CN100376643C - Outer wall decorating fluorocarbon paint and its production process - Google Patents
Outer wall decorating fluorocarbon paint and its production process Download PDFInfo
- Publication number
- CN100376643C CN100376643C CNB200410047914XA CN200410047914A CN100376643C CN 100376643 C CN100376643 C CN 100376643C CN B200410047914X A CNB200410047914X A CN B200410047914XA CN 200410047914 A CN200410047914 A CN 200410047914A CN 100376643 C CN100376643 C CN 100376643C
- Authority
- CN
- China
- Prior art keywords
- weight part
- decoration
- paint
- exterior wall
- vinylidene fluoride
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- NBVXSUQYWXRMNV-UHFFFAOYSA-N fluoromethane Chemical compound FC NBVXSUQYWXRMNV-UHFFFAOYSA-N 0.000 title claims abstract description 17
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 10
- 239000003973 paint Substances 0.000 title abstract 5
- 239000011248 coating agent Substances 0.000 claims abstract description 32
- 238000000576 coating method Methods 0.000 claims abstract description 32
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 19
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 14
- 239000000839 emulsion Substances 0.000 claims abstract description 13
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims abstract description 12
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims abstract description 9
- -1 polyoxyethylene Polymers 0.000 claims abstract description 9
- 239000000843 powder Substances 0.000 claims abstract description 9
- 229920000570 polyether Polymers 0.000 claims abstract description 8
- 229940058020 2-amino-2-methyl-1-propanol Drugs 0.000 claims abstract description 7
- CBTVGIZVANVGBH-UHFFFAOYSA-N aminomethyl propanol Chemical compound CC(C)(N)CO CBTVGIZVANVGBH-UHFFFAOYSA-N 0.000 claims abstract description 7
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 claims abstract description 7
- 235000013870 dimethyl polysiloxane Nutrition 0.000 claims abstract description 7
- 239000004205 dimethyl polysiloxane Substances 0.000 claims abstract description 7
- 229920001495 poly(sodium acrylate) polymer Polymers 0.000 claims abstract description 7
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 claims abstract description 6
- 239000004408 titanium dioxide Substances 0.000 claims abstract description 6
- 238000005034 decoration Methods 0.000 claims description 18
- 229910052731 fluorine Inorganic materials 0.000 claims description 14
- BQCIDUSAKPWEOX-UHFFFAOYSA-N 1,1-Difluoroethene Chemical compound FC(F)=C BQCIDUSAKPWEOX-UHFFFAOYSA-N 0.000 claims description 11
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 claims description 11
- 239000011737 fluorine Substances 0.000 claims description 11
- 229910002012 Aerosil® Inorganic materials 0.000 claims description 9
- 238000000034 method Methods 0.000 claims description 9
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 8
- 150000001735 carboxylic acids Chemical class 0.000 claims description 8
- 229910052708 sodium Inorganic materials 0.000 claims description 8
- 239000011734 sodium Substances 0.000 claims description 8
- 239000008367 deionised water Substances 0.000 claims description 7
- 229910021641 deionized water Inorganic materials 0.000 claims description 7
- NNMHYFLPFNGQFZ-UHFFFAOYSA-M sodium polyacrylate Chemical compound [Na+].[O-]C(=O)C=C NNMHYFLPFNGQFZ-UHFFFAOYSA-M 0.000 claims description 6
- 239000005995 Aluminium silicate Substances 0.000 claims description 5
- 235000012211 aluminium silicate Nutrition 0.000 claims description 5
- KQNPFQTWMSNSAP-UHFFFAOYSA-N isobutyric acid Chemical compound CC(C)C(O)=O KQNPFQTWMSNSAP-UHFFFAOYSA-N 0.000 claims description 5
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims description 5
- 238000009775 high-speed stirring Methods 0.000 claims description 3
- 239000004576 sand Substances 0.000 claims description 3
- 238000003756 stirring Methods 0.000 claims description 3
- 239000002245 particle Substances 0.000 claims description 2
- 230000007613 environmental effect Effects 0.000 abstract description 3
- 239000002904 solvent Substances 0.000 abstract description 3
- 239000004721 Polyphenylene oxide Substances 0.000 abstract 2
- LDQGUSNRMNGSGQ-UHFFFAOYSA-N CC(C)C(C(C)(C)CO)O.N=C=O Chemical compound CC(C)C(C(C)(C)CO)O.N=C=O LDQGUSNRMNGSGQ-UHFFFAOYSA-N 0.000 abstract 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 abstract 1
- 239000004354 Hydroxyethyl cellulose Substances 0.000 abstract 1
