CN103766395B - A kind of family expenses mosquitocide and preparation method thereof - Google Patents
A kind of family expenses mosquitocide and preparation method thereof Download PDFInfo
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- CN103766395B CN103766395B CN201410019565.4A CN201410019565A CN103766395B CN 103766395 B CN103766395 B CN 103766395B CN 201410019565 A CN201410019565 A CN 201410019565A CN 103766395 B CN103766395 B CN 103766395B
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- mosquitocide
- family expenses
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- 238000002360 preparation method Methods 0.000 title claims abstract description 10
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 claims abstract description 24
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 claims abstract description 24
- XYXNTHIYBIDHGM-UHFFFAOYSA-N ammonium thiosulfate Chemical compound [NH4+].[NH4+].[O-]S([O-])(=O)=S XYXNTHIYBIDHGM-UHFFFAOYSA-N 0.000 claims abstract description 24
- LHJQIRIGXXHNLA-UHFFFAOYSA-N calcium peroxide Chemical compound [Ca+2].[O-][O-] LHJQIRIGXXHNLA-UHFFFAOYSA-N 0.000 claims abstract description 24
- 239000002904 solvent Substances 0.000 claims abstract description 16
- TXUICONDJPYNPY-UHFFFAOYSA-N (1,10,13-trimethyl-3-oxo-4,5,6,7,8,9,11,12,14,15,16,17-dodecahydrocyclopenta[a]phenanthren-17-yl) heptanoate Chemical compound C1CC2CC(=O)C=C(C)C2(C)C2C1C1CCC(OC(=O)CCCCCC)C1(C)CC2 TXUICONDJPYNPY-UHFFFAOYSA-N 0.000 claims abstract description 12
- GEYOCULIXLDCMW-UHFFFAOYSA-N 1,2-phenylenediamine Chemical compound NC1=CC=CC=C1N GEYOCULIXLDCMW-UHFFFAOYSA-N 0.000 claims abstract description 12
- 239000004343 Calcium peroxide Substances 0.000 claims abstract description 12
- 229910021626 Tin(II) chloride Inorganic materials 0.000 claims abstract description 12
- YASYVMFAVPKPKE-UHFFFAOYSA-N acephate Chemical compound COP(=O)(SC)NC(C)=O YASYVMFAVPKPKE-UHFFFAOYSA-N 0.000 claims abstract description 12
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 claims abstract description 12
- 229910021502 aluminium hydroxide Inorganic materials 0.000 claims abstract description 12
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 claims abstract description 12
- 235000019402 calcium peroxide Nutrition 0.000 claims abstract description 12
- RYLHNOVXKPXDIP-UHFFFAOYSA-N flufenoxuron Chemical compound C=1C=C(NC(=O)NC(=O)C=2C(=CC=CC=2F)F)C(F)=CC=1OC1=CC=C(C(F)(F)F)C=C1Cl RYLHNOVXKPXDIP-UHFFFAOYSA-N 0.000 claims abstract description 12
- 229910052938 sodium sulfate Inorganic materials 0.000 claims abstract description 12
- 235000011152 sodium sulphate Nutrition 0.000 claims abstract description 12
- 239000001119 stannous chloride Substances 0.000 claims abstract description 12
- 235000011150 stannous chloride Nutrition 0.000 claims abstract description 12
- ISIJQEHRDSCQIU-UHFFFAOYSA-N tert-butyl 2,7-diazaspiro[4.5]decane-7-carboxylate Chemical compound C1N(C(=O)OC(C)(C)C)CCCC11CNCC1 ISIJQEHRDSCQIU-UHFFFAOYSA-N 0.000 claims abstract description 12
- 239000003054 catalyst Substances 0.000 claims abstract description 8
- -1 10 ~ 30 parts Chemical compound 0.000 claims abstract description 6
- 239000002994 raw material Substances 0.000 claims abstract description 6
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 15
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 claims description 10
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 claims description 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 6
- 238000003756 stirring Methods 0.000 claims description 5
- MLFHJEHSLIIPHL-UHFFFAOYSA-N isoamyl acetate Chemical compound CC(C)CCOC(C)=O MLFHJEHSLIIPHL-UHFFFAOYSA-N 0.000 claims description 4
- 150000005690 diesters Chemical class 0.000 claims description 3
- 235000006408 oxalic acid Nutrition 0.000 claims description 3
- 229940117955 isoamyl acetate Drugs 0.000 claims description 2
- 241000255925 Diptera Species 0.000 abstract description 13
