CN103444763B - A kind of composite insecticide containing penta pyrrole worm guanidine - Google Patents
A kind of composite insecticide containing penta pyrrole worm guanidine Download PDFInfo
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- CN103444763B CN103444763B CN201310444436.5A CN201310444436A CN103444763B CN 103444763 B CN103444763 B CN 103444763B CN 201310444436 A CN201310444436 A CN 201310444436A CN 103444763 B CN103444763 B CN 103444763B
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- Prior art keywords
- pyrrole worm
- worm guanidine
- chrysanthemum ester
- penta pyrrole
- ether chrysanthemum
- Prior art date
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- ZRALSGWEFCBTJO-UHFFFAOYSA-N Guanidine Chemical compound NC(N)=N ZRALSGWEFCBTJO-UHFFFAOYSA-N 0.000 title claims abstract description 84
- KAESVJOAVNADME-UHFFFAOYSA-N Pyrrole Chemical compound C=1C=CNC=1 KAESVJOAVNADME-UHFFFAOYSA-N 0.000 title claims abstract description 84
- CHJJGSNFBQVOTG-UHFFFAOYSA-N N-methyl-guanidine Natural products CNC(N)=N CHJJGSNFBQVOTG-UHFFFAOYSA-N 0.000 title claims abstract description 42
- SWSQBOPZIKWTGO-UHFFFAOYSA-N dimethylaminoamidine Natural products CN(C)C(N)=N SWSQBOPZIKWTGO-UHFFFAOYSA-N 0.000 title claims abstract description 42
- 239000002917 insecticide Substances 0.000 title claims abstract description 19
- 239000002131 composite material Substances 0.000 title claims abstract description 9
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims abstract description 80
- 241000723353 Chrysanthemum Species 0.000 claims abstract description 37
- 235000007516 Chrysanthemum Nutrition 0.000 claims abstract description 37
- 150000002148 esters Chemical class 0.000 claims abstract description 37
- 239000012752 auxiliary agent Substances 0.000 claims abstract description 9
- 239000000203 mixture Substances 0.000 claims abstract description 6
- 239000000843 powder Substances 0.000 claims description 14
- 238000009736 wetting Methods 0.000 claims description 10
- RCEAADKTGXTDOA-UHFFFAOYSA-N OS(O)(=O)=O.CCCCCCCCCCCC[Na] Chemical compound OS(O)(=O)=O.CCCCCCCCCCCC[Na] RCEAADKTGXTDOA-UHFFFAOYSA-N 0.000 claims description 7
- 239000004562 water dispersible granule Substances 0.000 claims description 7
- 239000004480 active ingredient Substances 0.000 claims description 6
- 239000005995 Aluminium silicate Substances 0.000 claims description 4
- 229920001732 Lignosulfonate Polymers 0.000 claims description 4
- 239000002202 Polyethylene glycol Substances 0.000 claims description 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 4
- DPXJVFZANSGRMM-UHFFFAOYSA-N acetic acid;2,3,4,5,6-pentahydroxyhexanal;sodium Chemical compound [Na].CC(O)=O.OCC(O)C(O)C(O)C(O)C=O DPXJVFZANSGRMM-UHFFFAOYSA-N 0.000 claims description 4
- 235000012211 aluminium silicate Nutrition 0.000 claims description 4
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 claims description 4
- 229910052921 ammonium sulfate Inorganic materials 0.000 claims description 4
- 235000011130 ammonium sulphate Nutrition 0.000 claims description 4
- UDHMTPILEWBIQI-UHFFFAOYSA-N butyl naphthalene-1-sulfonate;sodium Chemical compound [Na].C1=CC=C2C(S(=O)(=O)OCCCC)=CC=CC2=C1 UDHMTPILEWBIQI-UHFFFAOYSA-N 0.000 claims description 4
- 239000001768 carboxy methyl cellulose Substances 0.000 claims description 4
- LQZZUXJYWNFBMV-UHFFFAOYSA-N dodecan-1-ol Chemical class CCCCCCCCCCCCO LQZZUXJYWNFBMV-UHFFFAOYSA-N 0.000 claims description 4
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims description 4
