 A CN 107505575A
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battery bag
retired
retired battery
evaluation method
electrokinetic cell
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CN107505575B (en
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肖伟
陈家良
康权
舒小农
李澌翰
何岸
金晨宁
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Sichuan Energy Internet Research Institute EIRI Tsinghua University
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Sichuan Energy Internet Research Institute EIRI Tsinghua University
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    • GPHYSICS
    • G01MEASURING; TESTING
    • G01RMEASURING ELECTRIC VARIABLES; MEASURING MAGNETIC VARIABLES
    • G01R31/00Arrangements for testing electric properties; Arrangements for locating electric faults; Arrangements for electrical testing characterised by what is being tested not provided for elsewhere
    • G01R31/36Arrangements for testing, measuring or monitoring the electrical condition of accumulators or electric batteries, e.g. capacity or state of charge [SoC]
    • G01R31/392Determining battery ageing or deterioration, e.g. state of health
    • GPHYSICS
    • G01MEASURING; TESTING
    • G01RMEASURING ELECTRIC VARIABLES; MEASURING MAGNETIC VARIABLES
    • G01R31/00Arrangements for testing electric properties; Arrangements for locating electric faults; Arrangements for electrical testing characterised by what is being tested not provided for elsewhere
    • G01R31/36Arrangements for testing, measuring or monitoring the electrical condition of accumulators or electric batteries, e.g. capacity or state of charge [SoC]
    • G01R31/389Measuring internal impedance, internal conductance or related variables

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  • Physics & Mathematics (AREA)
  • General Physics & Mathematics (AREA)
  • Secondary Cells (AREA)

Abstract

The present invention relates to Cell Evaluation technical field, discloses a kind of fast evaluation method of retired electrokinetic cell.Including procedure below:Step 1, retired battery bag is placed on testboard, solid measure is carried out to retired battery bag first by charging/discharging apparatus;Step 2, determine again retired battery bag dump energy for 20% when power and internal resistance;Step 3, retired battery bag is fully charged, 1 time-of-week of standing;Step 4, the self-discharge rate for finally determining retired battery bag.The time of retired electrokinetic cell was tapered to 1 week or so from 12 months, the switching time tested between critical parameter is significantly simplify, drastically increases the efficiency of retired battery bag state estimation;Secondly, it greatly ensure that the accuracy of the retired battery status parameter of judge of acquisition.

Description

一种退役动力电池的快速评估方法A rapid evaluation method for decommissioned power batteries

技术领域technical field

本发明涉及电池评估技术领域,特别是一种退役动力电池的快速评估方法。The invention relates to the technical field of battery evaluation, in particular to a rapid evaluation method for decommissioned power batteries.

背景技术Background technique

当电池使用一段时间后,电池充满电时的容量低于电池额定容量的80%后,电池就应该被更换。因此对于退役电池包来说,首先需要确定其退役后的实际容量。而随着电池容量的衰减,相比新电池,退役电池包的内阻一般呈增大的趋势、电池的放电功率也会发生变化、电池的一致性以及电池的荷电保持能力变差。When the battery has been used for a period of time and the capacity of the battery is less than 80% of the rated capacity of the battery when it is fully charged, the battery should be replaced. Therefore, for the decommissioned battery pack, it is first necessary to determine its actual capacity after decommissioning. With the attenuation of battery capacity, compared with new batteries, the internal resistance of retired battery packs generally increases, the discharge power of batteries will also change, and the consistency of batteries and battery charge retention will deteriorate.

因此退役电池包的状态评估,需要综合容量、内阻、功率、自放电率、电池一致性,得到一个综合的评价指标。而容量、内阻、功率、自放电率、电池一致性等关键参数的测试,往往需要1-2个月的测试时间,这将大大阻碍退役动力电池的大规模利用。Therefore, the status evaluation of retired battery packs needs to integrate capacity, internal resistance, power, self-discharge rate, and battery consistency to obtain a comprehensive evaluation index. The testing of key parameters such as capacity, internal resistance, power, self-discharge rate, and battery consistency often takes 1-2 months, which will greatly hinder the large-scale utilization of decommissioned power batteries.