- 230000000694 effects Effects 0.000 abstract description 4
- 239000003814 drug Substances 0.000 description 4
- 239000000077 insect repellent Substances 0.000 description 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 3
- 229940079593 drug Drugs 0.000 description 3
- IKHGUXGNUITLKF-UHFFFAOYSA-N Acetaldehyde Chemical compound CC=O IKHGUXGNUITLKF-UHFFFAOYSA-N 0.000 description 2
- 239000003125 aqueous solvent Substances 0.000 description 2
- 235000019504 cigarettes Nutrition 0.000 description 2
- 239000000428 dust Substances 0.000 description 2
- 125000005575 polycyclic aromatic hydrocarbon group Chemical group 0.000 description 2
- 241000238631 Hexapoda Species 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 239000008280 blood Substances 0.000 description 1
- 210000004369 blood Anatomy 0.000 description 1
- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 230000008451 emotion Effects 0.000 description 1
- 239000002917 insecticide Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000012766 organic filler Substances 0.000 description 1
- 239000013618 particulate matter Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
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- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention discloses a kind of family expenses mosquitocide and preparation method thereof, mosquitocide comprises the raw material of following parts by weight: ATS (Ammonium thiosulphate) 10 ~ 20 parts, 10 ~ 20 parts, sodium sulphate, flufenoxuron 20 ~ 30 parts, dimethylbenzene 30 ~ 40 parts, calper calcium peroxide 20 ~ 30 parts, stannous chloride 15 ~ 25 parts, butyl acrylate 25 ~ 35 parts, o-phenylenediamine 20 ~ 30 parts, orthene 10 ~ 20 parts, 20 ~ 30 parts, aluminium hydroxide, 10 ~ 30 parts, phosphorous acid, catalyzer 2 ~ 20 parts, solvent 80 ~ 100 parts.ATS (Ammonium thiosulphate), sodium sulphate, flufenoxuron, dimethylbenzene, calper calcium peroxide, catalysts and solvents mix by preparation method, add thermal response, then stannous chloride, butyl acrylate, o-phenylenediamine, orthene, aluminium hydroxide, phosphorous acid is added, continue to add thermal response, be cooled to room temperature.Mosquitocide of the present invention has the effect of good kill mosquitoes, and action time is fast.
Description
Technical field
The present invention relates to mosquitocide field, particularly relate to a kind of family expenses mosquitocide and preparation method thereof.
Background technology
Mosquito is the stinking one of Chinese people " blood sucker ", and the detest of people to this insect is long-standing.Them are said: " though micro-helpless crowd, only little difficult gas defence " in " hating mosquito " poem that Song dynasty famous scholar OUYANG xiu is write; Allow people's sighing with emotion " smoked bitter cigarette dust burns wall tired according to candle ", the just outstanding this idea that have expressed people.Time-honored mosquito-repellent incense is the earliest by the insecticide used, and the similar mosquito-repelling rod that Chinese medicine is made just appearred period in the Southern Song Dynasty before thousands of year.In order to prevent the disaster of mosquito, people have invented mosquito-repellent incense gradually.But containing harmful material in the cigarette of mosquito incense burning, i.e. ultrafine dust (particulate matter that diameter is less than 2.5 microns), polycyclic aromatic hydrocarbons (PAH) (PAHs), carbonyls (as formaldehyde and acetaldehyde) and benzene.Meanwhile, except the obvious harmful substance of this 4 class, also have a large amount of organic fillers, binder, dyestuff and other additives in mosquito-repellent incense, mosquito-repellent incense just can be made to smoulder by nonflame.
Summary of the invention
The object of this invention is to provide a kind of family expenses mosquitocide, can effective kill mosquitoes, fast and effect action time is rapidly.