- 229920001223 polyethylene glycol Polymers 0.000 claims description 4
- 235000019812 sodium carboxymethyl cellulose Nutrition 0.000 claims description 4
- 229920001027 sodium carboxymethylcellulose Polymers 0.000 claims description 4
- YDEXUEFDPVHGHE-GGMCWBHBSA-L disodium;(2r)-3-(2-hydroxy-3-methoxyphenyl)-2-[2-methoxy-4-(3-sulfonatopropyl)phenoxy]propane-1-sulfonate Chemical compound [Na+].[Na+].COC1=CC=CC(C[C@H](CS([O-])(=O)=O)OC=2C(=CC(CCCS([O-])(=O)=O)=CC=2)OC)=C1O YDEXUEFDPVHGHE-GGMCWBHBSA-L 0.000 claims description 3
- 239000011230 binding agent Substances 0.000 claims description 2
- 238000005469 granulation Methods 0.000 claims description 2
- 230000003179 granulation Effects 0.000 claims description 2
- 238000010298 pulverizing process Methods 0.000 claims description 2
- 238000003756 stirring Methods 0.000 claims description 2
- 239000004615 ingredient Substances 0.000 claims 2
- LCRMGUFGEDUSOG-UHFFFAOYSA-N naphthalen-1-ylsulfonyloxymethyl naphthalene-1-sulfonate;sodium Chemical compound [Na].C1=CC=C2C(S(=O)(OCOS(=O)(=O)C=3C4=CC=CC=C4C=CC=3)=O)=CC=CC2=C1 LCRMGUFGEDUSOG-UHFFFAOYSA-N 0.000 claims 1
- 241000176086 Sogatella furcifera Species 0.000 abstract description 17
- 239000000575 pesticide Substances 0.000 abstract description 11
- 239000003814 drug Substances 0.000 abstract description 8
- 241000209094 Oryza Species 0.000 abstract description 7
- 235000007164 Oryza sativa Nutrition 0.000 abstract description 7
- 235000009566 rice Nutrition 0.000 abstract description 7
- 238000012360 testing method Methods 0.000 abstract description 5
- 230000000749 insecticidal effect Effects 0.000 abstract description 4
- 230000002045 lasting effect Effects 0.000 abstract description 3
- 230000003111 delayed effect Effects 0.000 abstract description 2
- 238000003912 environmental pollution Methods 0.000 abstract description 2
- 230000002195 synergetic effect Effects 0.000 abstract description 2
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 9
- 239000000839 emulsion Substances 0.000 description 6
- 238000000034 method Methods 0.000 description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 4
- 241000894007 species Species 0.000 description 4
- 239000007921 spray Substances 0.000 description 4
- DMAXMXPDVWTIRV-UHFFFAOYSA-N 2-(2-phenylethyl)phenol Chemical compound OC1=CC=CC=C1CCC1=CC=CC=C1 DMAXMXPDVWTIRV-UHFFFAOYSA-N 0.000 description 3
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 description 3
- 239000005906 Imidacloprid Substances 0.000 description 3
- 229920000877 Melamine resin Polymers 0.000 description 3
- 150000004996 alkyl benzenes Chemical class 0.000 description 3
- WMGSQTMJHBYJMQ-UHFFFAOYSA-N aluminum;magnesium;silicate Chemical compound [Mg+2].[Al+3].[O-][Si]([O-])([O-])[O-] WMGSQTMJHBYJMQ-UHFFFAOYSA-N 0.000 description 3
- 239000011575 calcium Substances 0.000 description 3
- 229910052791 calcium Inorganic materials 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 3
- 239000007859 condensation product Substances 0.000 description 3
- 229940056881 imidacloprid Drugs 0.000 description 3
- 239000012071 phase Substances 0.000 description 3
- 229920006324 polyoxymethylene Polymers 0.000 description 3
- 229920001296 polysiloxane Polymers 0.000 description 3
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 3
- 229920001285 xanthan gum Polymers 0.000 description 3
- 241001498622 Cixius wagneri Species 0.000 description 2
- 239000008346 aqueous phase Substances 0.000 description 2
- 235000021329 brown rice Nutrition 0.000 description 2
