CN105394047B - A kind of composition pesticide containing kasugarnycin and epoxiconazole - Google Patents
A kind of composition pesticide containing kasugarnycin and epoxiconazole Download PDFInfo
- Publication number
- CN105394047B CN105394047B CN201510899556.3A CN201510899556A CN105394047B CN 105394047 B CN105394047 B CN 105394047B CN 201510899556 A CN201510899556 A CN 201510899556A CN 105394047 B CN105394047 B CN 105394047B
- Authority
- CN
- China
- Prior art keywords
- active component
- epoxiconazole
- kasugarnycin
- composition pesticide
- composition
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- ZMYFCFLJBGAQRS-IRXDYDNUSA-N (2R,3S)-epoxiconazole Chemical compound C1=CC(F)=CC=C1[C@@]1(CN2N=CN=C2)[C@H](C=2C(=CC=CC=2)Cl)O1 ZMYFCFLJBGAQRS-IRXDYDNUSA-N 0.000 title claims abstract description 80
- 239000005767 Epoxiconazole Substances 0.000 title claims abstract description 80
- 239000000203 mixture Substances 0.000 title claims abstract description 77
- 239000000575 pesticide Substances 0.000 title claims abstract description 39
- 230000000694 effects Effects 0.000 claims abstract description 13
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 40
- 229910001868 water Inorganic materials 0.000 claims description 39
- 239000002270 dispersing agent Substances 0.000 claims description 27
- 239000000080 wetting agent Substances 0.000 claims description 23
- 150000001875 compounds Chemical class 0.000 claims description 22
- 235000007164 Oryza sativa Nutrition 0.000 claims description 20
- 235000009566 rice Nutrition 0.000 claims description 20
- 239000000945 filler Substances 0.000 claims description 19
- 239000003995 emulsifying agent Substances 0.000 claims description 18
- 239000002904 solvent Substances 0.000 claims description 17
- 239000003814 drug Substances 0.000 claims description 16
- 239000003921 oil Substances 0.000 claims description 15
- 239000003795 chemical substances by application Substances 0.000 claims description 14
- 238000000034 method Methods 0.000 claims description 14
- 239000012071 phase Substances 0.000 claims description 14
- 239000007884 disintegrant Substances 0.000 claims description 12
- 239000004563 wettable powder Substances 0.000 claims description 12
- 239000004530 micro-emulsion Substances 0.000 claims description 10
- 239000011230 binding agent Substances 0.000 claims description 9
- 229940079593 drug Drugs 0.000 claims description 9
- 239000003905 agrochemical Substances 0.000 claims description 8
- 239000002562 thickening agent Substances 0.000 claims description 8
- 239000004562 water dispersible granule Substances 0.000 claims description 8
- 238000013019 agitation Methods 0.000 claims description 7
- 239000008346 aqueous phase Substances 0.000 claims description 7
- 239000013530 defoamer Substances 0.000 claims description 7
- 239000000839 emulsion Substances 0.000 claims description 7
- 238000002156 mixing Methods 0.000 claims description 7
- 239000000375 suspending agent Substances 0.000 claims description 6
- 239000000463 material Substances 0.000 claims description 5
- 238000000498 ball milling Methods 0.000 claims description 4
- 239000000843 powder Substances 0.000 claims description 4
- 238000004519 manufacturing process Methods 0.000 claims description 3
- 239000002245 particle Substances 0.000 claims description 2
- 240000007594 Oryza sativa Species 0.000 claims 1
- 239000008267 milk Substances 0.000 claims 1
- 210000004080 milk Anatomy 0.000 claims 1
- 235000013336 milk Nutrition 0.000 claims 1
- 230000002265 prevention Effects 0.000 abstract description 7
- 238000013329 compounding Methods 0.000 abstract description 6
- 230000002195 synergetic effect Effects 0.000 abstract description 4
- 239000000306 component Substances 0.000 description 32
- 241000209094 Oryza Species 0.000 description 23
- 230000001988 toxicity Effects 0.000 description 12
- 231100000419 toxicity Toxicity 0.000 description 12
- 201000010099 disease Diseases 0.000 description 9
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 9
- 239000004615 ingredient Substances 0.000 description 8
- 210000000481 breast Anatomy 0.000 description 7
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 6
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 6
- YDEXUEFDPVHGHE-GGMCWBHBSA-L disodium;(2r)-3-(2-hydroxy-3-methoxyphenyl)-2-[2-methoxy-4-(3-sulfonatopropyl)phenoxy]propane-1-sulfonate Chemical compound [Na+].[Na+].COC1=CC=CC(C[C@H](CS([O-])(=O)=O)OC=2C(=CC(CCCS([O-])(=O)=O)=CC=2)OC)=C1O YDEXUEFDPVHGHE-GGMCWBHBSA-L 0.000 description 6
- -1 fluorine ring Azoles Chemical class 0.000 description 6
- RCEAADKTGXTDOA-UHFFFAOYSA-N OS(O)(=O)=O.CCCCCCCCCCCC[Na] Chemical compound OS(O)(=O)=O.CCCCCCCCCCCC[Na] RCEAADKTGXTDOA-UHFFFAOYSA-N 0.000 description 5
- 239000012752 auxiliary agent Substances 0.000 description 5
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 4
- 241001330975 Magnaporthe oryzae Species 0.000 description 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 4
- 229920002472 Starch Polymers 0.000 description 4
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 description 4
- 229910052921 ammonium sulfate Inorganic materials 0.000 description 4
- 235000011130 ammonium sulphate Nutrition 0.000 description 4
- 230000000844 anti-bacterial effect Effects 0.000 description 4
- 229940088417 precipitated calcium carbonate Drugs 0.000 description 4
- HNJBEVLQSNELDL-UHFFFAOYSA-N pyrrolidin-2-one Chemical compound O=C1CCCN1 HNJBEVLQSNELDL-UHFFFAOYSA-N 0.000 description 4
