CN105176270A - Anti-stripping external wall coating material and preparation method thereof - Google Patents
Anti-stripping external wall coating material and preparation method thereof Download PDFInfo
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- CN105176270A CN105176270A CN201510682328.0A CN201510682328A CN105176270A CN 105176270 A CN105176270 A CN 105176270A CN 201510682328 A CN201510682328 A CN 201510682328A CN 105176270 A CN105176270 A CN 105176270A
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Abstract
The invention discloses an anti-stripping external wall coating material. The anti-stripping external wall coating material is prepared from the following ingredients in parts by weight: 55 to 68 parts of epoxy-acrylic resin, 25 to 37 parts of polystyrene rubber, 6 to 9 parts of mica powder, 3 to 8 parts of nano silicon dioxide, 1 to 5 parts of nano titanium dioxide, 2 to 3 parts of zinc chloride, 1 to 3 parts of nano sea-foam stone powder, 4 to 8 parts of talcum powder, 12 to 24 parts of styrene-acrylic emulsion, 1 to 3 parts of chlorinated paraffin, 2 to 5 parts of butyl zirconate, 4 to 8 parts of butyl titanate, 4 to 8 parts of diphenylamine, 26 to 46 parts of deionized water, 12 to 16 parts of urea, 6 to 12 parts of polyacrylamide, 3 to 9 parts of dispersing agent, 2 to 8 parts of emulsifying agent, 1 to 5 parts of titanate coupler and 6 to 9 parts of antioxidant TNP (Trinitrophenyl Group). According to the anti-stripping external wall coating material disclosed by the invention, the epoxy-acrylic resin is modified through the nano silicon dioxide, so that the strength of the epoxy-acrylic resin is effectively increased, and meanwhile, the water resistance, the hot water resistance, the drug resistance, the cohesiveness and the toughness are increased.
Description
Technical field
The present invention relates to a kind of coating and preparation method thereof, a kind of antistripping exterior coating and preparation method thereof, belongs to technical field of coatings specifically.
Background technology
Coating is the requisite finishing material of building materials field, especially exterior coating, exist wrinkling, come off, the various problems such as variable color, its performance directly has influence on the attractive in appearance of buildings and work-ing life.Seek strong adhesion, the environmental protection coating material of uvioresistant, not dry linting becomes a kind of inexorable trend.The reason of the problem such as cause exterior coating to occur variable color, to peel off has a lot, and the weathering of the fracture and physically trapping particle that mainly comprise C-C key and C-O key in polymerized emulsion thing comes off.
Summary of the invention
Technical problem to be solved by this invention is, for the shortcoming of above prior art, proposes a kind of antistripping exterior coating and preparation method thereof, there is excellent antistripping and water tolerance, the performance of its cohesiveness and toughness is excellent, as exterior coating, also has good weather resistance simultaneously.
In order to solve the problems of the technologies described above, technical scheme of the present invention is achieved in the following ways: provide a kind of antistripping exterior coating, this coating is counted by weight and is comprised following component: epoxy acrylic resin 55-68 part, polystyrene rubber 25-37 part, mica powder 6-9 part, nano silicon 3-8 part, nano titanium oxide 1-5 part, zinc chloride 2-3 part, Nano sepiolite powder 1-3 part, talcum powder 4-8 part, benzene emulsion 12-24 part, clorafin 1-3 part, tetrabutyl zirconate 2-5 part, butyl (tetra) titanate 4-8 part, pentanoic 4-8 part, deionized water 26-46 part, urea 12-16 part, polyacrylamide 6-12 part, dispersion agent 3-9 part, emulsifying agent 2-8 part, titanate coupling agent 1-5 part, antioxidant TNP: 6-9 part,
Described dispersion agent is one or both in carboxymethyl cellulose, Sodium hexametaphosphate 99 or water glass; Described emulsifying agent is polyoxyethylene octylphenol ether or styroyl phenol polyoxyethylene polyoxypropylene ether.
