CN1073607C - Electronic radiation solidifying paint for building material surface - Google Patents
Electronic radiation solidifying paint for building material surface Download PDFInfo
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- CN1073607C CN1073607C CN96122264A CN96122264A CN1073607C CN 1073607 C CN1073607 C CN 1073607C CN 96122264 A CN96122264 A CN 96122264A CN 96122264 A CN96122264 A CN 96122264A CN 1073607 C CN1073607 C CN 1073607C
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- 239000004566 building material Substances 0.000 title claims abstract description 26
- 230000005855 radiation Effects 0.000 title description 8
- 239000003973 paint Substances 0.000 title description 4
- 239000011248 coating agent Substances 0.000 claims abstract description 29
- 238000000576 coating method Methods 0.000 claims abstract description 29
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims abstract description 20
- 229920006337 unsaturated polyester resin Polymers 0.000 claims abstract description 18
- 239000000654 additive Substances 0.000 claims abstract description 14
- 239000004925 Acrylic resin Substances 0.000 claims abstract description 13
- 238000003847 radiation curing Methods 0.000 claims abstract description 13
- KCTAWXVAICEBSD-UHFFFAOYSA-N prop-2-enoyloxy prop-2-eneperoxoate Chemical compound C=CC(=O)OOOC(=O)C=C KCTAWXVAICEBSD-UHFFFAOYSA-N 0.000 claims abstract description 11
- DAKWPKUUDNSNPN-UHFFFAOYSA-N Trimethylolpropane triacrylate Chemical compound C=CC(=O)OCC(CC)(COC(=O)C=C)COC(=O)C=C DAKWPKUUDNSNPN-UHFFFAOYSA-N 0.000 claims abstract description 9
- 239000000049 pigment Substances 0.000 claims abstract description 6
- 239000002994 raw material Substances 0.000 claims description 13
- 239000002253 acid Substances 0.000 claims description 12
- FIHBHSQYSYVZQE-UHFFFAOYSA-N 6-prop-2-enoyloxyhexyl prop-2-enoate Chemical compound C=CC(=O)OCCCCCCOC(=O)C=C FIHBHSQYSYVZQE-UHFFFAOYSA-N 0.000 claims description 9
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 9
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 8
- 229910052799 carbon Inorganic materials 0.000 claims description 8
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- 239000003795 chemical substances by application Substances 0.000 claims description 3
- 239000002270 dispersing agent Substances 0.000 claims description 3
- MOUPNEIJQCETIW-UHFFFAOYSA-N lead chromate Chemical compound [Pb+2].[O-][Cr]([O-])(=O)=O MOUPNEIJQCETIW-UHFFFAOYSA-N 0.000 claims description 3
- 238000009736 wetting Methods 0.000 claims description 3
- 239000004215 Carbon black (E152) Substances 0.000 claims description 2
- 125000001931 aliphatic group Chemical group 0.000 claims description 2
- 229930195733 hydrocarbon Natural products 0.000 claims description 2
- 150000002430 hydrocarbons Chemical class 0.000 claims description 2
- 239000000080 wetting agent Substances 0.000 claims description 2
- 238000001723 curing Methods 0.000 abstract description 7
- 230000007797 corrosion Effects 0.000 abstract description 5
- 238000005260 corrosion Methods 0.000 abstract description 5
- -1 1,6-hexanediol diol Chemical class 0.000 abstract description 4
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 abstract description 2
- 231100000344 non-irritating Toxicity 0.000 abstract description 2
- 231100000252 nontoxic Toxicity 0.000 abstract description 2
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- 229940096522 trimethylolpropane triacrylate Drugs 0.000 description 7
- 239000002023 wood Substances 0.000 description 6
- 239000008199 coating composition Substances 0.000 description 5
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 3
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- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 2