- 239000008107 starch Substances 0.000 description 4
- 235000019698 starch Nutrition 0.000 description 4
- 241000196324 Embryophyta Species 0.000 description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 3
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 3
- 229910019142 PO4 Inorganic materials 0.000 description 3
- 239000003899 bactericide agent Substances 0.000 description 3
- 238000001035 drying Methods 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 3
- 235000021317 phosphate Nutrition 0.000 description 3
- 238000007873 sieving Methods 0.000 description 3
- 239000007921 spray Substances 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- QPUYECUOLPXSFR-UHFFFAOYSA-N 1-methylnaphthalene Chemical compound C1=CC=C2C(C)=CC=CC2=C1 QPUYECUOLPXSFR-UHFFFAOYSA-N 0.000 description 2
- DMAXMXPDVWTIRV-UHFFFAOYSA-N 2-(2-phenylethyl)phenol Chemical compound OC1=CC=CC=C1CCC1=CC=CC=C1 DMAXMXPDVWTIRV-UHFFFAOYSA-N 0.000 description 2
- 206010067484 Adverse reaction Diseases 0.000 description 2
- 239000005995 Aluminium silicate Substances 0.000 description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- 241001272567 Hominoidea Species 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- IUOKJNROJISWRO-UHFFFAOYSA-N N-(2-cyano-3-methylbutan-2-yl)-2-(2,4-dichlorophenoxy)propanamide Chemical compound CC(C)C(C)(C#N)NC(=O)C(C)OC1=CC=C(Cl)C=C1Cl IUOKJNROJISWRO-UHFFFAOYSA-N 0.000 description 2
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 2
- 239000004372 Polyvinyl alcohol Substances 0.000 description 2
- 230000006838 adverse reaction Effects 0.000 description 2
- 235000012211 aluminium silicate Nutrition 0.000 description 2
- 235000013339 cereals Nutrition 0.000 description 2
- 239000004927 clay Substances 0.000 description 2
- 239000002131 composite material Substances 0.000 description 2
- 238000009833 condensation Methods 0.000 description 2
- 230000005494 condensation Effects 0.000 description 2
- JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 description 2
- 235000014113 dietary fatty acids Nutrition 0.000 description 2
- 239000000194 fatty acid Substances 0.000 description 2
- 229930195729 fatty acid Natural products 0.000 description 2
- 238000009472 formulation Methods 0.000 description 2
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 2
- 229920001568 phenolic resin Polymers 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 2
- 239000010452 phosphate Substances 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- 229940051841 polyoxyethylene ether Drugs 0.000 description 2
- 229920000056 polyoxyethylene ether Polymers 0.000 description 2
- 229920002451 polyvinyl alcohol Polymers 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 230000003449 preventive effect Effects 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- 238000005507 spraying Methods 0.000 description 2
- 239000004546 suspension concentrate Substances 0.000 description 2
- 230000001225 therapeutic effect Effects 0.000 description 2
- 229920001285 xanthan gum Polymers 0.000 description 2
- IXPNQXFRVYWDDI-UHFFFAOYSA-N 1-methyl-2,4-dioxo-1,3-diazinane-5-carboximidamide Chemical compound CN1CC(C(N)=N)C(=O)NC1=O IXPNQXFRVYWDDI-UHFFFAOYSA-N 0.000 description 1
- WODGMMJHSAKKNF-UHFFFAOYSA-N 2-methylnaphthalene-1-sulfonic acid Chemical compound C1=CC=CC2=C(S(O)(=O)=O)C(C)=CC=C21 WODGMMJHSAKKNF-UHFFFAOYSA-N 0.000 description 1
- 241000186046 Actinomyces Species 0.000 description 1
- 229920001817 Agar Polymers 0.000 description 1
- 241001530056 Athelia rolfsii Species 0.000 description 1
- 229910021532 Calcite Inorganic materials 0.000 description 1
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 1
- 241000221785 Erysiphales Species 0.000 description 1
- 108010010803 Gelatin Proteins 0.000 description 1
- 235000007688 Lycopersicon esculentum Nutrition 0.000 description 1
- 206010034133 Pathogen resistance Diseases 0.000 description 1
- 229920001214 Polysorbate 60 Polymers 0.000 description 1
- 240000000528 Ricinus communis Species 0.000 description 1
- 235000004443 Ricinus communis Nutrition 0.000 description 1
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 1
- 240000003768 Solanum lycopersicum Species 0.000 description 1
- 241000209140 Triticum Species 0.000 description 1
- 235000021307 Triticum Nutrition 0.000 description 1
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 1
- 240000008042 Zea mays Species 0.000 description 1
- 235000005824 Zea mays ssp. parviglumis Nutrition 0.000 description 1
- 235000002017 Zea mays subsp mays Nutrition 0.000 description 1
- 235000010489 acacia gum Nutrition 0.000 description 1
- 239000001785 acacia senegal l. willd gum Substances 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000008272 agar Substances 0.000 description 1
- 150000004996 alkyl benzenes Chemical class 0.000 description 1
- 230000002528 anti-freeze Effects 0.000 description 1
- 229960000892 attapulgite Drugs 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 229940077388 benzenesulfonate Drugs 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- UDHMTPILEWBIQI-UHFFFAOYSA-N butyl naphthalene-1-sulfonate;sodium Chemical compound [Na].C1=CC=C2C(S(=O)(=O)OCCCC)=CC=CC2=C1 UDHMTPILEWBIQI-UHFFFAOYSA-N 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- OOCMUZJPDXYRFD-UHFFFAOYSA-L calcium;2-dodecylbenzenesulfonate Chemical compound [Ca+2].CCCCCCCCCCCCC1=CC=CC=C1S([O-])(=O)=O.CCCCCCCCCCCCC1=CC=CC=C1S([O-])(=O)=O OOCMUZJPDXYRFD-UHFFFAOYSA-L 0.000 description 1