The technical scheme that the present invention limits further is: aforesaid antistripping exterior coating, this coating is counted by weight and is comprised following component: epoxy acrylic resin 55 parts, polystyrene rubber 25 parts, mica powder 6 parts, nano silicon 3 parts, nano titanium oxide 1 part, zinc chloride 2 parts, Nano sepiolite powder 1 part, talcum powder 4 parts, benzene emulsion 12 parts, clorafin 1 part, tetrabutyl zirconate 2 parts, butyl (tetra) titanate 4 parts, pentanoic 4 parts, deionized water 26 parts, 12 parts, urea, polyacrylamide 6 parts, dispersion agent 3 parts, emulsifying agent 2 parts, titanate coupling agent 1 part, antioxidant TNP: 6 parts,
Described dispersion agent is one or both in carboxymethyl cellulose, Sodium hexametaphosphate 99 or water glass; Described emulsifying agent is polyoxyethylene octylphenol ether or styroyl phenol polyoxyethylene polyoxypropylene ether.
Aforesaid antistripping exterior coating, this coating is counted by weight and is comprised following component: epoxy acrylic resin 62 parts, polystyrene rubber 32 parts, mica powder 7 parts, nano silicon 5 parts, nano titanium oxide 3 parts, zinc chloride 3 parts, Nano sepiolite powder 2 parts, talcum powder 6 parts, benzene emulsion 17 parts, clorafin 2 parts, tetrabutyl zirconate 4 parts, butyl (tetra) titanate 6 parts, pentanoic 6 parts, deionized water 32 parts, 14 parts, urea, polyacrylamide 10 parts, dispersion agent 6 parts, emulsifying agent 6 parts, titanate coupling agent 3 parts, antioxidant TNP: 7 parts;
Described dispersion agent is one or both in carboxymethyl cellulose, Sodium hexametaphosphate 99 or water glass; Described emulsifying agent is polyoxyethylene octylphenol ether or styroyl phenol polyoxyethylene polyoxypropylene ether.
Aforesaid antistripping exterior coating, this coating is counted by weight and is comprised following component: epoxy acrylic resin 68 parts, polystyrene rubber 37 parts, mica powder 9 parts, nano silicon 8 parts, nano titanium oxide 5 parts, zinc chloride 3 parts, Nano sepiolite powder 3 parts, talcum powder 8 parts, benzene emulsion 24 parts, clorafin 3 parts, tetrabutyl zirconate 5 parts, butyl (tetra) titanate 8 parts, pentanoic 8 parts, deionized water 46 parts, 16 parts, urea, polyacrylamide 12 parts, dispersion agent 9 parts, emulsifying agent 8 parts, titanate coupling agent 5 parts, antioxidant TNP: 9 parts;
Described dispersion agent is one or both in carboxymethyl cellulose, Sodium hexametaphosphate 99 or water glass; Described emulsifying agent is polyoxyethylene octylphenol ether or styroyl phenol polyoxyethylene polyoxypropylene ether.
A preparation method for antistripping exterior coating, comprises the following steps:
(1) first will dispersion agent heat after be dissolved in deionized water, be uniformly mixed after adding the tetrabutyl zirconate of 1/2nd amounts and butyl (tetra) titanate, stirring velocity is 200-250r/min, and stirring 10-15min stirs;
(2) in the slurry in step (1), add mica powder, zinc chloride, Nano sepiolite powder and talcum powder, and regulate stirring velocity to 300-350r/min, stir 10-20min and make slurry;
(3) tetrabutyl zirconate of epoxy acrylic resin and polystyrene rubber and residual content and butyl (tetra) titanate are mixed, under 250-300r/min, stir 20-30min obtain mixed emulsion; Then nano silicon, nano titanium oxide and dispersion agent are carried out being uniformly mixed and stir 15-20min under 100-200r/min, in nano material, add titanate coupling agent, continue to stir 30-50min at 200-300r/min and obtain modified epoxy acrylate resin slurry;
(4) the modified epoxy acrylate resin slurry that slurry obtained in step (2) and step (3) obtain is added in benzene emulsion, again regulate stirring velocity to 150-200r/min, stir 1-3h;
(5) in whipping process, add remaining furnish component, continue to stir 20-30min, after leaving standstill, obtain antistripping exterior coating.
The invention has the beneficial effects as follows: the present invention, by nano-silicon dioxide modified epoxy acrylic resin, effectively improves the intensity of epoxy acrylic resin, also improves water-based, hot water resistance, resistance physical property, cohesiveness, toughness etc. simultaneously; Modified epoxy acrylate resin and polystyrene rubber are as major ingredient and add deionized water, substantially increase sticking power of the present invention, hardness, wear resistance and consistency, reduce set shrinking percentage, stable after making paint solidification, and make snappiness of the present invention good, also can reduce water-absorbent of the present invention.
