CN104800091B - Composition and method for thickening for transparent type pure amino acid surfactant system cleaning products from thickening - Google Patents
Composition and method for thickening for transparent type pure amino acid surfactant system cleaning products from thickening Download PDFInfo
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- CN104800091B CN104800091B CN201510190450.6A CN201510190450A CN104800091B CN 104800091 B CN104800091 B CN 104800091B CN 201510190450 A CN201510190450 A CN 201510190450A CN 104800091 B CN104800091 B CN 104800091B
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- 238000004140 cleaning Methods 0.000 title claims abstract description 75
- 150000001413 amino acids Chemical class 0.000 title claims abstract description 72
- 239000004094 surface-active agent Substances 0.000 title claims abstract description 51
- 238000000034 method Methods 0.000 title claims abstract description 22
- 239000000203 mixture Substances 0.000 title claims abstract description 21
- 230000008719 thickening Effects 0.000 title abstract description 24
- 235000001014 amino acid Nutrition 0.000 claims abstract description 72
- WHUUTDBJXJRKMK-UHFFFAOYSA-N Glutamic acid Natural products OC(=O)C(N)CCC(O)=O WHUUTDBJXJRKMK-UHFFFAOYSA-N 0.000 claims abstract description 34
- 235000013922 glutamic acid Nutrition 0.000 claims abstract description 34
- 239000004220 glutamic acid Substances 0.000 claims abstract description 34
- KZRXPHCVIMWWDS-AWEZNQCLSA-N (4S)-4-amino-5-dodecanoyloxy-5-oxopentanoic acid Chemical compound CCCCCCCCCCCC(=O)OC(=O)[C@@H](N)CCC(O)=O KZRXPHCVIMWWDS-AWEZNQCLSA-N 0.000 claims abstract description 31
- 229940071085 lauroyl glutamate Drugs 0.000 claims abstract description 31
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 claims abstract description 27
- 239000007788 liquid Substances 0.000 claims abstract description 20
- -1 acyl glutamic acid Chemical compound 0.000 claims abstract description 17
- 239000007787 solid Substances 0.000 claims abstract description 9
- 238000005406 washing Methods 0.000 claims abstract description 5
- 239000004615 ingredient Substances 0.000 claims abstract description 4
- 239000003921 oil Substances 0.000 claims description 33
- 238000003756 stirring Methods 0.000 claims description 29
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 13
- 239000000341 volatile oil Substances 0.000 claims description 9
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims description 8
- 241000196324 Embryophyta Species 0.000 claims description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 8
- 238000000605 extraction Methods 0.000 claims description 7
- 239000003755 preservative agent Substances 0.000 claims description 7
- 230000002335 preservative effect Effects 0.000 claims description 7
- 239000002562 thickening agent Substances 0.000 claims description 7
- 235000011187 glycerol Nutrition 0.000 claims description 6
- LPUQAYUQRXPFSQ-DFWYDOINSA-M monosodium L-glutamate Chemical compound [Na+].[O-]C(=O)[C@@H](N)CCC(O)=O LPUQAYUQRXPFSQ-DFWYDOINSA-M 0.000 claims description 6
- ULWHHBHJGPPBCO-UHFFFAOYSA-N propane-1,1-diol Chemical class CCC(O)O ULWHHBHJGPPBCO-UHFFFAOYSA-N 0.000 claims description 6
- 229940079781 sodium cocoyl glutamate Drugs 0.000 claims description 6
- QCDWFXQBSFUVSP-UHFFFAOYSA-N 2-phenoxyethanol Chemical compound OCCOC1=CC=CC=C1 QCDWFXQBSFUVSP-UHFFFAOYSA-N 0.000 claims description 5
- 229960003237 betaine Drugs 0.000 claims description 5
- KWIUHFFTVRNATP-UHFFFAOYSA-N glycine betaine Chemical compound C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 claims description 5
- 229960005323 phenoxyethanol Drugs 0.000 claims description 5
- 229940045944 sodium lauroyl glutamate Drugs 0.000 claims description 5
- IWIUXJGIDSGWDN-UQKRIMTDSA-M sodium;(2s)-2-(dodecanoylamino)pentanedioate;hydron Chemical compound [Na+].CCCCCCCCCCCC(=O)N[C@H](C([O-])=O)CCC(O)=O IWIUXJGIDSGWDN-UQKRIMTDSA-M 0.000 claims description 5
- 239000002904 solvent Substances 0.000 claims description 5
- 239000002253 acid Substances 0.000 claims description 4
- 229910021529 ammonia Inorganic materials 0.000 claims description 4
- 125000000400 lauroyl group Chemical group O=C([*])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 4
- 241000208152 Geranium Species 0.000 claims description 3
- 238000004519 manufacturing process Methods 0.000 claims description 3
- DWNBOPVKNPVNQG-LURJTMIESA-N (2s)-4-hydroxy-2-(propylamino)butanoic acid Chemical compound CCCN[C@H](C(O)=O)CCO DWNBOPVKNPVNQG-LURJTMIESA-N 0.000 claims 1
- 235000019082 Osmanthus Nutrition 0.000 claims 1
- 241000333181 Osmanthus Species 0.000 claims 1