其次,现有的大多关于动力状态评估的研究主要集中在电池模型以及状态估算算法的研究上,前期也需要大量的测试数据来验证电池模型及状态估算算法的正确性。而对于退役动力电池,其退役前的使用工况千差万别,所以很难采用统一的电池模型及状态估算算法来评估退役动力电池的状态。Secondly, most of the existing research on power state assessment mainly focuses on the battery model and state estimation algorithm, and a large amount of test data is also needed in the early stage to verify the correctness of the battery model and state estimation algorithm. As for decommissioned power batteries, the working conditions before decommissioning vary greatly, so it is difficult to use a unified battery model and state estimation algorithm to evaluate the state of decommissioned power batteries.

发明内容Contents of the invention

本发明所要解决的技术问题是:针对上述存在的问题,本发明通过提取评判动力电池关键的评判因素,并设计制定了一套简单快捷的测试方法,旨在达到可快速评估退役动力电池的目的,提供了一种退役动力电池的快速评估方法。The technical problem to be solved by the present invention is: in view of the above existing problems, the present invention extracts the key evaluation factors for judging power batteries, and designs and formulates a set of simple and quick test methods, aiming to achieve the purpose of quickly evaluating decommissioned power batteries , providing a rapid evaluation method for decommissioned power batteries.

本发明采用的技术方案如下:一种退役动力电池的快速评估方法,包括以下过程:步骤1、将退役电池包放置在测试台上,首先使用充放电设备对退役电池包进行容量测定;步骤2、再测定退役电池包剩余电量为20%时的功率和内阻;步骤3、将退役电池包充满电,静置1周时间;步骤4、最后测定退役电池包的自放电率。The technical scheme adopted in the present invention is as follows: a rapid evaluation method for decommissioned power batteries, including the following process: step 1, place the decommissioned battery pack on the test bench, first use the charging and discharging equipment to measure the capacity of the decommissioned battery pack; step 2 , and then measure the power and internal resistance of the retired battery pack when the remaining power is 20%; step 3, fully charge the retired battery pack, and let it stand for 1 week; step 4, finally measure the self-discharge rate of the retired battery pack.

进一步的,所述步骤1的具体过程包括:步骤11、退役电池包到达测试台的工作台1,以1C的电流将退役电池包放电至电池包的截止条件,静置半小时;步骤12、以0.5C的电流对退役电池包进行充电,静置半小时;步骤13、以1C的电流对退役电池包进行放电,退役电池包所放出的容量即为退役电池包实际容量,获取所述退役电池包实际容量。Further, the specific process of step 1 includes: step 11, the decommissioned battery pack arrives at the workbench 1 of the test bench, discharges the decommissioned battery pack to the cut-off condition of the battery pack with a current of 1C, and stands still for half an hour; step 12, Charge the decommissioned battery pack with a current of 0.5C and let it stand for half an hour; step 13, discharge the decommissioned battery pack with a current of 1C, the capacity released by the decommissioned battery pack is the actual capacity of the decommissioned battery pack, and obtain the decommissioned battery pack The actual capacity of the battery pack.

进一步的,所述退役动力电池的快速评估方法还包括以下过程:所述步骤1完成之后,采用退役电池包原电池管理系统检测并获取退役电池包的所有单体电压情况。Further, the rapid evaluation method of the decommissioned power battery also includes the following process: after the completion of the step 1, the decommissioned battery pack primary battery management system is used to detect and obtain the voltage conditions of all the cells of the decommissioned battery pack.

进一步的,所述步骤2的具体过程包括:退役电池包从工作台1到达测试台上的工作台2,将退役电池包以1C的电流充电或放电至剩余电量为20%,静置半小时;然后以1C的电流对退役电池包进行功率和内阻测试,得到退役电池包剩余电量为20%时的功率和内阻,并记录。Further, the specific process of step 2 includes: the decommissioned battery pack arrives at the workbench 2 on the test bench from workbench 1, charges or discharges the decommissioned battery pack with a current of 1C until the remaining power is 20%, and stands still for half an hour ; Then test the power and internal resistance of the decommissioned battery pack with a current of 1C, and obtain the power and internal resistance when the remaining power of the decommissioned battery pack is 20%, and record it.