- 239000004202 carbamide Substances 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 239000001768 carboxy methyl cellulose Substances 0.000 description 1
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 1
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 229910052570 clay Inorganic materials 0.000 description 1
- 235000005822 corn Nutrition 0.000 description 1
- 238000012136 culture method Methods 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 239000008367 deionised water Substances 0.000 description 1
- 229910021641 deionized water Inorganic materials 0.000 description 1
- GUJOJGAPFQRJSV-UHFFFAOYSA-N dialuminum;dioxosilane;oxygen(2-);hydrate Chemical compound O.[O-2].[O-2].[O-2].[Al+3].[Al+3].O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O GUJOJGAPFQRJSV-UHFFFAOYSA-N 0.000 description 1
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 description 1
- MOTZDAYCYVMXPC-UHFFFAOYSA-N dodecyl hydrogen sulfate Chemical compound CCCCCCCCCCCCOS(O)(=O)=O MOTZDAYCYVMXPC-UHFFFAOYSA-N 0.000 description 1
- 229940043264 dodecyl sulfate Drugs 0.000 description 1
- 239000002552 dosage form Substances 0.000 description 1
- 230000000857 drug effect Effects 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 235000013312 flour Nutrition 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- NVVZQXQBYZPMLJ-UHFFFAOYSA-N formaldehyde;naphthalene-1-sulfonic acid Chemical compound O=C.C1=CC=C2C(S(=O)(=O)O)=CC=CC2=C1 NVVZQXQBYZPMLJ-UHFFFAOYSA-N 0.000 description 1
- 229920000159 gelatin Polymers 0.000 description 1
- 239000008273 gelatin Substances 0.000 description 1
- 235000019322 gelatine Nutrition 0.000 description 1
- 235000011852 gelatine desserts Nutrition 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 229910052900 illite Inorganic materials 0.000 description 1
- 238000011081 inoculation Methods 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- UFHLMYOGRXOCSL-UHFFFAOYSA-N isoprothiolane Chemical compound CC(C)OC(=O)C(C(=O)OC(C)C)=C1SCCS1 UFHLMYOGRXOCSL-UHFFFAOYSA-N 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 description 1
- 239000010445 mica Substances 0.000 description 1
- 229910052618 mica group Inorganic materials 0.000 description 1
- 239000003607 modifier Substances 0.000 description 1
- 230000003020 moisturizing effect Effects 0.000 description 1
- 238000012544 monitoring process Methods 0.000 description 1
- 229910052901 montmorillonite Inorganic materials 0.000 description 1
- LCRMGUFGEDUSOG-UHFFFAOYSA-N naphthalen-1-ylsulfonyloxymethyl naphthalene-1-sulfonate;sodium Chemical compound [Na].C1=CC=C2C(S(=O)(OCOS(=O)(=O)C=3C4=CC=CC=C4C=CC=3)=O)=CC=CC2=C1 LCRMGUFGEDUSOG-UHFFFAOYSA-N 0.000 description 1
- VGIBGUSAECPPNB-UHFFFAOYSA-L nonaaluminum;magnesium;tripotassium;1,3-dioxido-2,4,5-trioxa-1,3-disilabicyclo[1.1.1]pentane;iron(2+);oxygen(2-);fluoride;hydroxide Chemical compound [OH-].[O-2].[O-2].[O-2].[O-2].[O-2].[F-].[Mg+2].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[K+].[K+].[K+].[Fe+2].O1[Si]2([O-])O[Si]1([O-])O2.O1[Si]2([O-])O[Si]1([O-])O2.O1[Si]2([O-])O[Si]1([O-])O2.O1[Si]2([O-])O[Si]1([O-])O2.O1[Si]2([O-])O[Si]1([O-])O2.O1[Si]2([O-])O[Si]1([O-])O2.O1[Si]2([O-])O[Si]1([O-])O2 VGIBGUSAECPPNB-UHFFFAOYSA-L 0.000 description 1
- 229910052625 palygorskite Inorganic materials 0.000 description 1
- 239000010451 perlite Substances 0.000 description 1
- 235000019362 perlite Nutrition 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
- 231100000572 poisoning Toxicity 0.000 description 1
- 230000000607 poisoning effect Effects 0.000 description 1
- 229920005646 polycarboxylate Polymers 0.000 description 1
- 229920001451 polypropylene glycol Polymers 0.000 description 1
- 235000019422 polyvinyl alcohol Nutrition 0.000 description 1
- 239000001267 polyvinylpyrrolidone Substances 0.000 description 1
- 229920000036 polyvinylpyrrolidone Polymers 0.000 description 1
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 description 1
- ULWHHBHJGPPBCO-UHFFFAOYSA-N propane-1,1-diol Chemical class CCC(O)O ULWHHBHJGPPBCO-UHFFFAOYSA-N 0.000 description 1
- 229910052903 pyrophyllite Inorganic materials 0.000 description 1
- 235000010413 sodium alginate Nutrition 0.000 description 1
- 239000000661 sodium alginate Substances 0.000 description 1
- 229940005550 sodium alginate Drugs 0.000 description 1
- PYODKQIVQIVELM-UHFFFAOYSA-M sodium;2,3-bis(2-methylpropyl)naphthalene-1-sulfonate Chemical compound [Na+].C1=CC=C2C(S([O-])(=O)=O)=C(CC(C)C)C(CC(C)C)=CC2=C1 PYODKQIVQIVELM-UHFFFAOYSA-M 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 230000008961 swelling Effects 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 150000003852 triazoles Chemical class 0.000 description 1
- DQJCHOQLCLEDLL-UHFFFAOYSA-N tricyclazole Chemical compound CC1=CC=CC2=C1N1C=NN=C1S2 DQJCHOQLCLEDLL-UHFFFAOYSA-N 0.000 description 1
- 230000001018 virulence Effects 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention discloses a kind of composition pesticide containing kasugarnycin and epoxiconazole, the composition pesticide includes active component kasugarnycin and epoxiconazole, and the weight of active component kasugarnycin and epoxiconazole ratio is 1 in the composition pesticide:50~50:1.There is obvious synergistic function after kasugarnycin and epoxiconazole compounding used in the present invention, improve prevention effect；Reduce dosage, so as to reduce cost and alleviate the pollution to environment.