- 230000000694 effects Effects 0.000 abstract description 18
- 230000002195 synergetic effect Effects 0.000 abstract description 6
- 238000005187 foaming Methods 0.000 abstract description 4
- 230000000052 comparative effect Effects 0.000 description 10
- 229920002125 Sokalan® Polymers 0.000 description 5
- 229960001631 carbomer Drugs 0.000 description 5
- 239000003795 chemical substances by application Substances 0.000 description 5
- NIXOWILDQLNWCW-UHFFFAOYSA-N Acrylic acid Chemical compound OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 4
- 229920002678 cellulose Polymers 0.000 description 4
- 235000010980 cellulose Nutrition 0.000 description 4
- 239000000230 xanthan gum Substances 0.000 description 4
- 229920001285 xanthan gum Polymers 0.000 description 4
- 235000010493 xanthan gum Nutrition 0.000 description 4
- 229940082509 xanthan gum Drugs 0.000 description 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 3
- 230000003213 activating effect Effects 0.000 description 3
- 239000001913 cellulose Substances 0.000 description 3
- IPGANOYOHAODGA-UHFFFAOYSA-N dilithium;dimagnesium;dioxido(oxo)silane Chemical compound [Li+].[Li+].[Mg+2].[Mg+2].[O-][Si]([O-])=O.[O-][Si]([O-])=O.[O-][Si]([O-])=O IPGANOYOHAODGA-UHFFFAOYSA-N 0.000 description 3
- 239000002585 base Substances 0.000 description 2
- 239000003153 chemical reaction reagent Substances 0.000 description 2
- 230000001276 controlling effect Effects 0.000 description 2
- 239000006071 cream Substances 0.000 description 2
- 238000007599 discharging Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 238000005491 wire drawing Methods 0.000 description 2
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical group NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 1
- 206010049244 Ankyloglossia congenital Diseases 0.000 description 1
- 235000016068 Berberis vulgaris Nutrition 0.000 description 1
- 241000335053 Beta vulgaris Species 0.000 description 1
- 241000195940 Bryophyta Species 0.000 description 1
- 244000060011 Cocos nucifera Species 0.000 description 1
- 235000013162 Cocos nucifera Nutrition 0.000 description 1
- 239000004354 Hydroxyethyl cellulose Substances 0.000 description 1
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 description 1
- UUFVSGRELDGPGL-QJRAZLAKSA-N N-oleoyl-L-glutamic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)N[C@H](C(O)=O)CCC(O)=O UUFVSGRELDGPGL-QJRAZLAKSA-N 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- HEBRLWPITKEBDB-XCYGSCDUSA-N [NH4+].C(C)O.C(C)O.C(C)O.N[C@@H](CCC(=O)[O-])C(=O)OC(CCCCCCCCCCC)=O Chemical compound [NH4+].C(C)O.C(C)O.C(C)O.N[C@@H](CCC(=O)[O-])C(=O)OC(CCCCCCCCCCC)=O HEBRLWPITKEBDB-XCYGSCDUSA-N 0.000 description 1
- SNGZVXPRGLTKNU-RGMNGODLSA-N [Na].C(CC)N[C@@H](CCO)C(=O)O Chemical compound [Na].C(CC)N[C@@H](CCO)C(=O)O SNGZVXPRGLTKNU-RGMNGODLSA-N 0.000 description 1
- 239000004480 active ingredient Substances 0.000 description 1
- 125000002252 acyl group Chemical group 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 description 1
- GCICAPWZNUIIDV-UHFFFAOYSA-N lithium magnesium Chemical compound [Li].[Mg] GCICAPWZNUIIDV-UHFFFAOYSA-N 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 235000011929 mousse Nutrition 0.000 description 1
- 239000008213 purified water Substances 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 239000002453 shampoo Substances 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
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- Cosmetics (AREA)
- Detergent Compositions (AREA)
Abstract
It is made up of the invention discloses a kind of for transparent type pure amino acid surfactant system cleaning products from the composition and method for thickening thickened, said composition lauroyl glutamate and cocounut oil acyl glutamic acid with triethanolamine；As the recipe ingredient of transparent type pure amino acid surfactant system cleaning products, the viscosity of regulation transparent type pure amino acid surfactant system cleaning products in from liquid to solids range is realized by controlling the quality proportioning between lauroyl glutamate, cocounut oil acyl glutamic acid and triethanolamine.Said composition can from liquid to solids range in any regulation transparent type pure amino acid cleaning products viscosity, face cleaning product, hair washing product or the bath product of different viscosities requirement are obtained respectively, it is and few with dosage, thickening effect is good, composition has cleaning, foaming effect simultaneously, has synergistic function to the cleaning effect of pure amino acid cleaning products.
