CN103340203B - Synergistic herbicide composition - Google Patents
Synergistic herbicide composition Download PDFInfo
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- CN103340203B CN103340203B CN201310300101.6A CN201310300101A CN103340203B CN 103340203 B CN103340203 B CN 103340203B CN 201310300101 A CN201310300101 A CN 201310300101A CN 103340203 B CN103340203 B CN 103340203B
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- CN
- China
- Prior art keywords
- synergistic herbicide
- mesotrione
- butachlor
- flupoxam
- herbicide compositions
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention relates to a synergistic herbicide composition and an application method thereof and in particular relates to a synergistic herbicide composition which is prepared through ternary combination of mesotrione, butachlor and flupoxam and is applied to corn fields. The synergistic herbicide composition comprises (a) 2-(2'-nitro-4'-methanesulfonylbenzoyl)-1,3-cyclohexanedione, (b) 2-chloro-N-(2,6-diethylphenyl)-N-(butoxymethyl)acetamide and (c) 1-[4-chloro-A-(2,2,3,3,3-pentafluoropropyl)m-methyl]-3-carbamoyl-5-phenyl-1H-1,2,4-triazole, wherein the weight ratio of (a) to (b) to (c) is (1-50):(1-50):(1-50). The synergistic herbicide composition has a beneficial effect on controlling weeds in the corn fields, effectively controls annual grassy and broadleaf weeds in the corn fields, effectively controls generation of weeds with resistance, and simultaneously can reduce the overall use cost and expand the weed control spectrum.
Description
Technical field
The present invention relates to a kind of Synergistic herbicide compositions and application method thereof, relate in particular to a kind of mesotrione, butachlor and flupoxam component ternary built, be applied to the Herbicidal combinations of the synergy between corn field.
Background technology
Corn is one of the cereal crops the most widely that distribute in the world, and cultivated area is only second to wheat and paddy rice and occupies the 3rd.China produces corn per year and accounts for second place of the world, and corn field field sowing area accounts for 1/3 of dry land sowing area, and corn yield accounts for 1/4,2011 year national corn yield of cereal crops gross yield and breaks through 200,000,000 tons.
The geographical distributed pole of corn is that extensively the harm of weeds kind is also very complicated, and weeds and corn are fought for moisture, nutrient, illumination and space, affect the normal growth of Maize at Seedling Stage, even can cause Severe Reduction.Annual China corn crop smothering area approximately reaches more than 7,000,000 hectares.According to national weeds findings of the survey, whole nation corn field weed You22 section, 38 belongs to, 43 kinds, wherein the weeds of main harm corn field have: lady's-grass grass, barnyard grass, green foxtail, eleusine indica, Amaranthus retroflexus, kitchen garden, iron amaranth, multitude, Ji, field bindweed, Commeline communis etc., and harm in seedling stage is maximum, can cause that milpa is short and small, bar spire Huang etc. has a strong impact on corn yield, can underproduction amplitude reach 35% left and right.Wherein, Huang-Huai-Hai is the corn producing region of China's maximum, take Summer Maize as main, and this district's crop-planting yields two crops a year, and mostly is corn, wheat crop rotation, also has the interplantings such as corn and soybean, peanut.This district's main weeds is lady's-grass grass, kitchen garden, eleusine indica, field bindweed, lamb's-quarters, india lovegrass, the rhizome of nutgrass flatsedge etc., and corn field crop smothering generation area accounts for 82% ~ 96% of cultivated area, and wherein the above area of medium harm reaches 66%.
Along with the development of agricultural cience and farming techniques, one of the applying as saving of labor, save time of chemical herbicide, cost-effective strong well stimulation.
Mesotrione (Mesotrione) Chinese name makes again nitre sulphur ketone or mesotrione or Meath logical, and its chemical name is 2-(2-nitro-4-methylsulfonyl-benzoyl) cyclohexane-1,3-diketone, and its structural formula is:
Mesotrione is the three ketones weed killer herbicide of Switzerland Syngenta Co.,Ltd exploitation.Its mechanism of action is the inhibitor to oxypyroracemic acid dioxygenase (HPPD), tyrosine can be converted into plastoquinone.Have in soil fast degradation, consumption low, environment is not affected to its drug effect without impact, rainfall and to features such as corn have no adverse effects.
Mesotrione is as interior absorption corn field broad spectrum type weed killer herbicide, mesotrione can effectively be prevented and kill off corn field annual broadleaf weed and some grassy weed, as piemarker, Siberian cocklebur, thorn amaranth, Chenopodium weeds, summer cypress, Polygonum weeds, leaf mustard, barnyard grass, chickweed, lady's-grass grass etc., not only to corn safety, and to environment, succession crop safety.