- YWTYJOPNNQFBPC-UHFFFAOYSA-N imidacloprid Chemical compound [O-][N+](=O)\N=C1/NCCN1CC1=CC=C(Cl)N=C1 YWTYJOPNNQFBPC-UHFFFAOYSA-N 0.000 description 2
- 238000011835 investigation Methods 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 231100000572 poisoning Toxicity 0.000 description 2
- 230000000607 poisoning effect Effects 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 239000005885 Buprofezin Substances 0.000 description 1
- 241000238631 Hexapoda Species 0.000 description 1
- 241001465754 Metazoa Species 0.000 description 1
- SECXISVLQFMRJM-UHFFFAOYSA-N N-Methylpyrrolidone Chemical compound CN1CCCC1=O SECXISVLQFMRJM-UHFFFAOYSA-N 0.000 description 1
- 241000819999 Nymphes Species 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- 208000027418 Wounds and injury Diseases 0.000 description 1
- 238000013019 agitation Methods 0.000 description 1
- 230000002528 anti-freeze Effects 0.000 description 1
- -1 antifreeze Substances 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- PRLVTUNWOQKEAI-VKAVYKQESA-N buprofezin Chemical compound O=C1N(C(C)C)\C(=N\C(C)(C)C)SCN1C1=CC=CC=C1 PRLVTUNWOQKEAI-VKAVYKQESA-N 0.000 description 1
- 235000019994 cava Nutrition 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000005660 chlorination reaction Methods 0.000 description 1
- 230000006378 damage Effects 0.000 description 1
- 239000013530 defoamer Substances 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000036039 immunity Effects 0.000 description 1
- 208000014674 injury Diseases 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 231100000053 low toxicity Toxicity 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- VEMKTZHHVJILDY-UHFFFAOYSA-N resmethrin Chemical compound CC1(C)C(C=C(C)C)C1C(=O)OCC1=COC(CC=2C=CC=CC=2)=C1 VEMKTZHHVJILDY-UHFFFAOYSA-N 0.000 description 1
- 238000005070 sampling Methods 0.000 description 1
- 238000012216 screening Methods 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000000375 suspending agent Substances 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
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- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention discloses a kind of composite insecticide containing penta pyrrole worm guanidine, belong to pesticide control technical field.The weight ratio of penta pyrrole worm guanidine and ether chrysanthemum ester is 1:60-60:1.Also include auxiliary agent and carrier in its composition, wherein penta pyrrole worm guanidine and ether chrysanthemum ester account for the 5%-60% of insecticidal total weight, and auxiliary agent accounts for the 5%-30% of insecticidal total weight, and all the other are carrier.Insecticide of the present invention, through actual test, has significant control efficiency to rice hoppers.Composite insecticide of the present invention, compared with common insecticides, has the following advantages: this kind has obvious synergistic effect to rice fulgorid compared with single dose, can significantly improve control efficiency; Can high malicious insecticide in Substitute For Partial, reduce dosage, reduce the residual of environmental pollution and agricultural product; The pesticide resistance of rice fulgorid to single insecticide can be delayed, there is the advantage of lasting period length, compared with single medicament, can reduce costs.
Description
Technical field
The invention belongs to pesticide control technical field, relate to one and prevent and treat rice hoppers insecticide.