进一步的,所述步骤3中,将退役电池包充满电后,退役电池包从工作台2到测试台上的静置存放区,然后静置1周时间。Further, in step 3, after the decommissioned battery pack is fully charged, the decommissioned battery pack is moved from the workbench 2 to the static storage area on the test bench, and then left to stand for 1 week.

进一步的,所述步骤4的具体过程包括:退役电池包从静置存放区到达测试台的工作台3,用1C的电流将退役电池包放电至截止电压,此时退役电池包放出的容量与退役电池包实际容量的比值,即为退役电池包的自放电率。Further, the specific process of step 4 includes: the decommissioned battery pack arrives at the workbench 3 of the test bench from the static storage area, and discharges the decommissioned battery pack to the cut-off voltage with a current of 1C. At this time, the discharged capacity of the decommissioned battery pack is the same as The ratio of the actual capacity of the retired battery pack is the self-discharge rate of the retired battery pack.

与现有技术相比,采用上述技术方案的有益效果为:Compared with the prior art, the beneficial effects of adopting the above technical solution are:

1、通过建立一套测试流水线,在流水线上分别测试实际容量、电压一致性、功率及内阻,自放电率,将通常退役动力电池测试的时间从1-2个月缩减到1周左右,显著地简化了评判参数间测试的切换时间,极大地提高了退役电池包状态评估的效率。1. By establishing a test assembly line, the actual capacity, voltage consistency, power and internal resistance, and self-discharge rate are respectively tested on the assembly line, which reduces the test time of the usually decommissioned power battery from 1-2 months to about 1 week. It significantly simplifies the switching time of the test between the evaluation parameters, and greatly improves the efficiency of the status evaluation of the decommissioned battery pack.

2、本发明通过提取退役动力电池的关键参数,制定简单快捷的测试方法,直接测得每个退役电池包的关键测试指标,极大地保证了获得的评判退役电池状态参数的准确性。2. The present invention extracts the key parameters of the decommissioned power battery, formulates a simple and fast test method, and directly measures the key test indicators of each decommissioned battery pack, which greatly ensures the accuracy of the obtained decommissioned battery status parameters.

附图说明Description of drawings

图1是本发明退役动力电池的快速评估方法的流程示意图。Fig. 1 is a schematic flow chart of the rapid evaluation method for decommissioned power batteries of the present invention.

具体实施方式detailed description

下面结合附图对本发明做进一步描述。The present invention will be further described below in conjunction with the accompanying drawings.

如图1所示,针对退役电池包的测量设置流水线测试台,分别在不同的工作台上测量实际容量、电压一致性、功率及内阻,自放电率参数来进行评估。依次设置工作台1、工作台2、静置存放区、工作台3。工作台1配置一套电源及负载设备,目的是通过充放电完成电池的容量测试;工作台2处配置的是功率及内阻测试设备,目的是完成在电池在低剩余电量(SOC)情况下的放电能力测试;工作台3处配置一台单独的负载设备,目的是完成电池在静置一周后的自放电情况。As shown in Figure 1, an assembly line test bench is set up for the measurement of decommissioned battery packs, and the actual capacity, voltage consistency, power and internal resistance are measured on different work benches, and the self-discharge rate parameters are evaluated. Set workbench 1, workbench 2, static storage area, and workbench 3 in sequence. Workbench 1 is equipped with a set of power supply and load equipment, the purpose of which is to complete the battery capacity test through charging and discharging; workbench 2 is equipped with power and internal resistance test equipment, the purpose is to complete the battery in the case of low remaining power (SOC). Discharge capacity test; workbench 3 is equipped with a separate load device, the purpose is to complete the self-discharge of the battery after standing for a week.