The present invention is by the following technical solutions:
A kind of family expenses mosquitocide, comprises the raw material of following parts by weight: ATS (Ammonium thiosulphate) 10 ~ 20 parts, 10 ~ 20 parts, sodium sulphate, flufenoxuron 20 ~ 30 parts, dimethylbenzene 30 ~ 40 parts, calper calcium peroxide 20 ~ 30 parts, stannous chloride 15 ~ 25 parts, butyl acrylate 25 ~ 35 parts, o-phenylenediamine 20 ~ 30 parts, orthene 10 ~ 20 parts, 20 ~ 30 parts, aluminium hydroxide, 10 ~ 30 parts, phosphorous acid, catalyzer 2 ~ 20 parts, solvent 80 ~ 100 parts.
As preferably, solvent is water or ethanol.
As preferably, when solvent is water, the content of water is 90 ~ 100 parts.
As preferably, when solvent is ethanol, the content of ethanol is 80 ~ 90 parts.
As preferably, catalyzer is the one in oxalic acid second diester, ethyl acetate or isoamyl acetate.
Present invention also offers the preparation method of above-mentioned family expenses mosquitocide, comprise the following steps: ATS (Ammonium thiosulphate), sodium sulphate, flufenoxuron, dimethylbenzene, calper calcium peroxide, catalysts and solvents are mixed, be heated to 40 ~ 50 DEG C of reaction 1 ~ 2h, then stannous chloride, butyl acrylate, o-phenylenediamine, orthene, aluminium hydroxide, phosphorous acid is added, stir, continue to be heated to 60 ~ 70 DEG C of reaction 1 ~ 2h, be cooled to room temperature.
Mosquitocide of the present invention has the effect of good kill mosquitoes, and action time is fast, and about 15min can kill most of mosquito, can substantially kill all mosquitoes after 1h.
Embodiment
embodiment 1
A kind of family expenses mosquitocide, comprises the raw material of following parts by weight: ATS (Ammonium thiosulphate) 10 parts, 10 parts, sodium sulphate, flufenoxuron 20 parts, dimethylbenzene 30 parts, calper calcium peroxide 20 parts, stannous chloride 15 parts, butyl acrylate 25 parts, o-phenylenediamine 20 parts, orthene 10 parts, 20 parts, aluminium hydroxide, 10 parts, phosphorous acid, catalyzer oxalic acid second diester 2 parts, aqueous solvent 90 parts.
The preparation method of above-mentioned family expenses mosquitocide, comprise the following steps: ATS (Ammonium thiosulphate), sodium sulphate, flufenoxuron, dimethylbenzene, calper calcium peroxide, catalysts and solvents are mixed, be heated to 40 DEG C of reaction 1h, then stannous chloride, butyl acrylate, o-phenylenediamine, orthene, aluminium hydroxide, phosphorous acid is added, stir, continue to be heated to 60 DEG C of reaction 1h, be cooled to room temperature.
embodiment 2
A kind of family expenses mosquitocide, comprises the raw material of following parts by weight: ATS (Ammonium thiosulphate) 20 parts, 20 parts, sodium sulphate, flufenoxuron 30 parts, dimethylbenzene 40 parts, calper calcium peroxide 30 parts, stannous chloride 25 parts, butyl acrylate 35 parts, o-phenylenediamine 30 parts, orthene 20 parts, 30 parts, aluminium hydroxide, 30 parts, phosphorous acid, catalyst acetic acid ethyl ester 20 parts, aqueous solvent 100 parts.
The preparation method of above-mentioned family expenses mosquitocide, comprise the following steps: ATS (Ammonium thiosulphate), sodium sulphate, flufenoxuron, dimethylbenzene, calper calcium peroxide, catalysts and solvents are mixed, be heated to 50 DEG C of reaction 2h, then stannous chloride, butyl acrylate, o-phenylenediamine, orthene, aluminium hydroxide, phosphorous acid is added, stir, continue to be heated to 70 DEG C of reaction 2h, be cooled to room temperature.
embodiment 3
A kind of family expenses mosquitocide, comprises the raw material of following parts by weight: ATS (Ammonium thiosulphate) 15 parts, 15 parts, sodium sulphate, flufenoxuron 25 parts, dimethylbenzene 35 parts, calper calcium peroxide 25 parts, stannous chloride 20 parts, butyl acrylate 30 parts, o-phenylenediamine 25 parts, orthene 15 parts, 25 parts, aluminium hydroxide, 20 parts, phosphorous acid, catalyst acetic acid ethyl ester 2 ~ 20 parts, etoh solvent 85 parts.