Description
Technical field
The present invention relates to a kind of composition for transparent type pure amino acid surfactant system cleaning products from thickening
And method for thickening (" AAG " technology), belong to daily-use chemical industry production technical field.
Background technology
With the development of society, people are more and more stronger to beautiful, to health pursuit, cleaning products are healthy and beautiful the
One station.Cleaning products are also widest using crowd, and men and women, old and young have the demand of clean body.Mildy wash, shampoo,
Shower cream etc. is almost everyone indispensable daily necessities.It can be seen that market scale and economic benefit that this kind of product is huge.But city
Existing cleaning products are mostly based on traditional sulfate surfactant (such as AES, K12) on field.Amino acid system it is clear
Clean product is gentle, green product of new generation, but it is exactly to be difficult to thicken that this kind of product, which all suffers from a common problem, especially
It is pure amino acid cleaning products, there is presently no effective thickening mode and thickener.The pure amino acid cleaning products of all-transparent
It is the problem in this field problem again.
Thickening of traditional thickener (such as carbomer, xanthan gum, cellulose, lithium magnesium silicate etc.) to amino acid system product
Effect is undesirable, and in order to reach the purpose of thickening, some producers need to increase dosage, but produce effects or little.Such as carbomer, silicon
Although sour magnesium lithium, thickening of the xanthan gum/cellulose to amino acid surfactant product some effect, this is suitable only for making
Make opaque type amino acid system cleaning products (such as the faster amino acid mildy wash/face cleaning cream of developed recently, amino acid hair washing
Water, these products are not transparent type, usually milky appearance), the amino acid system cleaning products of transparent type are not applied to
.Even if carbomer is used for addition when thickening amino acid cleaning products and reaches 5% (carbomer addition is general in AES systems
For 1-2%), its thickening effect is also very little.Lithium magnesium silicate, xanthan gum/cellulose increase in amino acid cleaning products
Usage amount can have part thickening effect, but can also influence the transparent type degree of system simultaneously, or make donor frenulum next sticky
Wire drawing sense (effects of some modified celluloses).
The content of the invention
In order to solve the pure amino acid cleaning products of transparent type in the prior art thickening problem, it is an object of the invention to
It is to provide a kind of transparent type amino acid surfactant system cleaning products that can be used for from the composition thickened, said composition
Can from liquid to solids range in any regulation transparent type pure amino acid system cleaning products viscosity, obtain different viscosities respectively
It is required that face cleaning product, hair washing product or bath product, composition thickening effect is good, while also has certain cleaning, foaming effect
Fruit, there is synergistic function to the cleaning effect of pure amino acid cleaning products.
Another object of the present invention is to be to provide one kind by by lauroyl glutamate and cocounut oil acyl glutamic acid and three
The composition of monoethanolamine composition effectively any in liquid to solids range can adjust transparent type pure amino acid cleaning products viscosity
Method, composition is good to the thickening effect of pure amino acid type cleaning products, and to the cleaning effect of pure amino acid cleaning products
With synergistic function.
The invention provides a kind of combination for transparent type pure amino acid surfactant system cleaning products from thickening
Thing, said composition are made up of lauroyl glutamate and cocounut oil acyl glutamic acid with triethanolamine.