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- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 239000004568 cement Substances 0.000 description 2
- 229910052602 gypsum Inorganic materials 0.000 description 2
- 239000010440 gypsum Substances 0.000 description 2
- ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 description 2
- 229910000021 magnesium carbonate Inorganic materials 0.000 description 2
- 235000014380 magnesium carbonate Nutrition 0.000 description 2
- 239000001095 magnesium carbonate Substances 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 238000005025 nuclear technology Methods 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 229910052710 silicon Inorganic materials 0.000 description 2
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- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- NQEUTICDPLLXAY-UHFFFAOYSA-N 2-[2-[2-(2-hydroxyethoxy)ethoxy]ethoxycarbonyl]benzoic acid Chemical compound OCCOCCOCCOC(=O)C1=CC=CC=C1C(O)=O NQEUTICDPLLXAY-UHFFFAOYSA-N 0.000 description 1
- HWSSEYVMGDIFMH-UHFFFAOYSA-N 2-[2-[2-(2-methylprop-2-enoyloxy)ethoxy]ethoxy]ethyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCCOCCOCCOC(=O)C(C)=C HWSSEYVMGDIFMH-UHFFFAOYSA-N 0.000 description 1
- GTELLNMUWNJXMQ-UHFFFAOYSA-N 2-ethyl-2-(hydroxymethyl)propane-1,3-diol;prop-2-enoic acid Chemical class OC(=O)C=C.OC(=O)C=C.OC(=O)C=C.CCC(CO)(CO)CO GTELLNMUWNJXMQ-UHFFFAOYSA-N 0.000 description 1
- 229920000178 Acrylic resin Polymers 0.000 description 1
- ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 description 1
- JQRRFDWXQOQICD-UHFFFAOYSA-N biphenylen-1-ylboronic acid Chemical compound C12=CC=CC=C2C2=C1C=CC=C2B(O)O JQRRFDWXQOQICD-UHFFFAOYSA-N 0.000 description 1
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 1
- KBLWLMPSVYBVDK-UHFFFAOYSA-N cyclohexyl prop-2-enoate Chemical compound C=CC(=O)OC1CCCCC1 KBLWLMPSVYBVDK-UHFFFAOYSA-N 0.000 description 1
- 239000013530 defoamer Substances 0.000 description 1
- 238000002845 discoloration Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000003822 epoxy resin Substances 0.000 description 1
- 125000005448 ethoxyethyl group Chemical group [H]C([H])([H])C([H])([H])OC([H])([H])C([H])([H])* 0.000 description 1
- 230000009970 fire resistant effect Effects 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- YDKNBNOOCSNPNS-UHFFFAOYSA-N methyl 1,3-benzoxazole-2-carboxylate Chemical compound C1=CC=C2OC(C(=O)OC)=NC2=C1 YDKNBNOOCSNPNS-UHFFFAOYSA-N 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 239000011120 plywood Substances 0.000 description 1
- 229920000647 polyepoxide Polymers 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 230000036632 reaction speed Effects 0.000 description 1
- 239000002344 surface layer Substances 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 229920006305 unsaturated polyester Polymers 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Landscapes
- Macromonomer-Based Addition Polymer (AREA)
- Paints Or Removers (AREA)
Abstract
本发明涉及一种新型建材表面电子辐射固化涂料，它是由改性不饱和聚酯树脂、环氧丙烯酸酯树脂、三羟甲基丙烷三丙烯酸酯、苯乙烯、1，6-己二醇二丙烯酸酯、添加剂和颜料等组成；该配方配制的涂料无毒、无刺激、无需溶剂，可刷、喷、涂，其所需固化环境优异，且其涂膜性能优良、表面光洁度高、耐水洗、耐污、耐腐蚀、节能、无污染。The invention relates to a new type of electronic radiation curing coating on the surface of building materials, which is composed of modified unsaturated polyester resin, epoxy acrylate resin, trimethylolpropane triacrylate, styrene, 1,6-hexanediol diol It is composed of acrylate, additives and pigments; the coating prepared by this formula is non-toxic, non-irritating, and solvent-free, and can be brushed, sprayed, and painted. It requires an excellent curing environment, and its coating film performance is excellent, the surface finish is high, and it is washable. , Pollution resistance, corrosion resistance, energy saving, pollution-free.
Description
本发明涉及一种新型建材表面电子辐射固化涂料。The invention relates to a novel electronic radiation curing coating on the surface of building materials.
