CN103524033A - High-temperature alloy bushing plate plated by platinum and alloy thereof, and preparation method of high-temperature alloy bushing plate - Google Patents
High-temperature alloy bushing plate plated by platinum and alloy thereof, and preparation method of high-temperature alloy bushing plate Download PDFInfo
- Publication number
- CN103524033A CN103524033A CN201210232548.XA CN201210232548A CN103524033A CN 103524033 A CN103524033 A CN 103524033A CN 201210232548 A CN201210232548 A CN 201210232548A CN 103524033 A CN103524033 A CN 103524033A
- Authority
- CN
- China
- Prior art keywords
- bushing
- platinum
- alloy
- superalloy
- small opening
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 title claims abstract description 68
- 229910052697 platinum Inorganic materials 0.000 title claims abstract description 33
- 239000000956 alloy Substances 0.000 title claims abstract description 29
- 229910045601 alloy Inorganic materials 0.000 title claims abstract description 28
- 238000002360 preparation method Methods 0.000 title claims abstract description 7
- 238000000576 coating method Methods 0.000 claims abstract description 25
- 239000011248 coating agent Substances 0.000 claims abstract description 21
- VBJZVLUMGGDVMO-UHFFFAOYSA-N hafnium atom Chemical compound [Hf] VBJZVLUMGGDVMO-UHFFFAOYSA-N 0.000 claims abstract description 4
- 229910000765 intermetallic Inorganic materials 0.000 claims abstract description 4
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 claims abstract description 3
- BPUBBGLMJRNUCC-UHFFFAOYSA-N oxygen(2-);tantalum(5+) Chemical compound [O-2].[O-2].[O-2].[O-2].[O-2].[Ta+5].[Ta+5] BPUBBGLMJRNUCC-UHFFFAOYSA-N 0.000 claims abstract description 3
- 239000000126 substance Substances 0.000 claims abstract description 3
- 229910052715 tantalum Inorganic materials 0.000 claims abstract description 3
- GUVRBAGPIYLISA-UHFFFAOYSA-N tantalum atom Chemical compound [Ta] GUVRBAGPIYLISA-UHFFFAOYSA-N 0.000 claims abstract description 3
- 229910001936 tantalum oxide Inorganic materials 0.000 claims abstract description 3
- 229910052726 zirconium Inorganic materials 0.000 claims abstract description 3
- 229910000601 superalloy Inorganic materials 0.000 claims description 33
- 238000007747 plating Methods 0.000 claims description 14
- 239000000463 material Substances 0.000 claims description 10
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 claims description 8
- 239000008186 active pharmaceutical agent Substances 0.000 claims description 8
- 229910001260 Pt alloy Inorganic materials 0.000 claims description 6
- 229910052786 argon Inorganic materials 0.000 claims description 4
- 239000007789 gas Substances 0.000 claims description 4
- 241000588731 Hafnia Species 0.000 claims description 2
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 claims description 2
- 238000005275 alloying Methods 0.000 claims description 2
- 229910052735 hafnium Inorganic materials 0.000 claims description 2
- CJNBYAVZURUTKZ-UHFFFAOYSA-N hafnium(IV) oxide Inorganic materials O=[Hf]=O CJNBYAVZURUTKZ-UHFFFAOYSA-N 0.000 claims description 2
- 238000000034 method Methods 0.000 abstract description 2
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 abstract 1
- 229910001928 zirconium oxide Inorganic materials 0.000 abstract 1
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 8
- 230000003245 working effect Effects 0.000 description 5
- 229910052759 nickel Inorganic materials 0.000 description 4
- PXXKQOPKNFECSZ-UHFFFAOYSA-N platinum rhodium Chemical compound [Rh].[Pt] PXXKQOPKNFECSZ-UHFFFAOYSA-N 0.000 description 4
- 238000005728 strengthening Methods 0.000 description 3
- 239000011521 glass Substances 0.000 description 2
- 239000003365 glass fiber Substances 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 239000006060 molten glass Substances 0.000 description 2
- 208000037656 Respiratory Sounds Diseases 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000001953 recrystallisation Methods 0.000 description 1
- 238000007634 remodeling Methods 0.000 description 1
- 229910052703 rhodium Inorganic materials 0.000 description 1
- 239000010948 rhodium Substances 0.000 description 1
- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 description 1
- 238000004062 sedimentation Methods 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
Images
Landscapes
- Electroplating Methods And Accessories (AREA)
Abstract