Lauroyl glutamate and the mass ratio of cocounut oil acyl glutamic acid and triethanolamine are 8~16 in preferable composition:6~
8, wherein, lauroyl glutamate and the mass ratio of cocounut oil acyl glutamic acid and triethanolamine are 1~7:1~7.
, should present invention also offers a kind of transparent type pure amino acid surfactant system cleaning products from the method thickened
Method is using the composition being made up of lauroyl glutamate and cocounut oil acyl glutamic acid with triethanolamine as transparent type pure amino acid
The recipe ingredient of surfactant system cleaning products, by controlling lauroyl glutamate, cocounut oil acyl glutamic acid and triethanolamine
Between quality proportioning the cleaning production of transparent type pure amino acid surfactant system is adjusted in from liquid to solids range to realize
The viscosity of product.
The transparent type pure amino acid surfactant system cleaning products of the present invention also include following excellent from the method thickened
Select scheme：
In preferable scheme by by lauroyl glutamate and the mass ratio of cocounut oil acyl glutamic acid and triethanolamine 8~
16:In the range of 6~8, and the mass ratio of lauroyl glutamate and cocounut oil acyl glutamic acid is 1~7:Regulate and control in the range of 1~7, it is controllable
Transparent type pure amino acid surfactant system cleaning products processed are solid or viscosity >=55mPa.s liquid, and wherein viscosity is surveyed
The temperature of examination is 25 DEG C.
Transparent type pure amino acid surfactant system cleaning products component described in preferable scheme includes solvent, ammonia
Base acid surfaces activating agent, NMF, essential oil, preservative, plant extraction liquid and by lauroyl glutamate and cocounut oil acyl glutamic acid with
The thickener of triethanolamine composition.
Transparent type pure amino acid surfactant system cleaning products include following content of component in preferable scheme：It is molten
30~90 parts of agent；2~14 parts of lauroyl glutamate；2~14 parts of cocounut oil acyl glutamic acid；6~8 parts of triethanolamine；Amino acid surface
2~10 parts of activating agent；0.2~2 part of NMF；0.1~0.5 part of essential oil；0.02~0.8 part of preservative；Plant extraction liquid 0.5~
2 parts；And lauroyl glutamate and cocounut oil acyl glutamic acid gross mass are 8~16 parts.
More preferably transparent type pure amino acid surfactant system cleaning products include following content of component in scheme：
20~50 parts of water；5~20 parts of glycerine；5~20 parts of propane diols；2~14 parts of lauroyl glutamate；2~14 parts of cocounut oil acyl glutamic acid；
6~8 parts of triethanolamine；1~5 part of sodium lauroyl glutamate；1~5 part of sodium cocoyl glutamate；0.2~2 part of glycine betaine；India
0.1~0.5 part of certain herbaceous plants with big flowers essential oil；0.02~0.8 part of Phenoxyethanol；0.5~2 part of camomile extract；And lauroyl glutamate and coconut palm
Oleoyl glutamic acid gross mass is 8~16 parts.
More preferably solvent is placed in agitated kettle in scheme, 65~75 DEG C, after stirring are heated to, into agitated kettle
Lauroyl glutamate and cocounut oil acyl glutamic acid, amino acid surfactant are sequentially added, stirring adds three ethanol to dissolving
Amine, stir 10~20 minutes；Then 55~65 DEG C are cooled to, adds NMF, stirring is further cooled to 35~45 to dissolving
DEG C, essential oil, preservative and plant extraction liquid are sequentially added, after stirring, stands defoaming, the transparent type for producing required viscosity is pure
Amino acid surfactant system cleaning products.
Stirring is to be carried out in stir speed (S.S.) under conditions of 300~500 revs/min in further preferred scheme.Described
Stirring can be achieved by conventional mixer.
It can be obtained in preferable scheme by adjusting the viscosity of transparent type pure amino acid surfactant system cleaning products
Face cleaning product, hair washing product or the bath product of transparent type pure amino acid surfactant system.
