CN105064069A - Disperse dye color fasteness elevator and preparation method thereof - Google Patents
Disperse dye color fasteness elevator and preparation method thereof Download PDFInfo
- Publication number
- CN105064069A CN105064069A CN201510442666.7A CN201510442666A CN105064069A CN 105064069 A CN105064069 A CN 105064069A CN 201510442666 A CN201510442666 A CN 201510442666A CN 105064069 A CN105064069 A CN 105064069A
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- CN
- China
- Prior art keywords
- elevator
- polyoxyethylene ether
- fasteness
- color
- disperse dye
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
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- 238000002360 preparation method Methods 0.000 title claims abstract description 10
- 239000000986 disperse dye Substances 0.000 title abstract description 7
- 229940051841 polyoxyethylene ether Drugs 0.000 claims abstract description 26
- 229920000056 polyoxyethylene ether Polymers 0.000 claims abstract description 26
- 239000002202 Polyethylene glycol Substances 0.000 claims abstract description 23
- 229920001223 polyethylene glycol Polymers 0.000 claims abstract description 23
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 18
- 235000011114 ammonium hydroxide Nutrition 0.000 claims abstract description 12
- 239000008367 deionised water Substances 0.000 claims abstract description 11
- 229910021641 deionized water Inorganic materials 0.000 claims abstract description 11
- 238000004044 disperse dyeing Methods 0.000 claims description 20
- 238000003756 stirring Methods 0.000 claims description 20
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 claims description 12
- 229940049964 oleate Drugs 0.000 claims description 11
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 claims description 11
- 239000000203 mixture Substances 0.000 claims description 10
- 238000004043 dyeing Methods 0.000 abstract description 11
- 239000004744 fabric Substances 0.000 abstract description 8
- 150000001412 amines Chemical class 0.000 abstract description 2
- 230000007613 environmental effect Effects 0.000 abstract description 2
- MUHFRORXWCGZGE-KTKRTIGZSA-N 2-hydroxyethyl (z)-octadec-9-enoate Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OCCO MUHFRORXWCGZGE-KTKRTIGZSA-N 0.000 abstract 1
- 150000002191 fatty alcohols Chemical class 0.000 abstract 1
- 229940095098 glycol oleate Drugs 0.000 abstract 1
- 239000000975 dye Substances 0.000 description 10
- 239000000835 fiber Substances 0.000 description 8
- 238000004140 cleaning Methods 0.000 description 7
- 238000000034 method Methods 0.000 description 7
- 238000005406 washing Methods 0.000 description 5
- 239000004094 surface-active agent Substances 0.000 description 4
- 239000004753 textile Substances 0.000 description 4
- 229920004933 Terylene® Polymers 0.000 description 3
- 239000006185 dispersion Substances 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 239000005020 polyethylene terephthalate Substances 0.000 description 3
- 238000007639 printing Methods 0.000 description 3
- 230000005611 electricity Effects 0.000 description 2
- 229920000728 polyester Polymers 0.000 description 2
- -1 polyoxyethylene groups Polymers 0.000 description 2
- 238000010186 staining Methods 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 239000002699 waste material Substances 0.000 description 2
- PXFBZOLANLWPMH-UHFFFAOYSA-N 16-Epiaffinine Natural products C1C(C2=CC=CC=C2N2)=C2C(=O)CC2C(=CC)CN(C)C1C2CO PXFBZOLANLWPMH-UHFFFAOYSA-N 0.000 description 1
- 229920002972 Acrylic fiber Polymers 0.000 description 1
- 241001313855 Bletilla Species 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 1
- 229920002334 Spandex Polymers 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 125000002091 cationic group Chemical group 0.000 description 1
- 239000003093 cationic surfactant Substances 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 238000005202 decontamination Methods 0.000 description 1
- 230000003588 decontaminative effect Effects 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 239000003599 detergent Substances 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 238000004945 emulsification Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 229940117927 ethylene oxide Drugs 0.000 description 1
- 238000005562 fading Methods 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
- JMANVNJQNLATNU-UHFFFAOYSA-N glycolonitrile Natural products N#CC#N JMANVNJQNLATNU-UHFFFAOYSA-N 0.000 description 1