Embodiment
The present invention is described in further detail below:
embodiment 1
A kind of antistripping exterior coating that the present embodiment provides, this coating is counted by weight and is comprised following component: epoxy acrylic resin 55 parts, polystyrene rubber 25 parts, mica powder 6 parts, nano silicon 3 parts, nano titanium oxide 1 part, zinc chloride 2 parts, Nano sepiolite powder 1 part, talcum powder 4 parts, benzene emulsion 12 parts, clorafin 1 part, tetrabutyl zirconate 2 parts, butyl (tetra) titanate 4 parts, pentanoic 4 parts, deionized water 26 parts, 12 parts, urea, polyacrylamide 6 parts, carboxymethyl cellulose 3 parts, polyoxyethylene octylphenol ether 2 parts, titanate coupling agent 1 part, antioxidant TNP: 6 parts.
The preparation method of the antistripping exterior coating of the present embodiment, comprises the following steps:
(1) first will carboxymethyl cellulose heat after be dissolved in deionized water, be uniformly mixed after adding the tetrabutyl zirconate of 1/2nd amounts and butyl (tetra) titanate, stirring velocity is 200-250r/min, and stirring 10-15min stirs;
(2) in the slurry in step (1), add mica powder, zinc chloride, Nano sepiolite powder and talcum powder, and regulate stirring velocity to 300-350r/min, stir 10-20min and make slurry;
(3) tetrabutyl zirconate of epoxy acrylic resin and polystyrene rubber and residual content and butyl (tetra) titanate are mixed, under 250-300r/min, stir 20-30min obtain mixed emulsion; Then nano silicon, nano titanium oxide and dispersion agent are carried out being uniformly mixed and stir 15-20min under 100-200r/min, in nano material, add titanate coupling agent, continue to stir 30-50min at 200-300r/min and obtain modified epoxy acrylate resin slurry;
(4) the modified epoxy acrylate resin slurry that slurry obtained in step (2) and step (3) obtain is added in benzene emulsion, again regulate stirring velocity to 150-200r/min, stir 1-3h;
(5) in whipping process, add remaining furnish component, continue to stir 20-30min, after leaving standstill, obtain antistripping exterior coating.
embodiment 2
A kind of antistripping exterior coating that the present embodiment provides, this coating is counted by weight and is comprised following component: epoxy acrylic resin 62 parts, polystyrene rubber 32 parts, mica powder 7 parts, nano silicon 5 parts, nano titanium oxide 3 parts, zinc chloride 3 parts, Nano sepiolite powder 2 parts, talcum powder 6 parts, benzene emulsion 17 parts, clorafin 2 parts, tetrabutyl zirconate 4 parts, butyl (tetra) titanate 6 parts, pentanoic 6 parts, deionized water 32 parts, 14 parts, urea, polyacrylamide 10 parts, Sodium hexametaphosphate 99 6 parts, 6 parts, styroyl phenol polyoxyethylene polyoxypropylene ether, titanate coupling agent 3 parts, antioxidant TNP: 7 parts.
The preparation method of the antistripping exterior coating of the present embodiment, comprises the following steps:
(1) first will Sodium hexametaphosphate 99 heat after be dissolved in deionized water, be uniformly mixed after adding the tetrabutyl zirconate of 1/2nd amounts and butyl (tetra) titanate, stirring velocity is 200-250r/min, and stirring 10-15min stirs;
(2) in the slurry in step (1), add mica powder, zinc chloride, Nano sepiolite powder and talcum powder, and regulate stirring velocity to 300-350r/min, stir 10-20min and make slurry;
(3) tetrabutyl zirconate of epoxy acrylic resin and polystyrene rubber and residual content and butyl (tetra) titanate are mixed, under 250-300r/min, stir 20-30min obtain mixed emulsion; Then nano silicon, nano titanium oxide and dispersion agent are carried out being uniformly mixed and stir 15-20min under 100-200r/min, in nano material, add titanate coupling agent, continue to stir 30-50min at 200-300r/min and obtain modified epoxy acrylate resin slurry;
(4) the modified epoxy acrylate resin slurry that slurry obtained in step (2) and step (3) obtain is added in benzene emulsion, again regulate stirring velocity to 150-200r/min, stir 1-3h;
(5) in whipping process, add remaining furnish component, continue to stir 20-30min, after leaving standstill, obtain antistripping exterior coating.