The present invention passes through reaction, formation lauroyl paddy ammonia by lauroyl glutamate and cocounut oil acyl glutamic acid with triethanolamine
Triethylenetetraminehexaacetic acid alcohol ammonium salt and cocounut oil acyl glutamic acid tri ethanol ammonium salt, the salt of both different molecular weights all there is certain thickening to make
With, by by both compound thickening effect is obtained Synergistic, arbitrarily can be adjusted in liquid to solids range transparent
The viscosity of type pure amino acid surfactant system cleaning products.Meanwhile lauroyl glutamate tri ethanol ammonium salt and cocounut oil acyl paddy
Propylhomoserin tri ethanol ammonium salt also has foaming, the cleaning function of amino acid surfactant simultaneously, to transparent type pure amino acid surface
The cleaning performance of surfactant system cleaning products has synergistic function.
Glycerine, propane diols, sodium lauroyl glutamate, sodium cocoyl glutamate, glycine betaine, the day used in inventive formulation
The reagents such as Zhu Kui essential oils, Phenoxyethanol and camomile extract are all commercially available conventional reagent.
The most preferred method of the present invention：Comprise the following steps：
1st, Jiang Shui, glycerine, propane diols are placed in agitated kettle, are opened mixer and are entered with 300~500 revs/min of stir speed (S.S.)
Row stirring, while heated to 65~75 DEG C；
2nd, by lauroyl glutamate and cocounut oil acyl glutamic acid, agitated kettle is added, 65~75 DEG C of temperature is maintained, 300~500
Rev/min stir speed (S.S.) under stir to being completely dissolved；
3rd, sodium lauroyl glutamate and sodium cocoyl glutamate are added into agitated kettle again, 65~75 DEG C of temperature is maintained, 300
Stirred under~500 revs/min of stir speed (S.S.) to being completely dissolved；
4th, triethanolamine is further slowly added to agitated kettle, 65~75 DEG C of temperature is maintained, in 300~500 revs/min stir
Mix and stirred 15~25 minutes under speed, the pH for making the addition maintenance mixture of triethanolamine is 5.5~6；
5th, stop heating, continue to stir under 300~500 revs/min of speed, beet is added when cooling to 55~65 DEG C
Alkali, stirring to dissolving；
6th, continue to be cooled to 35~45 DEG C, sequentially add Geranium Essential, Phenoxyethanol, camomile extract, stirring is equal
It is even；
7th, stopping stirring, discharging is filling after standing defoaming 20~28 hours, that is, obtains the pure ammonia of transparent type of required viscosity
Base acid surfaces surfactant system cleaning products.
Compared with the prior art, the beneficial effects of the invention are as follows：
1st, first passage lauroyl glutamate and cocounut oil acyl glutamic acid and triethanolamine compounding are come to transparent type amino acid table
Surfactant system cleaning products are thickened, and are efficiently solved in the prior art without suitable transparent type amino acid surface activity
The thickener and transparent type amino acid surfactant system cleaning products can not be thickened that agent system cleaning products thicken
The defects of.
It is 2nd, of the invention by regulating and controlling to the ratio between lauroyl glutamate and cocounut oil acyl glutamic acid and triethanolamine,
Any regulation can be carried out to the viscosity of transparent type amino acid surfactant system cleaning products in the range of liquid to solid-state,
The transparent type amino acid surfactant system cleaning products of different viscosities can be obtained.
3rd, the salt that generation is reacted between lauroyl glutamate and cocounut oil acyl glutamic acid and triethanolamine has amino acid table
The foaming of face activating agent and cleaning function, have and have to the cleaning effect of transparent type amino acid surfactant system cleaning products
There is synergistic function, can be as the active ingredient of transparent type amino acid surfactant system cleaning products, to product
Quality is without influence.
Embodiment
Following comparative example, embodiment are intended to further illustrate present invention, rather than limit the claims in the present invention
Protection domain.
Embodiment 1
Formula and technique：
Pure amino acid surfactant system face cleaning product formula：
34 parts of purified water, 17 parts of glycerine, 15 parts of propane diols, 8 parts of lauroyl glutamate, cocounut oil acyl glutamic acid 2, lauroyl paddy
2 parts of propylhomoserin sodium, 2 parts of sodium cocoyl glutamate, 7 parts of triethanolamine, 1 part of glycine betaine, 0.2 part of Geranium Essential, Phenoxyethanol 0.8
Part, 1 part of camomile extract.
The technique for preparing pure amino acid surfactant system face cleaning product by above-mentioned recipe ingredient quality：
(1) in 10 liters of agitated kettles, by water, glycerine and propane diols in agitated kettle, 300 revs/min stir and heat
To 70 DEG C.