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 abstract 1
- YJSNJJXORGMUNM-UHFFFAOYSA-N [F].FC(F)=C Chemical compound [F].FC(F)=C YJSNJJXORGMUNM-UHFFFAOYSA-N 0.000 abstract 1
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 abstract 1
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 abstract 1
- 229920002635 polyurethane Polymers 0.000 abstract 1
- 239000004814 polyurethane Substances 0.000 abstract 1
- 239000000377 silicon dioxide Substances 0.000 abstract 1
- 238000007711 solidification Methods 0.000 abstract 1
- 230000008023 solidification Effects 0.000 abstract 1
- 230000032683 aging Effects 0.000 description 3
- 238000011109 contamination Methods 0.000 description 3
- 125000001153 fluoro group Chemical group F* 0.000 description 3
- 238000005299 abrasion Methods 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 239000012752 auxiliary agent Substances 0.000 description 2
- 238000010276 construction Methods 0.000 description 2
- 238000006253 efflorescence Methods 0.000 description 2
- 230000014759 maintenance of location Effects 0.000 description 2
- 206010037844 rash Diseases 0.000 description 2
- 238000009736 wetting Methods 0.000 description 2
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 230000015271 coagulation Effects 0.000 description 1
- 238000005345 coagulation Methods 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000009418 renovation Methods 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 229920003002 synthetic resin Polymers 0.000 description 1
- 239000000057 synthetic resin Substances 0.000 description 1
- 239000008399 tap water Substances 0.000 description 1
- 235000020679 tap water Nutrition 0.000 description 1
Landscapes
- Paints Or Removers (AREA)
Abstract
The present invention relates to outer wall decorating fluorocarbon paint and a production method. The paint is composed of water vinylidene fluoride fluorine emulsion, hydroxyethyl cellulose, polysodium carbonate, alkylphenol polyoxyethylene, polyether modified dimethyl polysiloxane, 2-amino-2-methyl-1-propanol, titanium dioxide powder, talcum powder, kaoline, 2, 2, 4-trimethyl-1, 3-pentanediol monoisocyanate, polysodium acrylate, polyurethane modified polyether and gaseous silica powder which are heated, stirred and ground. The paint has the characteristics of environmental protection and normal temperature solidification. The coating film of the paint has the advantages of good weatherability, solvent resistance and stain resistance.
Description
Technical field
The present invention relates to a kind of decoration of exterior wall with fluorocarbon coating and manufacture method, be used for protection, the decoration of concrete structure exterior wall surface.
Technical background
Available coagulation soil skin coating adopts synthetic resin emulsion, adds that auxiliary agent and color stuffing are formulated, and its weak point is coating efflorescence easy to change, easy, and contamination resistance is poor, and weathering resistance is poor, and the artificial accelerated aging time only is individual hour of hundreds of.
Summary of the invention
The technical problem to be solved in the present invention: avoid above-mentioned weak point of the prior art and provide that a kind of manufacture method is easy, the decoration of exterior wall of good, the water-thinned Normal temperature of characteristics, its durability of coating with protection environment is with fluorocarbon coating and manufacture method.
The technical solution used in the present invention
Decoration of exterior wall fluorocarbon coating of the present invention, it is characterized in that vinylidene fluoride water-based fluorine emulsion by 1 weight part, 0.005 the Natvosol of weight part, 0.02 the poly carboxylic acid sodium of weight part, 0.002 the alkylphenol polyoxyethylene of weight part, be the two the deionized water of 3 times of weight parts of poly carboxylic acid sodium and alkylphenol polyoxyethylene, 0.002 the polyether-modified dimethyl polysiloxane of weight part, 0.002 2-amino-2-methyl-1-propanol, 0.01 the titanium dioxide of weight part, 0.06 the talcum powder of weight part, 0.02 the kaolin of weight part, 0.06 2 of weight part, 2,4-trimethylammonium-1, the 3-pentanediol mono isobutyrate, 0.01 the sodium polyacrylate of weight part, 0.001 the polyurethane-modified polyethers of weight part, 0.0005 the aerosil powder of weight part is formed, wherein the particle diameter of aerosil powder is 1～100nm.
