The helium hydride ion, HeH, is the simplest heteronuclear diatomic, and is composed of the two m... more The helium hydride ion, HeH, is the simplest heteronuclear diatomic, and is composed of the two most abundant elements in the universe. It is widely believed that this ion was among the first molecules to be formed; thus it has been of great interest to scientists studying the chemistry of the early universe.ab HeH is also isoelectronic to H2 which makes it a great target ion for theorists to include adiabatic and non-adiabatic corrections to its Born-Oppenheimer potential energy surface. The accuracy of such calculations is further improved by incorporating electron relativistic and quantum electrodynamic effects.c
The hydrohelium cation, HeH(+), serves as an important benchmark for ab initio calculations that ... more The hydrohelium cation, HeH(+), serves as an important benchmark for ab initio calculations that take into account non-adiabatic, relativistic, and quantum electrodynamic effects. Such calculations are capable of predicting molecular transitions to an accuracy of ~300 MHz or less. However, in order to continue to push the boundaries on these calculations, new measurements of these transitions are required. Here we measure seven rovibrational transitions in the fundamental vibrational band to a precision of ~1 MHz using the technique of Noise Immune Cavity Enhanced Optical Heterodyne Velocity Modulation Spectroscopy. These newly measured transitions are included in a fit to the rotation-vibration term values to derive refined spectroscopic constants in the v = 0 and v = 1 vibrational states, as well as to calculate rotation-vibration energy levels with high precision.
The helium hydride ion, HeH, is the simplest heteronuclear diatomic, and is composed of the two m... more The helium hydride ion, HeH, is the simplest heteronuclear diatomic, and is composed of the two most abundant elements in the universe. It is widely believed that this ion was among the first molecules to be formed; thus it has been of great interest to scientists studying the chemistry of the early universe.ab HeH is also isoelectronic to H2 which makes it a great target ion for theorists to include adiabatic and non-adiabatic corrections to its Born-Oppenheimer potential energy surface. The accuracy of such calculations is further improved by incorporating electron relativistic and quantum electrodynamic effects.c
The hydrohelium cation, HeH(+), serves as an important benchmark for ab initio calculations that ... more The hydrohelium cation, HeH(+), serves as an important benchmark for ab initio calculations that take into account non-adiabatic, relativistic, and quantum electrodynamic effects. Such calculations are capable of predicting molecular transitions to an accuracy of ~300 MHz or less. However, in order to continue to push the boundaries on these calculations, new measurements of these transitions are required. Here we measure seven rovibrational transitions in the fundamental vibrational band to a precision of ~1 MHz using the technique of Noise Immune Cavity Enhanced Optical Heterodyne Velocity Modulation Spectroscopy. These newly measured transitions are included in a fit to the rotation-vibration term values to derive refined spectroscopic constants in the v = 0 and v = 1 vibrational states, as well as to calculate rotation-vibration energy levels with high precision.
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