Background technology
Rice fulgorid (comprises rice fulgorid, small brown rice planthopper, white-backed planthopper) be that one migrates very capable (except small brown rice planthopper), there is high intrinsic rate of increase, when condition is suitable for, population often increases rapidly, very easily population outbreak, therefore, chemical control controls the most effective approach of rice fulgorid population, since the eighties, pesticide control is with Buprofezin, Imidacloprid, organic phosphor and built agent thereof are main, play an important role in Rice Production, especially at the novel super-high effect chlorination nicotinic insecticide-Imidacloprid of the mid-90 exploitation, good to rice fulgorid quick-acting, lasting effect is long, consumption is few, to people and animals' low toxicity and and environmentally compatible, become rapidly the main pesticide species preventing and treating rice hoppers, due to single for a long time, extensive use continuously, be equivalent to the resistance screening that rice fulgorid is extensive in field, rice fulgorid produces obvious pesticide resistance to Imidacloprid, control efficiency sharply declines, the pesticide species current Rice Production effectively controlling rice fulgorid also lacks very much, although there is new pesticide species to release, but cost accounting is too large, and the use of single pesticide species, rice fulgorid easily develops immunity to drugs.
Summary of the invention
Technical problem to be solved by this invention is to provide a kind of insecticide containing penta pyrrole worm guanidine and ether chrysanthemum ester preventing and treating rice hoppers with better control efficiency.
The composite insecticide containing penta pyrrole worm guanidine and ether chrysanthemum ester of the present invention, its active ingredient is penta pyrrole worm guanidine and ether chrysanthemum ester, and wherein the weight ratio of penta pyrrole worm guanidine and ether chrysanthemum ester is 1:60-60:1; Also include auxiliary agent and carrier in said composition, wherein penta pyrrole worm guanidine and ether chrysanthemum ester account for the 5%-60% of insecticidal total weight, and auxiliary agent accounts for the 5%-30% of insecticidal total weight, and all the other are carrier.
Wherein said auxiliary agent is lauryl sodium sulfate, ethoxylated dodecyl alcohol, lignosulfonates, sulfonic acid polyformaldehyde condensation product (NNO), polyethylene glycol, ammonium sulfate, sodium carboxymethylcellulose, sodium butylnaphthalenesulfonate, 1-METHYLPYRROLIDONE, alkyl benzene calcium sulfonate, phenethyl phenol mela mine-formaldehyde resin polyoxyethyl ether, ethylene glycol, silicone compound, xanthans, aluminium-magnesium silicate.
Wherein said carrier is kaolin, diatomite, water.
The composite insecticide containing penta pyrrole worm guanidine and ether chrysanthemum ester of the present invention can be water dispersible granules, wetting powder or aqueous emulsion.
Insecticide of the present invention, through actual test, has significant control efficiency to rice hoppers.
Composite insecticide of the present invention, compared with common insecticides, has the following advantages: 1, this kind has obvious synergistic effect to rice fulgorid compared with single dose, can significantly improve control efficiency; 2, can high malicious insecticide in Substitute For Partial, reduce dosage, reduce the residual of environmental pollution and agricultural product; 3, the pesticide resistance of rice fulgorid to single insecticide can be delayed, 4, there is lasting period long advantage, compared with single medicament, can reduce costs.
Embodiment
embodiment 1:30.5% penta pyrrole worm guanidine ether chrysanthemum ester water dispersible granules
0.5g penta pyrrole worm guanidine, 30g ether chrysanthemum ester, 4g lauryl sodium sulfate, 2g ethoxylated dodecyl alcohol, 2g lignosulfonates, 2g sulfonic acid polyformaldehyde condensation product (NNO), 2g polyethylene glycol, 4g ammonium sulfate, 10g sodium carboxymethylcellulose, kaolin are mended to 100g, obtained 30.5% penta pyrrole worm guanidine ether chrysanthemum ester wetting powders.
embodiment 2:30.5% penta pyrrole worm guanidine ether chrysanthemum ester water dispersible granules
30g penta pyrrole worm guanidine, 0.5g ether chrysanthemum ester, 4g lauryl sodium sulfate, 2g ethoxylated dodecyl alcohol, 2g lignosulfonates, 2g sulfonic acid polyformaldehyde condensation product (NNO), 2g polyethylene glycol, 4g ammonium sulfate, 10g sodium carboxymethylcellulose, kaolin are mended to 100g, obtained 30.5% penta pyrrole worm guanidine ether chrysanthemum ester water dispersible granules.