The invention relates to a high-temperature alloy bushing plate, and particularly relates to a high-temperature alloy bushing plate plated by platinum and alloy thereof, and a preparation method of the high-temperature alloy bushing plate. The method is characterized in that one or more holes are formed on the high-temperature alloy bushing plate; tap holes are of funnel-shaped structures; the diameter of the upper end of each tap hole is greater than that of the lower end of each tape hole; platinum coatings and alloy coatings of platinum are coated at the inner surfaces of the tap holes of the high-temperature alloy bushing plate and the edges of the upper openings of the tape holes; alloy elements are one or more of zirconium, tantalum and celtium; the alloy in each coating exists in a form of a simple substance or forms an intermetallic compound together with the platinum, or is one or more of zirconium oxide, tantalum oxide and celtium oxide; the platinum coatings and the alloy coatings at the inner surfaces of the tap holes of the high-temperature alloy bushing plate and the edges of the upper openings of the tape hole are 5-50mum thick.
Description
Technical field
The present invention relates to a kind of superalloy bushing, especially relate to superalloy bushing of a kind of platinum plating and alloy thereof and preparation method thereof.
Background technology
Superalloy bushing is one of parts important in glass fiber industry, and it has a significant impact job stabilization and former yarn quality.Domestic glass fibre producer is generally used nickel-base high-temperature alloy material, but the life-span is shorter, relatively waste.On market, use platinum rhodium material as bushing, but price costliness very make its production increase cost.Substituting of the High-Temperature Strengthening of superalloy drain board material and cheap material is the important problem in glass industry always, at present by intermetallic compound (Pt
3hf, Pt
3zr etc.) strengthening and refractory oxide (ZrO
2, Y
2o
3) disperse phase strengthens to improve thermostability and the recrystallization temperature of bushing, and hinder and move to reach the object of improving material property for Wrong Shipment.Along with the price of platinum and rhodium rises steadily and the maximization of glass bushing, the strengthening of platinum rhodium and find novel material and new technology seems very important.
Summary of the invention
The technical problem to be solved in the present invention is to provide superalloy bushing of a kind of platinum plating and alloy thereof and preparation method thereof, the method can overcome the shortcomings such as in prior art, work-ing life is short, cost value is high, it is characterized in that the small opening internal surface of bushing and small opening edge suitable for reading are coated with platinum coating and alloy coat thereof.
Described bushing coat-thickness is 5～50 μ m.
The small opening of described bushing is funnel shaped structure, and small opening upper end diameter is greater than small opening lower end diameter.
On described superalloy bushing, there is a hole.
On described superalloy bushing, there are a plurality of holes.
The coating of described bushing is platinum.
The coating of described bushing is platinum alloy, and alloying element is wherein one or more in zirconium, tantalum, hafnium.
Alloy in the coating of described bushing exists with simple substance form or forms intermetallic compound with platinum.
Alloy in the coating of described bushing is one or more in zirconium white, tantalum oxide, hafnia.
The present invention is to provide the preparation method of the superalloy bushing of a kind of platinum plating and alloy thereof, it is characterized in that comprising the step of following order:
(1) superalloy bushing and platinum alloy silk are placed in vacuum chamber;
(2) in vacuum chamber, vacuumize, internal pressure is 4 * 10
-3pa;
(3) superalloy bushing, as base material, is placed in vacuum chamber, and bushing centerline hole is sea line, connects volts DS, and voltage is-300～-400V;
(4) platinum filament or platinum alloy silk, as target, pass bushing hole, and parallel with small opening medullary ray, connect volts DS, and voltage is-800～-900V;
(5) applying argon gas, to vacuum system, makes the operating air pressure in vacuum system reach 1～10Pa;
(6) keep 1-2 hour, powered-down, opens vacuum chamber, takes out bushing.