Butachlor (Butachlor) Chinese name is again weed eradication spy or Machete, and its chemical name is the chloro-N-of 2-(2,6-diethyl phenyl)-N-(fourth oxygen methyl) acetamide, and its structural formula is:
Butachlor is in amide-type selectivity, to inhale conduction weed killer herbicide; After the main young shoot by weeds, leaves of plants table absorb, suppress in vivo and destroy protease, affecting the formation of protein, suppressing weeds young shoot and young root normal growth and grow, thereby making weeds dead.Can prevent and kill off annual gramineous weed and some broadleaf weed such as barnyard grass, lady's-grass grass, green foxtail.Butachlor is selectivity preemergence herbicide.
Flupoxam (Flupoxam) Chinese name is again amine grass ether or amine grass azoles, and its chemical name is 1-[4-chloro-Α-(2,2; 3,3,3-, five fluorine propoxyl group) tolyl between]-3-carbamoyl-5-phenyl-1H-1; 2,4-triazole (CAS No.119126-15-7), its structural formula is:
Flupoxam belongs to triazolopyrimidine sulfonamides, is typical inhibitor of acetolactate synthetase.By suppressing the synthetic protein biosynthesis block that makes of branched-chain amino acid, plant stops growing.Longevity of residure length, broad weed-killing spectrum, soil, cauline leaf are processed and all can.The scope of application is suitable for the Tanakas such as corn, soybean, wheat, barley and prevents and treats life in 1 year and perennial broadleaf weed as knotweed, Veronica, Siberian cocklebur, black nightshade, Amaranthus retroflexus, lamb's-quarters, piemarker, clearvers, datura etc.Children grassy weed in age is also had to certain inhibitory action.
Because weed killer herbicide relates to the effect of weeds and the balance to two aspects of safety of crop in using, specification requirement is high, can not at will use with.The composition composite for mesotrione of the present invention, butachlor and flupoxam have not been reported.
Summary of the invention
The present invention seeks in order to solve the problems of the technologies described above, the invention provides a kind of Synergistic herbicide compositions, said composition, by mesotrione, butachlor and flupoxam are carried out to ternary built, makes resulting new compositions obtain gain effect in the control of corn weeds in field.
The present invention passes through repetition test and finds, the above-mentioned composition that contains mesotrione, butachlor and flupoxam composition presents obvious gain effect for suppressing undesirable plant growth.
An object of the present invention is to provide a kind of Herbicidal combination that contains following compositions:
(a) 2-(2 '-nitro-4 '-methyl sulphonyl benzoyl)-1, hydroresorcinol (mesotrione);
(b) the chloro-N-of 2-(2,6-diethyl phenyl)-N-(fourth oxygen methyl) acetamide (butachlor);
(c) tolyl between the chloro-Α of 1-[4--(2,2,3,3,3-, five fluorine propoxyl group)]-3-carbamoyl-5-phenyl-1H-1,2,4-triazole (flupoxam).
A kind of Synergistic herbicide compositions is to take following technical scheme to realize:
A Synergistic herbicide compositions, comprises active principle
(a) 2-(2 '-nitro-4 '-methyl sulphonyl benzoyl)-1, hydroresorcinol (mesotrione);
(b) the chloro-N-of 2-(2,6-diethyl phenyl)-N-(fourth oxygen methyl) acetamide (butachlor);
(c) tolyl between the chloro-Α of 1-[4--(2,2,3,3,3-, five fluorine propoxyl group)]-3-carbamoyl-5-phenyl-1H-1,2,4-triazole (flupoxam).
Described Synergistic herbicide compositions, is characterized in that, described component (a) is 1-50:1-50:1-50 with weight proportion (b) and (c).
The Herbicidal combinations of described synergy, wherein, described component (a) is 1-20:1-20:1-20 with weight proportion (b) and (c).
Described Synergistic herbicide compositions can be mixed with the upper any formulation allowing of agricultural.Preferred wetting powder, missible oil, suspending agent, oil-suspending agent, microcapsules, microemulsion, aqueous emulsion, suspended emulsion, water dispersible granules, ZC.
The present invention also provides a kind of Synergistic herbicide compositions, and the reactive compound combination that comprises described cooperative effective quantity mixes with at least one preparation technique usual auxiliaries.
The present invention also provides the method for the undesirable plant of a kind of collaborative control, comprises described synergistic complex Herbicidal combinations is applied on the growth place or leaf or stem of undesirable plant.Described undesirable plant is grassy weed, broad leaved weed and sedge weed.