embodiment 3
A kind of antistripping exterior coating that the present embodiment provides, this coating is counted by weight and is comprised following component: epoxy acrylic resin 68 parts, polystyrene rubber 37 parts, mica powder 9 parts, nano silicon 8 parts, nano titanium oxide 5 parts, zinc chloride 3 parts, Nano sepiolite powder 3 parts, talcum powder 8 parts, benzene emulsion 24 parts, clorafin 3 parts, tetrabutyl zirconate 5 parts, butyl (tetra) titanate 8 parts, pentanoic 8 parts, deionized water 46 parts, 16 parts, urea, polyacrylamide 12 parts, water glass 9 parts, 8 parts, ethyl phenol polyoxyethylene polyoxypropylene ether, titanate coupling agent 5 parts, antioxidant TNP: 9 parts.
The preparation method of the antistripping exterior coating of the present embodiment, comprises the following steps:
(1) first will water glass heat after be dissolved in deionized water, be uniformly mixed after adding the tetrabutyl zirconate of 1/2nd amounts and butyl (tetra) titanate, stirring velocity is 200-250r/min, and stirring 10-15min stirs;
(2) in the slurry in step (1), add mica powder, zinc chloride, Nano sepiolite powder and talcum powder, and regulate stirring velocity to 300-350r/min, stir 10-20min and make slurry;
(3) tetrabutyl zirconate of epoxy acrylic resin and polystyrene rubber and residual content and butyl (tetra) titanate are mixed, under 250-300r/min, stir 20-30min obtain mixed emulsion; Then nano silicon, nano titanium oxide and dispersion agent are carried out being uniformly mixed and stir 15-20min under 100-200r/min, in nano material, add titanate coupling agent, continue to stir 30-50min at 200-300r/min and obtain modified epoxy acrylate resin slurry;
(4) the modified epoxy acrylate resin slurry that slurry obtained in step (2) and step (3) obtain is added in benzene emulsion, again regulate stirring velocity to 150-200r/min, stir 1-3h;
(5) in whipping process, add remaining furnish component, continue to stir 20-30min, after leaving standstill, obtain antistripping exterior coating.
Above embodiment is only and technological thought of the present invention is described, can not limit protection scope of the present invention with this, and every technological thought proposed according to the present invention, any change that technical scheme basis is done, all falls within scope.
Claims (5)
1. an antistripping exterior coating, it is characterized in that this coating is counted by weight and comprise following component: epoxy acrylic resin 55-68 part, polystyrene rubber 25-37 part, mica powder 6-9 part, nano silicon 3-8 part, nano titanium oxide 1-5 part, zinc chloride 2-3 part, Nano sepiolite powder 1-3 part, talcum powder 4-8 part, benzene emulsion 12-24 part, clorafin 1-3 part, tetrabutyl zirconate 2-5 part, butyl (tetra) titanate 4-8 part, pentanoic 4-8 part, deionized water 26-46 part, urea 12-16 part, polyacrylamide 6-12 part, dispersion agent 3-9 part, emulsifying agent 2-8 part, titanate coupling agent 1-5 part, antioxidant TNP: 6-9 part,
Described dispersion agent is one or both in carboxymethyl cellulose, Sodium hexametaphosphate 99 or water glass; Described emulsifying agent is polyoxyethylene octylphenol ether or styroyl phenol polyoxyethylene polyoxypropylene ether.
2. antistripping exterior coating according to claim 1, it is characterized in that: this coating is counted by weight and comprised following component: epoxy acrylic resin 55 parts, polystyrene rubber 25 parts, mica powder 6 parts, nano silicon 3 parts, nano titanium oxide 1 part, zinc chloride 2 parts, Nano sepiolite powder 1 part, talcum powder 4 parts, benzene emulsion 12 parts, clorafin 1 part, tetrabutyl zirconate 2 parts, butyl (tetra) titanate 4 parts, pentanoic 4 parts, deionized water 26 parts, 12 parts, urea, polyacrylamide 6 parts, dispersion agent 3 parts, emulsifying agent 2 parts, titanate coupling agent 1 part, antioxidant TNP 6 parts,
Described dispersion agent is one or both in carboxymethyl cellulose, Sodium hexametaphosphate 99 or water glass; Described emulsifying agent is polyoxyethylene octylphenol ether or styroyl phenol polyoxyethylene polyoxypropylene ether.