目前，随着高层建筑的日趋增多，室内外的各类装潢业也日趋兴旺；现大多采用在壁上多彩喷塑技术或贴装饰性墙纸、壁布作为墙壁表面装饰，但这些装饰材料易脱落、变色，且采用多彩喷塑技术时，喷塑的涂料本身散发着异味并有一定的毒性对人体极为有害，另外还不具有防火、隔热、耐腐蚀的作用；目前新型防火、耐水洗、耐腐蚀的建筑装饰材料的需求随着消防的严格要求也日趋增长；在中国93215903.6中公开了一种“菱镁阻燃装饰板”，该板材是以菱镁板为基材，在其上涂刷一层粘接层，粘接层的上层粘贴一层纸膜层，纸膜层可以任意选择花色图案，纸膜层的上面贴附一表层，表面为阻燃层。该纸膜层贴附的表面需可阻燃，但其粘接层粘接较繁琐，粘接后表面不易平整，易起泡，且怕水洗。随着科学技术的发展，核技术的应用也日趋增多。目前辐射加工技术是核技术中应用范围最广、最为活跃的新兴加工领域，它于本世纪七十年代形成了一些规模性产业部门。由于采用辐射技术加工的建筑材料具有较高的强度和良好的表面化学物理性质，因而采用涂层固化辐射加工建材的技术也应用较多；如在北美(美、加)、西欧(法、意、德)、俄、日以及印尼等国都有辐射加工木板、压合板、硅水泥板、石膏板、铁板等新型建筑材料的厂家。在俄罗斯的Slmferopol和Klev工厂生产了一种EB涂层固化木板，其配方是由三羟甲基丙烷二烯丙基醚和改性不饱和聚酯50％、三乙二醇二甲基丙烯酸酯40％、三乙二醇邻苯二酸酯10％组成；该配方配制的涂料涂在木板上进行辐照时所耗氮量较少，但氧的残余量高、辐照剂量大、固化速度慢。美国Sartomer公司推荐的木材涂层配方是由丙烯酸氨基酯12％、丙氧化新戊二醇二丙烯酸酯20.15％、乙氧化三羟甲基丙烷三丙烯酸酯22％、乙氧基乙氧基乙基丙烯酸酯7％、氧化钛35％、添加剂3.85％组成；该配方配制的涂料涂在木材上后辐照时，其固化速度快，但原料难得且价高。国内上海科技大学、四川大学等单位也作过木板、硅水泥板、石膏板等建材的辐射固化研究。如上海科技大学研制的金属板涂层固化技术，其涂层配方是由丙烯酸树脂35％、丙烯酸聚氨酯15％、丙烯酸丁酯32％、丙烯酸4％，丙烯酸环己酯9％、丙烯酸2-乙基乙酯5％组成；该配方配制的涂料刷涂于金属板表面时，其柔性好，加工时固化速度快；但其光泽度差、耗氮量大。At present, with the increasing number of high-rise buildings, all kinds of indoor and outdoor decoration industries are also becoming more and more prosperous; now most of them use colorful spray technology on the wall or paste decorative wallpaper and wall covering as wall surface decoration, but these decorative materials are easy to fall off. , discoloration, and when the colorful spray technology is used, the spray paint itself emits peculiar smell and has certain toxicity, which is extremely harmful to the human body. In addition, it does not have the functions of fire prevention, heat insulation, and corrosion resistance; The demand for corrosion-resistant building decoration materials is also increasing with the strict requirements of fire protection; a "magnesite flame-retardant decorative board" is disclosed in China 93215903.6, which is based on magnesite board and coated with Brush one layer of adhesive layer, paste a layer of paper film layer on the upper layer of the adhesive layer, the paper film layer can choose color patterns arbitrarily, and attach a surface layer on the paper film layer, the surface is a flame-retardant layer. The surface to which the paper film layer is attached needs to be flame retardant, but the bonding of the adhesive layer is cumbersome, and the surface is not easy to be smooth after bonding, easy to foam, and is afraid of washing. With the development of science and technology, the application of nuclear technology is also increasing. At present, radiation processing technology is the most widely used and most active emerging processing field in nuclear technology. It formed some large-scale industrial sectors in the 1970s. Due to the high strength and good surface chemical and physical properties of building materials processed by radiation technology, the technology of coating curing radiation processing building materials is also widely used; for example, in North America (US, Canada), Western Europe (France, Italy) , Germany), Russia, Japan, Indonesia and other countries have manufacturers of new building materials such as radiation processing wood boards, plywood boards, silicon cement boards, gypsum boards, and iron boards. An EB-coated cured wood board was produced at the Slmferopol and Klev factories in Russia, the formulation of which was trimethylolpropane diallyl ether and