The preferred eleusine indica of described undesirable plant, barnyard grass, lady's-grass, green foxtail, yard grass, moleplant seed and wild oat etc.; Important broad leaved weed has lamb's-quarters, amaranth, clearvers, knotweed, german chamomile, saltbush, datura, chickweed, summer cypress, piemarker and black nightshade etc.
The present invention also provides the method for the undesirable plant of a kind of collaborative control, comprises described Synergistic herbicide compositions is used under the seed of useful crop plant, useful crop or other breeding part existence of useful crop.Wherein said useful crop corn crop.
The combination of active principles of different agricultural chemicals is made to agricultural chemicals, is a kind of effectively and efficiently mode of the upper resistant weed of current development novel pesticide and control agricultural.The agricultural chemicals of different cultivars shows three kinds of type of action: summation action, synergistic effect and antagonism after mixing conventionally.But be specially which kind of effect, unpredictable, only have by great many of experiments and just can know.Compound synergic is good formula, owing to obviously having improved actual control efficiency, has reduced the usage amount of agricultural chemicals, thereby has delayed widely drug-fast generation speed, is the important means of comprehensive weeding.
An object of the present invention is to provide a kind of Synergistic herbicide compositions, comprise
(a) 2-(2 '-nitro-4 '-methyl sulphonyl benzoyl)-1, hydroresorcinol (mesotrione);
(b) the chloro-N-of 2-(2,6-diethyl phenyl)-N-(fourth oxygen methyl) acetamide (butachlor);
(c) tolyl between the chloro-Α of 1-[4--(2,2,3,3,3-, five fluorine propoxyl group)]-3-carbamoyl-5-phenyl-1H-1,2,4-triazole (flupoxam).
Inventor is by a large amount of screening tests, the different proportionings of mesotrione, butachlor, flupoxam test and effectiveness analysis have been carried out a large amount of, discovery is in certain ratio range, resulting Herbicidal combinations has gain effect, and is not only the simple addition of three kinds of medicaments.
Above-mentioned three kinds of active components (a): (b): (c) scope is 1-50:1-50:1-50 by weight ratio, preferably 1-20:1-20-1:20.
The present invention also provides a kind of Synergistic herbicide compositions, and the reactive compound combination that comprises described cooperative effective quantity mixes with at least one preparation technique usual auxiliaries.
Described usual auxiliaries is one or more in solvent, emulsifier, wetting agent, stabilizing agent, dispersant, thickener, defoamer, antifreezing agent, disintegrant, binding agent, filler, filler, deionized water etc.
The emulsifier that is applicable to preparation Synergistic herbicide compositions of the present invention can be anion and/or non-example type emulsifier, such as alkylphenol polyoxyethylene, alkylphenol-polyethenoxy polyethenoxy ether, Ben-zylphenol Polyoxyethyl Ether, polyoxyethylene fatty acid ester, polyoxyethylene aliphatic alcohol ether, polyoxyethylene fatty amine, alkyl phenol polyglycol ether etc.The auxiliary agent using in Synergistic herbicide compositions of the present invention comprises that liquid-carrier, solid carrier, dispersant, emulsifier, stabilizing agent, antifreezing agent, thickener etc. and other are of value to the known substance of active ingredient stable and drug effect performance in preparation, all various compositions conventional in agricultural chemicals or that allow to use, be not particularly limited, concrete composition and consumption require to determine by simple experiment according to formula.
The dispersant that is applicable to preparation Synergistic herbicide compositions of the present invention can be alkylnaphthalene sulfonate, two (alkyl) naphthalenesulfonate formaldehyde condensation compound, naphthalene sulfonic acid-formaldehyde condensation product, alkylphenol-polyethenoxy based phosphates, alkylphenol-polyethenoxy base ether formaldehyde condensation products sulphate, alkylphenol polyoxyethylene phosphate, alkylphenol polyoxyethylene, castor oil ethylene oxide adduct, oxirane-propylene oxide block copolymer, alkylphenol polyoxyethylene formaldehyde condensation is dirty, octylphenol polyethylene oxyethylene group ether sulfate and methylcellulose.Such as sodium lignin sulfonate, calcium lignosulfonate, methyl naphthalene sulfonate formaldehyde condensate, the dirt of sodium naphthalene sulfonate formaldehyde condensation, methanonaphthalene sodium sulfonate etc.
Other additive, can enumerate the carboxymethyl cellulose conventionally using with auxiliary agent form when preparation, ethylene glycol and propane diols etc.
Synergistic herbicide compositions in the present invention can also contain colouring agent, for example inorganic pigment iron oxide, titanium oxide or Prussian blue; Organic dyestuff alizarin, azo dyes, metal phthalocyanine orchid or kiton colors etc.