3. antistripping exterior coating according to claim 1, it is characterized in that: this coating is counted by weight and comprised following component: epoxy acrylic resin 62 parts, polystyrene rubber 32 parts, mica powder 7 parts, nano silicon 5 parts, nano titanium oxide 3 parts, zinc chloride 3 parts, Nano sepiolite powder 2 parts, talcum powder 6 parts, benzene emulsion 17 parts, clorafin 2 parts, tetrabutyl zirconate 4 parts, butyl (tetra) titanate 6 parts, pentanoic 6 parts, deionized water 32 parts, 14 parts, urea, polyacrylamide 10 parts, dispersion agent 6 parts, emulsifying agent 6 parts, titanate coupling agent 3 parts, antioxidant TNP: 7 parts,
Described dispersion agent is one or both in carboxymethyl cellulose, Sodium hexametaphosphate 99 or water glass; Described emulsifying agent is polyoxyethylene octylphenol ether or styroyl phenol polyoxyethylene polyoxypropylene ether.
4. antistripping exterior coating according to claim 1, it is characterized in that: this coating is counted by weight and comprised following component: epoxy acrylic resin 68 parts, polystyrene rubber 37 parts, mica powder 9 parts, nano silicon 8 parts, nano titanium oxide 5 parts, zinc chloride 3 parts, Nano sepiolite powder 3 parts, talcum powder 8 parts, benzene emulsion 24 parts, clorafin 3 parts, tetrabutyl zirconate 5 parts, butyl (tetra) titanate 8 parts, pentanoic 8 parts, deionized water 46 parts, 16 parts, urea, polyacrylamide 12 parts, dispersion agent 9 parts, emulsifying agent 8 parts, titanate coupling agent 5 parts, antioxidant TNP: 9 parts,
Described dispersion agent is one or both in carboxymethyl cellulose, Sodium hexametaphosphate 99 or water glass; Described emulsifying agent is polyoxyethylene octylphenol ether or styroyl phenol polyoxyethylene polyoxypropylene ether.
5. the preparation method of antistripping exterior coating according to claim 1, is characterized in that comprising the following steps:
(1) first will dispersion agent heat after be dissolved in deionized water, be uniformly mixed after adding the tetrabutyl zirconate of 1/2nd amounts and butyl (tetra) titanate, stirring velocity is 200-250r/min, and stirring 10-15min stirs;
(2) in the slurry in step (1), add mica powder, zinc chloride, Nano sepiolite powder and talcum powder, and regulate stirring velocity to 300-350r/min, stir 10-20min and make slurry;
(3) tetrabutyl zirconate of epoxy acrylic resin and polystyrene rubber and residual content and butyl (tetra) titanate are mixed, under 250-300r/min, stir 20-30min obtain mixed emulsion; Then nano silicon, nano titanium oxide and dispersion agent are carried out being uniformly mixed and stir 15-20min under 100-200r/min, in nano material, add titanate coupling agent, continue to stir 30-50min at 200-300r/min and obtain modified epoxy acrylate resin slurry;
(4) the modified epoxy acrylate resin slurry that slurry obtained in step (2) and step (3) obtain is added in benzene emulsion, again regulate stirring velocity to 150-200r/min, stir 1-3h;
(5) in whipping process, add remaining furnish component, continue to stir 20-30min, after leaving standstill, obtain antistripping exterior coating.
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN106433539A (en) * | 2016-08-27 | 2017-02-22 | 安徽天瞳智能科技有限公司 | Preparation method of high temperature-resistant adhesive |
| CN107629505A (en) * | 2017-09-21 | 2018-01-26 | 苏州振振好新型建材科技有限公司 | A kind of exterior wall color inhibition sliver paint |
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| CN103351130A (en) * | 2013-06-21 | 2013-10-16 | 天长市开林化工有限公司 | Preparation method and using method of anti-stripping exterior wall putty powder |
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2015
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106433539A (en) * | 2016-08-27 | 2017-02-22 | 安徽天瞳智能科技有限公司 | Preparation method of high temperature-resistant adhesive |
| CN107629505A (en) * | 2017-09-21 | 2018-01-26 | 苏州振振好新型建材科技有限公司 | A kind of exterior wall color inhibition sliver paint |
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