modified unsaturated polyester 50%, triethylene glycol dimethacrylate 40% and 10% triethylene glycol phthalate; the coating prepared by this formula consumes less nitrogen when it is irradiated on wood boards, but the residual amount of oxygen is high, the radiation dose is large, and the curing speed is high. slow. The wood coating formula recommended by Sartomer in the United States is composed of 12% acrylated amino ester, 20.15% propoxylated neopentyl glycol diacrylate, 22% ethoxylated trimethylol propane triacrylate, ethoxylated ethoxyethyl 7% acrylate, 35% titanium oxide, and 3.85% additives; the coating prepared by this formula has a fast curing speed when it is applied on wood and then irradiated, but the raw materials are rare and expensive. Domestic units such as Shanghai University of Science and Technology and Sichuan University have also done research on radiation curing of building materials such as wood boards, silicon cement boards, and gypsum boards. For example, the metal plate coating curing technology developed by Shanghai University of Science and Technology, its coating formula is composed of acrylic resin 35%, acrylic polyurethane 15%, butyl acrylate 32%, acrylic acid 4%, cyclohexyl acrylate 9%, It consists of 5% ethyl ethyl ester; when the paint prepared by this formula is brushed on the surface of the metal plate, it has good flexibility and fast curing speed during processing; but its gloss is poor and the nitrogen consumption is large.
本发明的目的是为了提供一种无毒、无刺激、无需溶剂、可刷、喷、涂、其所需固化环境优异、涂膜性能优良、表面光洁度高、耐水洗、耐污、耐腐蚀、节能、无污染的新型建材表面电子辐射固化涂料。The purpose of the present invention is to provide a non-toxic, non-irritating, solvent-free, brushable, sprayable, coating, excellent curing environment required, excellent coating performance, high surface finish, washable, stain-resistant, corrosion-resistant, Energy-saving and pollution-free electronic radiation curing coating on the surface of new building materials.
本发明的目的可通过如下措施来实现：The purpose of the present invention can be achieved through the following measures:
一种新型建材表面电子辐射固化涂料是由下述重量百分含量的原料制成：改性不饱和聚酯树脂10-55％、环氧丙烯酸酯树脂10-30％、三羟甲基丙烷三丙烯酸酯5-21％、苯乙烯3-20％、1,6-己二醇二丙烯酸酯5-20％、添加剂0.5-3％、颜料5-25％。A new type of electronic radiation curing coating on the surface of building materials is made of the following raw materials in percentage by weight: 10-55% of modified unsaturated polyester resin, 10-30% of epoxy acrylate resin, trimethylolpropane three Acrylic ester 5-21%, styrene 3-20%, 1,6-hexanediol diacrylate 5-20%, additive 0.5-3%, pigment 5-25%.
本发明的目的还可通过如下措施来实现：The object of the present invention can also be achieved by the following measures:
新型建材表面电子辐射固化涂料的涂料的原料配方中的添加剂为消泡剂、流平剂、湿润分散剂；其颜料至少为碳黑、甲苯胺红、钛白、中铬黄中的一种；配方中的改性不饱和聚酯树脂(兰州科近公司产)的分子结构式为：
本发明相比现有技术具有如下优点：Compared with the prior art, the present invention has the following advantages:
1、本发明的涂料配方中以改性不饱和聚酯树脂及环氧丙烯酸酯树脂作为主要成膜物，从而使涂料具有质优价廉，且防火，耐水洗、耐酸特性，经2000次以上水洗不露底、10％ HCL浸泡48小时不起泡，不脱落。1. In the coating formula of the present invention, modified unsaturated polyester resin and epoxy acrylate resin are used as the main film-forming substances, so that the coating has high quality and low price, and is fireproof, water-resistant, and acid-resistant. After more than 2000 times Washed without revealing the bottom, soaked in 10% HCL for 48 hours without foaming or falling off.