(2) lauroyl glutamate is taken, cocounut oil acyl glutamic acid, adds agitated kettle, 70 DEG C, 400 revs/min are stirred to completely molten
Solution.
(3) sodium lauroyl glutamate and sodium cocoyl glutamate are taken, adds agitated kettle, 70 DEG C, 400 revs/min are stirred to complete
Fully dissolved.
(4) triethanolamine is taken, is slowly added to agitated kettle, 70 DEG C, 400 revs/min are stirred 20 minutes.
(5) stop heating, continue to add glycine betaine, stirring and dissolving when stirring cools to 60 DEG C.
(6) continue to be cooled to 40 DEG C, be separately added into essential oil, preservative, plant extraction liquid, stir.
(7) stop stirring, discharging, it is static defoaming 24 hours after it is filling.
Obtained amino acid cleansing product is water white transparency type product, and the relatively low liquid of viscosity (viscosity 55mPa.s, 20
℃).The liquid can be used as face cleaning foam or face cleaning mousse to use.
Embodiment 2~7
The pure amino acid surfactant system face cleaning product formula of 2~embodiment of embodiment 7 such as (the total matter of each component of table 1
It is 90 parts to measure part).
The technique of 2~embodiment of embodiment 7 is same as Example 1.
Formula in the embodiment 2 of table 1 to embodiment 7
Embodiment 2 to the final products of the gained of embodiment 7 are water white transparency types, its viscosity number such as table 2 below.
The embodiment 1 of table 2 is to embodiment, 7 sample viscosity values (25 DEG C)
From Table 2, it can be seen that by adjusting lauroyl glutamate and cocounut oil acyl glutamic acid in 1~embodiment of embodiment 7
With the ratio of triethanolamine, the viscous of pure amino acid surfactant system face cleaning product can be adjusted in the range of liquid to solid-state
Degree, can obtain different types of face cleaning product.
Comparative example 1~8
Pure amino acid surfactant system face cleaning product formula (gross mass part of 1~comparative example of comparative example 8
For 90 parts)：
Formula in the comparative example 1 of table 3 to comparative example 8
The technique for preparing pure amino acid surfactant cleaning products by above-mentioned formula：
The technique of 1~comparative example of comparative example 8 is in addition to thickener is previously added in water, other techniques and reality
It is identical to apply example 1.
The comparative example 1 of table 3 to the properties of sample of comparative example 8 is evaluated
Interpretation of result：Carbomer amino acid table live body system thickening power very little, lithium magnesium silicate and xanthan gum have a little thickening
Effect, but influence transparency.Hydroxyethyl cellulose, which increases, has used rear thickening power slightly larger, and does not influence transparency, but has viscous
Greasy wire drawing sense.Therefore these thickeners are not suitable in transparent amino acid cleaning products.
Claims (7)
1. a kind of method that transparent type pure amino acid surfactant system cleaning products thicken certainly, it is characterised in that will be by the moon
The composition that osmanthus acyl glutamic acid and cocounut oil acyl glutamic acid form with triethanolamine is as transparent type pure amino acid surfactant body
It is the recipe ingredient of cleaning products, by controlling the quality between lauroyl glutamate, cocounut oil acyl glutamic acid and triethanolamine to match somebody with somebody
Than come realize in from liquid to solids range adjust transparent type pure amino acid surfactant system cleaning products viscosity；Pass through
By lauroyl glutamate and the mass ratio of cocounut oil acyl glutamic acid and triethanolamine 8~16:In the range of 6~8, and lauroyl paddy ammonia
The mass ratio of acid and cocounut oil acyl glutamic acid is 1~7:Regulate and control in the range of 1~7, can control transparent type pure amino acid surfactant
System cleaning products are solid or viscosity >=55mPa.s liquid, and the wherein temperature of viscosity test is 25 DEG C.
2. according to the method for claim 1, it is characterised in that described transparent type pure amino acid surfactant system is clear
Clean product component includes solvent, amino acid surfactant, NMF, essential oil, preservative, plant extraction liquid and by lauroyl paddy
The thickener of propylhomoserin and cocounut oil acyl glutamic acid and triethanolamine composition.