The filler that is applicable to preparation Synergistic herbicide compositions of the present invention comprises liquid-carrier, comprises aromatic hydrocarbons, aliphatic hydrocarbon.Particularly suitable be polar solvent, as alcohols and their ether and ester.In addition also have vegetable oil and the molten fiber of methyl.Meanwhile, the mixture of different liquids is also suitable for.
The filler that is applicable to Synergistic herbicide compositions of the present invention comprises solid carrier, comprises diatomite, Magnesiumaluminumsilicate, atlapulgite, kaolin, clay, gypsum, bentonite, white carbon, precipitated calcium carbonate, lime stone, wood chip, corn starch, soluble starch etc.
Other additive, can enumerate the carboxymethyl cellulose conventionally using with auxiliary agent form when preparation, ethylene glycol and propane diols etc.
Novel built Herbicidal combinations in the present invention can also contain colouring agent, for example inorganic pigment iron oxide, titanium oxide or Prussian blue; Organic dyestuff alizarin, azo dyes, metal phthalocyanine orchid or kiton colors etc.
Can any conventional form use composition of the present invention.The blade face formulation example of premix composition is:
GR: granule
WP: wetting powder
WG: water dispersibles granula
SG: soluble granule
SL: soluble concentrate
EC: missible oil
EW: emulsion, aqueous emulsion
ME: microemulsion
SC: suspending agent
CS: microcapsule suspending agent
OD: oil-based suspension
SE: suspension emulsion
The preferred formulation of the present invention can be wetting powder, missible oil, suspending agent, oil-suspending agent, microcapsules, microemulsion, aqueous emulsion, suspended emulsion, water dispersible granules, ZC, ultra low volume liquids.
Synergistic herbicide compositions of the present invention is used with preparation, contains various known or be used in the industrial various adjuvants and the carrier that disperse of being conducive in preparation.The selection of preparation and method of application can affect the activity of selected compound, so synergistic composition of the present invention can be used as weed killer herbicide, it demonstrates the synergistic activity of weed control.Synergistic herbicide compositions of the present invention can be with the weed killer herbicide same way processing of processing conventionally.Compound can or be used respectively or as the parts of three parts of weeding systems and combined administration.
The object of processing is to use composition in the place of needs control by method easily.Described " place " comprises soil, seed and seedling, and the plant having grown.
Above-mentioned preparation can be prepared into the packaging bag of the weed killer herbicide together with other compositions (thinner, emulsifier, surfactant etc.) that contain with preparation.Prepared by the method that preparation also can be mixed by bucket, in bucket mixing method, composition be obtain respectively and in grower's place combination.
The Synergistic herbicide compositions of the actual employing of the present invention can, with the known variety of way of those skilled in the art, be used with various concentration.The present composition before by seedling or postemergence application in selecting accordingly.
These preparations can be applied to conventional method the region that is intended to control.For example, pulvis and fluid composition can be used by the agent of dusting, spray boom and manual sprayer and duster.Preparation also can be executed powder by aircraft or spraying or rope band and use.For the growth of restriction or the seed control germinateing or the seedling that emerges, pulvis and liquid preparation can be distributed in in soil, at least second inch, soil table is dark, or impose on soil table by spraying or spreading.Preparation also can add in irrigation water and use.Make like this preparation be penetrated in soil with irrigation water.The pulvis, granule composite or the liquid preparation that impose on soil table can be distributed in below soil table by the operation of ploughing of conventional mode.
The formulation example that is applicable to bucket mixing composition is solution, dilution emulsion, suspending agent or its mixing and pulvis.
Conventionally, bucket mixing composition be with solvent (as water) dilution, form containing different agricultural chemicals, and one or more premix compositions of further auxiliary agent optionally.
Generally, blade face bucket mixture comprises 0.1-20%, the reactive compound of 0.1-15% particularly, and 99.9%-80%, solid-state or the liquid flux of 99.9-85% (comprising ratio of solvent as water) particularly, wherein auxiliary agent can be to take bucket mixture as basis, the surfactant of content 0-20%, particularly 0.1-15%.
Conventionally the pre-mixing agent of foliage applying comprises 0.1-99.9%, the active compound component of 1-95% particularly, and 99.9-0.1%, solid-state or the liquid flux of 99-5% (comprising if ratio of solvent is as water) particularly, wherein auxiliary agent can be to take pre-mixing agent as basis, the surfactant of content 0-50%, particularly 0.5-40%.