2、本发明的涂料配方中添加三羟甲基丙烷三丙烯酸酯作为活性单体，可提高反应速度，增加成膜物硬度，并可降低加工辐射建材时的辐照剂量。2. Adding trimethylolpropane triacrylate as an active monomer in the coating formula of the present invention can increase the reaction speed, increase the hardness of the film-forming material, and reduce the radiation dose when processing radiation building materials.
3、本发明的涂料配方中添加苯乙烯作为活性单体，以便降低成本，提高成膜硬度；并添加1,6-己二醇二丙烯酸酯作活性单体，以增加膜的附着力，使涂层表面的光洁度提高，并附着均匀。3. Styrene is added as an active monomer in the coating formula of the present invention to reduce costs and improve film-forming hardness; and 1,6-hexanediol diacrylate is added as an active monomer to increase the adhesion of the film and make The smoothness of the coating surface is improved and the adhesion is uniform.
4、本发明的涂料涂在建材表面经辐照时，其用N2量少，环境氧浓度高，从而可降低加工成本，另其所需辐照设备的能量低、剂量低，从而可降低设备运行成本。4. When the coating of the present invention is applied to the surface of building materials and irradiated, it uses N. The amount is small and the ambient oxygen concentration is high, thereby reducing processing costs. In addition, the energy and dose of the required irradiation equipment are low, thereby reducing equipment operating costs.
5、本发明的涂料涂覆建材表面时，再经电子辐照，使其表面固化，从而可改善建材表面的物理化学性质，使建材表面的光洁度提高达到釉面效果，其光泽可提高94％，并耐水洗、防火、耐污、耐热、耐腐蚀；并还可大大提高建材的强度，可作为吊顶、室内外墙装饰材料。5. When the paint of the present invention is coated on the surface of building materials, the surface is cured by electron irradiation, thereby improving the physical and chemical properties of the building material surface, improving the smoothness of the building material surface to achieve the glaze effect, and its gloss can be increased by 94%. , and water-resistant, fire-resistant, stain-resistant, heat-resistant, and corrosion-resistant; and can also greatly improve the strength of building materials, and can be used as decorative materials for ceilings, interior and exterior walls.
本发明还将结合实施例作进一步详述：The present invention will also be described in further detail in conjunction with embodiment:
实施例一：Embodiment one:
一种新型建材表面电子辐射固化涂料的原料重量百分含量为：改性不饱和聚酯树脂55％、环氧丙烯酸酯树脂10％、三羟甲基丙烷三丙烯酸酯21％、苯乙烯3％、1,6-己二醇二丙烯酸酯5％、添加剂1％、颜料碳黑5％。所述的改性不饱和聚酯树脂的分子结构式中的R的碳数为2，其结构式为HO-CH2-CH2-OH，平均分子量为2000、酸值为20；所述的环氧丙烯酸酯树脂的酸值为10；所述的添加剂为消泡剂、流平剂和湿润分散剂可从市场上直接购买成品，其各自的使用量应视成品的性能指标现场给定其各自的含量，但添加剂的总量不变。The weight percentage of raw materials of electronic radiation curing coating on the surface of a new building material is: modified unsaturated polyester resin 55%, epoxy acrylate resin 10%, trimethylol propane triacrylate 21%, styrene 3% , 1,6-hexanediol diacrylate 5%, additive 1%, pigment carbon black 5%. The carbon number of R in the molecular structural formula of the modified unsaturated polyester resin is 2, the structural formula is HO-CH 2 -CH 2 -OH, the average molecular weight is 2000, and the acid value is 20; the epoxy resin The acid number of acrylate resin is 10; Described additive is that defoamer, leveling agent and wetting dispersant can directly buy finished product from the market, and its respective consumption should be given its respective on-site according to the performance index of finished product content, but the total amount of additives remains unchanged.