The decoration of exterior wall that the adopts manufacture method of fluorocarbon coating, it is characterized in that by vinylidene fluoride water-based fluorine emulsion 1 weight part, deionized water dissolving with alkylphenol polyoxyethylene 3 times of weight parts of the two of the poly carboxylic acid sodium of 0.02 weight part and 0.002 weight part with it, the Natvosol that adds 0.005 weight part then therein, 0.002 the polyether-modified dimethyl polysiloxane of weight part, 0.002 the 2-amino-2-methyl-1-propanol of weight part, its temperature is controlled at 25 ℃, behind the high-speed stirring 0.5h, the aerosil powder that under condition of stirring, adds 0.0005 weight part, 0.01 the titanium dioxide of weight part, 0.06 the talcum powder of weight part, 0.02 the kaolin of weight part, grind 0.5～1h with sand mill then, add 2 of 0.06 weight part afterwards, 2,4-trimethylammonium-1, the vinylidene fluoride water-based fluorine emulsion of 3-pentanediol mono isobutyrate and 1 weight part adds the sodium polyacrylate of 0.01 weight part at last, 0.001 the polyurethane-modified polyethers of weight part is made the decoration of exterior wall fluorocarbon coating.
Decoration of exterior wall fluorocarbon coating of the present invention, the aerosil that is added a certain amount of auxiliary agent, a certain amount of color stuffing and surface process special processing by vinylidene fluoride water-based fluorine emulsion is formulated.In vinylidene fluoride water-based fluorine emulsion; the bond energy that is higher than C-H because of the bond energy of the C-F in its molecule; negative charge is more concentrated on the fluorine atom; electronic cloud gathers; make the accessible carbon atom of fluorine atom, hidden the C-C key, promptly fluorine atom has been protected the C-C key; durability of coating, solvent resistance, abrasion resistance are increased, particularly have excellent weather resistance.In addition, the coating that vinylidene fluoride water-based fluorine emulsion forms, its surface free energy is low, and it is wetting that its surface is difficult to, and therefore has good contamination resistance energy.The deionized water that uses is by the deionized water of tap water through the exchange of zwitterion exchange column.The polyether-modified dimethyl polysiloxane that uses helps to eliminate the bubble in the coating.The pH value that the 2-amino-2-methyl-1-propanol that uses helps to regulate coating improves dispersing of pigments efficient.The poly carboxylic acid sodium that uses can provide dispersed efficiently to color stuffing, makes dope viscosity stable.The alkylphenol polyoxyethylene of using can effective wetting color stuffing, and keeps the stability of coating.Sodium polyacrylate, the polyurethane-modified polyethers that uses helps to improve the thixotropy and the application property of coating, improves the stability in storage of coating.The aerosil that uses helps to improve the thixotropy and the application property of coating, improves the stability in storage of coating, and improves and film to the reflection potential of sunlight.
The present invention's beneficial effect compared with prior art
1, decoration of exterior wall fluorocarbon coating of the present invention has good environmental protection, the characteristics of ambient cure, and its coating has good weathering resistance, solvent resistance, contamination resistance, abrasion resistance, and its artificial accelerated aging test reaches 2000h.Can be used for protection, decoration and the renovation construction of concrete structure exterior wall surface, also can be used for the decoration construction of masonry type building outside surface.
2, the decoration of exterior wall of the present invention manufacture method of fluorocarbon coating, technology is simple, need not specific installation.
3, the decoration of exterior wall of the present invention ratio of performance to price height of fluorocarbon coating.
Embodiment 1
The decoration of exterior wall of the present invention manufacture method of fluorocarbon coating.In stainless charging basket, by vinylidene fluoride water-based fluorine emulsion 1 weight part, deionized water dissolving with alkylphenol polyoxyethylene 3 times of weight parts of the two of the poly carboxylic acid sodium of 0.02 weight part and 0.002 weight part with it, the Natvosol that adds 0.005 weight part then therein, 0.002 the polyether-modified dimethyl polysiloxane of weight part, 0.002 the 2-amino-2-methyl-1-propanol of weight part, its temperature is controlled at 25 ℃, behind the high-speed stirring 0.5h, the aerosil powder that under condition of stirring, adds 0.0005 weight part, 0.01 the titanium dioxide of weight part, 0.06 the talcum powder of weight part, 0.02 the kaolin of weight part, grind 0.5～1h with sand mill then, add 2 of 0.06 weight part afterwards, 2,4-trimethylammonium-1, the vinylidene fluoride water-based fluorine emulsion of 3-pentanediol mono isobutyrate and 1 weight part adds the sodium polyacrylate of 0.01 weight part at last, 0.001 the polyurethane-modified polyethers of weight part is made the decoration of exterior wall fluorocarbon coating.The raw materials used commercially available product that all adopts.