Composition through preparation of the present invention comprises 0.5-99.9%, 1-95% particularly, the active compound component of 1-50% advantageously, and 99.5-0.1%, the particularly solid of 99-5% quality or liquid assistant agent (comprising if solvent is as water), wherein said auxiliary agent (or assistant agent) can be the surfactant of the 0-50% based on pre-mixing agent quality, particularly 0.5-40%.
The cooperative effective quantity that is applicable to the combination of composition of the present invention can be according to condition at that time as the variations such as kind of weed pressure, time of application, method of application, weather, soil regime, features of terrain, target crop.In practicing, about 0.10kg/ha-1.00kg/ha is enough provided, preferably the rate of application of the active component of approximately 0.25 kg/ha-0.75 kg/ha is suitable.
Term used herein " weed killer herbicide " refers to the compound of control or limiting plant growth.Term used " herbicidally effective amount " refers to that the combination of this compound or these compounds can produce the amount of control or restriction effect.Control or restriction effect refer to all situations that nature is grown that departs from that comprises, such as: kill, suppress, burn leaf, dwarfing etc." plant " refers to all entities department of plant, comprising: seed, seedling, sapling, root, stem tuber, stem, handle, Ye Heguo.
The present invention also provides the method for the undesirable plant of a kind of collaborative control, comprises described Synergistic herbicide compositions is applied on the growth place or leaf or stem of undesirable plant.Described undesirable plant is grassy weed, broad leaved weed and sedge weed.The preferred eleusine indica of described undesirable plant, barnyard grass, lady's-grass, green foxtail, yard grass, moleplant seed and wild oat etc.; Important broad leaved weed has lamb's-quarters, amaranth, clearvers, knotweed, german chamomile, saltbush, datura, chickweed, summer cypress, piemarker and black nightshade etc.
From the following embodiments can be seen that, Synergistic herbicide compositions of the present invention shows good activity of weeding, and the activity of weeding of single reactive compound a little less than, the activity of combination of the present invention surpass simply adding of each single compound activity and.
During active sum when the activity of weeding of reactive compound combination surpasses each reactive compound and uses separately, always there is synergy.
The present invention compared with prior art at least has following obvious advantage and beneficial effect:
1, the invention provides a kind of Synergistic herbicide compositions, three kinds of weed killer herbicides as built agent composition are complementary not enough, herbicidal effect is remarkable, and herbicide spectrum width can seal the weeds that do not emerge, can prevent and kill off the weeds that emerged again, both can prevent and kill off grassy weed, and can prevent and treat again after the spectrum seedling of broad leaved weed with complex weedicide, both ensure the safety when stubble corn, can not endanger succession crop again, effectively prevent and kill off annual and biennial weeds.
2, the using method of complex weedicide of the present invention, optimum period medication, consumption is few, and preventive effect is high, and reduces expenses for prevention and control, alleviates the pollution to environment, is beneficial to the safety of people, animal, beneficial organism and maintaining of the ecological balance, meets sustainable development requirement.
3, the composition that the present invention contains mesotrione, butachlor and flupoxam composition presents obvious gain effect for suppressing undesirable plant growth.
Embodiment
FORMULATION EXAMPLE
Embodiment 1 1% mesotrione+5% butachlor+20% flupoxam oil-suspending agent
The former medicine 1% of mesotrione
Butachlor active compound 5%
The former medicine 20% of flupoxam
Fatty alcohol-polyoxyethylene ether sulfosuccinic acid monoesters disodium 10%
MODIFIED LIGNOSULPHONATE 5%
Xanthans 1%
Bentonite 1%
Glycerine 5%
Soybean oil complements to 100%
Above-mentioned each component is mixed in proportion, and through sand milling, be prepared into oil-suspending agent.
Embodiment 2 5% mesotrione+7.5% butachlor+15% flupoxam wetting powders
The former medicine 5% of mesotrione
Butachlor active compound 7.5%
The former medicine 15% of flupoxam
Lauryl sodium sulfate 10%
Sodium lignin sulfonate 5%
White carbon 10%
Kaolin complements to 100%
Said components is mixed in proportion, and grind, pulverize, be prepared into wetting powder.
Embodiment 3 10% mesotrione+50% butachlor+10% flupoxam aqueous emulsions
Mesotrione 10%
Butachlor 50%
Flupoxam 10%
1-METHYLPYRROLIDONE 25%
Calcium dodecyl benzene sulfonate 5%
Agriculture breast 600# 7%
Water complements to 100%
After above-mentioned oil phase component is mixed, add in water, obtain aqueous emulsion.