Description
Technical field
The present invention relates to technical field of pesticide combination, and in particular to a kind of pesticide combination containing kasugarnycin and epoxiconazole
Thing.
Background technology
Rice is one of China's staple food crop, and national Monitoring of Paddy Rice Plant Area accounts for the 30% of cereal crops area, yield
Close to the half of total output of grain.Rice blast is one of important disease of rice, and the disease is widely distributed, and China South And North Rice Regions have
Occur.Plant disease epidemic area, can cause the significantly underproduction, the underproduction 40%~50% when serious, or even No kernels or seeds are gathered, as in a year of scarcity.At present, prevent and treat
The conventional dose of rice blast has tricyclazole, fenoxanil, Isoprothiolane, different rice blast net, kasugarnycin etc., if long-term continuous
Using single medicament, pathogen resistance can be caused to strengthen, prevention effect declines, and increases dose.Therefore, it is badly in need of exploitation to prevent harnessing the river
Efficient, the safe and environment-friendly composite bactericide of rice rice blast.
Chinese patent application 201410682289.X provides a kind of fenoxanil and the Bactericidal composite of kasugarnycin compounding
Thing, it can be used to prevent and treat rice blast, but its drug effect is up for improving.
The content of the invention
In view of this, for overcome the deficiencies in the prior art, the present invention, which provides, a kind of new contains kasugarnycin and epoxiconazole
Composition pesticide, said composition is efficient, safe and environment-friendly and be advantageous to germ resistance management.
A kind of composition pesticide containing kasugarnycin and epoxiconazole provided by the invention, the composition pesticide bag
Include active component kasugarnycin and epoxiconazole, active component kasugarnycin and epoxiconazole in the composition pesticide
Percentage by weight is 1:50~50:1.
Further, the active component kasugarnycin and epoxiconazole percentage by weight are 1:30~30:1.
Further, the weight sum of active component kasugarnycin and epoxiconazole accounts for composition pesticide in the composition pesticide
The percentage of gross weight is 5% one 70%, and remaining component is acceptable auxiliary element in agricultural chemicals.
Further, the weight sum of active component kasugarnycin and epoxiconazole accounts for composition pesticide in the composition pesticide
The percentage of gross weight is 10% one 50%, and remaining component is acceptable auxiliary element in agricultural chemicals.
According to the above-mentioned wettable powder composition containing kasugarnycin and epoxiconazole agricultural chemicals, include by weight percentage：
Active component kasugarnycin 1~50%, active component epoxiconazole 1~60%, dispersant 4~10%, wetting agent 2~10%, filler
Supply 100%.Its compound method：By active component kasugarnycin active compound, active component epoxiconazole raw drug, dispersant, wetting agent,
Filler is knocked down in blender and mixed, then is well mixed after airslide disintegrating mill crushes, that is, the wettable of the present composition is made
Powder product.
According to the above-mentioned water dispersible granules composition containing kasugarnycin and epoxiconazole agricultural chemicals, include by weight percentage：
Active component kasugarnycin 1~50%, active component epoxiconazole 1~60%, dispersant 2~12%, wetting agent 1~8%, disintegrant 1
~10%, binding agent 1~8%, filler supplies 100%.Its compound method：By active component kasugarnycin active compound, active component fluorine ring
Azoles active compound, dispersant, wetting agent, disintegrant, filler etc. are well mixed in the ratio of formula, through air-flow crushing into wettable powder
Agent, adds other auxiliary agents such as binding agent and material is made in a certain amount of water mixing extruding, is then dried, sieves this i.e. obtained hair
The water dispersible granules product of bright composition.
According to the above-mentioned suspension agent composition containing kasugarnycin and epoxiconazole agricultural chemicals, include by weight percentage：It is living
Property component kasugarnycin 1~50%, active component epoxiconazole 1~60%, wetting agent 2~10%, dispersant 2~10%, defoamer
0.1~2%, thickener 0.1~2%, antifreezing agent 0.1~10%, add water to 100%.Its compound method：Activity in being formulated by more than
Mixed in composition kasugarnycin active compound, active component epoxiconazole raw drug, wetting agent, dispersant input mixing kettle by high speed shear
Close, then add defoamer, thickener, antifreezing agent, ball milling 2~3 hours in ball milling kettle so that diameter of particle in below 5mm,
The suspending agent product of the present composition is made.