This coating has good environmental protection, the characteristics of normal temperature cure, and its coating is by manually adding The speed degradation shows that the gloss retention of 2000h is more than 80%; Acid resisting test soaks Steep the H in 10%2SO
4In the solution 7 days, it filmed intact. With being coated with of acrylic acid aqueous coating Film test is compared, and artificial accelerated aging test is 20% through the 500h gloss retention, and produces Efflorescence; Film through acid resisting test, impregnated in 10% H2SO
4In the solution 7 days, produce drum Bubble, flavescence.
Claims (2)
1. decoration of exterior wall fluorocarbon coating, it is characterized in that vinylidene fluoride water-based fluorine emulsion by 1 weight part, 0.005 the Natvosol of weight part, 0.02 the poly carboxylic acid sodium of weight part, 0.002 the alkylphenol polyoxyethylene of weight part, be the two the deionized water of 3 times of weight parts of poly carboxylic acid sodium and alkylphenol polyoxyethylene, 0.002 the polyether-modified dimethyl polysiloxane of weight part, 0.002 2-amino-2-methyl-1-propanol, 0.01 the titanium dioxide of weight part, 0.06 the talcum powder of weight part, 0.02 the kaolin of weight part, 0.06 2 of weight part, 2,4-trimethylammonium-1, the 3-pentanediol mono isobutyrate, 0.01 the sodium polyacrylate of weight part, 0.001 the polyurethane-modified polyethers of weight part, 0.0005 the aerosil powder of weight part is formed, wherein the particle diameter of aerosil powder is 1～100nm.
2. a decoration of exterior wall is with the manufacture method of fluorocarbon coating, it is characterized in that by vinylidene fluoride water-based fluorine emulsion 1 weight part, deionized water dissolving with alkylphenol polyoxyethylene 3 times of weight parts of the two of the poly carboxylic acid sodium of 0.02 weight part and 0.002 weight part with it, the Natvosol that adds 0.005 weight part then therein, 0.002 the polyether-modified dimethyl polysiloxane of weight part, 0.002 the 2-amino-2-methyl-1-propanol of weight part, its temperature is controlled at 25 ℃, behind the high-speed stirring 0.5h, the aerosil powder that under condition of stirring, adds 0.0005 weight part, 0.01 the titanium dioxide of weight part, 0.06 the talcum powder of weight part, 0.02 the kaolin of weight part, grind 0.5～1h with sand mill then, add 2 of 0.06 weight part afterwards, 2,4-trimethylammonium-1, the vinylidene fluoride water-based fluorine emulsion of 3-pentanediol mono isobutyrate and 1 weight part adds the sodium polyacrylate of 0.01 weight part at last, 0.001 the polyurethane-modified polyethers of weight part is made the decoration of exterior wall fluorocarbon coating.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB200410047914XA CN100376643C (en) | 2004-06-11 | 2004-06-11 | Outer wall decorating fluorocarbon paint and its production process |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB200410047914XA CN100376643C (en) | 2004-06-11 | 2004-06-11 | Outer wall decorating fluorocarbon paint and its production process |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1706897A CN1706897A (en) | 2005-12-14 |
| CN100376643C true CN100376643C (en) | 2008-03-26 |
Family
ID=35581016
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB200410047914XA Expired - Fee Related CN100376643C (en) | 2004-06-11 | 2004-06-11 | Outer wall decorating fluorocarbon paint and its production process |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN100376643C (en) |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN100393826C (en) * | 2006-06-01 | 2008-06-11 | 江苏兰陵化工集团有限公司 | Water fluorine carbon emulsion paint and preparation process thereof |
| CN102358821B (en) * | 2011-06-28 | 2013-01-02 | 厦门固克涂料集团有限公司 | Fluorine-silicon multi-color stone-like coat system |
| CN102952436A (en) * | 2012-11-29 | 2013-03-06 | 益阳祥瑞科技有限公司 | Water-based white fluorocarbon coating |
| CN109054529A (en) * | 2018-07-24 | 2018-12-21 | 珠海市氟特科技有限公司 | A kind of waterborne normal-temperature is from melt type PVDF fluorocarbon coating and preparation method thereof |