- 239000007970 homogeneous dispersion Substances 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 238000005286 illumination Methods 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 238000001764 infiltration Methods 0.000 description 1
- 230000008595 infiltration Effects 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 210000003296 saliva Anatomy 0.000 description 1
- 239000013535 sea water Substances 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- 239000004759 spandex Substances 0.000 description 1
- 238000013112 stability test Methods 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
- 210000004243 sweat Anatomy 0.000 description 1
- 230000008961 swelling Effects 0.000 description 1
- 230000010148 water-pollination Effects 0.000 description 1
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- Coloring (AREA)
Abstract
The invention discloses a disperse dye color fasteness elevator, which comprises the following components by mass fraction: 10-20% of fatty amine polyoxyethylene ether (EO15), 3-6% of polyethylene glycol oleate (600 molecular weight), 3-6% of fatty alcohol polyoxyethylene ether (EO15), 1-5% of ammoniacal liquor and the balance of deionized water. The invention also discloses a preparation method of the disperse dye color fasteness elevator, the product is the specialized color fasteness elevator for the disperse dye dyed fabrics, can effectively wash and remove the surface dyeing on the surface of the fabrics, and can increase the color fasteness of the disperse dye. The color fasteness elevator has the advantage of convenient usage, and accords with environmental protection requirement.
Description
Technical field
The present invention relates to a kind of textile auxiliary, specifically a kind of disperse dyeing fastness elevator and preparation method thereof.
Background technology
Dyefastness is also known as COLOR FASTNESS, colorfastness.Refer to the resistance of the Color pair of textiles various effect in processing and use procedure.Festness ratings is evaluated according to the variable color of sample and the staining of the adjacent fabric that is unstained.Textile color stability test is a conventional detection project in the test of textiles inherent quality.Due to DISPERSE DYES not containing water-soluble group, molecular weight is lower, dyes by means of the acting on homogeneous dispersion in dye liquor of dispersant.Though containing polar group (as hydroxyl, amino, hydroxyl alkylamino, cyanogen alkylamino etc.) in molecule, still belong to nonionic dye.Dyeing course belongs to physics dyeing substantially, especially contaminates terylene, high owing to having its permutation degree, the characteristics such as fiber gap is few, and hydrophobicity is strong, makes swelling of fiber under conventional High Temperature High Pressure, thermosol, and dyestuff just can enter fiber and upper dye.The rear fastness that dyeed is undesirable, there is a large amount of loose colours, easily at high temperature, extrude, rub, wash, drench with rain, tan by the sun, illumination, Seawater immersion, saliva dipping, the external factor such as water stain, sweat stain effect under there is comparatively serious phenomenon of fading, other clothings can be stain, even can be absorbed by human body skin, thus be harmed the health of people.General reduction cleaning technique cannot remove loose colour completely, after causing dye, every fastness index is low, especially for deeply, gorgeous color, fastness is poorer, the mode that some printing and dyeing enterprises adopt washing repeatedly to shape, both fibre damage was caused, cause again a large amount of water, gas, electricity waste, this problem greatly annoyings dyeing & printing enterprise, the present invention uses conventional surfactant material, excavate the characteristic of several surfactant, the cleaning completely of loose colour is achieved, every fastness index of significant increase disperse dyeing, solve disperse dyeing fastness poorer, solve the mode that printing and dyeing enterprise adopts washing repeatedly to shape, avoid causing fibre damage, cause again a large amount of water, gas, the phenomenon of electricity waste, the real important breakthrough for energy-saving and emission-reduction.
Summary of the invention
The invention provides a kind of disperse dyeing fastness elevator and preparation method thereof, its object is to solve the undesirable problem of disperse dyeing fastness.