Effect: the present invention compared with prior art, has the following advantages:
(1) sedimentation velocity is fast, and concentration is high, and thickness is easily controlled, and has improved efficiency prepared by coating;
(2) to the small opening internal surface of the superalloy bushing of curve form and small opening edge suitable for reading, can prepare coating;
(3) can obtain smooth, bright and clean, the fine and close coating that there is no continuously crackle;
(4) between coating and superalloy bushing, combination is firm;
(5) reduce costs, the advantage such as increase the service life.
Accompanying drawing explanation
Fig. 1 is a kind of platinum plating superalloy bushing containing a plurality of small openings.
Fig. 2 is a kind of platinum plating superalloy bushing that contains a small opening.
Embodiment
Below in conjunction with specific embodiment, further illustrate the present invention, should understand these embodiment is only not used in and limits the scope of the invention for the present invention is described, after having read the present invention, those skilled in the art all fall within the application's claims to the modification of the various equivalent form of values of the present invention and limit.
Embodiment 1
With reference to Fig. 1, the superalloy bushing of a kind of platinum plating and alloy thereof comprises: platinum plating coating 10, superalloy support 20.
Concrete operation step is: use nickel base superalloy bushing as base material, wherein small opening is 3, and upper part small opening maximum diameter is 50mm, minimum diameter is 30mm, and superalloy bushing is placed in vacuum chamber, and bushing centerline hole is sea line, connect volts DS, voltage is-350V; Platinum filament, as target, passes bushing hole, and parallel with small opening medullary ray, connects volts DS, and voltage is-800V; Applying argon gas, to vacuum system, makes the operating air pressure in vacuum system reach 5Pa, through 2h platinum plating coating, the fine and close platinum coating that can be coated with 5～6 μ m thickness at small opening internal surface and the small opening edge suitable for reading of superalloy bushing.In 1000 ℃ of high-temperature molten glass, use, will extend one-month period than the work-ing life of nickel base superalloy bushing itself its work-ing life, and cost is more cheap than platinum rhodium.
Embodiment 2
With reference to Fig. 2, the superalloy bushing of a kind of platinum plating and alloy thereof comprises: platinum plating coating 10, superalloy base material 30, heat electric wire 40.
Concrete operation step is: use nickel base superalloy bushing as base material, wherein small opening is one, and upper part small opening maximum diameter is 50mm, minimum diameter is 30mm, and superalloy bushing is placed in vacuum chamber, and bushing centerline hole is sea line, connect volts DS, voltage is-350V; Platinum filament, as target, passes bushing hole, and parallel with small opening medullary ray, connects volts DS, and voltage is-800V; Applying argon gas, to vacuum system, makes the operating air pressure in vacuum system reach 5Pa, through 2h platinum plating coating, the fine and close platinum coating that can be coated with 5～6 μ m thickness at small opening internal surface and the small opening edge suitable for reading of superalloy bushing.In 1000 ℃ of high-temperature molten glass, use, will extend one-month period than the work-ing life of nickel base superalloy bushing itself its work-ing life, and cost is more cheap than platinum rhodium.
Above are only single embodiment of the present invention, but design concept of the present invention is not limited to this, allly utilizes this design to carry out the change of unsubstantiality to the present invention, all should belong to the behavior of invading the scope of protection of the invention.In every case be the content that does not depart from technical solution of the present invention, any type of simple modification, equivalent variations and the remodeling above embodiment done according to technical spirit of the present invention, still belong to the protection domain of technical solution of the present invention.
Claims (10)
1. a superalloy bushing for platinum plating and alloy thereof, is characterized in that the small opening internal surface of bushing and small opening edge suitable for reading are coated with platinum coating and alloy coat thereof.
2. according to the bushing described in claims 1, it is characterized in that coat-thickness is 5～50 μ m.
3. according to the bushing described in claims 1, it is characterized in that small opening is funnel shaped structure, small opening upper end diameter is greater than small opening lower end diameter.