1.获取退役电池包实际容量1. Obtain the actual capacity of the decommissioned battery pack

退役电池包到达测试台的工作台1,以1C的电流将退役电池包放电至电池包的截止条件,静置半小时;以0.5C的电流对退役电池包进行充电,静置半小时;以1C的电流对退役电池包进行放电,退役电池包所放出的容量即为退役电池包实际容量,所示实际容量也为退役电池包退役时剩余容量,获取所述退役电池包实际容量。同时采用退役电池包原电池管理系统检测并获取退役电池包的所有单体电压情况。The retired battery pack arrives at workbench 1 of the test bench, discharges the retired battery pack to the cut-off condition of the battery pack with a current of 1C, and stands still for half an hour; charges the retired battery pack with a current of 0.5C, and stands still for half an hour; The current of 1C discharges the decommissioned battery pack, the capacity released by the decommissioned battery pack is the actual capacity of the decommissioned battery pack, and the actual capacity shown is also the remaining capacity of the decommissioned battery pack when decommissioned, and the actual capacity of the decommissioned battery pack is obtained. At the same time, the primary battery management system of the decommissioned battery pack is used to detect and obtain all the voltage conditions of the decommissioned battery packs.

2.测定退役电池包功率和内阻2. Measure the power and internal resistance of retired battery packs

对退役电池包的功率测定,只需进行低剩余电量(SOC)下的功率,本实施例选择SOC为20%的情况,退役电池包从工作台1到达测试台上的工作台2,将退役电池包以1C的电流充电或放电至剩余电量为20%,静置半小时;然后以1C的电流对退役电池包进行功率和内阻测试,测试过程可以参照国标GB/T 31467.2-2015中的功率和内阻测试工况,得到退役电池包剩余电量为20%时的功率和内阻,并记录。For the power measurement of the decommissioned battery pack, only the power under the low remaining power (SOC) is needed. In this embodiment, the SOC is 20%. The battery pack is charged or discharged with a current of 1C until the remaining power is 20%, and then left for half an hour; then the power and internal resistance of the retired battery pack are tested with a current of 1C. The test process can refer to the national standard GB/T 31467.2-2015 Under the power and internal resistance test conditions, the power and internal resistance of the decommissioned battery pack when the remaining power is 20% are obtained and recorded.

3.测完功率和内阻,将退役电池包充满电,然后退役电池包到达静置存放区,静置1周时间。3. After measuring the power and internal resistance, fully charge the decommissioned battery pack, and then the decommissioned battery pack arrives at the static storage area for 1 week.

所述静置存放区包含放置退役电池包的电池架,从工作台2测试完的电池包随传送带进入静置存放区,并依次有序地摆放在电池架上面。当工作台3上的电池包做完测试离开工作台3后,并达到设置了静置时间后,该静置存放区电池架依次有序地将要进行自放电测试的电池包送上传送带。因此该静置存放区可以保障退役电池包顺畅地完成各项测试。The static storage area includes battery racks for placing decommissioned battery packs. The battery packs tested from workbench 2 enter the static storage area along with the conveyor belt, and are sequentially and orderly placed on the battery racks. After the battery packs on the workbench 3 leave the workbench 3 after finishing the test and reach the set rest time, the battery racks in the rest storage area sequentially send the battery packs to be tested for self-discharge to the conveyor belt. Therefore, the static storage area can ensure the smooth completion of various tests of the decommissioned battery pack.

4.测定退役电池包的自放电率4. Determining the self-discharge rate of retired battery packs

退役电池包从静置存放区到达测试台的工作台3,用1C的电流将退役电池包放电至截止电压,此时退役电池包放出的容量与退役电池包实际容量的比值,即为退役电池包的自放电率。The decommissioned battery pack arrives at the workbench 3 of the test bench from the static storage area, and the decommissioned battery pack is discharged to the cut-off voltage with a current of 1C. At this time, the ratio of the discharged capacity of the decommissioned battery pack to the actual capacity of the decommissioned battery pack is the decommissioned battery The self-discharge rate of the package.