Disperse dyeing fastness elevator, its composition and mass fraction as follows:
Aliphatic amine polyoxyethylene ether (EO15) 10 ~ 20%;
Polyethylene glycol (PEG) oleate (600 molecular weight) 3 ~ 6%;
Fatty alcohol-polyoxyethylene ether (EO25) 3 ~ 6%;
Ammoniacal liquor 1 ~ 5%;
Surplus is deionized water.
The preparation method of above-mentioned disperse dyeing fastness elevator, the steps include:
1) aliphatic amine polyoxyethylene ether (EO15) of 10 ~ 20 weight portions is fully mixed with the polyethylene glycol (PEG) oleate (600 molecular weight) of 3 ~ 6 weight portions and the fatty alcohol-polyoxyethylene ether (EO9) of 3 ~ 6 weight portions, stir, for subsequent use;
2) added gradually by the mixture prepared in the deionized water weighed in proportion and dissolve, limit edged stirs, until add completely, stirs; Drop into the ammoniacal liquor of 1 ~ 5 weight portion, and stir, blanking.
The present invention is a kind of disperse dyeing fastness elevator, wherein aliphatic amine polyoxyethylene ether is obtained by reacting by high fatty amine and ethyleneoxide addition, it is when polyoxyethylene groups number is less, embody the character of certain cationic surfactant, along with the growth of polyoxyethylene chain, cationic weakens gradually, embodies the character of non-ionic surface active agent, makes it have the several functions such as washing, level dyeing, infiltration, anti-staining and dispersion.Under cryogenic, fiber more affine than dyestuff, can remove the loose colour be attached on fiber to aliphatic amine polyoxyethylene ether (EO15).
Polyethylene glycol (PEG) oleate (600 molecular weight) has good emulsibility, cleaning, lubricity.Loose colour can be helped to be scattered in water.Fatty alcohol-polyoxyethylene ether, as non-ionic surface active agent, plays emulsification, foaming, decontamination.Wherein the fatty alcohol-polyoxyethylene ether of 25 EO numbers has higher HLB value (hydrophilic lipophilic balance), and namely hydrophily is very strong, promotes that loose colour is scattered in water further, thus prevents from returning and be stained with.
In addition, add the ammoniacal liquor of special ratios, to play the effect regulating pH value.
This product is the special dyeing fastness elevator for disperse dyeing fabric, can the effective eccysis fabric face not yet various oligomer that discharge when high temperature (100 DEG C ~ 130 DEG C) dyes of the loose colour of set and terylene, thus significantly improves dyefastness; Also can pollute at cotton, sticky, hair, spandex in eccysis polyester blended fabric, the DISPERSE DYES on the fibers such as acrylic fibers.Be particularly suitable for level Four is spelled in bletilla, dark high fastness requires terylene and BLENDED FABRIC cleaning technique thereof, in reduction cleaning operation, add this product can obtain very gratifying washing fastness, for shallow, middle chromaticity kind, if be applied to soap washing, the dyefastness that can contribute to polyester blended fabric reaches test stone.This product is soluble in water, and all keeps stable, easy to use in the scope of pH value 2 ~ 12, and meets environmental requirement.
Detailed description of the invention
The present invention is further elaborated by specific embodiment:
Embodiment one
Disperse dyeing fastness elevator, its composition and mass fraction as follows:
Aliphatic amine polyoxyethylene ether (EO15) 20%;
Polyethylene glycol (PEG) oleate (600 molecular weight) 3%;
Fatty alcohol-polyoxyethylene ether (EO25) 3%;
Ammoniacal liquor 1%;
Deionized water 73%.
The preparation method of above-mentioned disperse dyeing fastness elevator, the steps include:
1) aliphatic amine polyoxyethylene ether (EO15) of 20 weight portions is fully mixed with the polyethylene glycol (PEG) oleate (600 molecular weight) of 3 weight portions and the fatty alcohol-polyoxyethylene ether (EO9) of 3 weight portions, stir, for subsequent use;
2) added gradually by the mixture prepared in the deionized water of 73 weight portions and dissolve, limit edged stirs, until add completely, stirs; Drop into the ammoniacal liquor of 1 weight portion, and stir, blanking.