4. according to the bushing described in claims 1, it is characterized in that on superalloy bushing, there is a hole.
5. according to the bushing described in claims 1, it is characterized in that on superalloy bushing, there are a plurality of holes.
6. according to the bushing described in claims 1, it is characterized in that coating is platinum.
7. according to the bushing described in claims 1, it is characterized in that coating is platinum alloy, alloying element is wherein one or more in zirconium, tantalum, hafnium.
8. according to the bushing described in claims 1, it is characterized in that the alloy in coating exists with simple substance form or forms intermetallic compound with platinum.
9. according to the bushing described in claims 1, it is characterized in that alloy in coating is one or more in zirconium white, tantalum oxide, hafnia.
10. a preparation method for the superalloy bushing of platinum plating and alloy thereof, is characterized in that comprising the step of following order:
(1) superalloy bushing and platinum alloy silk are placed in vacuum chamber;
(2) in vacuum chamber, vacuumize, internal pressure is 4 * 10
-3pa;
(3) superalloy bushing, as base material, is placed in vacuum chamber, and bushing centerline hole is sea line, connects volts DS, and voltage is-300～-400V;
(4) platinum filament or platinum alloy silk, as target, pass bushing hole, and parallel with small opening medullary ray, connect volts DS, and voltage is-800～-900V;
(5) applying argon gas, to vacuum system, makes the operating air pressure in vacuum system reach 1～10Pa;
(6) keep 1-2 hour, powered-down, opens vacuum chamber, takes out bushing.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210232548.XA CN103524033A (en) | 2012-07-06 | 2012-07-06 | High-temperature alloy bushing plate plated by platinum and alloy thereof, and preparation method of high-temperature alloy bushing plate |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210232548.XA CN103524033A (en) | 2012-07-06 | 2012-07-06 | High-temperature alloy bushing plate plated by platinum and alloy thereof, and preparation method of high-temperature alloy bushing plate |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN103524033A true CN103524033A (en) | 2014-01-22 |
Family
ID=49926451
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201210232548.XA Pending CN103524033A (en) | 2012-07-06 | 2012-07-06 | High-temperature alloy bushing plate plated by platinum and alloy thereof, and preparation method of high-temperature alloy bushing plate |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103524033A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104843989A (en) * | 2015-04-14 | 2015-08-19 | 南京航空航天大学 | Method for rapidly adjusting glass flow amount through alloy bushing plate |
Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3988135A (en) * | 1975-07-28 | 1976-10-26 | Kaiser Glass Fiber Corporation | Assembly for the drawing of glass fibers |
| US4846865A (en) * | 1988-03-15 | 1989-07-11 | Owens-Corning Fiberglas Corporation | Clad precious metal bushing and method for making |
| CN1445185A (en) * | 2002-01-28 | 2003-10-01 | W.C.贺利氏股份有限及两合公司 | Crucible for drawing glass fibre |
| CN201254524Y (en) * | 2008-08-11 | 2009-06-10 | 四川威玻新材料集团有限公司 | Novel glass fiber forming drawing platinum-rhodium alloy bushing plate |
| CN101506113A (en) * | 2006-08-23 | 2009-08-12 | 日本电气硝子株式会社 | Bushing for production of glass continuous filament, equipment for producing glass continuous filament and process for production of the filament using the equipment |
| CN101787514A (en) * | 2010-03-15 | 2010-07-28 | 南京航空航天大学 | Platinum-group metal coating on surface of refractory metal and preparation method thereof |
| CN202705230U (en) * | 2012-07-06 | 2013-01-30 | 苏州宏久航空防热材料科技有限公司 | High-temperature alloy leaky plate plated with platinum and platinum alloy |
-
2012
- 2012-07-06 CN CN201210232548.XA patent/CN103524033A/en active Pending
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3988135A (en) * | 1975-07-28 | 1976-10-26 | Kaiser Glass Fiber Corporation | Assembly for the drawing of glass fibers |