本发明并不局限于前述的具体实施方式。本发明扩展到任何在本说明书中披露的新特征或任何新的组合,以及披露的任一新的方法或过程的步骤或任何新的组合。如果本领域技术人员,在不脱离本发明的精神所做的非实质性改变或改进,都应该属于本发明权利要求保护的范围。The present invention is not limited to the foregoing specific embodiments. The present invention extends to any new feature or any new combination disclosed in this specification, and any new method or process step or any new combination disclosed. Any insubstantial changes or improvements made by those skilled in the art without departing from the spirit of the present invention shall all fall within the protection scope of the claims of the present invention.

Claims (6)

1. a kind of fast evaluation method of retired electrokinetic cell, it is characterised in that including procedure below:Step 1, by retired battery Bag is placed on testboard, and solid measure is carried out to retired battery bag first by charging/discharging apparatus;Step 2, determine again it is retired Power and internal resistance when battery bag dump energy is 20%;Step 3, retired battery bag is fully charged, 1 time-of-week of standing;Step 4, Finally determine the self-discharge rate of retired battery bag.
2. the fast evaluation method of retired electrokinetic cell as claimed in claim 1, it is characterised in that the step 1 it is specific Process includes:Step 11, retired battery bag reach the workbench 1 of testboard, and retired battery bag is discharged into electricity with 1C electric current Chi Bao blanking voltage, stand half an hour;Step 12, with 0.5C electric current retired battery bag is charged, stand half an hour; Step 13, with 1C electric current retired battery bag is discharged, the capacity that retired battery bag is released is that retired battery bag is real Border capacity, obtain the retired battery bag actual capacity.
3. the fast evaluation method of retired electrokinetic cell as claimed in claim 2, it is characterised in that the retired electrokinetic cell Fast evaluation method also include procedure below:After the step 1 is completed, examined using retired battery bag galvanic cell management system Survey and obtain all monomer voltage situations of retired battery bag.
4. the fast evaluation method of retired electrokinetic cell as claimed in claim 3, it is characterised in that the step 2 it is specific Process includes:Retired battery bag reaches the workbench 2 on testboard from workbench 1, and retired battery bag is charged with 1C electric current Or it is 20% to be discharged to dump energy, stands half an hour;Then power is carried out to retired battery bag with 1C electric current and internal resistance is surveyed Examination, power when retired battery bag dump energy is 20% and internal resistance are obtained, and recorded.
5. the fast evaluation method of retired electrokinetic cell as claimed in claim 4, it is characterised in that in the step 3, will move back After labour battery bag is fully charged, standing storage area of the retired battery bag from workbench 2 to testboard, 1 time-of-week is then stood.
6. the fast evaluation method of retired electrokinetic cell as claimed in claim 5, it is characterised in that the step 4 it is specific Process includes:Retired battery bag reaches the workbench 3 of testboard from storage area is stood, and retired battery bag is discharged with 1C electric current To blanking voltage, the ratio of capacity and retired battery bag actual capacity that now retired battery bag is released, as retired battery bag Self-discharge rate.
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Cited By (6)

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CN109450029A (en) * 2018-11-26 2019-03-08 暨南大学 A kind of retired power battery energy storage method and accumulator
CN110687463A (en) * 2018-07-04 2020-01-14 中国电力科学研究院有限公司 Working condition adaptability evaluation method and device for retired power battery
CN111562509A (en) * 2020-04-03 2020-08-21 中国电力科学研究院有限公司 A method and system for determining the remaining life of a retired power battery
CN114545258A (en) * 2022-01-28 2022-05-27 蜂巢能源科技股份有限公司 Determination method and determination device of battery pack self-discharge
CN117577977A (en) * 2024-01-17 2024-02-20 深圳市杰成镍钴新能源科技有限公司 Whole-pack recycling control method for retired battery pack
CN118707354A (en) * 2024-08-28 2024-09-27 佛山市南海瑞泰机动车报废有限公司 A durability performance testing system for recycled batteries of new energy vehicles

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