Embodiment two
Disperse dyeing fastness elevator, its composition and mass fraction as follows:
Aliphatic amine polyoxyethylene ether (EO15) 10%;
Polyethylene glycol (PEG) oleate (600 molecular weight) 6%;
Fatty alcohol-polyoxyethylene ether (EO25) 6%;
Ammoniacal liquor 5%;
Deionized water 73%.
The preparation method of above-mentioned disperse dyeing fastness elevator, the steps include:
1) aliphatic amine polyoxyethylene ether (EO15) of 10 weight portions is fully mixed with the polyethylene glycol (PEG) oleate (600 molecular weight) of 6 weight portions and the fatty alcohol-polyoxyethylene ether (EO9) of 6 weight portions, stir, for subsequent use;
2) added gradually by the mixture prepared in the deionized water of 73 weight portions and dissolve, limit edged stirs, until add completely, stirs; Drop into the ammoniacal liquor of 5 weight portions, and stir, blanking.
Embodiment three
Disperse dyeing fastness elevator, its composition and mass fraction as follows:
Aliphatic amine polyoxyethylene ether (EO15) 15%;
Polyethylene glycol (PEG) oleate (600 molecular weight) 4%;
Fatty alcohol-polyoxyethylene ether (EO25) 4%;
Ammoniacal liquor 3%;
Deionized water 74%.
The preparation method of above-mentioned disperse dyeing fastness elevator, the steps include:
1) aliphatic amine polyoxyethylene ether (EO15) of 15 weight portions is fully mixed with the polyethylene glycol (PEG) oleate (600 molecular weight) of 4 weight portions and the fatty alcohol-polyoxyethylene ether (EO9) of 4 weight portions, stir, for subsequent use;
2) added gradually by the mixture prepared in the deionized water of 74 weight portions and dissolve, limit edged stirs, until add completely, stirs; Drop into the ammoniacal liquor of 3 weight portions, and stir, blanking.
Disperse dyeing fastness elevator in embodiment one, two, three is sundown liquid, the pH value of its 10% aqueous solution is 6.0 ~ 8.0, and this disperse dyeing fastness elevator is soluble in water, all can keep stability in the scope that pH value is 2 ~ 12.
The occupation mode of this product is as follows:
1. be applied to reduction cleaning technique;
Consumption is 1.0 ~ 3.0%(OWF), in reduction detergent synchronously adds and processes and bathe.
2. be applied to the process of soaping of dispersion/active one bath dyeing;
Consumption is 1.0 ~ 3.0%(OWF), 80 ~ 90 DEG C × 20 ~ 30min
3. be applied to dispersion dyeing stamp cleaning;
Consumption is 1.0 ~ 3.0%(OWF), normal temperature or less than 60 DEG C × 20 ~ 30min
Consumption is 0.5 ~ 2%(OWF), add in dye liquor with dyestuff simultaneously, carry out normal dyeing technique.
Above are only the specific embodiment of the present invention, but design concept of the present invention is not limited thereto, all changes utilizing this design the present invention to be carried out to unsubstantiality, all should belong to the behavior of invading scope.
Claims (2)
1. disperse dyeing fastness elevator, its composition and mass fraction as follows:
Aliphatic amine polyoxyethylene ether (EO15) 10 ~ 20%;
Polyethylene glycol (PEG) oleate (600 molecular weight) 3 ~ 6%;
Fatty alcohol-polyoxyethylene ether (EO25) 3 ~ 6%;
Ammoniacal liquor 1 ~ 5%;
Surplus is deionized water.