According to the formula of embodiment 1,2, by active ingredient, auxiliary agent, carrier mixing, after stirring, obtain female powder through pulverizing, female powder is mixed with binding agent, then granulation, dry, sieve, penta 30.5% pyrrole worm guanidine ether chrysanthemum ester water dispersible granules can be obtained.
embodiment 3: 21% penta pyrrole worm guanidine ether chrysanthemum ester wetting powders
9g penta pyrrole worm guanidine, 12g ether chrysanthemum ester, 4g lauryl sodium sulfate, 4g sodium lignin sulfonate, 2g sodium butylnaphthalenesulfonate, diatomite supply 100g.Obtained 21% penta pyrrole worm guanidine ether chrysanthemum ester wetting powders.
Embodiment 4:28% penta pyrrole worm guanidine ether chrysanthemum ester wetting powder
12g penta pyrrole worm guanidine, 16g ether chrysanthemum ester, 6g lauryl sodium sulfate, 5g sodium lignin sulfonate, 4g sodium butylnaphthalenesulfonate, diatomite supply 100g.Obtained 28% penta pyrrole worm guanidine ether chrysanthemum ester wetting powders.
According to the formula of embodiment 3,4, active ingredient, auxiliary agent, carrier are added together, after air-flow crushing, mix and blend 30 minutes in cone-type mixer, can obtain penta pyrrole worm guanidine ether chrysanthemum ester wetting powder.
embodiment 5:21% penta pyrrole worm guanidine ether chrysanthemum ester aqueous emulsions
9g penta pyrrole worm guanidine, 12g ether chrysanthemum ester, 10g dimethylbenzene, 5gN-methyl pyrrolidone, 2g alkyl benzene calcium sulfonate, 6g phenethyl phenol mela mine-formaldehyde resin polyoxyethyl ether, 4g ethylene glycol, 0.4g silicone compound, 0.1g xanthans, 0.8g aluminium-magnesium silicate, water are mended to 100g, obtained 21% penta pyrrole worm guanidine ether chrysanthemum ester aqueous emulsions.
embodiment 6:28% penta pyrrole worm guanidine ether chrysanthemum ester aqueous emulsions
12g penta pyrrole worm guanidine, 16g ether chrysanthemum ester, 10g dimethylbenzene, 5gN-methyl pyrrolidone, 2g alkyl benzene calcium sulfonate, 6g phenethyl phenol mela mine-formaldehyde resin polyoxyethyl ether, 4g ethylene glycol, 0.4g silicone compound, 0.1g xanthans, 0.8g aluminium-magnesium silicate, water are mended to 100g, obtained 28% penta pyrrole worm guanidine ether chrysanthemum ester aqueous emulsions.
According to the formula of embodiment 5,6, active ingredient, solvent, emulsifier are added together, are dissolved into homogeneous oil phase; Water, antifreeze, thickener, defoamer are mixed, becomes homogeneous aqueous phase.Under high velocity agitation, aqueous phase is added oil phase, penta pyrrole worm guanidine ether chrysanthemum ester aqueous emulsion can be obtained.