The preparation method of above-mentioned family expenses mosquitocide, comprise the following steps: ATS (Ammonium thiosulphate), sodium sulphate, flufenoxuron, dimethylbenzene, calper calcium peroxide, catalysts and solvents are mixed, be heated to 45 DEG C of reaction 1.5h, then stannous chloride, butyl acrylate, o-phenylenediamine, orthene, aluminium hydroxide, phosphorous acid is added, stir, continue to be heated to 65 DEG C of reaction 1.5h, be cooled to room temperature.
test
By the mosquitocide diluted concentration of embodiment 1 ~ 3 to 0.01g/L, carry out sprinkling rear enclosed space in indoor, result following (initial mosquito number is 30, unit: only):
| Embodiment 1 | Embodiment 2 | Embodiment 3 | |
| Residual borer population after medication 15min | 9 | 7 | 6 |
| Residual borer population after medication 30min | 2 | 2 | 3 |
| Residual borer population after medication 1h | 1 | 0 | 1 |
Conclusion: mosquitocide of the present invention has the effect of good kill mosquitoes, action time is fast, and about 15min can kill most of mosquito, can substantially kill all mosquitoes after 1h.
Claims (3)
1. a family expenses mosquitocide, is characterized in that: the raw material comprising following parts by weight: ATS (Ammonium thiosulphate) 10 ~ 20 parts, 10 ~ 20 parts, sodium sulphate, flufenoxuron 20 ~ 30 parts, dimethylbenzene 30 ~ 40 parts, calper calcium peroxide 20 ~ 30 parts, stannous chloride 15 ~ 25 parts, butyl acrylate 25 ~ 35 parts, o-phenylenediamine 20 ~ 30 parts, orthene 10 ~ 20 parts, 20 ~ 30 parts, aluminium hydroxide, 10 ~ 30 parts, phosphorous acid, catalyzer 2 ~ 20 parts, solvent 80 ~ 100 parts; Solvent is water or ethanol; Its preparation method comprises the following steps: ATS (Ammonium thiosulphate), sodium sulphate, flufenoxuron, dimethylbenzene, calper calcium peroxide, catalysts and solvents are mixed, be heated to 40 ~ 50 DEG C of reaction 1 ~ 2h, then stannous chloride, butyl acrylate, o-phenylenediamine, orthene, aluminium hydroxide, phosphorous acid is added, stir, continue to be heated to 60 ~ 70 DEG C of reaction 1 ~ 2h, be cooled to room temperature; Catalyzer is the one in oxalic acid second diester, ethyl acetate or isoamyl acetate.
2. family expenses mosquitocide according to claim 1, is characterized in that: when solvent is water, and the parts by weight of water are 90 ~ 100 parts.
3. family expenses mosquitocide according to claim 1, is characterized in that: when solvent is ethanol, and the parts by weight of ethanol are 80 ~ 90 parts.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410019565.4A CN103766395B (en) | 2014-01-16 | 2014-01-16 | A kind of family expenses mosquitocide and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410019565.4A CN103766395B (en) | 2014-01-16 | 2014-01-16 | A kind of family expenses mosquitocide and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103766395A CN103766395A (en) | 2014-05-07 |
| CN103766395B true CN103766395B (en) | 2016-02-24 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN201410019565.4A Expired - Fee Related CN103766395B (en) | 2014-01-16 | 2014-01-16 | A kind of family expenses mosquitocide and preparation method thereof |
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Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA2459698C (en) * | 2001-09-07 | 2010-02-23 | Syngenta Participations Ag | Surfactant systems for agriculturally active compounds |
| WO2007085899A2 (en) * | 2005-07-06 | 2007-08-02 | Foamix Ltd. | Foamable arthropocidal composition for tropical application |
| CN100382698C (en) * | 2005-08-12 | 2008-04-23 | 南京第一农药有限公司 | Synergistic compound pesticide contg. flufenoxuron |
| CN102396529A (en) * | 2010-09-13 | 2012-04-04 | 刘亮 | High-efficiency mothproofing agent |
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Granted publication date: 20160224 Termination date: 20170116 |
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