| US4846865A (en) * | 1988-03-15 | 1989-07-11 | Owens-Corning Fiberglas Corporation | Clad precious metal bushing and method for making |
| CN1445185A (en) * | 2002-01-28 | 2003-10-01 | W.C.贺利氏股份有限及两合公司 | Crucible for drawing glass fibre |
| CN101506113A (en) * | 2006-08-23 | 2009-08-12 | 日本电气硝子株式会社 | Bushing for production of glass continuous filament, equipment for producing glass continuous filament and process for production of the filament using the equipment |
| CN201254524Y (en) * | 2008-08-11 | 2009-06-10 | 四川威玻新材料集团有限公司 | Novel glass fiber forming drawing platinum-rhodium alloy bushing plate |
| CN101787514A (en) * | 2010-03-15 | 2010-07-28 | 南京航空航天大学 | Platinum-group metal coating on surface of refractory metal and preparation method thereof |
| CN202705230U (en) * | 2012-07-06 | 2013-01-30 | 苏州宏久航空防热材料科技有限公司 | High-temperature alloy leaky plate plated with platinum and platinum alloy |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104843989A (en) * | 2015-04-14 | 2015-08-19 | 南京航空航天大学 | Method for rapidly adjusting glass flow amount through alloy bushing plate |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN102094164B (en) | Nanometer zirconium oxide thermal barrier coating and preparation method thereof | |
| CN107739141B (en) | Platinum channel, manufacturing method thereof and zirconia dry powder mixture for coating | |
| Song et al. | Effect of TiO2 nanoparticles on the microstructure and corrosion behavior of MAO coatings on magnesium alloy | |
| RU2011137423A (en) | METHOD FOR PRODUCING A THERMAL BARRIER COVERING A METAL SUBSTRATE FROM A HEAT-RESISTANT ALLOY, AND A THERMOMECHANICAL DETAIL OBTAINED BY THIS METHOD OF MANUFACTURE | |
| JP2015166479A (en) | New structure for thermal barrier coating improved in erosion and impact property and having ultralow thermal conductivity | |
| CN202705230U (en) | High-temperature alloy leaky plate plated with platinum and platinum alloy | |
| CN107326330A (en) | A kind of integrated evaporation boat of the internal heat type with aluminum oxide porous textured buffer layers | |
| CN101439267A (en) | A kind of preparation method of hydrogen permeable palladium composite membrane | |
| CN103524033A (en) | High-temperature alloy bushing plate plated by platinum and alloy thereof, and preparation method of high-temperature alloy bushing plate | |
| CN102758203B (en) | A method for metallizing the surface of an optical fiber | |
| CN105671619A (en) | Methods of forming an article using electrophoretic deposition, and related article | |
| CN108620298A (en) | Electrothermal silicon carbide element surface oxidation-resistant coating and preparation method thereof | |
| CN102774089A (en) | Novel gradient thermal barrier coating | |
| CN102179969B (en) | Coat for accurately measuring stress in thermal barrier coating | |
| JP6219828B2 (en) | Molten glass filament supply device and manufacturing method thereof | |
| CN117720342A (en) | Ceramic materials, powders and layer systems including ceramic materials | |
| CN104376952A (en) | Platinum-alloy-plated high-temperature alloy iron core | |
| CN208570139U (en) | A kind of high temperature resistant sensor, high temperature resistant winding coil conducting wire | |
| CN104501592B (en) | Low energy consumption resistance furnace for magnesium alloy smelting | |
| CN201970511U (en) | Coating for accurately measuring stress in thermal barrier coating | |
| CN208240383U (en) | A kind of winding wire resistant to high temperature | |
| CN206623480U (en) | A kind of aluminium plating zinc plate | |
| JP2017052672A (en) | Sealing agent, sealing agent coating solution, corrosion-resistant coating film, high-temperature member, and method for producing high-temperature member | |
| CN103722803A (en) | Strong-strength radiation coating for aircraft engine | |
| Wang et al. | In situ formation of Al2O3–ZrO2–Y2O3 composite ceramic coating by plasma electrolytic oxidation on ZAlSi12Cu3Ni2 alloy |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C12 | Rejection of a patent application after its publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20140122 |