3. according to the method for claim 2, it is characterised in that described transparent type pure amino acid surfactant system is clear
Clean product includes following content of component：
30~90 parts of solvent；
2~14 parts of lauroyl glutamate；
2~14 parts of cocounut oil acyl glutamic acid；
6~8 parts of triethanolamine；
2~10 parts of amino acid surfactant；
0.2~2 part of NMF；
0.1~0.5 part of essential oil；
0.02~0.8 part of preservative；
0.5~2 part of plant extraction liquid；
And lauroyl glutamate and cocounut oil acyl glutamic acid gross mass are 8~16 parts.
4. according to the method for claim 3, it is characterised in that described transparent type pure amino acid surfactant system is clear
Clean product includes following content of component：
20~50 parts of water；
5~20 parts of glycerine；
5~20 parts of propane diols；
2~14 parts of lauroyl glutamate；
2~14 parts of cocounut oil acyl glutamic acid；
6~8 parts of triethanolamine；
1~5 part of sodium lauroyl glutamate；
1~5 part of sodium cocoyl glutamate；
0.2~2 part of glycine betaine；
0.1~0.5 part of Geranium Essential；
0.02~0.8 part of Phenoxyethanol；
0.5~2 part of camomile extract；
And lauroyl glutamate and cocounut oil acyl glutamic acid gross mass are 8~16 parts.
5. according to the method for claim 2, it is characterised in that solvent is placed in agitated kettle, 65~75 DEG C is heated to, stirs
After mixing uniformly, lauroyl glutamate and cocounut oil acyl glutamic acid, amino acid surfactant are sequentially added into agitated kettle, stirring is extremely
Dissolving, triethanolamine is added, stirred 10~20 minutes；Then 55~65 DEG C are cooled to, adds NMF, stirring is extremely dissolved,
35~45 DEG C are further cooled to, sequentially adds essential oil, preservative and plant extraction liquid, after stirring, defoaming is stood, produces
The transparent type pure amino acid surfactant system cleaning products of required viscosity.
6. according to the method for claim 5, it is characterised in that described stirring be stir speed (S.S.) 300~500 turns/
Carried out under conditions of point.
7. according to the method for claim 1, it is characterised in that by adjusting transparent type pure amino acid surfactant system
The viscosity of cleaning products can obtain the face cleaning product, hair washing product or production of taking a shower of transparent type pure amino acid surfactant system
Product.
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| CN105997768A (en) * | 2016-07-29 | 2016-10-12 | 济宁医学院 | Mild moistening amino acid facial cleanser |
| CN106727114A (en) * | 2016-12-12 | 2017-05-31 | 德阳力久云智知识产权运营有限公司 | One kind is without silicone oil shampoo and preparation method thereof |
| CN110267638B (en) | 2017-02-08 | 2022-05-27 | 联合利华知识产权控股有限公司 | Xanthan structured high polyol liquid detergent |
| CN108165383A (en) * | 2017-12-25 | 2018-06-15 | 上海和黄白猫有限公司 | Transparent facial soap of amino acid of the composite parts containing Chinese herbal medicine and preparation method thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2003147399A (en) * | 2001-11-13 | 2003-05-21 | Kawaken Fine Chem Co Ltd | Liquid detergent composition |
| CN102988243A (en) * | 2012-12-21 | 2013-03-27 | 宁波御坊堂生物科技有限公司 | Face cleaning crystal hard gel and preparation method thereof |
| CN103479532A (en) * | 2012-06-12 | 2014-01-01 | 苏州元素集化学工业有限公司 | Surfactant composition and uses thereof |
| CN104042507A (en) * | 2014-06-17 | 2014-09-17 | 宁波御坊堂生物科技有限公司 | High-light-transmission pure amino-acid self-thickening soft cleansing gel and preparation method thereof |
-
2015
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Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2003147399A (en) * | 2001-11-13 | 2003-05-21 | Kawaken Fine Chem Co Ltd | Liquid detergent composition |
| CN103479532A (en) * | 2012-06-12 | 2014-01-01 | 苏州元素集化学工业有限公司 | Surfactant composition and uses thereof |
| CN102988243A (en) * | 2012-12-21 | 2013-03-27 | 宁波御坊堂生物科技有限公司 | Face cleaning crystal hard gel and preparation method thereof |
| CN104042507A (en) * | 2014-06-17 | 2014-09-17 | 宁波御坊堂生物科技有限公司 | High-light-transmission pure amino-acid self-thickening soft cleansing gel and preparation method thereof |
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