实施例二：Embodiment two:
一种新型建材表面电子辐射固化涂料的原料重量百分含量为：改性不饱和聚酯树脂45％、环氧丙烯酸酯树脂15％、三羟甲基丙烷三丙烯酸酯20％、苯乙烯7％、1,6-己二醇二丙烯酸酯5％、添加剂1％、甲苯胺红7％。所述的改性不饱和聚酯树脂的分子结构式中的R的碳数为3，其结构式为HO-CH2CH2CH2-OH，平均分子量为2500、酸值为25。The weight percentage of raw materials for electronic radiation curing coating on the surface of a new building material is: 45% modified unsaturated polyester resin, 15% epoxy acrylate resin, 20% trimethylol propane triacrylate, 7% styrene , 1,6-hexanediol diacrylate 5%, additive 1%, toluidine red 7%. The carbon number of R in the molecular structural formula of the modified unsaturated polyester resin is 3, the structural formula is HO-CH 2 CH 2 CH 2 -OH, the average molecular weight is 2500, and the acid value is 25.
实施例三：Embodiment three:
一种新型建材表面电子辐射固化涂料的原料重量百分含量为：改性不饱和聚酯树脂35％、环氧丙烯酸酯树脂20％、三羟甲基丙烷三丙烯酸酯15％、苯乙烯8％、1,6-己二醇二丙烯酸酯6％、添加剂1.5％、钛白14.5％。所述的改性不饱和聚酯树脂的分子结构式中的R的碳数为4，其结构式为HO-CH2(CH2)2CH2-OH，平均分子量为3000、酸值为30。The weight percent of raw materials of electronic radiation curing coating on the surface of a new building material is: 35% modified unsaturated polyester resin, 20% epoxy acrylate resin, 15% trimethylolpropane triacrylate, 8% styrene , 1,6-hexanediol diacrylate 6%, additive 1.5%, titanium dioxide 14.5%. The carbon number of R in the molecular structural formula of the modified unsaturated polyester resin is 4, the structural formula is HO-CH 2 (CH 2 ) 2 CH 2 -OH, the average molecular weight is 3000, and the acid value is 30.
实施例四：Embodiment four:
一种新型建材表面电子辐射固化涂料的原料重量百分含量为：改性不饱和聚酯树脂25％、环氧丙烯酸酯树脂25％、三羟甲基丙烷三丙烯酸酯10％、苯乙烯20％、1,6-己二醇二丙烯酸酯10％、添加剂0.5％、钛白9.5％。所述的改性不饱和聚酯树脂的分子结构式中的R的碳数为4，其结构式为HO-CH2(CH2)2CH2-OH，平均分子量为2800、酸值为27。The weight percent of raw materials for electronic radiation curing coating on the surface of a new building material is: 25% modified unsaturated polyester resin, 25% epoxy acrylate resin, 10% trimethylolpropane triacrylate, 20% styrene , 1,6-hexanediol diacrylate 10%, additive 0.5%, titanium dioxide 9.5%. The carbon number of R in the molecular structural formula of the modified unsaturated polyester resin is 4, the structural formula is HO-CH 2 (CH 2 ) 2 CH 2 -OH, the average molecular weight is 2800, and the acid value is 27.
实施例五：Embodiment five:
一种新型建材表面电子辐射固化涂料的原料重量百分含量为：改性不饱和聚酯树脂15％、环氧丙烯酸酯树脂30％、三羟甲基丙烷三丙烯酸酯5％、苯乙烯10％、1,6-己二醇二丙烯酸酯15％、添加剂0.5％、钛白24.5％。所述的改性不饱和聚酯树脂的分子结构式中的R的碳数为3，其结构式为：
实施例六：Embodiment six:
一种新型建材表面电子辐射固化涂料的原料重量百分含量为：改性不饱和聚酯树脂10％、环氧丙烯酸酯树脂30％、三羟甲基丙烷三丙烯酸酯10％、苯乙烯13％、1,6-己二醇二丙烯酸酯20％、添加剂3％、中铬黄14％。所述的改性不饱和聚酯树脂的分子结构式中的R的碳数为2其结构式为HO-CH2-CH2-OH，平均分子量为2200、酸值为22。The weight percent of raw materials of electronic radiation curing coating on the surface of a new building material is: 10% of modified unsaturated polyester resin, 30% of epoxy acrylate resin, 10% of trimethylolpropane triacrylate, and 13% of styrene , 1,6-hexanediol diacrylate 20%, additive 3%, medium chrome yellow 14%. The carbon number of R in the molecular structural formula of the modified unsaturated polyester resin is 2, the structural formula is HO-CH 2 -CH 2 -OH, the average molecular weight is 2200, and the acid value is 22.