Embodiment 4 50% mesotrione+10% butachlor+10% flupoxam water dispersible granules
Mesotrione 50%
Butachlor 10%
Flupoxam 10%
Polyvinyl alcohol 4%
Saponin 3%
Methylcellulose 5%
Kaolin complements to 100%
To after above-mentioned each component co-grinding, add a small amount of water extruder grain, dry and obtain water dispersible granules.
Embodiment 5 10% mesotrione+10% butachlor+50% flupoxam aqueous emulsions
Mesotrione 10%
Butachlor 10%
Flupoxam 50%
1-METHYLPYRROLIDONE 25%
Calcium dodecyl benzene sulfonate 5%
Agriculture breast 600# 7%
Water complements to 100%
After above-mentioned oil phase component is mixed, add in water, obtain aqueous emulsion.
Embodiment 6 10% mesotrione+20% butachlor+10% flupoxam suspending agents
Mesotrione 10%
Butachlor 20%
Flupoxam 10%
Fatty alcohol-polyoxyethylene ether sulfosuccinic acid monoesters disodium 10%
MODIFIED LIGNOSULPHONATE 5%
Xanthans 1%
Bentonite 1%
Glycerine 5%
Water complements to 100%
Above-mentioned each component is mixed in proportion, and through sand milling, be prepared into suspending agent.
Embodiment 7 50% mesotrione+1% butachlor+1% flupoxam aqueous emulsions
Mesotrione 50%
Butachlor 1%
Flupoxam 1%
1-METHYLPYRROLIDONE 25%
Calcium dodecyl benzene sulfonate 5%
Agriculture breast 600# 7%
Water complements to 100%
After above-mentioned oil phase component is mixed, add in water, obtain aqueous emulsion.
Embodiment 8 14% mesotrione+7% butachlor+28% flupoxam suspending agents
Mesotrione 14%
Butachlor 7%
Flupoxam 28%
Fatty alcohol-polyoxyethylene ether sulfosuccinic acid monoesters disodium 10%
MODIFIED LIGNOSULPHONATE 5%
Xanthans 1%
Bentonite 1%
Glycerine 5%
Water complements to 100%
Above-mentioned each component is mixed in proportion, and through sand milling, be prepared into suspending agent.
Embodiment 9 10% mesotrione+3% butachlor+30% flupoxam suspension emulsions
Mesotrione 10%
Butachlor 3%
Flupoxam 30%
Methyl naphthalene sulfonate formaldehyde condensate 5%
Ethoxylated castor oil 3%
Bentonite 1%
Aromatic solvent 100 20%
Water complements to 100%
Mesotrione, flupoxam, methyl naphthalene sulfonate formaldehyde condensate are obtained to the suspending agent of mesotrione, flupoxam after grinding and/or high speed shear; Butachlor, aromatic solvent 100, ethoxylated castor oil mixing and stirring are obtained to the missible oil of butachlor; The butachlor ec obtaining is joined in mesotrione+flupoxam suspending agent, obtain 10% mesotrione+3% butachlor+30% flupoxam suspension emulsion.
Embodiment 10 1% mesotrione+1% butachlor+5% flupoxam aqueous emulsions
Oil phase:
Mesotrione 1%
Butachlor 1%
Methyl oleate 10%
Ethoxylated castor oil 5%
Water:
Flupoxam 50%
The sodium salt 1% of the naphthalene sulfonic acids-formaldehyde condensation products of sulfonation
Water complements to 100%
Mesotrione and butachlor are dissolved in methyl oleate, add ethoxylated castor oil to obtain oil phase; According to formula, by the sodium salt of the naphthalene sulfonic acids-formaldehyde condensation products of flupoxam and sulfonation, water, mix and obtain water; Under agitation add water to obtain aqueous emulsion oil phase.
Embodiment 11 1% mesotrione+50% butachlor+1% flupoxam water dispersible granules
Mesotrione 1%
Butachlor 50%
Flupoxam 1%
Polyvinyl alcohol 4%
Saponin 3%
Methylcellulose 5%
Kaolin complements to 100%
To after above-mentioned each component co-grinding, add a small amount of water extruder grain, dry and obtain water dispersible granules.
Embodiment 12 15% mesotrione+30% butachlor+15% flupoxam water dispersible granules
Mesotrione 15%
Butachlor 30%
Flupoxam 15%
Polyvinyl alcohol 4%
Saponin 3%
Methylcellulose 5%
Kaolin complements to 100%
To after above-mentioned each component co-grinding, add a small amount of water extruder grain, dry and obtain water dispersible granules
Embodiment 13 10% mesotrione+10% butachlor+10% flupoxam water dispersible granules
Mesotrione 10%
Butachlor 10%
Flupoxam 10%
Polyvinyl alcohol 4%
Saponin 3%
Methylcellulose 5%
Kaolin complements to 100%
To after above-mentioned each component co-grinding, add a small amount of water extruder grain, dry and obtain water dispersible granules
Embodiment 14 20% mesotrione+20% butachlor+1% flupoxam missible oil
Mesotrione 20%
Butachlor 20%
Flupoxam 1%
Ethoxylated castor oil 4%
Calcium dodecyl benzene sulfonate 3%
Aromatic solvent 200 complements to 100%
Above-mentioned each component mix and blend is obtained to transparent phase.