According to the above-mentioned water emulsion composition containing kasugarnycin and epoxiconazole agricultural chemicals, include by weight percentage：It is living
Property component kasugarnycin 1~50%, active component epoxiconazole 1~60%, solvent 5~30%, emulsifying agent 3~15%, is added water to
100%.Its compound method：Active component epoxiconazole, solvent, emulsifying agent are added together, make to be dissolved into homogeneous oil phase；By activity
Component kasugarnycin and water are mixed to prepare aqueous phase；Under high velocity agitation, it is oil phase is mixed with water, the present composition is made
Aqueous emulsion product.
According to the above-mentioned micro-emulsion composition containing kasugarnycin and epoxiconazole agricultural chemicals, include by weight percentage：It is living
Property component kasugarnycin 1~50%, active component epoxiconazole 1~60%, solvent 5~30%, emulsifying agent 3~25%, is added water to
100%.Its compound method：Active component epoxiconazole, solvent, emulsifying agent are added together, make to be dissolved into homogeneous oil phase；By activity
Component kasugarnycin and water are mixed to prepare aqueous phase；Under agitation, it is oil phase is mixed with water, the micro emulsion of the present composition is made
Agent product.
Surfactant（Emulsifying agent）, dispersant, wetting agent belong to auxiliary agent, it is auxiliary agent in composition pesticide of the present invention, molten
Agent and filler（Carrier）It is known in those skilled in the art.According to different dosage forms, art technology can be also contained in composition
Thickener, defoamer, disintegrant, binding agent or antifreeze etc. well known to personnel.
The auxiliary agent is selected from：600# phosphates, sodium lignin sulfonate, alkyl benzene sulfonate calcium salt, AEO,
Dispersing agent MF, APES phosphate, alkyl phenol formaldehyde resin polyoxyethylene ether, the condensation of phosphate naphthalenesulfonateformaldehyde formaldehyde
It is thing, condensation compound of methyl naphthalene sulfonic acid and formaldehyde, spaonin powder, sodium metnylene bis-naphthalene sulfonate, sodium lignin sulfonate, sldium lauryl sulfate, poly-
Oxygen ethene sorbitan fatty acid ester, Nekal BX, sodium methylene bis-naphthalene sulfonate, sodium butylnaphthalenesulfonate, polymer wood quality
Modifier, agriculture breast 600#, agriculture breast 1601#, dispersant NNO, lauryl sodium sulfate, polycarboxylate, phenethyl phenol polyoxypropylene
APEO, APES, three phenethyl phenol polyethenoxy ethers, dinaphthylmethanedisulfonic acid sodium, Lauxite
Performed polymer, sodium alginate etc..
The solvent is polyvinylpyrrolidone, cyclohexanone, ethanol, N- methyl adjoin pyrrolidone, methyl naphthalene, isopropanol, first
One or more in alcohol, dimethylbenzene etc..
The filler（Carrier）It is selected from：White carbon, kaolin, precipitated calcium carbonate, talcum powder, clay, diatomite, swelling
Soil, attapulgite, pyrophyllite, montmorillonite, clay, illite, mica powder, perlite, calcite, deionized water, water or castor-oil plant
One or more in oil etc..
The thickener is selected from：Arabic gum, xanthans, white carbon etc..
The defoamer is selected from：Organosilicon etc..
The disintegrant is selected from：Sodium acid carbonate, urea, ammonium sulfate etc..
The binding agent is selected from：Starch, gelatin, corn flour, polyvinyl alcohol, carboxymethyl cellulose etc..
The antifreezing agent is selected from：Polyvinyl alcohol, ethylene glycol, propane diols, glycerine etc..
Kasugarnycin, molecular formula：C14H25N3O9；Chemical structural formula is：
Kasugarnycin is a kind of biological bactericide a kind of as caused by little Jin actinomyces, has very strong interior sorptivety permeability,
There is preventive and therapeutic action simultaneously, its therapeutic action is more notable, is currently used primarily in the diseases such as preventing and treating rice blast.
Epoxiconazole, molecular formula：；Chemical constitution is：
Epoxiconazole is absorbability triazole bactericidal agent, mainly prevent and treat wheat rust, powdery mildew, rice blast, banded sclerotial blight,
The diseases such as sigatoka.
The bactericidal composition of the present invention can apply to prevent and treat in plant disease agriculturally, especially prevent and treat rice rice blast
Disease.
The method of the composition generally use spraying of the present invention uses, and also can take other according to agriculture needs of production
Use technology.
Compared with prior art, the beneficial effects of the present invention are：
1. there is obvious synergistic function after the kasugarnycin and epoxiconazole compounding used in the present invention, improve anti-
Control effect；
2. reduce dosage after the kasugarnycin and epoxiconazole compounding used in the present invention, so as to reduce cost and subtract
The light pollution to environment.
Embodiment
The present invention is further illustrated in the following embodiments, and this does not limit the scope of the invention.
Toxicity determines embodiment
Kasugarnycin compounds the Toxicity Determination to rice blast fungus with epoxiconazole
Subjects：Pick up from the rice blast fungus in field
Test method：Reference≤People's Republic of China (PRC) agricultural industry criteria NY/Tll54.7 1 >=, pot-culture method.Choosing
The tri-leaf period rice seedlings that growth potential is consistent are taken, per the young plant of basin 2, each processing is from 5 basins for examination rice seedling.By Pyricularia oryzae in tomato
Cultivated on oat-agar cultures base, with spore under sterile washing after production spore, be made 1 × 105Individual spore/mL suspension, uniformly
Ground spray inoculation is inoculated with black polybag moisturizing culture 24h in rear enclosure on for examination rice seedling.After being inoculated with 24h, chemicals treatment is carried out,
Each medicament sets 5 concentration gradients, is sprayed with Potter spray towers under 50Psl pressure, per basin about 5mL., will after spray
Rice seedling is placed in 25 DEG C or so, relative humidity>Cultivate under conditions of 90%, investigated after 7d according to the morbidity grade scale of rice blast
The disease index of whole strain blade, and calculate prevention effect.