| CN115491094B (en) * | 2022-10-26 | 2023-05-09 | 浙江鱼童新材料股份有限公司 | A kind of normal temperature curing fluorocarbon coating and preparation method thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH10237253A (en) * | 1997-02-21 | 1998-09-08 | Asahi Glass Co Ltd | Fluoro rubber composition |
| EP1026200A1 (en) * | 1997-10-24 | 2000-08-09 | Daikin Industries, Ltd. | Aqueous fluoropolymer dispersion composition |
| US6517940B1 (en) * | 2000-05-02 | 2003-02-11 | Ppg Industries Ohio, Inc. | Exterior-durable multi-layer composite coating compositions |
| CN1401713A (en) * | 2002-09-05 | 2003-03-12 | 上海一宁建筑材料有限公司 | Water fluorine-carbon nanapaint and producing process thereof |
-
2004
- 2004-06-11 CN CNB200410047914XA patent/CN100376643C/en not_active Expired - Fee Related
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH10237253A (en) * | 1997-02-21 | 1998-09-08 | Asahi Glass Co Ltd | Fluoro rubber composition |
| EP1026200A1 (en) * | 1997-10-24 | 2000-08-09 | Daikin Industries, Ltd. | Aqueous fluoropolymer dispersion composition |
| US6517940B1 (en) * | 2000-05-02 | 2003-02-11 | Ppg Industries Ohio, Inc. | Exterior-durable multi-layer composite coating compositions |
| CN1401713A (en) * | 2002-09-05 | 2003-03-12 | 上海一宁建筑材料有限公司 | Water fluorine-carbon nanapaint and producing process thereof |
Non-Patent Citations (1)
| Title |
|---|
| 氟树脂涂料及其应用. 周立新，程江，杨卓如.合成材料老化与应用，第32卷第3期. 2003 * |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1706897A (en) | 2005-12-14 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN102585626B (en) | Water-based fluorocarbon heat insulation coating and preparation method | |
| CN103102792B (en) | Aqueous double-component polyurethane low luster coating and preparation method thereof | |
| CN101108931B (en) | Aquosity elastic heat preserving insulating paint and its preparing process | |
| CN103319971B (en) | A kind of metallic travel aqueous fluorocarbon coating and preparation method thereof for exterior wall | |
| CN110183923A (en) | A kind of colorful water-water coating and preparation method thereof | |
| CN102850878A (en) | Weather-resistant exterior wall paint and preparation method thereof | |
| CN101104659A (en) | Preparation method of soap-free fluorine-containing polyacrylate core-shell emulsion with crosslinked network structure | |
| CN107325663A (en) | Architectural reflective heat-insulation paint and preparation method thereof | |
| CN102863892B (en) | Water-base polyurethane coating for fan blades and preparation method thereof | |
| CN102876143A (en) | Marble paint and preparation method thereof | |
| CN101845254B (en) | Elastic aqueous fluorocarbon paint for external walls | |
| CN110713760A (en) | Water-based acrylic floor paint and preparation method thereof | |
| CN103614063B (en) | A kind of clear aqueous waterproof paint for building and preparation method thereof | |
| CN103666130A (en) | Preparation method of full water-borne fluorocarbon acid-resistant texture coating | |
| CN100376643C (en) | Outer wall decorating fluorocarbon paint and its production process | |
| CN112680014B (en) | Reflective heat insulation sand-in-water coating and preparation method thereof | |
| CN102676009B (en) | Anionic ecological multicolour paint and preparation method thereof | |
| CN102850861A (en) | Brick paint and preparation method thereof | |
| CN107828323B (en) | Metal-like coating for building exterior wall and preparation method thereof | |
| CN106085036A (en) | A kind of exterior wall functional paint | |
| CN103614017B (en) | A kind of waterproof paint containing rosin | |
| CN101633812A (en) | Flexible texture coating and preparation method thereof | |
| CN107641397A (en) | A kind of fade-proof coating and preparation method thereof | |
| CN103897109A (en) | Acrylic modified polysiloxane resin and paint containing same | |
| CN101864235B (en) | Method for preparing exterior wall coating |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20080326 |
|
| CF01 | Termination of patent right due to non-payment of annual fee |