Embodiment 15 20% mesotrione+1% butachlor+20% flupoxam suspending agents
Mesotrione 20%
Butachlor 1%
Flupoxam 20%
Fatty alcohol-polyoxyethylene ether sulfosuccinic acid monoesters disodium 10%
MODIFIED LIGNOSULPHONATE 5%
Xanthans 1%
Bentonite 1%
Glycerine 5%
Water complements to 100%
Above-mentioned each component is mixed in proportion, and through sand milling, be prepared into suspending agent.
Embodiment 16 1% mesotrione+20% butachlor+1% flupoxam suspending agents
Mesotrione 1%
Butachlor 20%
Flupoxam 1%
Fatty alcohol-polyoxyethylene ether sulfosuccinic acid monoesters disodium 10%
MODIFIED LIGNOSULPHONATE 5%
Xanthans 1%
Bentonite 1%
Glycerine 5%
Water complements to 100%
Above-mentioned each component is mixed in proportion, and through sand milling, be prepared into suspending agent.
Embodiment 17 10% mesotrione+10% butachlor+20% flupoxam ZC
Atlox 4913 4%
Citric acid 0.05%
Catalyzer 0.1%
Water 13%
Flupoxam 20%
PAPI 1.35%
Solvesso 200 10%
Atlox4913 16%
Dispersant LFH 0.3%
Defoamer 0.16%
Urea 8.4%
Mesotrione 10%
Butachlor 10%
Water complements to 100%
By PAPI, the oil phase that butachlor, Solvesso 100 form adds in the aqueous solution containing Atlox4913, forms emulsion.Then heat and be incubated 50
ounder C, add catalyst reaction 2 hours.After cooling, obtain the microcapsules of butachlor.
Atlox 4913, dispersant LFH, and defoamer, urea, mesotrione, flupoxam, water mix in proportion, and through sand milling, are prepared into suspending agent.
The microcapsules of the butachlor obtaining is added in the suspending agent of mesotrione+flupoxam, stir and obtain 10% mesotrione+10% butachlor+20% flupoxam ZC.
Embodiment 18 20% mesotrione+40% butachlor+40% flupoxams
Mesotrione 20%
Butachlor 40%
Flupoxam 40%
Above embodiment proportioning is weight per distribution ratio.
The preventing iron test of biological test example to corn weeds in field
Test method:
Between corn field, the main weeds that occur have: eleusine indica, lady's-grass grass, barnyard grass, green foxtail, piemarker, chickweed, thorn amaranth, Siberian cocklebur, leaf mustard, Amaranthus retroflexus, recessed amaranth, field thistle, setose thistle, bur beggar-ticks, beggar-ticks, pale persicaria, willow spurt knotweed, kitchen garden, flowerofanhour root or herb, clearvers, sunflower, smallflower galinsoga herb, corn radish, salsola collina, thorn bur, corn sow thistle, chickweed, datura, lamb's-quarters, little lamb's-quarters, black nightshade, dayflower, artemisiifolia, big dish, penny cress, leaf mustard, wild mustard and other japanese bearbinds belong to, Chenopodium, Polygonum, artemisia, rape belongs to weeds, lamb's-quarters, amaranth, clearvers, knotweed, german chamomile, saltbush, datura, chickweed, summer cypress, piemarker and black nightshade etc.
In test, we just select several more difficult cutting weeds as subjects below.
Medicament adopts now with the current mode, and we test with the formula of embodiment the inside.The cultivation of target weeds adopts potted plant cultivation, uses 10*10cm plastic basin, will not use soil in the corn field of weed killer herbicide as culture soil.The barnyard grass gathering between corn field upper one year, eleusine indica, lamb's-quarters, Amaranthus retroflexus seed are sprinkling upon to soil surface, wait it to grow 2 ~ 4 leaves.Then spray successively mesotrione, butachlor, flupoxam, according to the medicament of the present invention's preparation.Then carry out observation analysis.After medication, weeds are carried out to normal management, and in medication, note in 48 hours rainproof.The growing state of observation post administration weeds, each processes the preventive effect to weeds to record weed killer herbicide.After weeds medicine 30 days, each processed the fresh weight preventive effect to weeds investigation.