Prevention effect is converted into niqueMin (y), liquor strength (ug/ml) is converted into logarithm value (x), with least square method
Concentration EC in calculating virulence equation and suppressing50.The toxicity index and co-toxicity coefficient (CTC) of medicament are calculated according to the abundant methods of Sun Yun.
Survey toxicity index (ATI)=(standard agent EC50/ reagent agent EC50) ×100
A percentage composition+B medicament toxicity index x mixtures in theoretical toxicity index (TTI)=A medicament toxicity index × mixture
Middle B percentage composition
Co-toxicity coefficient (CTC)=[mixture actual measurement toxicity index (ATI)/mixture theoretical toxicity index (TTI) × 100
When CTC≤80, then composition shows as Hangzhoupro effect short of money, when 80<CTC<120, then composition show as summation action,
When CTC >=120, then composition shows as synergistic effect.
Toxicity Determination result see the table below 1：
The kasugarnycin of table 1 compounds the Toxicity Determination result to rice blast fungus with epoxiconazole
Toxicity Determination result shows that kasugarnycin is matched 1 with epoxiconazole:50~50:Between 1, to rice rice blast
Germ has synergistic effect, especially 1:30~30:Between 1, for co-toxicity coefficient more than 150, synergy is more obvious.
The composition pesticide of the present invention can be prepared into any one formulation of suitable agricultural use with known method, than
Preferable formulation is wettable powder, suspending agent, water dispersible granules, aqueous emulsion and microemulsion.
In order to make the purpose , technical scheme and advantage of the present invention be clearer, present invention specific examples below
Illustrate, but the present invention is limited to absolutely not these examples.
Embodiment 1:51% kasugarnycin epoxiconazole water dispersant
Ingredient names percentage by weight
Kasugarnycin 1.0%
Epoxiconazole 50.0%
Lauryl sodium sulfate (wetting agent) 4.0%
Sodium lignin sulfonate (dispersant) 5.0%
Ammonium sulfate (disintegrant) 4.0%
Starch（Binding agent） 2.0%
Precipitated calcium carbonate (filler) complements to 100.0%
Active component, dispersant, wetting agent, disintegrant and filler are well mixed in the ratio of formula, through air-flow crushing
Into wettable powder, add a certain amount of water mixing extruding and make material, 51% kasugarnycin epoxiconazole is obtained after drying and sieving
Water dispersible granules.
Embodiment 2：31% kasugarnycin epoxiconazole suspension concentrate
Ingredient names percentage by weight
Kasugarnycin 1.0%
Epoxiconazole 30.0%
Dispersant NNO（Dispersant） 3.0%
Alkyl phenol formaldehyde resin polyoxyethylene ether（Wetting agent） 2.0%
Polyoxyethylene sorbitan fatty acid ester（Wetting agent） 1.0%
Xanthans (thickener) 0.3%
Organosilicon (defoamer) 0.2%
Ethylene glycol (antifreezing agent) 3.0%
Water complements to 100.0%
The each components such as active component, dispersant, thickener, wetting agent and water are well mixed in the ratio of formula, through grinding
31% kasugarnycin epoxiconazole suspension concentrate is obtained after mill and/or high speed shear.
Embodiment 3:10% kasugarnycin epoxiconazole aqueous emulsion
Ingredient names percentage by weight
Kasugarnycin 5.0%
Epoxiconazole 5.0%
N monomethyls adjoin pyrrolidone (solvent) 10.0%
Calcium dodecyl benzene sulfonate (emulsifying agent) 5.0%
Agriculture breast 600# (emulsifying agent) 5.0%
Water complements to 100.0%
Epoxiconazole raw drug, solvent, emulsifying agent are added together, make to be dissolved into homogeneous oil phase；Kasugarnycin and water are mixed
Aqueous phase is made；Under high velocity agitation, it is oil phase is mixed with water, 10% kasugarnycin epoxiconazole aqueous emulsion is made.
Embodiment 4:70% kasugarnycin epoxiconazole water dispersant
Ingredient names percentage by weight
Kasugarnycin 10.0%
Epoxiconazole 60.0%
Lauryl sodium sulfate (wetting agent) 3.0%
Sodium lignin sulfonate (dispersant) 4.0%
Ammonium sulfate (disintegrant) 3.0%
Starch（Binding agent） 2.0%
Precipitated calcium carbonate (filler) complements to 100.0%
Active component, dispersant, wetting agent, disintegrant and filler are well mixed in the ratio of formula, through air-flow crushing
Into wettable powder, add a certain amount of water mixing extruding and make material, 70% kasugarnycin epoxiconazole is obtained after drying and sieving
Water dispersible granules.
Embodiment 5：5% kasugarnycin epoxiconazole microemulsion
Ingredient names percentage by weight
Kasugarnycin 1.0%
Epoxiconazole 4.0%
Isopropanol (solvent) 15.0%
N monomethyls adjoin pyrrolidone (solvent) 10.0%
Agriculture breast 600# (emulsifying agent) 8.0%
Agriculture breast 1601# (emulsifying agent) 8.0%
Water complements to 100.0%
Epoxiconazole raw drug, solvent, emulsifying agent are added together, make to be dissolved into homogeneous oil phase；Kasugarnycin and water are mixed
Aqueous phase is made；Under agitation, it is oil phase is mixed with water uniformly, 5% kasugarnycin epoxiconazole microemulsion is made.