Claims (4)
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| CN96122264A CN1073607C (en) | 1996-11-20 | 1996-11-20 | Electronic radiation solidifying paint for building material surface |
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Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
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| US7758621B2 (en) | 1997-05-15 | 2010-07-20 | Palomar Medical Technologies, Inc. | Method and apparatus for therapeutic EMR treatment on the skin |
| US7763016B2 (en) | 1997-05-15 | 2010-07-27 | Palomar Medical Technologies, Inc. | Light energy delivery head |
| US7942916B2 (en) | 2002-05-23 | 2011-05-17 | Palomar Medical Technologies, Inc. | Phototreatment device for use with coolants and topical substances |
| US8328794B2 (en) | 1996-12-02 | 2012-12-11 | Palomar Medical Technologies, Inc. | System for electromagnetic radiation dermatology and head for use therewith |
| US8346347B2 (en) | 2005-09-15 | 2013-01-01 | Palomar Medical Technologies, Inc. | Skin optical characterization device |
| US8915948B2 (en) | 2002-06-19 | 2014-12-23 | Palomar Medical Technologies, Llc | Method and apparatus for photothermal treatment of tissue at depth |
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| CN102286240A (en) * | 2011-09-14 | 2011-12-21 | 上海长润发涂料有限公司 | PE (Polyurethane) gloss white paint |
| CN102732072B (en) * | 2012-07-17 | 2014-12-17 | 东莞市高能磁电技术有限公司 | Preparation method of high-adhesion polishing-free PE (polyethylene) top-coat paint and product |
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| CN1046545A (en) * | 1989-02-17 | 1990-10-31 | 斯韦德罗有限公司 | Can form the pigmentable of transparent wear-resistant coating, the coating composition of radiation-hardenable |
| CN1053804A (en) * | 1990-01-08 | 1991-08-14 | 陶氏康宁公司 | The attrition resistant cyclic ether acrylate coating composition of radiation-hardenable |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN1046545A (en) * | 1989-02-17 | 1990-10-31 | 斯韦德罗有限公司 | Can form the pigmentable of transparent wear-resistant coating, the coating composition of radiation-hardenable |
| CN1053804A (en) * | 1990-01-08 | 1991-08-14 | 陶氏康宁公司 | The attrition resistant cyclic ether acrylate coating composition of radiation-hardenable |
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US8328794B2 (en) | 1996-12-02 | 2012-12-11 | Palomar Medical Technologies, Inc. | System for electromagnetic radiation dermatology and head for use therewith |
| US7758621B2 (en) | 1997-05-15 | 2010-07-20 | Palomar Medical Technologies, Inc. | Method and apparatus for therapeutic EMR treatment on the skin |
| US7763016B2 (en) | 1997-05-15 | 2010-07-27 | Palomar Medical Technologies, Inc. | Light energy delivery head |
| US7935107B2 (en) | 1997-05-15 | 2011-05-03 | Palomar Medical Technologies, Inc. | Heads for dermatology treatment |
| US8002768B1 (en) | 1997-05-15 | 2011-08-23 | Palomar Medical Technologies, Inc. | Light energy delivery head |
| US8109924B2 (en) | 1997-05-15 | 2012-02-07 | Palomar Medical Technologies, Inc. | Heads for dermatology treatment |
| US7942916B2 (en) | 2002-05-23 | 2011-05-17 | Palomar Medical Technologies, Inc. | Phototreatment device for use with coolants and topical substances |
| US8915948B2 (en) | 2002-06-19 | 2014-12-23 | Palomar Medical Technologies, Llc | Method and apparatus for photothermal treatment of tissue at depth |
| US8346347B2 (en) | 2005-09-15 | 2013-01-01 | Palomar Medical Technologies, Inc. | Skin optical characterization device |
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| CN1182765A (en) | 1998-05-27 |
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