2. the preparation method of disperse dyeing fastness elevator as claimed in claim 1, the steps include:
1) aliphatic amine polyoxyethylene ether (EO15) of 10 ~ 20 weight portions is fully mixed with the polyethylene glycol (PEG) oleate (600 molecular weight) of 3 ~ 6 weight portions and the fatty alcohol-polyoxyethylene ether (EO9) of 3 ~ 6 weight portions, stir, for subsequent use;
2) added gradually by the mixture prepared in the deionized water weighed in proportion and dissolve, limit edged stirs, until add completely, stirs; Drop into the ammoniacal liquor of 1 ~ 5 weight portion, and stir, blanking.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510442666.7A CN105064069A (en) | 2015-07-24 | 2015-07-24 | Disperse dye color fasteness elevator and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510442666.7A CN105064069A (en) | 2015-07-24 | 2015-07-24 | Disperse dye color fasteness elevator and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN105064069A true CN105064069A (en) | 2015-11-18 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510442666.7A Pending CN105064069A (en) | 2015-07-24 | 2015-07-24 | Disperse dye color fasteness elevator and preparation method thereof |
Country Status (1)
| Country | Link |
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| CN (1) | CN105064069A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105908537A (en) * | 2016-05-18 | 2016-08-31 | 太仓协大申泰羊毛衫有限公司 | Woolen sweater color fastness improver |
| CN106351040A (en) * | 2016-09-29 | 2017-01-25 | 东莞市博科纺织科技有限公司 | Low-polymer protective agent and preparation method thereof |
| CN116556084A (en) * | 2023-05-30 | 2023-08-08 | 常州保洁洗涤剂制造有限公司 | One-step energy-saving auxiliary agent for cone dyeing and preparation method thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101314922A (en) * | 2008-06-24 | 2008-12-03 | 苏州大学 | Anti-staining detergent for textile dyeing and printing |
| CN102619113A (en) * | 2012-04-01 | 2012-08-01 | 祝洪哲 | Short-process low temperature soaping additive and preparation method thereof |
| CN103952035A (en) * | 2014-04-30 | 2014-07-30 | 湘潭嘉立科技有限公司 | Water-based pigment paste and preparation method thereof |
| CN104652143A (en) * | 2015-02-10 | 2015-05-27 | 浙江工业职业技术学院 | Reductive cleansing agent and preparation method thereof |
-
2015
- 2015-07-24 CN CN201510442666.7A patent/CN105064069A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101314922A (en) * | 2008-06-24 | 2008-12-03 | 苏州大学 | Anti-staining detergent for textile dyeing and printing |
| CN102619113A (en) * | 2012-04-01 | 2012-08-01 | 祝洪哲 | Short-process low temperature soaping additive and preparation method thereof |
| CN103952035A (en) * | 2014-04-30 | 2014-07-30 | 湘潭嘉立科技有限公司 | Water-based pigment paste and preparation method thereof |
| CN104652143A (en) * | 2015-02-10 | 2015-05-27 | 浙江工业职业技术学院 | Reductive cleansing agent and preparation method thereof |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105908537A (en) * | 2016-05-18 | 2016-08-31 | 太仓协大申泰羊毛衫有限公司 | Woolen sweater color fastness improver |
| CN106351040A (en) * | 2016-09-29 | 2017-01-25 | 东莞市博科纺织科技有限公司 | Low-polymer protective agent and preparation method thereof |
| CN106351040B (en) * | 2016-09-29 | 2019-01-25 | 广东博科纺织科技有限公司 | A kind of oligomer preventing agent and preparation method thereof |
| CN116556084A (en) * | 2023-05-30 | 2023-08-08 | 常州保洁洗涤剂制造有限公司 | One-step energy-saving auxiliary agent for cone dyeing and preparation method thereof |
| CN116556084B (en) * | 2023-05-30 | 2023-11-10 | 常州保洁洗涤剂制造有限公司 | One-step energy-saving auxiliary agent for cone dyeing and preparation method thereof |
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Application publication date: 20151118 |