Embodiment 6：31% kasugarnycin epoxiconazole water dispersant
Ingredient names percentage by weight
Kasugarnycin 30.0%
Epoxiconazole 1.0%
Lauryl sodium sulfate (wetting agent) 5.0%
Sodium lignin sulfonate (dispersant) 6.0%
Ammonium sulfate (disintegrant) 5.0%
Starch（Binding agent） 2.0%
Precipitated calcium carbonate (filler) complements to 100.0%
Active component, dispersant, wetting agent, disintegrant and filler are well mixed in the ratio of formula, through air-flow crushing
Into wettable powder, add a certain amount of water mixing extruding and make material, 31% kasugarnycin epoxiconazole is obtained after drying and sieving
Water dispersible granules.
Embodiment 7:51% kasugarnycin epoxiconazole wettable powder
Ingredient names percentage by weight
Kasugarnycin 50.0%
Epoxiconazole 1.0%
Lauryl sodium sulfate (wetting agent) 3.0%
Sodium lignin sulfonate (dispersant) 5.0%
White Carbon black (filler) 10.0%
Kaolin (filler) complements to 100.0%
Active component, various auxiliary agents and filler etc. are sufficiently mixed in the ratio of formula, after ultra-fine pulverizer disintegrating, i.e.,
Obtain 51% kasugarnycin epoxiconazole wettable powder.
Embodiment 8：50% kasugarnycin epoxiconazole microemulsion
Ingredient names percentage by weight
Kasugarnycin 4.0%
Epoxiconazole 46.0%
Isopropanol (solvent) 15.0%
N monomethyls adjoin pyrrolidone (solvent) 10.0%
Agriculture breast 600# (emulsifying agent) 8.0%
Agriculture breast 1601# (emulsifying agent) 8.0%
Water complements to 100.0%
Epoxiconazole raw drug, solvent, emulsifying agent are added together, make to be dissolved into homogeneous oil phase；Kasugarnycin and water are mixed
Aqueous phase is made；Under agitation, it is oil phase is mixed with water uniformly, 50% kasugarnycin epoxiconazole microemulsion is made.
Above-described embodiment is applied to preventing and treating rice blast, and different preparation compositions are diluted with water spraying to rice blast
Prevention effect be shown in Table 2.
Prevention effect of the 2 different preparation compositions of table to rice blast
7 days after dispenser it can be seen from the result of the test of table 2, kasugarnycin is with epoxiconazole complex composition to rice rice blast
The preventive effect of disease is significantly higher than single dose comparison medicament more than 85%.Each processing is tested not occur the adverse reactions such as poisoning and ask
Topic.Thus illustrate that kasugarnycin is significantly better than single dose with epoxiconazole compounded combination using actual prevention effect, the result and interior
Raw embodiment experimental result of surveying is consistent, and illustrates that the two compounding has significant synergies.
According to routine observation after dispenser, under treatment dosage, rice growth is normal, has no any adverse reaction, right
Rice safety.
Kasugarnycin can reduce dosage with epoxiconazole compounding use, reduce the pollution to environment, while can delay medicine
The generation of agent resistance problem, agricultural synthesis is administered have it is important significant.
Although by referring to some preferred embodiments of the present invention, invention has been described, this area
It is to be appreciated by one skilled in the art that various changes can be made to it in the form and details, without departing from appended
The spirit and scope of the present invention that claims are limited.
Claims (10)
1. a kind of composition pesticide containing kasugarnycin and epoxiconazole, the composition pesticide include active component kasugarnycin and
Epoxiconazole, the weight of active component kasugarnycin and epoxiconazole ratio is 1 in the composition pesticide：10~10:1；Described agriculture
Drug composition includes or not comprising other activity.
2. composition pesticide according to claim 1, active component kasugarnycin and epoxiconazole in the composition pesticide
Weight sum account for the percentage of composition pesticide gross weight as 5% one 70%, remaining component is that acceptable aids in agricultural chemicals
Composition.
3. composition pesticide according to claim 2, active component kasugarnycin and epoxiconazole in the composition pesticide
Weight sum account for the percentage of composition pesticide gross weight as 10% one 50%.
4. according to the composition pesticide described in claim 1-3 any one, described composition pesticide is wettable powder group
Compound, water dispersible granules composition, suspension agent composition, water emulsion composition or micro-emulsion composition.
5. composition pesticide according to claim 4, described composition pesticide is wettable powder composition, by weight
Percentages include：Active component kasugarnycin 1~50%, active component epoxiconazole 1~60%, dispersant 4~10%, wetting
Agent 2~10%, filler supplies 100%；Its compound method：By active component kasugarnycin active compound, active component epoxiconazole raw drug, divide
Powder, wetting agent, filler are knocked down in blender and mixed, then are well mixed after airslide disintegrating mill crushes, that is, are made of the present invention group
The wettable powder product of compound.
6. composition pesticide according to claim 4, described composition pesticide is water dispersible granules composition, by weight
Percentages include：Active component kasugarnycin 1~50%, active component epoxiconazole 1~60%, dispersant 2~12%, wetting agent 1
~8%, disintegrant 1~10%, binding agent 1~8%, filler supplies 100%；Its compound method：By active component kasugarnycin active compound,
Active component epoxiconazole raw drug, dispersant, wetting agent, disintegrant, filler etc. are well mixed in the ratio of formula, through air-flow crushing
Into wettable powder, add binding agent and material is made in a certain amount of water mixing extruding, be then dried, sieve i.e. obtained moisture
Shot agent product.