Fresh weight preventive effect (%)=[check plot weeds fresh weight-treatment region weeds fresh weight]/[check plot weeds fresh weight] * 100
Dispenser is the investigation of weeds fresh weight preventive effect after 30 days
Table 1
Conclusion: as can be seen from Table 1, dispenser is after 30 days, and according to ternary recompounded composite of the present invention, to barnyard grass, eleusine indica, lamb's-quarters, the preventive effect of Amaranthus retroflexus, all more than 80%, apparently higher than the preventive effect of single dose, has obvious gain effect.And according to composition of the present invention, the amount of application of active ingredient obviously reduces than single dose amount of application.
Synergistic herbicidal agents provided by the invention is the ternary built of butachlor, mesotrione and flupoxam, can be applied to corn field as closed soil treatment agent and seedling after cauline leaf inorganic agent, can effectively control 1 year grass family of corn field and broad leaved weed, it is desirable corn field herbicide, can effectively control the generation of resistant weed, can reduce whole use cost, and expand herbicide spectrum, and then serve better agricultural production simultaneously.
Claims (7)
1. a Synergistic herbicide compositions, is characterized in that, comprises active principle
(a) 2-(2 '-nitro-4 '-methyl sulphonyl benzoyl)-1, hydroresorcinol;
(b) the chloro-N-of 2-(2,6-diethyl phenyl)-N-(fourth oxygen methyl) acetamide;
(c) tolyl between the chloro-Α of 1-[4--(2,2,3,3,3-, five fluorine propoxyl group)]-3-carbamoyl-5-phenyl-1H-1,2,4-triazole;
Described component (a) is 1-50:1-50:1-50 with weight proportion (b) and (c).
2. Synergistic herbicide compositions according to claim 1, is characterized in that, described component (a) is 1-20:1-20:1-20 with weight proportion (b) and (c).
3. Synergistic herbicide compositions according to claim 1, is characterized in that, the reactive compound combination that comprises described cooperative effective quantity mixes with at least one preparation technique usual auxiliaries.
4. Synergistic herbicide compositions according to claim 1, is characterized in that, can be mixed with the upper any formulation allowing of agricultural.
5. Synergistic herbicide compositions according to claim 4, is characterized in that, described formulation is wetting powder, missible oil, suspending agent, microcapsules, microemulsion, aqueous emulsion, suspended emulsion, water dispersible granules, ZC.
6. a method for the undesirable plant of collaborative control, is characterized in that, comprises Synergistic herbicide compositions claimed in claim 1 is applied on the growth place or leaf or stem of undesirable plant.
7. method according to claim 6, is characterized in that, described undesirable plant is grassy weed, broad leaved weed and sedge weed.
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| CN105340905A (en) * | 2015-11-02 | 2016-02-24 | 张英芹 | Preparation method of high-stability mesotrione-atrazine water suspension |
| CN105340904A (en) * | 2015-11-02 | 2016-02-24 | 张英芹 | Mesotrione-atrazine water suspension |
| CN107333787A (en) * | 2017-06-14 | 2017-11-10 | 合肥助航生态农业科技有限公司 | Corn field herbicide |
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| WO2003022049A1 (en) * | 2001-09-07 | 2003-03-20 | Syngenta Participations Ag | Surfactant systems for agriculturally active compounds |
| WO2003047346A1 (en) * | 2001-12-05 | 2003-06-12 | Bayer Cropscience Aktiengesellschaft | Herbicides based on substituted carboxylic acid anilides |
| CN101600349A (en) * | 2007-02-06 | 2009-12-09 | 日本曹达株式会社 | Broad-leaved perennial weed control agent for grass and the lawn the method for control of broad-leaved perennial weed |
| CN102215695A (en) * | 2008-09-29 | 2011-10-12 | 孟山都技术公司 | Glyphosate formulations containing amidoalkylamine surfactants |
| CN102293202A (en) * | 2011-09-27 | 2011-12-28 | 湖南振农科技有限公司 | Omnibearing herbicide for paddy fields |
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| WO2003022049A1 (en) * | 2001-09-07 | 2003-03-20 | Syngenta Participations Ag | Surfactant systems for agriculturally active compounds |
| WO2003047346A1 (en) * | 2001-12-05 | 2003-06-12 | Bayer Cropscience Aktiengesellschaft | Herbicides based on substituted carboxylic acid anilides |
| CN101600349A (en) * | 2007-02-06 | 2009-12-09 | 日本曹达株式会社 | Broad-leaved perennial weed control agent for grass and the lawn the method for control of broad-leaved perennial weed |
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