the test of pesticide effectiveness:select the preparation of embodiment 2,3,6 to carry out contrast test to the control efficiency of rice fulgorid, method is as follows:
Each 15 grams/acre, 25 grams/acre, 25 grams/acre, the preparation of embodiment 2,3,6 is set, 10% penta pyrrole worm guanidine WP45 gram/acre, 10% ether chrysanthemum ester suspending agent 60 grams/acre and blank totally 6 process, randomized arrangement, often process repetition 3 times, plot area 50m2, is separated by with the mud ridge between process, prevent water in field crossfire, guarantee the accuracy of each pharmacy test data.Phase spray medicine is contained in rice fulgorid nymph, the Changjiang river-10 type sprayer is adopted slightly to spray, by experimental scheme process by low concentration to high concentration successively dispenser, amount of liquid medicine 750kg/hm2, spray medicine before and spray medicine after 1,3,7d, the parallel jump method sampling in every community, often some investigation 2 caves, amount to investigation 20 cave rice fulgorid insect population radix, whether checkout facility medicament has poisoning to crop simultaneously, record type and the extent of injury of poisoning, calculate control efficiency with check plot rice fulgorid nature insect population gradient.
Claims (2)
1. the composite insecticide containing penta pyrrole worm guanidine, it is characterized in that being 30.5% penta pyrrole worm guanidine ether chrysanthemum ester water dispersible granules, be prepared from by following ingredients: 0.5g penta pyrrole worm guanidine, 30g ether chrysanthemum ester, 4g lauryl sodium sulfate, 2g ethoxylated dodecyl alcohol, 2g lignosulfonates, 2g sodium methylene bis-naphthalene sulfonate, 2g polyethylene glycol, 4g ammonium sulfate, 10g sodium carboxymethylcellulose, kaolin is mended to 100g, according to formula by active ingredient, auxiliary agent, carrier mixes, after stirring, female powder is obtained through pulverizing, female powder is mixed with binding agent, then granulation, dry, sieve, penta 30.5% pyrrole worm guanidine ether chrysanthemum ester water dispersible granules can be obtained.
2. the composite insecticide containing penta pyrrole worm guanidine, it is characterized in that being 28% penta pyrrole worm guanidine ether chrysanthemum ester wetting powders, be prepared from by following ingredients: 12g penta pyrrole worm guanidine, 16g ether chrysanthemum ester, 6g lauryl sodium sulfate, 5g sodium lignin sulfonate, 4g sodium butylnaphthalenesulfonate, diatomite supply 100g, obtained 28% penta pyrrole worm guanidine ether chrysanthemum ester wetting powders, according to formula, active ingredient, auxiliary agent, carrier are added together, after air-flow crushing, mix and blend 30 minutes in cone-type mixer, can obtain penta pyrrole worm guanidine ether chrysanthemum ester wetting powder.
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| CN108402072A (en) * | 2018-05-09 | 2018-08-17 | 惠州市欧野科技有限公司 | A kind of composition pesticide containing sulfime ether and guadipyr |
| CN110050796B (en) * | 2019-05-09 | 2021-07-02 | 山东省农业科学院植物保护研究所 | A kind of insecticide for preventing and treating Bemisia tabaci and using method thereof |
| CN114946874B (en) * | 2022-06-10 | 2024-07-16 | 广西壮族自治区农业科学院 | Insecticidal pesticide composition for preventing and treating citrus thrips |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101821232A (en) * | 2008-11-25 | 2010-09-01 | 覃兆海 | Condensed amino nitroguanidine compounds, synthesis and use as botanical insecticides thereof |
| CN102863360A (en) * | 2012-10-16 | 2013-01-09 | 中国农业大学 | Synthetic method of novel nitro arylideneamino guanidine derivatives |
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Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101821232A (en) * | 2008-11-25 | 2010-09-01 | 覃兆海 | Condensed amino nitroguanidine compounds, synthesis and use as botanical insecticides thereof |
| CN102863360A (en) * | 2012-10-16 | 2013-01-09 | 中国农业大学 | Synthetic method of novel nitro arylideneamino guanidine derivatives |
Non-Patent Citations (2)
| Title |
|---|
| 10%醚菊酯悬浮剂防治稻飞虱的效果;廖永红;《农技服务》;20110331(第03期);全文 * |
| 醚菊酯防治稻飞虱药效试验;林抗美等;《农药》;19930625(第06期);全文 * |
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