7. composition pesticide according to claim 4, described composition pesticide is suspension agent composition, by weight percentage
Include than meter：Active component kasugarnycin 1~50%, active component epoxiconazole 1~60%, wetting agent 2~10%, dispersant 2
~10%, defoamer 0.1~2%, thickener 0.1~2%, antifreezing agent 0.1~10%, add water to 100%；Its compound method：By more than
Pass through in active component kasugarnycin active compound, active component epoxiconazole raw drug, wetting agent, dispersant input mixing kettle in formula
High speed shear mixes, and then adds defoamer, thickener, antifreezing agent, ball milling 2~3 hours in ball milling kettle so that diameter of particle
In below 5mm, suspending agent product is made.
8. composition pesticide according to claim 4, described composition pesticide is water emulsion composition, by weight percentage
Include than meter：Active component kasugarnycin 1~50%, active component epoxiconazole 1~60%, solvent 5~30%, emulsifying agent 3~
15%, add water to 100%；Its compound method：Active component epoxiconazole, solvent, emulsifying agent are added together, make to be dissolved into uniform oil
Phase；Active component kasugarnycin and water are mixed to prepare aqueous phase；Under high velocity agitation, it is oil phase is mixed with water, water and milk is made
Agent product.
9. composition pesticide according to claim 4, described composition pesticide is micro-emulsion composition, by weight percentage
Include than meter：Active component kasugarnycin 1~50%, active component epoxiconazole 1~60%, solvent 5~30%, emulsifying agent 3~
25%, add water to 100%；Its compound method：Active component epoxiconazole, solvent, emulsifying agent are added together, make to be dissolved into uniform oil
Phase；Active component kasugarnycin and water are mixed to prepare aqueous phase；Under agitation, it is oil phase is mixed with water, microemulsion production is made
Product.
10. application of the composition pesticide in rice blast is prevented and treated described in claim 1-9 any one.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510899556.3A CN105394047B (en) | 2015-12-09 | 2015-12-09 | A kind of composition pesticide containing kasugarnycin and epoxiconazole |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510899556.3A CN105394047B (en) | 2015-12-09 | 2015-12-09 | A kind of composition pesticide containing kasugarnycin and epoxiconazole |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN105394047A CN105394047A (en) | 2016-03-16 |
| CN105394047B true CN105394047B (en) | 2017-11-14 |
Family
ID=55460099
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510899556.3A Active CN105394047B (en) | 2015-12-09 | 2015-12-09 | A kind of composition pesticide containing kasugarnycin and epoxiconazole |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN105394047B (en) |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA2459698C (en) * | 2001-09-07 | 2010-02-23 | Syngenta Participations Ag | Surfactant systems for agriculturally active compounds |
| CN102100232B (en) * | 2009-12-16 | 2014-10-29 | 北京绿色农华植保科技有限责任公司 | Preparation method of chunleimeisu and difenoconazole powder |
| CN102379291A (en) * | 2010-08-27 | 2012-03-21 | 青岛奥迪斯生物科技有限公司 | Bactericidal combination containing difenoconazole and kasugamycin |
| CN103875494B (en) * | 2014-04-14 | 2015-09-16 | 吴洁远 | Two season super hybridization rice standardized planting method |
-
2015
- 2015-12-09 CN CN201510899556.3A patent/CN105394047B/en active Active
Also Published As
| Publication number | Publication date |
|---|---|
| CN105394047A (en) | 2016-03-16 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN101690483B (en) | Bactericidal composition containing triazole class compounds | |
| CN105475303B (en) | A kind of composition pesticide containing kasugarnycin and gold alloy hydride | |
| CN102197818A (en) | Bactericidal composition | |
| CN105961399B (en) | Bactericidal composition and its application | |
| CN102630679B (en) | Pesticide composition containing orysastrobin | |
| CN101642104A (en) | Sterilization composition containing fenoxanil | |
| CN101849546A (en) | Pesticide composition | |
| CN102669100B (en) | Oxine-copper and validamycin compound pesticide composition and preparation method and application thereof | |
| CN102428930A (en) | Cyanoxastrobin-containing bactericidal composition | |
| CN101664033B (en) | Ethirimol-contained bactericide combination | |
| CN102715173B (en) | Bactericidal composition containing phenylate diazole and fluoxastrobin and application of bactericidal composition | |
| CN101697725A (en) | Pesticide composition containing protective bactericide | |
| CN101356922B (en) | Composition containing ethiprole and imidacloprid with synergistic disinsection action | |
| CN103355298A (en) | Bactericidal composition containing fenhexamid and antibiotics | |
| CN102696625A (en) | Sterilization composition containing difenoconazole and picoxystrobin and application of sterilization composition | |
| CN103190420B (en) | Propiconazole-containing bactericidal composition | |
| CN102972402B (en) | Kasugamycin-containing pesticide composition | |
| CN105394047B (en) | A kind of composition pesticide containing kasugarnycin and epoxiconazole | |
| CN104026136B (en) | Agricultural fungicidal composition | |
| CN106135232B (en) | bactericidal composition | |
| CN102715168A (en) | Sterilization combination containing phenylate diazole and azoxystrobin and application thereof | |
| CN106689148A (en) | Pesticide composition containing dichloroxazole and dimethomorph | |
| CN104604931A (en) | Sterilization composition containing bixafen and iprobenfos as well as application of sterilization composition | |
| CN108782569A (en) | A kind of bactericidal composition containing triticonazole and amino-oligosaccharide | |
| CN104068023B (en) | A kind of agricultural bactericidal composition |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant |